CN108505342A - It is a kind of continuously to spin viscose filament yarn finish and its preparation method and application - Google Patents
It is a kind of continuously to spin viscose filament yarn finish and its preparation method and application Download PDFInfo
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- CN108505342A CN108505342A CN201810421051.XA CN201810421051A CN108505342A CN 108505342 A CN108505342 A CN 108505342A CN 201810421051 A CN201810421051 A CN 201810421051A CN 108505342 A CN108505342 A CN 108505342A
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- filament yarn
- viscose filament
- finish
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- spinning
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of continuous spinning viscose filament yarn finishes and its preparation method and application.Finish each component is by mass percentage:Cithrol 36~40%, fatty alcohol polyoxyethylene ether aliphatic ester 11~15%;Polyether-modified Polysiloxane Phosphate sodium salt 6~10%, deionized water 35~39%.Oil performance obtained by the present invention is excellent, it is soluble easily in water, biodegradable, easily move back oil, and viscose filament yarn cohesive force can be improved, reduce frictional coefficient of fiber, fully inhibited, eliminate electrostatic and generate and accumulation, ensure the excellent process passability of weaving process.
Description
Technical field
The present invention relates to chemical industry finish fields, more particularly to a kind of continuous spinning viscose filament yarn finish.
Background technology
Viscose rayon category regenerated celulose fibre.It is using native cellulose as raw material, through works such as alkalization, aging, sulfonation
Soluble cellulose sulphonic acid ester made of sequence, is re-dissolved in sig water and viscose glue is made, and is made through wet spinning.It is divided into as viscose glue
Long filament and short rayon fiber.
Viscose filament yarn spinning technique is divided into continuous spin and semicontinuous spinning.Continuous spinning process is a kind of relatively advanced production
Technology substantially increases production efficiency compared with semicontinuous spinning technique, but its spun parallel silk no twist, cohesive force
Difference, therefore fibre cohesion need to be increased by finish.And in fiber process, because of fiber and fiber, fiber and machine
Between friction produce electrostatic, and fiber insulating properties itself is very strong, and electrostatic charge is difficult to loss.The presence of electrostatic, in spinning
Tow can be caused to dissipate, it is difficult to wind, generate lousiness, fracture of wire.During follow-up high speed is weaved, antistatic property is insufficient, can make
At fracture of wire, the passability of weaving various processes is reduced.Textile made of fiber is also because of the effect of electrostatic, easy dust suction and flaw
It is dirty.Thus, the antistatic property for increasing fiber is extremely important.
The continuous viscose filament finish antistatic property that spins is unable to fully meet weaving speed high speed both at home and abroad at present
Demand becomes a big problem.
Invention content
Present invention aims to overcome that above-mentioned deficiency, provides a kind of antistatic property height, can fully meet continuous spunbond glue
The finish of continuous yarn spinning and textile technology.
The purpose of the present invention is achieved through the following technical solutions:A kind of continuous spinning viscose filament yarn finish, by quality percentage
Become than group:
Preferably, the cithrol structural formula is RCOO (CH2CH2O)nH, wherein R are C11~C17Alkane
Base, n are 13~100.
Preferably, the fatty alcohol polyoxyethylene ether fatty acid ester structure formula is R1O(CH2CH2O)nCOR2, wherein R1For C12
~C18Alkyl, R2For C1~C6Alkyl, n be 20~40.
Preferably, the Polyether-modified Polysiloxane Phosphate sodium salt structural formula is:
Wherein m=1~5;N=30~40;
X=1~5, y=0~5, z=1~5.
Preferably, the deionized water conductivity is less than 10 μ S/cm.
The above-mentioned continuous preparation method for spinning viscose filament yarn finish, includes the following steps:By above-mentioned mass percent
Stock, is warming up to 40~50 DEG C by deionized water, sequentially adds cithrol, fatty alcohol polyoxyethylene ether aliphatic acid
Ester and Polyether-modified Polysiloxane Phosphate sodium salt are mixed 40~60 minutes, obtain continuously spinning viscose filament yarn finish.
Application of the above-mentioned finish in continuous viscose filament spinning technique.By above-mentioned continuous spinning viscose filament yarn finish
It is added in slurry and prepares slurries, adjusting concentration of slurry is 10-100g/L, is continuously spun for viscose filament yarn by the way of spray
Silk sizing process.Make above-mentioned finish on the amount attachment viscose filament yarn of 0.3~1.5 weight %.
The beneficial effects of the invention are as follows:Continuous spinning viscose filament yarn oil performance prepared by the present invention is excellent, introduces one
Kind Polyether-modified Polysiloxane Phosphate salt is as antistatic agent.Since it is provided simultaneously with polyether segment and polysiloxanes segment, because
This its it is excellent with good hydrophily, antistatic property, heat resistance, lower temperature resistance, lubricity and physiological inertia, low surface tension etc.
Point.Acted synergistically by each component, can make finish quickly, uniformly spread over fiber surface, form one layer of oil film, assign fine
Tie up smooth surface and soft feeling, the low-fiber friction coefficient of drop;Due to antistatic agent the surface of fiber formed one it is hydrophilic
Adsorbed film is conducive to the timely loss of charge.Oil performance obtained by the present invention is excellent, soluble easily in water, biodegradable, easy
Oil is moved back, and viscose filament yarn cohesive force can be improved, reduces frictional coefficient of fiber, fully inhibits, eliminate electrostatic generation and accumulation, protect
The excellent process passability of card weaving process.
Finish prepared by the present invention can form one layer in continuous viscose filament spinning technique on viscose filament yarn surface
Oil film that is even, having some strength has the effects that lubrication, boundling, antistatic, and then improves viscose filament yarn surface property, reduces
Frictional coefficient of fiber improves fibre cohesion, inhibits and eliminate accumulation of static electricity, reduces lousiness, broken end, improves spinning efficiency.
Specific implementation mode
The present invention is described further with reference to specific embodiment
Embodiment 1
(1) raw material
By weight percentage, it is deionization, 40% cithrol, 15% fat of 5 μ S/cm by 35% conductivity
Fat alcohol polyoxyethylene ether fatty ester and 10% Polyether-modified Polysiloxane Phosphate sodium salt are made.Wherein,
Cithrol:It is poly- second two prepared by the lauric acid for being 12 by the Macrogol 600 and carbon number of n=14
Alcohol laurate.
Fatty alcohol polyoxyethylene ether aliphatic ester:Be by carbon number be 12 laruyl alcohol and n=20 polyoxyethylene ether and carbon number
For the ethoxylated dodecyl alcohol n-butyric acie ester of 4 n-butyric acie preparation.
Polyether-modified Polysiloxane Phosphate sodium salt:It is m=1, n=30, x=5, the polyether modified siloxane of y=0, z=2
Phosphoric acid ester sodium.
(2) preparation method
Deionized water is warming up to 50 DEG C, sequentially adds polyethylene glycol laurate, ethoxylated dodecyl alcohol n-butyric acie
Ester, Polyether-modified Polysiloxane Phosphate sodium salt are mixed 50 minutes, obtain continuously spinning viscose filament yarn finish.
Embodiment 2
(1) raw material
By weight percentage, it is deionization, 38% cithrol, 15% fat of 5 μ S/cm by 37% conductivity
Fat alcohol polyoxyethylene ether fatty ester and 10% Polyether-modified Polysiloxane Phosphate sodium salt are made.Wherein,
Cithrol:It is poly- second two prepared by the stearic acid for being 16 by the Macrogol 600 and carbon number of n=14
Alcohol stearate.
Fatty alcohol polyoxyethylene ether aliphatic ester:Be by carbon number be 18 octadecyl alcolol and n=23 polyoxyethylene ether and carbon number
For the polyoxyethylene octadecanol n-butyric acie ester of 4 n-butyric acie preparation.
Polyether-modified Polysiloxane Phosphate sodium salt:It is m=1, n=34, x=5, the polyether modified siloxane of y=3, z=3
Phosphoric acid ester sodium.
(2) preparation method
Deionized water is warming up to 50 DEG C, sequentially adds polyethylene glycol stearate, polyoxyethylene octadecanol n-butyric acie
Ester, Polyether-modified Polysiloxane Phosphate sodium salt are mixed 50 minutes, obtain continuously spinning viscose filament yarn finish.
Embodiment 3
(1) raw material
By weight percentage, it is deionization, 40% cithrol, 15% fat of 5 μ S/cm by 39% conductivity
Fat alcohol polyoxyethylene ether fatty ester and 6% Polyether-modified Polysiloxane Phosphate sodium salt are made.Wherein,
Cithrol:It is poly- second prepared by the lauric acid for being 12 by the Macrogol 4000 and carbon number of n=91
Glycol laurate.
Fatty alcohol polyoxyethylene ether aliphatic ester:Be by carbon number be 12 laruyl alcohol and n=23 polyoxyethylene ether and carbon number
For the ethoxylated dodecyl alcohol n-caproate of 6 n-caproic acid preparation.
Polyether-modified Polysiloxane Phosphate sodium salt:It is m=2, n=30, x=3, the polyether modified siloxane of y=3, z=3
Phosphoric acid ester sodium.
(2) preparation method
Deionized water is warming up to 50 DEG C, sequentially adds polyethylene glycol laurate, ethoxylated dodecyl alcohol n-caproic acid
Ester, Polyether-modified Polysiloxane Phosphate sodium salt are mixed 50 minutes, obtain continuously spinning viscose filament yarn finish.
Embodiment 4
(1) raw material
By weight percentage, it is deionization, 40% cithrol, 13% fat of 5 μ S/cm by 39% conductivity
Fat alcohol polyoxyethylene ether fatty ester and 8% Polyether-modified Polysiloxane Phosphate sodium salt are made.Wherein,
Cithrol:It is poly- second prepared by the stearic acid for being 16 by the Macrogol 4000 and carbon number of n=91
Glycol stearate.
Fatty alcohol polyoxyethylene ether aliphatic ester:Be by carbon number be 16 hexadecanol and n=30 polyoxyethylene ether and carbon number
For the hexadecanol polyoxyethylene ether n-caproate of 6 n-caproic acid preparation.
Polyether-modified Polysiloxane Phosphate sodium salt:It is m=1, n=40, x=3, the polyether modified siloxane of y=1, z=5
Phosphoric acid ester sodium.
(2) preparation method
Deionized water is warming up to 50 DEG C, sequentially adds 16 polyoxyethylene ether n-caproate of polyethylene glycol stearate,
Polyether-modified Polysiloxane Phosphate sodium salt is mixed 50 minutes, obtains continuously spinning viscose filament yarn finish.
Embodiment 5 is applied
The continuous spinning viscose filament yarn finish that Examples 1 to 4 is prepared is mixed with slurry, is configured to a concentration of 48g/L's
Starching working solution carries out spinning starching on viscose filament continuous spinning machine.Finish and application performance index of the present invention such as 1 institute of table
Show.
1 finish of the present invention of table and application performance index
Note:F/F:Fiber and fiber;F/M:Fiber and metal
Continuous spinning viscose filament yarn finish using the present invention, in spinning process, strand passability is good, fiber softening
Smooth, feel is good.It can fully inhibit in continuous spunbond glue continuous yarn spinning, weaving, eliminate electrostatic generation, accumulation, each
Excellent process passability can be assigned in a process.
Claims (9)
1. a kind of continuous spinning viscose filament yarn finish, which is characterized in that group becomes by mass percentage:
2. continuous spinning viscose filament yarn finish according to claim 1, which is characterized in that the cithrol
Structural formula is RCOO (CH2CH2O)nH, wherein R are C11~C17Alkyl, n be 13~100.
3. continuous spinning viscose filament yarn finish according to claim 1, which is characterized in that the fatty alcohol polyoxyethylene ether
Fatty acid ester structure formula is R1O(CH2CH2O)nCOR2, wherein R1For C12~C18Alkyl, R2For C1~C6Alkyl, n be 20~
40。
4. continuous spinning viscose filament yarn finish according to claim 1, which is characterized in that the polyether modified siloxane phosphorus
Sodium salt structural formula is:
Wherein m=1~5;N=30~40;
X=1~5, y=0~5, z=1~5.
5. continuous spinning viscose filament yarn finish according to claim 1, which is characterized in that the deionized water conductivity is small
In 10 μ S/cm.
6. the continuous preparation method for spinning viscose filament yarn finish described in claim 1, which is characterized in that include the following steps:
Mass percent stock as described in claim 1, is warming up to 40~50 DEG C by deionized water, sequentially adds polyethylene glycol fatty
Acid esters, fatty alcohol polyoxyethylene ether aliphatic ester and Polyether-modified Polysiloxane Phosphate sodium salt are mixed 40~60 minutes, obtain
Viscose filament yarn finish is spun to continuous.
7. application of the finish described in claim 1 in continuous viscose filament spinning technique.
8. application according to claim 7, which is characterized in that make finish described in claim 1 with 0.3~1.5 weight
It measures on the amount attachment viscose filament yarn of %.
9. application according to claim 8, which is characterized in that method is as follows:By continuous spunbond glue described in claim 1
Long filament, which is added to finish in slurry, prepares slurries, and adjusting concentration of slurry is 10-100g/L, and viscose glue is used for by the way of spray
Long filament continuous spinning sizing process.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112746353A (en) * | 2020-12-30 | 2021-05-04 | 苏州禾川化学技术服务有限公司 | Chemical fiber oiling agent for high-speed spinning and preparation method thereof |
CN113584639A (en) * | 2021-08-06 | 2021-11-02 | 厦门大邦瑞达印染材料有限公司 | Polyester fully drawn yarn oiling agent |
CN114381943A (en) * | 2022-01-13 | 2022-04-22 | 沈阳浩博实业有限公司 | Continuous spunbonded adhesive filament oil composition |
CN114737391A (en) * | 2022-05-17 | 2022-07-12 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
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Cited By (5)
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---|---|---|---|---|
CN112746353A (en) * | 2020-12-30 | 2021-05-04 | 苏州禾川化学技术服务有限公司 | Chemical fiber oiling agent for high-speed spinning and preparation method thereof |
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CN114737391B (en) * | 2022-05-17 | 2023-09-22 | 沈阳浩博实业有限公司 | Novel continuous spinning viscose filament yarn treating agent and preparation method and application thereof |
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