CN1263954A - High-speed spinning oil for terylene fibres and its preparing process - Google Patents
High-speed spinning oil for terylene fibres and its preparing process Download PDFInfo
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- CN1263954A CN1263954A CN 99124724 CN99124724A CN1263954A CN 1263954 A CN1263954 A CN 1263954A CN 99124724 CN99124724 CN 99124724 CN 99124724 A CN99124724 A CN 99124724A CN 1263954 A CN1263954 A CN 1263954A
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- polyoxyethylene ether
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Abstract
An FDY oil for high-speed spinning of terylene fibres is prepared from smoothing agent (55-65 wt.%), emulsifier (17-27), tow-collecting agent (5-15), antistatic agent (2-8) and additive (1-5) through pumping emulsifier, tow-collecting agent and antistatic agent into reactor, heating to 40-80 deg.C, uniform stirring, pumping smoothing agent in reactor, stirring for 30-50 min, adding additive, uniform stirring, cooling and filtering. It can improve the quality of spining terylene fibres.
Description
The present invention relates to a kind of high-speed spinning oil for terylene fibres and manufacture method thereof, belong to the processing technique field of synthetic fiber.
As everyone knows, because synthetic fiber do not have surface of natural fibers that special adhesiveness is arranged like that, therefore, in order to guarantee that synthetic fiber carry out spinning under certain condition smoothly, improve the quality of fibre property and silk, and improve the value of fibre, in spinning process, must use finish.Existing synthetic fiber finish because it constitutes the difference of component, is prone to lousiness, broken end phenomenon in the spinning application process, cause coiling and molding poor, and the high-class product rate is low, and corrosion phenomenon is serious, is difficult to adapt to the user demand of high speed PET spinning.
The purpose of this invention is to provide a kind of stable performance, good spinnability can satisfy the requirement of polyster fibre high-speed spinning process, effectively improves the high-speed spinning oil for terylene fibres and the manufacture method thereof of terylene spinning quality.
The present invention is a high-speed spinning oil for terylene fibres, mainly by smooth agent, and emulsifying agent, collecting agent, antistatic additive, compositions such as additive is characterized in that the percentage by weight of each component is: smooth agent 55～65%, emulsifying agent 17～27%, collecting agent 5～15%, antistatic additive 2-8%, additive 1～5%.
Described smooth agent can be mineral oil, double base alcohol ester, triol ester, polybutene class, the mixture of one or more in the end capped polyether.The effect of smooth agent can keep between fiber and the fiber, the suitable coefficient of friction between fiber and other contact components, increases embracing and power of fiber, helps carrying out smoothly of spin-drawing.
Described emulsifying agent can be castor oil polyoxyethylene ether, lauryl alcohol polyoxyethylene ether, polyoxyethylene nonylphenol ether, laurate polyoxyethylene ether, the mixture of one or more in the butanols high-molecular weight atactic polyethers.The effect of emulsifying agent is that with the various components in the finish, particularly emulsified object smooth agent reaches balance by physical and chemical process, makes finish become even, transparent, stable oily solution in use.
Described collecting agent can be the polyethylene glycol Glycol Oleic Acid Ester, the laurate polyoxyethylene ether, polyethylene glycol laurate dibasic acid esters, castor oil polyoxyethylene ether, the mixture of one or more in the octanol high-molecular weight atactic polyethers, the adding of collecting agent can improve the convergence and the flatness of finish, makes fiber not fluffy, at random in process, and fiber is played the obvolvent effect.
Described antistatic additive can be lauryl alcohol phosphate polyoxyethylene ether sylvite, hexadecanol phosphate kalium salt, octadecanol phosphate kalium salt, lauryl alcohol polyoxyethylene ether phosphate sylvite, one or more mixtures in the amphoteric phosphate ammonium salt.The effect of antistatic additive is can be adsorbed on fiber surface in the high speed spinning process, increases the hygroscopicity of fiber, improves electric conductivity, reduces the accumulation of static.
Described additive can be silicone oil, modified organic silicon, higher alcohol, the mixture of one or more in the higher acid.The adding of additive can guarantee the use and the bin stability of finish, reduces the finish surface tension, improves stability of emulsion.
The manufacture method that high speed PET of the present invention is spun the FDY finish can be: the percentage by weight of pressing each component, elder generation is with emulsifying agent, collecting agent, the antistatic additive suction reactor of accurate measurement, being heated to 40-80 ℃ stirs, again with in the smooth agent suction reactor, after stirring 30-50min, add additive, the back cooling stirs, filter packing.
The present invention compared with prior art has following distinguishing feature and good effect:
1, the finish emulsion particle is thin, and stable and easily preparation does not have obvious corruption.
2, be used for the high speed PET spinning technique, good spinnability, no abnormal broken end can obviously improve the high-class product rate under same process conditions.
3, even dyeing, finish good heat resistance, no obvious smoke; Convergence is good, and coiling and molding is good, and the fiber oil-containing is even, steady quality.
High speed PET of the present invention is spun the FDY finish and is applicable to FDY technical method of spinning and pulling one-step production line, meeting FDY measuring pump transferring oil chews and oils and the food tray dual mode that oils, can satisfy FDY hot-rolling draft process, use through the Duo Jia chemical fibre factory, spinning, the production that stretches run well, and the fiber quality index reaches customer requirements.
Below in conjunction with embodiment the present invention is further described:
By weight percentage, determine the ratio of each component:
Embodiment 1:
Emulsifying agent 22%, wherein castor oil polyoxyethylene ether (EL class) 11%, polyoxyethylene nonylphenol ether (TX class) 11%;
Collecting agent 10%, wherein laurate polyoxyethylene ether (LAE-9 class) 2%, octanol high-molecular weight atactic polyethers 8%;
Antistatic additive 5%, wherein hexadecanol phosphate kalium salt (PK class) 2%, amphoteric phosphate ammonium salt 3%;
Smooth agent 60% is end capped polyether;
Additive 3% is silicone oil.
Embodiment 2:
Emulsifying agent 24%, lauryl alcohol polyoxyethylene ether (MOA class) 8% wherein, butanols high-molecular weight atactic polyethers 7%, polyoxyethylene nonylphenol ether (TX class) 9%;
Collecting agent 12%, wherein the polyethylene glycol Glycol Oleic Acid Ester 5%, castor oil polyoxyethylene ether (EL class) 7%;
Antistatic additive 5%, lauryl alcohol phosphate polyoxyethylene ether sylvite (EP class) 1% wherein, lauryl alcohol polyoxyethylene phosphate sylvite (MPK class) 4%;
Smooth agent 56%, wherein triol ester 20%, end capped polyether 20%, mineral oil 16%;
Additive 3%, wherein modified organic silicon 2%, higher acid 1%.
Embodiment 3:
Emulsifying agent 20%, butanols high-molecular weight atactic polyethers 4% wherein, polyoxyethylene nonylphenol ether (TX class) 10%, castor oil polyoxyethylene ether (EL class) 6%;
Collecting agent 9%, polyethylene glycol laurate dibasic acid esters 5% wherein, laurate polyoxyethylene ether (LAE-9 class) 4%;
Antistatic additive 7%, octadecanol phosphate kalium salt (PK class) 4% wherein, lauryl alcohol polyoxyethylene ether phosphate sylvite 3%;
Smooth agent 61%, wherein binary alcohol esters 30%, end capped polyether 15%, polybutene class 16%;
Additive 3%, wherein higher alcohol 1%, modified organic silicon 2%.
After the described ratio batching of above-mentioned three embodiment, the manufacture method that its high speed PET is spun the FDY finish is:
With emulsifying agent, collecting agent, antistatic additive suction reactor, open and stir, be warming up to about 50 ℃, stir, again with smooth agent suction reactor, keep temperature to stir 30min for about 50 ℃, add additive at last, stir 15min, stir and finish, be cooled to about 40 ℃, blowing, filtration, packing are promptly.
The high speed PET of producing according to proportioning of the present invention and manufacture method is spun the FDY finish and can be reached following quality index:
1, the faint yellow transparent oily liquid of outward appearance (25 ℃)
2, pH value (10% aqueous solution, 20 ℃) 6.0-8.0
3, effective component content (%, 〉=) 90.0
4, kinematic viscosity (50 ± 0.1 ℃, m
2/ s) (2.7～3.5) * 10
-5
5, water-soluble 10% emulsion blue ribbon fluorescence is transparent
Claims (7)
1, a kind of high speed PET is spun the FDY finish, mainly by smooth agent, and emulsifying agent, collecting agent, antistatic additive, additive is formed, and it is characterized in that the percentage by weight of each component is: smooth agent 55-65%, emulsifying agent 17-27%, collecting agent 5-15%, antistatic additive 2-8%, additive 1-5%.
2, spin the FDY finish by the described high speed PET of claim 1, it is characterized in that described smooth agent can be mineral oil, double base alcohol ester, triol ester, polybutene class, the mixture of one or more in the end capped polyether.
3, spin the FDY finish by the described high speed PET of claim 1, it is characterized in that described emulsifying agent can be castor oil polyoxyethylene ether, the lauryl alcohol polyoxyethylene ether, polyoxyethylene nonylphenol ether, the laurate polyoxyethylene ether, the mixture of one or more in the butanols high-molecular weight atactic polyethers.
4, spin the FDY finish by the described high speed PET of claim 1, it is characterized in that described collecting agent can be the polyethylene glycol Glycol Oleic Acid Ester, the laurate polyoxyethylene ether, polyethylene glycol laurate dibasic acid esters, castor oil polyoxyethylene ether, the mixture of one or more in the octanol high-molecular weight atactic polyethers.
5, spin the FDY finish by the described high speed PET of claim 1, it is characterized in that described antistatic additive can be lauryl alcohol phosphate polyoxyethylene ether sylvite, the hexadecanol phosphate kalium salt, the octadecanol phosphate kalium salt, lauryl alcohol polyoxyethylene ether phosphate sylvite, one or more mixtures in the amphoteric phosphate ammonium salt.
6, spin the FDY finish by the described high speed PET of claim 1, it is characterized in that described additive can be silicone oil, modified organic silicon, higher alcohol, the mixture of one or more in the higher acid.
7, by claim 1 or 2,8,4,5,6 described high speed PET are spun the manufacture method of FDY finish, it is characterized in that percentage by weight, with emulsifying agent, collecting agent, the antistatic additive suction reactor of accurate measurement, be heated to 40-80 ℃ and stir earlier by each component, again with in the smooth agent suction reactor, after stirring 30-50min, add additive, back cooling, filtration, packing stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99124724 CN1079451C (en) | 1999-11-26 | 1999-11-26 | High-speed spinning oil for terylene fibres and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99124724 CN1079451C (en) | 1999-11-26 | 1999-11-26 | High-speed spinning oil for terylene fibres and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1263954A true CN1263954A (en) | 2000-08-23 |
| CN1079451C CN1079451C (en) | 2002-02-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99124724 Expired - Fee Related CN1079451C (en) | 1999-11-26 | 1999-11-26 | High-speed spinning oil for terylene fibres and its preparing process |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100422065C (en) * | 2003-03-31 | 2008-10-01 | 村田机械株式会社 | Dressing agent supply device for synthetic yarn winding device |
| CN102115978A (en) * | 2011-01-06 | 2011-07-06 | 吴江市良燕纺织助剂厂 | PET (polyester) high-speed spinning finish oil |
| CN102587142A (en) * | 2012-01-17 | 2012-07-18 | 浙江义乌金汇化纤有限公司 | Spinning oil used for easily-dyed terylene BCF (bromochlorodifluoromethane) carpet yarn |
| CN102817115A (en) * | 2012-08-01 | 2012-12-12 | 太仓市璜泾飞达制衣厂 | Terylene staple fiber oil agent |
| CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN102978934A (en) * | 2012-11-28 | 2013-03-20 | 浙江天圣控股集团有限公司 | Low-smoke FDY (Fully Drawn Yarn) oiling agent and preparation method thereof |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN103397519A (en) * | 2013-07-03 | 2013-11-20 | 江苏华西村股份有限公司特种化纤厂 | Method for producing polyester staple fiber special for high-cleanness nonwoven spunlace |
| CN103603203A (en) * | 2013-12-02 | 2014-02-26 | 天津工业大学 | Terylene POY oiling agent and preparation method thereof |
| CN104562303A (en) * | 2015-01-20 | 2015-04-29 | 南通恒润化工有限公司 | Industrial spinning oil agent for FDY chinlon 66 and preparation method thereof |
| CN104975494A (en) * | 2015-08-07 | 2015-10-14 | 太仓市隆纺油剂有限公司 | Chinlon DTY oiling agent with efficient permeability and splashing prevention property and preparation method of oiling agent |
| CN106436296A (en) * | 2016-07-05 | 2017-02-22 | 吴江市良燕纺织助剂厂 | Oil agent for spinning dacron |
| CN109722744A (en) * | 2018-12-21 | 2019-05-07 | 中芳特纤股份有限公司 | A kind of p-aramid fiber finish |
| CN116556056A (en) * | 2023-01-18 | 2023-08-08 | 浙江恒翔新材料有限公司 | Polyester POY (polyester pre-oriented yarn) oiling agent and preparation method thereof |
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| CN100385061C (en) * | 2005-01-26 | 2008-04-30 | 上海巨人高科技新型材料有限公司 | Nanometer polyester fiber FDY spinning oil prepn and its prepn process |
-
1999
- 1999-11-26 CN CN 99124724 patent/CN1079451C/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100422065C (en) * | 2003-03-31 | 2008-10-01 | 村田机械株式会社 | Dressing agent supply device for synthetic yarn winding device |
| CN102115978A (en) * | 2011-01-06 | 2011-07-06 | 吴江市良燕纺织助剂厂 | PET (polyester) high-speed spinning finish oil |
| CN102115978B (en) * | 2011-01-06 | 2014-01-08 | 吴江市良燕纺织助剂厂 | PET (polyester) high-speed spinning finish oil |
| CN102587142A (en) * | 2012-01-17 | 2012-07-18 | 浙江义乌金汇化纤有限公司 | Spinning oil used for easily-dyed terylene BCF (bromochlorodifluoromethane) carpet yarn |
| CN102587142B (en) * | 2012-01-17 | 2013-12-04 | 浙江义乌金汇化纤有限公司 | Spinning oil used for easily-dyed terylene BCF (bromochlorodifluoromethane) carpet yarn |
| CN102817115A (en) * | 2012-08-01 | 2012-12-12 | 太仓市璜泾飞达制衣厂 | Terylene staple fiber oil agent |
| CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN102912640B (en) * | 2012-10-25 | 2014-06-25 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN102978934B (en) * | 2012-11-28 | 2014-12-31 | 浙江天圣控股集团有限公司 | Low-smoke FDY (Fully Drawn Yarn) oiling agent and preparation method thereof |
| CN102978934A (en) * | 2012-11-28 | 2013-03-20 | 浙江天圣控股集团有限公司 | Low-smoke FDY (Fully Drawn Yarn) oiling agent and preparation method thereof |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN103147168B (en) * | 2013-03-06 | 2017-06-16 | 常州市灵达化学品有限公司 | A kind of spinning oil and preparation method |
| CN103397519B (en) * | 2013-07-03 | 2016-01-20 | 江苏华西村股份有限公司特种化纤厂 | High clean spunlace non-woven cloth special polyester staple fiber production method |
| CN103397519A (en) * | 2013-07-03 | 2013-11-20 | 江苏华西村股份有限公司特种化纤厂 | Method for producing polyester staple fiber special for high-cleanness nonwoven spunlace |
| CN103603203A (en) * | 2013-12-02 | 2014-02-26 | 天津工业大学 | Terylene POY oiling agent and preparation method thereof |
| CN104562303A (en) * | 2015-01-20 | 2015-04-29 | 南通恒润化工有限公司 | Industrial spinning oil agent for FDY chinlon 66 and preparation method thereof |
| CN104562303B (en) * | 2015-01-20 | 2018-04-13 | 南通恒润新材料科技有限公司 | 66 industrial spinning finish of FDY polyamide fibres and preparation method thereof |
| CN104975494A (en) * | 2015-08-07 | 2015-10-14 | 太仓市隆纺油剂有限公司 | Chinlon DTY oiling agent with efficient permeability and splashing prevention property and preparation method of oiling agent |
| CN106436296A (en) * | 2016-07-05 | 2017-02-22 | 吴江市良燕纺织助剂厂 | Oil agent for spinning dacron |
| CN109722744A (en) * | 2018-12-21 | 2019-05-07 | 中芳特纤股份有限公司 | A kind of p-aramid fiber finish |
| CN109722744B (en) * | 2018-12-21 | 2021-07-09 | 中芳特纤股份有限公司 | Para-aramid oiling agent |
| CN116556056A (en) * | 2023-01-18 | 2023-08-08 | 浙江恒翔新材料有限公司 | Polyester POY (polyester pre-oriented yarn) oiling agent and preparation method thereof |
| CN116556056B (en) * | 2023-01-18 | 2024-04-26 | 浙江恒翔新材料有限公司 | Polyester POY (polyester pre-oriented yarn) oiling agent and preparation method thereof |
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| CN1079451C (en) | 2002-02-20 |
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