CN1254527C - 在亲脂性流体处理过程中传递清洁清新气味的织物护理组合物和体系 - Google Patents
在亲脂性流体处理过程中传递清洁清新气味的织物护理组合物和体系 Download PDFInfo
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- CN1254527C CN1254527C CNB018107206A CN01810720A CN1254527C CN 1254527 C CN1254527 C CN 1254527C CN B018107206 A CNB018107206 A CN B018107206A CN 01810720 A CN01810720 A CN 01810720A CN 1254527 C CN1254527 C CN 1254527C
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- WXETUDXXEZHSCS-MAVITOTKSA-N vertofix coeur Chemical compound C[C@@H]1CC[C@@]2(C(/CC3)=C\C(C)=O)[C@@H]3C(C)(C)[C@@H]1C2 WXETUDXXEZHSCS-MAVITOTKSA-N 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
- F26B21/14—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects using gases or vapours other than air or steam, e.g. inert gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/0202—Separation of non-miscible liquids by ab- or adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/02—Dewatering or demulsification of hydrocarbon oils with electrical or magnetic means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D7/5013—Organic solvents containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D7/5027—Hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06L1/10—Regeneration of used chemical baths
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- Textile Engineering (AREA)
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Abstract
提供了包含一种香料的织物护理组合物,使用这类组合物的方法和在亲脂性流体处理过程中适于它们应用的体系。更具体地,本发明涉及包含一种香料的织物护理组合物和体系,和在用亲脂性流体清洗和处理衣物过程中使用这类组合物的方法。
Description
相关的申请
本申请要求根据35 U.S.C.§119(e)于2000年6月5日提交的美国临时申请序列号60/209,468,60/209,250,60/209,443和60/209,444的优先权,和根据35 U.S.C.§119(e)于2000年11月9日提交的美国临时申请序列号60/247,135的优先权。
发明领域
本发明涉及包含一种香料的织物护理组合物,使用这类组合物的方法,和用于在亲脂性流体处理过程中应用它们的体系。更具体地,本发明涉及包含一种香料的织物护理组合物和体系,和在用亲脂性流体清洗和处理衣物过程中使用这类组合物的方法。
发明背景
几个世纪以来,一直用基于水的方法来洗涤纺织品。在上一世纪,由于开发了自动洗衣机,这种家务被极大地简化。然而,虽然极大地简化了家庭洗衣方法,但使用自动洗衣机的家庭洗衣方法仍需要依据颜色和纺织原料进行大量的预分纺织品处理。典型地,白色织物与有色织物分开洗涤,光亮的有色纺织品(如黑红色和蓝色)与浅色制品分开洗涤。而且当被洗涤的纺织品包括“仅可干洗”的制品时,还需要分类和处理。
特别是最近,节水方面的努力和对环境的关注已驱使洗衣机厂商和洗涤剂厂商减少在家庭洗衣过程中对水的需要量。然而,这类努力集中在减少由洗涤介质产生的水消耗,而不是从最初基于水的方法出发来改变洗涤介质。
同时,围绕使用“Perc”(全氯乙烯的缩写)作为适于商业干洗方法的洗涤介质的关注已逐渐升温。这些关注已导致很多基于Perc的方法的被提议的替代方案的开发,但迄今所有的其他替代方法仍未见广泛应用。实例包括烃和液态二氧化碳。最近,在商业干洗领域中,被提议的作为代替Perc的备选方法涉及硅氧烷作为适于“仅可干洗”纺织品的洗涤液的应用(参见,例如美国专利:5,942,007,1999年8月24日;6,042,617和6,042,618,2000年3月28日;6,056,789,2000年5月2日;6,059,845,2000年5月9日;和6,063,135,2000年5月16日)。
已发现通过使用适于家庭洗衣方法的基于亲脂性流体的洗涤介质,可进一步简化自动家庭洗衣方法和消除对仅基于水的家庭洗衣方法的依赖。该方法不仅适于消费者的“仅可干洗”纺织品的家庭清洗,还适于那些通常在家里,在水洗涤介质中洗涤的“机洗”制品。而且当消费者仍倾向于分开洗涤这类制品时,本发明的方法通过洗涤“仅可干洗”和“机洗”制品的混合物,使得消费者具有使家庭洗衣方法显著简化的自由,从而极大地简化了预分类工作。
伴随洗涤过程中的这种惊人变化,出现了一种风险,即不能达到随几代人对古老的基于水的洗衣体系的实践建立起来的期待,不是由于清洗性能的不足,而是仅仅由于该方法看起来是如此与众不同的事实。
通常,消费者期望他们的衣服散发“清洁”的气味,即意味着具有许多在洗涤过程中传递给衣服的香料组分。然而,将香料传送给具有新洗涤方法用途的亲脂性流体体系,尤其是封闭的体系,从而在洗涤过程中重复利用亲油体系,并在随后的回收过程中再利用,对于这个方法产生了许多新的问题和需要考虑的事项。
另一个与基于亲脂性流体的洗涤介质有关的风险是与亲脂性流体有关的气味。亲脂性流体通常包含有效量的恶臭污染物。
因此,需要包含一种香料组分的织物护理组合物和体系,其中所述香料组分可掩盖和/或除去织物护理组合物的臭味和/或在基于亲脂性流体的洗涤过程中将该香料组分传递给织物;以及使用这类组合物的方法和/或适于处理需要处理的织物的体系。
发明概述
本发明通过提供适于在亲脂性流体织物处理体系中使用的包含香料组分的组合物和/或体系满足了上述需要。
在本发明的一个方面,提供了织物护理组合物,其包含:
a)亲脂性流体;和
b)香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分。
在本发明的另一个方面,提供了织物护理组合物,其包含:
a)亲脂性流体;
b)香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分;
c)乳化剂;和
d)水。
在另一个优选的实施方案中,使用亲脂性流体作为载体赋形剂,将织物护理组合物以液体形式喷涂到纺织品上,所述织物护理组合物包含香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分。
在另一个优选的实施方案中,通过喷嘴喷雾器,以汽相的形式,优选通过借助喷嘴喷雾器将织物护理组合物喷涂或喷雾,涂布到纺织品上,所述织物护理组合物包含香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分。
在另一个优选的实施方案中,包含香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分的织物护理组合物,其中组合物以一种形式,优选凝胶基体(gel-matirx)形式或浸渍板(impregnated sheet)的形式存在,使得当将组合物置于碰撞气体,优选加热的气体,优选空气,例如用于干燥纺织品的空气的气流中时,香料组分被涂布到纺织品上。换句话说,在例如纺织品的干燥周期期间,通过气体将香料组分传递到纺织品上。
在本发明的另一个方面,提供了一种处理需要处理的织物的方法,其包含用按照本发明的织物护理组合物接触所述织物。
在本发明的另一个方面,一种将香料组分传递到织物上的方法,其包含用按照本发明的织物护理组合物接触所述织物,使得所述香料组分被传递到所述织物上。
在本发明的另一个方面,提供了用按照本发明的方法处理的织物。
本发明的另一个方面,提供了用按照本发明的方法生产的香味织物(perfumed fabric)。
本发明的另一个方面。提供了香料传递体系,其包含:
a)亲脂性流体;和
b)香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分;
其中,所述香料组分通过接触所述织物而被传递给织物。
本发明的另一个方面,提供了一种产品的制品,其包含按照本发明的织物护理组合物,所述织物护理组合物与使用所述织物护理组合物来处理需要处理的织物的用法说明书包装在一起,所述处理包含用所述织物护理组合物接触所述织物的步骤。
用香料组分,和任选地用亲脂性流体接触纺织品,优选在一个包含要处理的纺织品的装置内进行接触。
因此,本发明提供了包含香料的组合物和/或体系,使用该组合物的方法和包含该组合物的产品的制品。
发明详述
此处使用的术语“织物”是指通常在传统的洗衣过程中或在干洗过程中清洗的任何制品。同样地,该术语包含衣服,亚麻,装饰织物,和衣服附件的制品。该术语还包含整体或部分用织物制造的其它物品,如手袋,家具罩,帆布等。
优选所述织物由选自天然纤维,合成纤维,和它们的混合物的纤维构成。更优选地,所述织物由选自:纤维素纤维,蛋白质纤维,合成纤维,长植物纤维,和它们的混合物的纤维构成。
优选纤维素纤维选自棉,人造丝,亚麻,Tencel,复/棉(poly/cotton)和它们的混合物。
Tencel是由来自在树木经常被再植的美国特殊的林场上生长的树木的木浆制成的纤维素纤维。该纤维是通过一种使用99%可回收和可再循环的无毒溶剂的特殊的“溶液纺丝”方法生产的。由于在该过程期间未产生有毒的化学产物,所以无有害的气体释放到大气中。Tencel具有华贵的纤维的所有特征:天然,棉的适当舒适感,人造丝的流畅的悬垂性(fluid drape)和丰富色彩,合成纤维的强度,和丝绸的奢华手感和光泽。Tencel的织物具有优越的强度,奢华的手感和流畅的悬垂性,具有天然的易吸收性和舒适性,并易于接受染料,具有从浅轻淡色彩到丰富的宝石色调。它们还抗皱和抗收缩,并常常是可洗涤的。Tencel可与其它纤维结合-Tencel增强它们的最佳属性。例如,一种可与亚麻,人造丝,合成弹力纤维,微旦聚酯和棉结合。Tencel的高强度使得能够生产具有较细的织物经纬密度的织物。市场上,Tencel可购自Courtaulds Fibers有限公司。
优选蛋白质纤维选自丝绸,羊毛和相关的哺乳动物纤维,和它们的混合物。优选合成纤维选自聚酯、丙烯酸类、尼龙、和它们的混合物。优选长植物纤维选自黄麻,亚麻,苎麻,椰纤维,爪哇木棉,剑麻,灰叶剑麻,蕉麻,***,印度麻和它们的混合物。
纱-提供一种更细密的,更柔软的并且很少起皱的织物。
此处使用的术语“亲脂性流体”是意图表示任何能去除皮脂的非含水流体,如同用下面描述的试验所限定的。
而且,任选的添加剂成分如表面活性剂,漂白剂等既可在织物施用前加入(直接加到亲脂性流体和/或水中),也可在织物施用期间的某一点加入。下面也更详细地描述这些任选的添加剂成分。
此处使用的术语“洗涤介质”指的是液体[包括但不局限于流体和/或溶液和/或溶剂和/或乳剂],其用于在自动家庭洗衣过程期间以洗涤量润湿纺织品。
此处使用的术语“硅氧烷”指的是非极性的并且不溶于水或低级醇的硅氧烷流体。它们完全溶于典型的脂肪族和芳香族溶剂,包括卤化的溶剂,但仅部分溶于中间石油馏分如萘。线性硅氧烷(参见例如美国专利5,443,747和5,977,040,它们全文结合于此作为参考)和环状硅氧烷在此处是有用的,包括选自八甲基-环四硅氧烷(四聚物),十二甲基-环六硅氧烷(六聚物),和优选十甲基-环五硅氧烷(五聚物,通常表示为“D5”)的环状硅氧烷。最优选的是那些其中硅氧烷包含大于约50%的环状硅氧烷五聚物,更优选大于约75%,最优选至少约90%的五聚物的洗涤介质。还优选的是包含硅氧烷的洗涤介质,所述硅氧烷是具有至少约90%(优选至少约95%)五聚物和少于约10%(优选少于约5%)四聚物和/或六聚物的环状硅氧烷的混合物。
此处使用的术语“体系”指的是常常但不总是由许多各种部分(即物质,组合物,装置,用具,程序,方法,条件等)形成的复合体,用于一个公用的方案或适合于一个公用的用途。
此处使用的短语“纺织品的干重”指的是不具有故意添加的流体重量的纺织品的重量。
此处使用的短语“纺织品的吸收能力”指的是可被纺织品吸收并保留在它的微孔和间隙中的流体的最大量。依照下列测量纺织品的吸收能力的试验方案测量纺织品的吸收能力。
测量纺织品吸收能力的试验方案
步骤1:漂洗并干燥即将加入亲脂性流体的贮液器或其它容器。清洗贮液器使其完全不含任何异物,尤其是肥皂,洗涤剂和湿润剂。
步骤2:称量要试验的“干”纺织品以获得该“干”纺织品的重量。
步骤3:将2L约20℃的亲脂性流体倒入贮液器。
步骤4:将来自步骤2的纺织品置于含亲脂性流体的贮液器中。
步骤5:在贮液器中搅拌该纺织品,以保证纺织品内部位留下气穴,并且被亲脂性流体彻底润湿。
步骤6:将纺织品从含亲脂性流体的贮液器中移走。
步骤7:如果必要,展开纺织品,使得相同或相对纺织品表面之间不互相接触。
步骤8:使来自步骤7的纺织品滴流,直至滴落频率不超过1滴/秒。
步骤9:称量来自步骤8的“湿”纺织品,以获得“湿”纺织品的重量。
步骤10:利用下面等式计算纺织品吸收的亲脂性流体的数量。
FA=(W-D)/D*100
其中:
FA=吸收的流体,%(即,以占纺织品干重的%计,纺织品的吸收能力)
W=湿的样本重量,g
D=最初的样本重量,g
术语“非浸渍(non-immersive)”指的是基本上所有的流体与纺织品密切接触。存在至多最小量的“自由”洗液。它不象“浸渍(immersive)”过程,即洗涤流体为这样的一种浴液,在其中纺织品如同在传统的垂直轴洗衣机中那样被浸没,或如同在传统的水平洗衣机中那样被浸渍。按照下面非浸渍方法的试验方案更详细地说明术语“非浸渍”。当满足下面试验方案时,用流体接触纺织品的方法为非浸渍方法。
非浸渍方法试验方案
步骤1:利用上述测量纺织品吸收能力的试验方案确定织物样品的吸收能力。
步骤2:进行纺织品与流体相接触的过程,使得一定量的流体接触纺织品。
步骤3:将来自步骤1的干织物样品接近步骤2的纺织品,并移动/搅拌/翻转纺织品和织物样品,使得流体从纺织品传递到织物样品上(纺织品和织物样品必须达到相同的饱和度)。
步骤4:称量来自步骤3的织物样品。
步骤5:利用下面等式计算被织物样品吸收的流体:
FA=(W-D)/D*100
其中:
FA=吸收的流体,%
W=湿样品重量,g
D=最初样品重量,g
步骤6:比较被织物样品吸收的流体与织物样品的吸收能力。如果被织物样品吸收的流体少于织物样品吸收能力的约0.8,则该方法为非浸渍方法。
织物护理组合物
本发明的织物护理组合物和/或体系包含一种香料组分,优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分。
本发明的香料组分优选包含香料成分,其不是通常要避免亲水成分的典型的洗衣香料。
当亲脂性流体为组合物的一个成分时,本发明的织物护理组合物和/或体系优选包含占组合物重量的至少约50%,更优选约50%-约100%的亲脂性流体。
本发明的含香料的织物护理组合物和/或体系的香料成分优选占织物护理组合物重量的约0.1%-约25%,更优选约0.2%-约10%,甚至更优选约0.3%-约5%,最优选约0.4%-约2%。
按照本发明的香料组分优选包含占香料组分重量的至少约25%,更优选至少约40%,甚至更优选至少约60%,最优选至少约75%的持久香料成分。
本发明的织物护理组合物和/或体系优选包含水;更优选包含水和一种乳剂。
当所述织物护理组合物中包含水时,优选水以占组合物重量的少于约50%,更优选约0.1%-约50%的含量存在。
优选织物护理组合物是液体形式,并优选通过将织物护理组合物喷到被处理的织物上而施用于织物。
亲脂性流体
此处的亲脂性流体是在操作条件下以液相存在的流体。通常,这种流体在环境温度和压力下可以为完全流动的,可以是易于熔化的固体,如在约0℃-约60℃的温度范围内变为液体的固体,或在环境温度和压力如25℃,1个大气压下,可包含液体和汽相的混合物。因而,该亲脂性流体本质上不是可压缩的气体如二氧化碳。优选此处的亲脂性流体是易燃的,或具有相对高的闪点和/或低的VOC特征,这些术语具有其用于干洗行业的常规含义,它们等于或优选超过已知的常规干洗流体的特性。
此处合适的亲脂性流体易于流动,并是非粘性的。通常,如在下文试验中定义的,此处的亲脂性流体必需是能至少部分溶解皮脂或身体污垢的流体。亲脂性流体的混合物也是合适的,并且假如满足试验的需要,亲脂性流体可包括任何部分的干-洗溶剂,尤其是包括非-氟化溶剂或全氟胺在内的更新类型的干-洗溶剂。一些全氟胺例如全氟三丁基胺,虽然不适于作为亲脂性流体使用,但可以是很多可能存在于亲脂性流体中的添加剂的一种。其它合适的亲脂性流体包括二醇溶剂体系,如高级二醇如C6-或C8-或更高级二醇;包括环状和无环两种类型的有机硅溶剂等;和它们的混合物。
优选适于作为亲脂性流体主要成分加入的非水性流体包括低-挥发性的非-氟化有机物,硅氧烷,尤其是除了氨基-官能的硅氧烷之外的那些硅氧烷,和它们的混合物。低挥发性非氟化有机物包括例如OLEAN和其它多元醇酯,或一些相对非挥发性的、可生物降解的、中链支化的石油馏分。适于用作亲脂性流体主要成分如大于50%的硅氧烷包括环戊硅氧烷,有时表示为“D5”,或具有大约相似挥发性的线性类似物,备选由其它相容的硅氧烷补充。合适的硅氧烷在参考文献中是众所周知的,参见例如Kirk Othmer著Encyclopedia of Chemical Technology,可购自许多商业来源,包括General Electric,Toshiba Silicone,Bayer,和Dow Corning公司。其它合适的流体可在市场上购自Procter & Gamble或Dow Chemical和其它供应商。例如一种合适的硅氧烷是购自GE的硅氧烷流体SF-1528。值得注意的是SF-1528流体是90%环戊硅氧烷(D5)。
依据处理的种类,可以机械方式,蒸发方式或它们的任一种结合的方式去除亲脂性流体。例如,如果处理的目的是提供清洗,以机械方式例如通过旋转从纺织品上去除至少50%的织物处理液是理想的。另一方面,如果处理的目的是将调节剂沉积在织物中,优选以蒸发的方式去除液体。
亲脂性流体的资格鉴定-亲脂性流体试验(LF试验)
用下述试验方法指出的任何一种非水性流体适于在此处作为亲脂性流体,所述非水流体既能满足适于干-洗流体的已知要求(如闪点等),又能至少部分溶解皮脂。可用任何已知的技术测量一种具体物质去除皮脂的能力。作为一般标准,全氟丁胺(Fluorinert FC-43)本身(加或不加添加剂)是参考物质,在D5溶解皮脂的情况下,根据定义此参考物质作为这里的亲脂性流体(它本来是非-溶剂)是不适合的。
下面是研究并鉴定其它物质如其它低粘度,自由-流动的硅氧烷用作亲脂性流体的方法。该方法使用市场上购自Crisco的低芥酸菜子油,油酸(95%纯度,购自Sigma Aldrich公司)和角鲨烯(99%纯度,购自J.T.Baker)作为皮脂的模拟污垢。在评价过程中,该试验物质基本上不含水,并不含任何的添加剂或其它物质。
制备三个管瓶。在第一个管瓶中放置1.0g低芥酸菜子油;在第二个管瓶中放置1.0g(95%)油酸,在第三个即最后的管瓶中放置1.0g角鲨烯(99.9%纯度)。向每个管瓶中加入1g检验其亲脂性的流体。在室温和压力下,在最大设置的标准旋涡混合器上分别混合每个包含亲油污垢和将被检验的流体的管瓶20秒。将小瓶放在工作台上让其在室温和大气压下静止15分钟。如果经过静置,在所有包含亲脂性污垢的管瓶中形成一个单一相,则该流体被鉴定为适于用作依照本发明的“亲脂性流体”。然而,如果在所有三个管瓶中形成两个或多个分离的层,则在否决或承认该流体适于用作“亲脂性流体”之前,需进一步确定在油相中溶解的流体量。
在这种情况下,用注射器小心地从每个管瓶的每个层吸取200微升的样品。将注射器吸取的样品置于GC自动取样器管瓶中,并在确定三个模拟污垢和被检验流体的各校准样品的保留时间后,进行常规的GC分析。如果依据GC分析,发现在由油酸、低芥酸菜子油或角鲨烯层组成的层的任何一个层中存在超过1%、优选更多的被检验流体,则该检验流体同样适于用作亲脂性流体。如果需要,利用二十七氟代三丁基胺即FluorinertFC-43(不合格)和环戊硅氧烷(通过)可进一步校准该方法。
适合的GC是惠普HP5890系列II型气相色谱仪,它备有分流/无分流注射器和火焰电离检测器(FID)。用于确定亲脂性流体存在量的合适的柱是J&W Scientific的DB-1HT型毛细管柱,该毛细管30米长,直径(id)0.25mm,膜厚0.1μm,目录号#1221131。该GC适合的操作条件如下:
载气:氢气
柱压头:9psi
流速:柱流速@-1.5ml/min
裂口@-250-500ml/min
隔片清洗@1ml/min
注射:HP 7673自动取样器,10μl注射器,1μl注射
注射温度:350℃
检测温度:380℃
烘箱温度程序:最初60℃,保持1分钟
升速25℃/分钟
最后380℃,保持30分钟
适于此处使用的优选的亲脂性流体,可在具有极好衣服护理成型性能(garment care profile)的基础上进一步鉴定其应用。衣服护理成型性能试验在本领域是众所周知的,它包括试验流体用于大范围的衣服或纺织品成分是否合格,纺织品成分包括织物、线和用作缝合线的弹性线等及纽扣类。优选的此处使用的亲脂性流体具有极好的衣服护理成型性能,例如它们具有良好的收缩或织物起褶成型性能(puckering profile),并且一点不损坏塑料钮扣。
为了衣服护理试验和其他鉴定如可燃性鉴定的目的,在亲脂性流体中使用的亲脂性流体可以混合物如与水的混合物的形式,以大约在最终亲脂性流体中使用的比率存在,所述最终亲脂性流体将用于接触纺织品。某些有资格用作亲脂性流体的去除皮脂的物质,例如乳酸乙酯,由于有溶解钮扣的倾向可能是完全不该采用的,并且如果在亲脂性流体中使用这种物质,应将其与水和/或其它溶剂一起配制,使得整个混合物基本上不损坏钮扣。其它的亲脂性流体例如D5很好地满足衣服护理需要。一些合适的亲脂性流体可在已批准的美国专利号5,865,852;5,942,007;6,042,617;6,042,618;6,056,789;6,059,845;和6,063,135中查到,这些专利全文引入本文作为参考。
亲脂性溶剂可包括线性和环状的聚硅氧烷、烃和氯化烃。更优选线性和环状的聚硅氧烷和乙二醇醚、乙酸酯、乳酸酯族的烃类。优选的亲脂性溶剂包括环状的硅氧烷,它们在760毫米汞柱时的沸点低于约250℃。特别优选用于本发明的环状硅氧烷是八甲基环四硅氧烷、十甲基环戊硅氧烷和十二甲基环己硅氧烷。优选地,环状硅氧烷包含十甲基环戊硅氧烷(D5,五聚物)及基本不含八甲基环四硅氧烷(四聚物)和十二甲基环己硅氧烷(六聚物)。
然而,应该理解这种有用的环状硅氧烷混合物除了优选的环状硅氧烷外,还可能包含少量其他环状硅氧烷,其他环状硅氧烷包括八甲基环四硅氧烷和六甲基环三硅氧烷或更高级的环状化合物如十四甲基环七硅氧烷。通常,在有用的环状硅氧烷混合物中,以混合物总重量为基础,这些其他环状硅氧烷的量小于约10%。环状硅氧烷混合物的工业标准是这类混合物包含的八甲基环四硅氧烷少于混合物重量的约1%。
因此,本发明亲脂性流体优选包含大于亲脂性流体重量的约50%、更优选大于约75%、甚至更优选至少约90%、最优选至少约95%的十甲基环戊硅氧烷。备选地,该亲脂性流体可为包含环状硅氧烷的混合物的硅氧烷,该混合物具有大于约50%、优选大于约75%、更优选至少约90%、最优选至少约95%直至约100%混合物重量的十甲基环戊硅氧烷和小于约10%、优选小于约5%、更优选小于约2%、甚至更优选小于约1%、最优选小于约0.5%至约0%混合物重量的八甲基环四硅氧烷和/或十二甲基环己硅氧烷。
香料
本发明的织物护理组合物可包含香料,以令人愉快的气味的方式来提供“香味信号”,这赋予被洗涤的织物以清洁和/或气味清新的印象。任何类型的香料可结合于本发明的组合物中。这类香料试剂的非限制实例包括芳香族和脂肪族酯,脂肪族和芳香族醇,脂肪族酮,芳香族酮,脂肪族内酯,脂肪族醛,芳香族醛,醛和胺的缩合产物,饱和的醇,饱和的酯,饱和的芳香酮,饱和的内酯,饱和的腈,饱和的醚,饱和的缩醛,饱和的酚,饱和的烃,芳香族硝基麝香,和它们的混合物,这些更全面地描述在美国专利号5,939,060和加拿大专利号1,325,601中。美国专利号5,744,435和5,721,202中描述了其它香料试剂,所有的所述专利引入本文作为参考。
可以理解本发明涉及基于溶剂的组合物和/或基本上无水的洗衣清洗方法和/或装置。在这些无水介质中香料的行为不同于在含水的传统洗涤条件中的香料行为。如同美国专利号5,780,404所教导的,在传统的使用水的洗衣清洗过程中,不优选具有高亲水性的香料成分,因为它们不是织物牢固的,并且随漂洗水流走,所述专利引入本文作为参考。组合物中的该溶剂具有保留所有香料成分的倾向,并防止香料沉积到织物上。因此,选择在织物上可有效提供最佳残余香味优点的香料成分是必要的。这是优选的,即至少约25%,优选至少约40%,更优选至少约60%,甚至更优选至少约75%重量香料由那些“持久”香料成分组成,所述持久香料成分选自干燥后可观地保留在织物上的“持久”香料成分和具有低气味检测阈的香料成分和它们的混合物。
a.耐久香料成分
耐久香料成分的特征在于它们的沸点(B.P.)。在标准状态下,760毫米汞柱的标准压力下,本发明的耐久香料成分具有约240℃的沸点,优选约250℃或更高的沸点。
在如由作者Steffen Arctander 1969年出版的“Perfume and FlavorChemicals(Aroma Chemicals)”中提供了很多香料成分的沸点,该出版物引入本文作为参考。可从不同的化学手册和数据库,例如Beilstein手册,Lange’s化学手册和CRC Handbook of Chemistry and Physics中获得其它沸点值。当仅在不同的压力,通常比760毫米汞柱的标准压力低的压力下提供沸点时,例如那些在A.J.Gordon和R.A.Ford著“The Chemist’sCompanion”,John Wiley&Sons,1972年,30-36页中提供的沸点,可通过利用沸点-压力列线图近似地估计标准压力下的沸点。也可通过引入本文作为参考的“Development of a Quantitative Structure-Property RelationshipModel for Estimating Normal Boiling Points of Small Multifunctional OrganicMolecules”,David T.Stanton,Journal of Chemical Information and ComputerScience,卷.40,No.1,2000,81-90页中描述的计算机程序计算沸点值。因此,当由耐久香料成分组成的香料组合物具有约250℃或更高的沸点时,在干燥步骤后,它们牢固保留在织物上。
本发明优选的耐久香料成分的非限制实例包括:环己基丙酸烯丙酯,黄葵内酯,苯甲酸戊酯,肉桂酸戊酯,戊基肉桂醛,戊基肉桂醛二甲缩醛,异水杨酸戊酯,橙花素(羟基香茅醛-甲基邻氨基苯甲酸酯的商品名),二苯酮,水杨酸苄酯,异丁基喹啉,β-石竹烯,荜澄茄烯,雪松醇,乙酸柏木酯,甲酸柏木酯(cedryl formate),肉桂酸肉桂酯,水杨酸环己酯,仙客来醛,二氢异茉莉酮酸酯,二苯甲烷,苯醚,十二内酯,iso E super(1-(1,2,3,4,5,6,7,8-八氢-2,3,8,8-四甲基-2-萘基)-乙酮的商品名),巴西酸业乙基酯,缩水甘油酸乙基甲基苯酯,十一烯酸乙酯,异丁子香酚,环十五内酯(15-羟基十五烷酸内酯的商品名),加乐麝香(1,3,4,6,7,8-六氢-4,6,6,7,8,8-六甲基环戊二烯并-γ-2-苯并吡喃的商品名),邻氨基苯甲酸香叶酯,十六醇一化物(hexadecanolide),水杨酸己烯酯,己基肉桂醛,水杨酸己酯,铃兰醛(对-叔-丁基-α-甲基氢化肉桂醛的商品名),苯甲酸芳樟酯,2-甲氧基萘,肉桂酸甲酯,二氢茉莉酮酸甲酯,β-甲基·萘基酮,麝香2,3-二氢-2-茚酮,麝香酮,西藏麝香(musk tibetine),肉豆蔻醚,δ-壬内酯,氧杂十六内酯-10,氧杂十六内酯-11,绿叶醇,粉檀麝香(5-乙酰基-1,1,2,3,3,6-六甲基茚满的商品名),苯甲酸苯乙酯,苯乙酸苯乙酯,苯庚醇,苯己醇,α-檀香醇,环十五内酯(15-羟基十五烷酸,内酯的商品名),吐纳麝香(tonalid),δ-十一内酯,γ-十一内酯,乙酸岩兰草酯,β-萘基甲基醚,苯氧乙酸烯丙酯,肉桂醇,肉桂醛,甲酸肉桂酯,香豆素,乙酸二甲基苄基原酯,肉桂酸乙酯,乙基香兰素(3-甲氧基-4-乙氧基苯甲醛),丁子香酚,乙酸丁子香酚酯,天芥菜精,吲哚醇(indol),异丁子香酚,乙酰二异戊烯(koavone),甲基-β-萘酮,肉桂酸甲酯,二氢茉莉酮酸甲酯(methyl dihdrojasmonate),β-甲基·萘基酮,甲基-n-氨茴酸甲酯,δ-壬内酯,γ-壬内酯,对甲氧基乙酰苯(乙酰茴香醚),异丁酸苯氧基乙酯,丙酸苯氧基乙酯,胡椒醛,柠檬酸三乙酯,香兰素,和它们的混合物。
在本发明中有用的其它耐久香料成分包括甲基-N-氨茴酸甲酯,丁酸苄酯,异戊酸苄酯,异丁酸香茅酯,丙酸香茅酯,δ-壬内酯,乙酸二甲基苄基原酯,十二醛,牻牛儿醇乙酸酯,异丁酸牻牛儿酯,γ-紫罗兰酮,对异丙基苯乙醛,顺茉莉酮,丁子香酚甲醚,羟基香茅醛,苯氧基乙醇,异戊酸苄酯,茴香醛,枯茗醇,顺茉莉酮,丁子香酚甲醚,和它们的混合物。
在本发明中使用的优选的香料组合物包含至少4种不同的耐久香料成分,优选至少5种耐久香料成分,更优选至少6种不同的耐久香料成分,甚至更优选至少7种不同的耐久香料成分。衍生自天然来源的最普通的香料成分由许多成分组成。当将每种此类物质用于配制本发明的优选的香料组合物时,为了定义本发明,将它算作一种单一的成分。
在香料领域,将一些不具有气味或具有非常微弱气味的物质用作稀释剂或补充剂。这些物质的非限制实例是双丙甘醇,邻苯二甲酸二乙酯,柠檬酸三乙酯,肉豆蔻酸异丙酯和苯甲酸苄酯。这些物质用于如稀释和稳定某些其它香料成分。在配制本发明的持久香料组合物过程中不考虑这些物质。
b.低气味检测阈香料成分
本发明的香料组合物可包含一种或多种低气味检测阈香料成分。有气味物质的气味检测阈是可被嗅觉检测的该物质的最低蒸汽浓度。在如“Standardized Human Olfactory Thresholds”M.Devos等,牛津大学出版社1990年出版,和“Compilation of Odor and Taste Threshold Values Data”,American Society for Testing and Materials,1978年,F.A.Fazzalari编辑,ASTM数据系列号DS 48A,两个所述出版物引入本文作为参考。使用少量的具有低气味检测阈值的香料成分可改善香料气味特性,即使它们不如上述公开的耐久香料成分那样显著。在本发明的持久香料组合物中有用的具有显著低检测阈的香料成分选自戊基甘醇酸烯丙酯,降龙涎香醚,茴香脑,2-乙基-4-(2,2,3-三甲基-3-环戊烯-1-基)-2-丁烯-1-醇(bacdanol),苄基丙酮,水杨酸苄酯,邻氨基苯甲酸丁酯,3-甲基邻苯丙酮二醚(calone),西塔娄克斯(cetalox),肉桂醇,香豆素,丙烯酸环己基氧基乙基酯(cyclogalbanate),女贞醛(Cyclal C),西玛醛(cymal),大马烯酮,α-二氢大马酮,4-癸烯醛,二氢异茉莉酸酮酯,γ-十二内酯,黑檀醇(ebanol),邻氨基苯甲酸乙酯,乙基-2-甲基丁酸酯,缩水甘油酸乙基甲基苯酯,乙基香兰素,丁子香酚,乙酸葡萄酵母酯(flor acetate),花青醛(florhydral),乙酸乙基甲基二噁茂烷酯,灌木烯(frutene),天芥菜精,3,3,5-三甲基环己基乙基醚,顺-3-己烯基水杨酸酯,吲哚,α-紫罗兰酮,β-紫罗兰酮,异环柠檬醛,异丁子香酚,α-异甲基紫罗兰酮,可翁酮(kenone),铃兰醛,里哪醇,2-羟基-2-甲基-6-(3,4-二氢环己醛),邻氨基苯甲酸甲酯,二氢茉莉酮酸甲酯,2-辛炔酸甲酯,四氢吡喃甲基异丁烯酯,甲基·β-萘基酮,甲基·壬基酮,β-萘甲醚,橙花醇,对-茴香醛,对-羟基苯基丁酮,苯乙醛,γ-十一内酯,十一醛和它们的混合物。除了耐久香料成分,这些物质优选以低含量存在,按本发明的总香料组分的重量计算,典型地少于约20%,优选少于约15%,更优选少于约10%。然而,仅需要低含量以提供香味效果。一些耐久香料成分也具有低气味检测阈。在配制本发明的持久香料组分时将这些物质认作耐久香料成分。
由于存在高含量的溶剂和相对低的香料对织物的传递,当前发明的织物护理组合物可包含相对高含量的香料,按洗涤剂组合物重量计算,典型地约0.01%-约5%,优选约0.1%-约4%,更优选约0.3%-约3%,甚至更优选约0.4%-约2%。
本发明还涉及非含水的清洗方法,其包含一种“最终”处理,以提供织物清新的好处。特别适于该方法的按照本发明的织物护理组合物优选包含亲脂性流体和香料组合物,所述香料组合物优选包含选自耐久香料成分,低气味检测阈香料成分和它们的混合物的持久香料成分。按香料组合物的组合物重量计算,香料在织物护理组合物中的含量典型为约0.0001%-约0.2%,优选约0.0002%-约0.1%,更优选约0.003%-约0.08%,最优选约0.005%-约0.05%。
持续香料释放剂
前体芳香物(pro-fragrances),前体香料(pro-perfumes)和前体谐香剂(Pro-accords)
本发明的织物护理组合物还包含一种香料传递体系,其包含一种或多种前体芳香物,前体香料和前体谐香剂,和它们的混合物,在下文中全部表示为“前体芳香物”。依据选择的前体芳香物,本发明的前体芳香物可显示不同的释放速率。另外,本发明的前体芳香物可与香原料混合,所述香原料从中释放出来以赋予使用者最初的芳香,香味,谐香或花香。
本发明的前体芳香物可与任何载体适当地混合,条件是,所述载体不催化或以其它方式促进从香原料的前体芳香物过早地释放。
下面是按照本发明的前体芳香物的非限制种类。
酯和聚酯—本发明的酯和聚酯前体芳香物能释放一种或多种香原料醇。优选的酯具有下面的化学式:
其中R是取代的或未取代的C1-C30亚烷基,C2-C30亚链烯基,C6-C30亚芳基,和它们的混合物;-OR1衍生自具有化学式HOR1的香原料醇,或备选地,在其中指数x大于1的情况下,R1是氢,从而使至少一个部分为羧酸,-CO2H单元,而不是酯单元;指数x是1或更大。优选的聚酯前体芳香物的非限制实例包括琥珀酸二牻牛儿酯,琥珀酸二香茅酯,己二酸二牻牛儿酯,己二酸二香茅酯等。
β-酮酸酯—本发明的β-酮酸酯能释放一种或多种香原料。按照本发明优选的β-酮酸酯具有下面化学式:
其中-OR衍生自香原料醇;R1,R2和R3每个独立地是氢,C1-C30烷基,C2-C30链烯基,C1-C30环烷基,C2-C30炔基,C6-C30芳基,C7-C30亚烷基烯基,C3-C30烯氧基烷基,和它们的混合物,条件是,至少一个R1,R2或R3是具有下面化学式的单元:
其中R4,R5和R6每个独立地是氢,C1-C30烷基,C2-C30链烯基,C1-C30环烷基,C1-C30烷氧基,C6-C30芳基,C7-C30亚烷基烯基,C3-C30烯氧基烷基,和它们的混合物,或R4,R5,和R6可一起形成C3-C8芳香族或非芳香族环,杂环或非杂环化合物。
按照本发明β-酮酸酯的非限制实例包括2,6-二甲基-7-辛烯-2-基3-(4-甲氧苯基)-3-氧-丙酸酯;3,7-二甲基-1,6-辛二烯-3-基3-(壬烷基)-3-氧-丙酸酯;9-癸烯-1-基3-(b-萘基)-3-氧-丙酸酯;(a,a-4-三甲基-3-环己烯基)甲基3-(b-萘基)-3-氧-丙酸酯;3,7-二甲基-1,6-辛二烯-3-基3-(4-甲氧苯基)-3-氧-丙酸酯;2,6-二甲基-7-辛烯-2-基3-(b-萘基)-3-氧-丙酸酯;2,6-二甲基-7-辛烯-2-基3-(4-硝苯基)-3-氧-丙酸酯;2,6-二甲基-7-辛烯-2-基3-(b-甲氧苯基)-3-氧-丙酸酯;3,7-二甲基-1,6-辛二烯-3-基3-(a-萘基)-3-氧-丙酸酯;顺3-己烯-1-基3-(b-萘基)-3-氧-丙酸酯;2,6-二甲基-7-辛烯-2-基3-(壬烷基)-3-氧-丙酸酯;2,6-二甲基-7-辛烯-2-基3-氧-丁酸酯;3,7-二甲基-1,6-辛二烯-3-基3-氧-丁酸酯;2,6-二甲基-7-辛烯-2-基3-(b-萘基)-3-氧-2-丙酸甲酯;3,7-二甲基-1,6-辛二烯-3-基3-(b-萘基)-3-氧-2,2-丙酸二甲酯;3,7-二甲基-1,6-辛二烯-3-基3-(b-萘基)-3-氧-2-丙酸甲酯;3,7-二甲基-2,6-辛二烯基3-(b-萘基)-3-氧-丙酸酯;3,7-二甲基-2,6-辛二烯基3-庚基-3-氧-丙酸酯;
缩醛和酮缩醇—按照本发明用作前体谐香剂的另一类化合物是具有下面化学式的缩醛和酮缩醇:
其中按照下面所示路线,缩醛和酮缩醇的水解释放出一种醛或酮的等价物和醇的两种等价物:
其中R是C1-C20线性烷基,C4-C20支链烷基,C6-C20环烷基,C6-C20支链环烷基,C6-C20线性链烯基,C6-C20支链链烯基,C6-C20环状的链烯基,C6-C20支链的环状链烯基,C6-C20取代的或未取代的芳基,优选取代芳基单元的部分是烷基部分,和它们的混合物。R1是氢,R,或在前体谐香剂是酮缩醇的情况下,R和R1可一起形成一个环。R2和R3是独立选自C5-C20线性、支链或取代的烷基;C4-C20线性、支链或取代的链烯基;C5-C20取代或未取代的环烷基;C5-C20取代或未取代的芳基;C2-C40取代或未取代的亚烷基氧基;C3-C40取代或未取代的亚烷基氧基烷基;C6-C40取代或未取代的亚烷基芳基;C6-C32取代或未取代的芳基氧基;C6-C40取代或未取代的亚烷基氧基芳基;C6-C40氧化烯芳基;和它们的混合物。
本发明的能被缩醛释放的醛的非限制实例包括4-(4-羟基-4-甲基戊基)-3-环己烯-1-羧甲醛(carboxaldehyde)(2-羟基-2-甲基-6-(3,4-二氢环己醛)),苯乙醛,甲基壬基乙醛,2-苯基丙-1-醛(hydrotropaldehyde),3-苯基丙-2-烯-1-醛(肉桂醛),3-苯基-2-苯基丙-2-烯-1-醛(a-戊基肉桂醛),3-苯基-2-己基内-2-烯醛(a-己基肉桂醛),3-(4-异丙基苯基)-2-甲基丙-1-醛(仙客来醛),3-(4-乙基苯基)-2,2-二甲基丙-1-醛(2,2-二甲基-(3-对苯乙基)丙醛),3-(4-叔-丁基苯基)-2-甲基丙醛,3-(3,4-亚甲二氧基苯基)-2-甲基丙-1-醛(helional),3-(4-乙基苯基)-2,2-二甲基丙醛,3-(3-异丙基苯基)丁-1-醛,2,6-二甲基庚-5-烯-1-醛(甜瓜醛),正-癸醛,正-十一醛,正-十二醛,3,7-二甲基-2,6-辛二烯-1-醛(柠檬醛),4-甲氧苯甲醛(茴香醛),3-甲氧基-4-羟基苯甲醛(香兰素),3-乙氧基-4-羟基苯甲醛(乙基香兰素),3,4-亚甲二氧基苯甲醛(天芥菜精),3,4-二甲氧基苯甲醛。
本发明的能被酮缩醇释放的酮的非限制实例包括a-二氢大马酮,b-二氢大马酮,d-二氢大马酮,b-大马烯酮,麝香酮,6,7-二氢-1,1,2,3,3-五甲基-4(5H)-2,3-二氢-1-茚酮(开司米酮),顺-茉莉酮,二氢茉莉酮,a-紫罗兰酮,b-紫罗兰酮,二氢-b-紫罗兰酮,g-甲基紫罗兰酮,a-异-甲基紫罗兰酮,4-(3,4-亚甲二氧基苯基)丁-2-酮,4-(4-羟基苯基)丁-2-酮,甲基b-萘基酮,甲基柏木酮,6-乙酰基-1,1,2,4,4,7-六甲基1,2,3,4-四氢化萘(吐纳麝香),1-香芹酮,5-环十六碳烯-1-酮,乙酰苯,癸酮,2-[2-(4-甲基-3-环己烯基-1-基)丙基]环戊-2-酮,2-仲-丁基环己酮,b-二氢紫罗兰酮,烯丙基紫罗兰酮,a-鸢尾酮,a-甲基紫罗兰酮(a-cetone),a-紫罗兰酮(a-irisone),乙酰茴香醚,香叶基丙酮,1-(2-甲基-5-异丙基-2-环己烯基)-1-丙酮,乙酰基二异戊烯,甲基环香茅酮(methyl cyclocitrone),4-叔-戊基环己酮,对-叔-丁基环己酮,邻-叔-丁基环己酮,乙基·戊基酮(ethyl amylketone),乙基戊基酮(ethyl pentyl ketone),薄荷酮,甲基-7,3-二氢-2H-1,5-苯并二氧肾上腺素(benzodioxepine)-3-酮,葑酮。
原酸酯—按照本发明用作前体谐香剂的另一类化合物是具有下面化学式的原酸酯:
其中按照下面所示路线,原酸酯水解释放酯的一种等价物和醇的两种等价物:
其中R是氢,C1-C20烷基,C4-C20环烷基,C6-C20链烯基,C6-C20芳基,和它们的混合物;R1,R2和R3每个独立地选自C5-C20线性、支链或取代的烷基;C4-C20线性、支链或取代的链烯基;C5-C20取代或未取代的环烷基;C5-C20取代或未取代的芳基,C2-C40取代或未取代的亚烷基氧基;C3-C40取代或未取代的亚烷基氧基烷基;C6-C40取代或未取代的亚烷基芳基;C6-C32取代或未取代的芳氧基;C6-C40取代或未取代的亚烷基氧基芳基;C6-C40氧化烯芳基;和它们的混合物。
原酸酯前体芳香物的非限制实例包括三牻牛儿基原甲酸酯,三(顺-3-己烯-1-基)原甲酸酯,三(苯乙基)原甲酸酯,双(香茅基)乙基原乙酸酯,三(香茅基)原甲酸酯,三(顺-6-壬烯)原甲酸酯,三(苯氧乙基)原甲酸酯,三(牻牛儿基,橙花基)原甲酸酯(70∶30牻牛儿基∶橙花基),三(9-癸烯基)原甲酸酯,三(3-甲基-5-苯基戊基)原甲酸酯,三(6-甲基庚-2-基)原甲酸酯,三[4-(2,2,6-三甲基-2-环己-1-烯)-3-丁烯-2-基]原甲酸酯,三[3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊-2-烯]原甲酸酯,三薄荷基原甲酸酯,三(4-异丙基环己基乙基-2-基)原甲酸酯,三-(6,8-二甲基壬-2-基)原甲酸酯,三-苯乙基原乙酸酯,三(顺-3-己烯-1-基)原乙酸酯,三(顺-6-壬烯基)原乙酸酯,三-香茅醇基原乙酸酯,双(牻牛儿基)苄基原乙酸酯,三(牻牛儿基)原乙酸酯,三(4-异丙基环己基甲基)原乙酸酯,三(苄基)原乙酸酯,三(2,6-二甲基-5-庚烯基)原乙酸酯,双(c/s-3-己烯-1-基)戊基原乙酸酯,和橙花基香茅基乙基原丁酸酯。
下面这些专利适当地描述了前体芳香物:美国5,378,468 Suffis等,1995年1月3日公布;美国5,626,852 Suffis等,1997年5月6日公布;美国5,710,122Sivik等,1998年1月20日;美国5,716,918 Sivik等,1998年2月10日公布;美国5,721,202 Waite等,1998年2月24日公布;美国5,744,435 Hartman等,1998年4月25日公布;美国5,756,827 Sivik,1998年5月26日公布;美国5,830,835 Sevems等,1998年11月3日公布;美国5,919,752 Morelli等,1999年7月6日公布;所有这些文献都全文引入本文作为本文的一部分。
乳化剂
在化学领域,乳化剂是众所周知的。在本质上,乳化剂将两种或多种不溶或半溶相结合在一起以建立一种稳定的或半稳定的乳状液。在要求的本发明中优选该乳化剂具有双重用途,即它不仅能作为乳化剂起作用,还能作为处理性能促进剂起作用。例如,该乳化剂还可作为一种表面活性剂,从而提高清洗性能。普通乳化剂和乳化剂/表面活性剂均可在市场上购买。
添加剂成分
添加剂材料可以广泛地变更,并可以有广泛的使用水平范围。如清洁酶如蛋白酶、淀粉酶、纤维素酶、脂肪酶等;以及漂白催化剂,包括具有锰和类似过渡金属的大环类型的催化剂,全部都可以在这里使用的洗熨洗涤产品中应用,其使用水平可以是非常低、或低于一般、或较高的水平。催化作用的添加剂材料如酶,可以以“向前”或“逆转”的模式使用,这是有用于本发明具体用途的独立发现。例如,使用脂解酶或其他水解酶时,可任选醇作为添加剂存在,将脂肪酸转变为酯,由此增加它们在亲脂性流体中的溶解度。这是一种“逆转”操作,与正规在水中使用这种水解酶将较少水-溶的脂肪酸酯类转变为更加水-溶的材料相反。在任何情况下,所有添加剂成分必须适于与亲脂性流体结合使用。
一些适合的洗涤添加剂包括但不限于助洗剂、表面活性剂、酶、漂白活化剂、漂白催化剂、漂白助促进剂、漂白剂、碱源、抗菌剂、色料、香料、前面未描述的其它香料、前面未描述的前体香料、整理助剂、钙皂分散剂、组合物臭气控制剂、气味中和剂、聚合物染料迁移抑制剂、结晶生长抑制剂、光漂白剂、重金属离子螯合剂、防晦暗剂、抗微生物剂、抗氧化剂、抗再沉积剂、污物释放聚合物、电解质,pH改性剂、增稠剂、研磨剂、二价或三价离子、金属离子盐、酶稳定剂、缓蚀剂、二胺或多胺和/或它们的烷氧基化产物、顽固泡沫稳定聚合物、溶剂、操作助剂、织物软化试剂、荧光增白剂、水溶助长剂、顽固泡沫或泡沫抑制剂、顽固泡沫或泡沫助促进剂、织物软化剂、抗静电剂、固色剂、染料磨损抑制剂、抗染污剂、减皱剂、阻皱剂、污物释放聚合物、拒污剂、防晒剂、抗褪色剂、及它们的混合物。
术语“表面活性剂”一般指的是无论在水中或在亲脂性流体中或二者的混合物中有表面活性的材料。一些作例证的表面活性剂包括用于常规水洗涤剂体系的非离子型、阳离子型和硅氧烷表面活性剂。适合的非离子型表面活性剂包括但不限于:
a)壬基酚和十四烷醇与聚环氧乙烷的缩合物,如Kasprzak的美国专利4685930中所述;及
b)脂肪醇的乙氧基化物,R-(OCH2CH2)aOH,a=1-100,典型地为12-40;R=8-20个C原子的烃残基,典型地为线性烷基。实例为有4或23个氧乙烯基团的聚氧乙烯十二烷基醚;有2、10或20个氧乙烯基团的聚氧乙烯十六烷基醚;有2、10、20、21或100个氧乙烯基团的聚氧乙烯十八烷基醚;有2或10个氧乙烯基团的聚氧乙烯(2),(10)油基醚。商业可得到的实例包括但不限于:ALFONIC、BRIJ、GENAPOL、NEODOL、SURFONIC、TRYCOL。也参阅Hill等的美国专利6013683。
适合的阳离子型表面活性剂,包括但不限于具有下列化学式的二烷基二甲基铵盐:
R’R”N+(CH3)2X-
其中R’R”各独立地选自12-30个C原子构成的基团,或由牛脂、椰子油或大豆油衍生的基团,X=Cl或Br。实例包括:
双十二烷基二甲基溴化铵(DDAB)、双十六烷基二甲基氯化铵、双十六烷基二甲基溴化铵、双十八烷基二甲基氯化铵、双二十烷基二甲基氯化铵、双二十二烷基二甲基氯化铵、双椰油基二甲基氯化铵、双牛脂基二甲基溴化铵(DTAB)。商业可得到的实例包括但不限于:ADOGEN、ARQUAD、TOMAH、VARIQUAT。也参阅Hill等的美国专利6013683。
适合的硅氧烷表面活性剂包括但不限于具有二甲基聚硅氧烷疏水部分和一个或多个亲水聚烷撑侧链的聚环氧烷聚硅氧烷,及其具有的化学通式为:
R1-(CH3)2SiO-[(CH3)2SiO]a-[(CH3)(R1)SiO]b-Si(CH3)2-R1
其中a+b为大约1-大约50,优选大约3-大约30,更优选大约10-大约25,及各R1是相同或不同的,并选自甲基和聚(环氧乙烷/环氧丙烷)共聚物基团,聚(环氧乙烷/环氧丙烷)共聚物基团具有的通式为:
-(CH2)nO(C2H4O)c(C3H6O)dR2
至少一个R1是聚(环氧乙烷/环氧丙烷)共聚物基团,其中n是3或4,优选3;总c(对于全部聚环氧烷侧基)的数值为1-大约100,优选约6-约100;总d为0-约14,优选0-约3;及更优选d是0;总c+d具有的数值为约5-约150,优选约9-约100;及各R2是相同或不同的,选自氢、具有1-4个碳原子的烷基、及乙酰基,优选氢和甲基。这些表面活性剂的实例可在Hill的美国专利5705562和Hill的美国专利5707613中查到,此二者都作为参考并入本文作为本文的一部分。
这种类型表面活性剂的实例是Silwet表面活性剂,这种表面活性剂可从CK Witco、OSi Division、Danbury、Connecticut公司得到。下列是典型的Silwet表面活性剂:
名称 | 平均分子量(MW) | 平均a+b | 平均总c |
L-7608L-7607L-77L-7605L-7604L-7600L-7657L-7602 | 6001,0006006,0004,0004,0005,0003,000 | 1212021112020 | 91799953687629 |
聚环氧烷基团(R1)的分子量小于或等于大约10,000。优选聚环氧烷基团分子量小于或等于大约8,000,及最优选在大约300-大约5,000的范围。因此数值c和d可以是提供分子量在此范围的那些数值。然而聚醚链(R1)中亚乙基氧的单元数(-C2H4O)必须足以使得聚环氧烷聚硅氧烷能在水中分散或在水中溶解。如果在聚环氧烷链中存在1,2-亚丙基氧基团,它们在链中可以是无规分布或以嵌段存在。优选的Silwet表面活性剂是L-7600、L-7602、L-7604、L-7605、L-7657、及它们的混合物。除了表面活性外,聚环氧烷聚硅氧烷表面活性剂还给织物提供其它益处,如抗静电性和柔软性。
聚环氧烷聚硅氧烷的制备是本领域熟知的。本发明聚环氧烷聚硅氧烷可根据美国专利3,299,112中阐明的程序来制备,该专利作为参考并入本文。
另一种适合的硅氧烷表面活性剂是SF-1488,它是可从GE硅氧烷流体得到的。
这些以及适合作为添加剂与亲脂性流体结合使用的其它表面活性剂是本领域熟知的,并在Kirk Othmer’s Encyclopedia of Chemical Technology,第三版22卷360-379页的“Surfactants and Detersive Systems”中有更详细的说明,该书全文结合入本文作为本文的一部分。此外,在1975年12月30日公开的Laughlin等人的美国专利3,929,678的第13栏14行-16栏6行中,一般性地公开了适合的非离子型洗涤剂表面活性剂,其结合在此作为本文的一部分。
上述添加剂也可以是抗静电剂。任何适合用于洗熨和干洗领域的熟知的抗静电剂都适合用于本方法和本发明组合物。特别适合的抗静电剂是已知提供抗静电优势的织物软化剂的子集(subset)。例如那些具有碘值在20以上的脂肪酰基织物软化剂,如N,N-二(牛脂酰基-氧-乙基)-N,N-二甲基硫酸铵单甲酯。然而可以理解术语抗静电剂不仅仅限于此织物软化剂的子集,而是应包括全部抗静电剂。
着色剂
此处使用的“着色剂”是为了赋予在自动亲脂性流体(如硅氧烷)洗衣过程中使用的组合物以颜色而单独加入的任何物质(包括染料和颜料),所述组合物包括亲脂性流体(如硅氧烷溶剂)洗涤介质组合物,而对在自动亲脂性流体洗衣过程期间和亲脂性流体洗涤介质接触的所有织物而言是安全的。着色剂对本发明组合物的安全性和作用可通过在自动亲脂性流体洗衣过程中用潜在的着色剂接触白色织物来确定,导致对白色织物产生几乎没有或观察不到的色彩的着色剂是在此处安全使用的着色剂,如同通过下面试验所确定的:
·各种织物内容的白色织物样品(每种3个)用作检测染料从着色剂转移的示踪物;
·测量每种织物样品以确定Hunter洁白刻度的基线值;
·利用产生C/2°光源的精密分光光度计进行测量;
·将数值记录为Lh,ah,和bh;
·随后在存在潜在的着色剂的条件下,将样品洗涤并干燥;
·在预定循环的结尾进行样品示踪物的分光光度测量;
·计算最初和最后循环之间的差异,并记录为ΔE值:
·ΔE={(Lhi-Lhf)2+(ahi-ahf)2+(bhi-bhf)2}的平方根;
·将3或更多循环的显著差异定义为ΔE>=5。
公认的,着色剂不包括那些不是为了赋予这类组合物或洗涤方法以色彩的目的而加入的那些活性成分。例如,由于存在一些低含量的杂质而使表而活性剂典型地被轻微着色;光漂白剂一般赋予溶液蓝色;增白剂也可提供某些色彩。因此,当本发明的组合物和方法典型地包括这类活性成分时,按照本发明的着色剂与它们一起加入,典型地掩饰或弥补由这类活性成分产生的任何色彩。
而着色剂通常是众所周知的,选择它们在本发明方法和组合物中使用,尤其是在硅氧烷溶剂体系中使用,需要仔细考虑洗涤方法的条件和可能与着色剂接触的典型的织物范围,以及使用着色剂的目的。特别是,在组合物中使用的着色剂一般存在于组合物中,以赋予该组合物理想的美学效果,所述组合物在洗涤过程中加入到亲脂性流体(如硅氧烷溶剂)中。一般加入这类组合物以将清洁剂(如表面活性剂,聚合物,酶,漂白剂)和/或织物处理剂(如柔软剂,抗静电剂,增白剂)传递给洗涤过程。这类着色剂因此提供了令消费者更加满意的组合物,如蓝色液体洗衣洗涤剂或染上绿色斑点的洗衣粉末。
这类着色剂不仅在这类组合物中必须是稳定的,并且与要和其它着色剂相接触的添加剂成分是相容的,而且必须不从洗涤介质沉积到和洗涤介质接触的织物上(即通过上文提供的试验定义的那样,它们必须是安全的)。在这类组合物中使用的着色剂可被用于该方法的自动洗衣机的亲脂性流体(尤其是硅氧烷溶剂)回收体系除去(如通过过滤和/或蒸馏),和/或该着色剂与用于染色在本方法中使用的亲脂性流体体系的任何一种着色剂体系相容,和/或该着色剂易于被在洗涤过程中利用的其它条件破坏(完全或至少很大部分),这也是非常理想的。可通过任何方式,包括但不局限于以化学方式(如氧化和/或还原反应),机械方式(如超声),电方式,和/或热降解方式破坏着色剂。这包括,例如通过利用体系中的臭氧或在加热步骤如干燥织物过程中来破坏着色剂。当选择着色剂时需要考虑的另一个事项是与提供一些颜色的其它添加剂活性成分的颜色兼容性。
着色剂作为适于亲脂性流体(如硅氧烷)洗涤溶液的色料的应用具有与对上述在加到体系中的组合物中使用的着色剂相似的要求—它们在洗涤过程中必须是至少部分稳定的(直至在至少部分洗涤过程中,提供洗涤介质的理想的色彩的程度),以及还必须不从洗涤介质中沉积到与洗涤介质接触的织物上(即通过本文前面提供的试验,确定它们必须是安全的)。这类着色剂在自动机器使用的再循环和再回收过程中稳定是理想的,但如果加到含有每种洗衣物的洗涤介质中的组合物包含一定含量的着色剂,所述含量足以提供洗涤介质的理想的颜色,或通过一些其它补充方法来补充,则这就是不必要的。
设计染色体系使得用于染色亲脂性流体(如硅氧烷溶剂)的着色剂和配制到组合物中的着色剂与每种洗衣物品共同加入也是可能的。例如,可配制来自添加的组合物的着色剂以与用于染色亲脂性流体(如硅氧烷溶剂)体系的着色剂相匹配,其能理想地补充由先前的洗涤周期导致的部分损耗的染色亲脂性流体着色剂。设计一种染色体系使得与组合物一同添加的着色剂改变亲脂性流体(如硅氧烷)洗涤介质的染色,但在洗涤过程中相同的阶段被随后去除也是可能的(如当处于臭氧处理步骤时,硅氧烷色调经历一种颜色改变;当溶剂回收过程完成时,该溶剂变回最初的颜色)。
而且,利用染色体系使得着色剂选择性溶于亲脂性流体和/或选择性溶于水是可能的,这对于当使用含水乳状液(如硅氧烷乳状液)作为洗涤介质时是理想的。这对于易于检测乳状液的状态,包括当打破该乳状液时,观察水和亲脂性流体相的能力可能是有用的。
起泡剂
由于亲脂性流体(尤其是硅氧烷)洗涤方法和清洗体系不能自然起泡,为满足消费者的需求,需要选择体系和/或特别加入的成分以产生气泡。此处使用的“起泡剂”指的是任何当包含于亲脂性流体(如硅氧烷)洗涤介质中时,在自动洗衣机运转过程中产生明显的气泡作用的化合物和/或化合物的混合物。因此起泡剂还包括作为顽固泡沫或泡沫助促进剂的物质,以及选择具有气泡特性的表面活性剂和/或乳化剂。通常泡沫的性质是众所周知的,已描述在如Lai和Dixit著的“Additives for Foams”,Foams,Theory,Measurements,and Applications(Marcel Dekker,inc.,N.Y.1996年出版;Prud’homme和Khan编辑,315页)中。
特别是,既可通过加入含一种或多种起泡剂的组合物,所述组合物被典型地加入以将清洗剂(如表面活性剂,聚合物,酶,漂白剂)和/或织物处理剂(如柔软剂,抗静电剂,增白剂)传递给洗涤过程来将起泡剂加入到亲脂性流体洗涤过程,也可通过加入单独的起泡剂组合物(类似于在自动分离洗衣机中单独加入“漂洗助剂”)将起泡剂加入到亲脂性流体洗涤过程。这类起泡剂不仅在这类组合物中必须是稳定的,并且与要接触的其它添加剂成分相容,而且如果其从洗涤介质沉积到与洗涤介质接触的织物上,不会对织物产生负面影响。
该起泡剂可被用于该方法的自动洗衣机的亲脂性流体(尤其是硅氧烷溶剂)回收体系除去(如通过过滤和/或蒸馏),和/或该起泡剂易于被在洗涤过程中利用的其它条件破坏(完全或至少很大部分)也是非常理想的。可通过任何方式,包括但不局限于以化学方式(如氧化和/或还原反应),机械方式(如超声),电方式,和/或热降解方式破坏起泡剂。这包括,例如通过利用体系中的臭氧或在加热步骤如干燥织物过程中来破坏起泡剂。备选地,如果在回收亲脂性流体后再利用起泡剂,这类起泡剂在自动洗衣机的再循环和再回收过程中稳定存在是理想的。如果与每种洗衣物一起加入到洗涤介质中的该组合物包含一定含量的起泡剂,该含量足以补充在前个洗涤周期中损失的起泡剂,则不需要完全稳定性。
也必须进行仔细的考虑以避免对洗衣机的运转产生负面影响,或使亲脂性流体(如硅氧烷溶剂)的再循环或再回收变得容易,从而设计正确的起泡性能以满足消费者的需要。因此考虑洗衣机的类型和利用的方法以确定起泡剂在洗涤介质中的含量是必要的。例如,使用较低浓度的起泡剂,利用喷雾器将洗涤介质分散到织物上的方法似乎比仅利用滚筒搅拌洗涤介质的浸渍浴方法产生更多的泡沫。本领域的技术人员可容易地选择使这种起泡性能与使用的洗衣机和方法相匹配所需要的含量。
最后,含起泡剂的组合物可包含添加的水,该组合物与亲脂性流体不混溶或易混溶(如作为一种乳状液)。典型地,以至少约0.1%(或至少约0.5%,或至少约1%)的起泡剂的含量将水加入到含亲脂性流体的洗涤介质(如硅氧烷洗涤介质)中。
方法
关于本发明的方法,将含硅氧烷的洗涤介质与纺织品相接触的方法可以是任何一种方法,其与点状润湿和/或手工润湿纺织品相反,通过自动洗衣机,以洗涤量完全润湿纺织品。这包括在洗涤介质的浸渍浴中接触纺织品,或优选按照小体积润湿方法如喷涂,使用尽可能较小体积的洗涤介质以均匀润湿纺织品。最优选的是用一种方法接触纺织品,所述方法包含至少一个非浸渍步骤,从而用洗涤介质以洗涤量润湿(优选通过均匀的喷涂)纺织品,所述洗涤介质例如仅为少于约200%(或少于约150%)重量的纺织品。
本发明的一个方面涉及用洗涤介质接触纺织品,所述洗涤介质包含少于约50%水,更优选少于约30%,少于约20%,少于约10%,少于约5%,少于约1%,最优选不含有目的地加入的水。然而,在本发明的另一个方面,一些有目的地加入的水是含有硅氧烷的洗涤介质的一部分,该洗涤介质包括例如或者与硅氧烷不混溶或者作为一种含硅氧烷、水和乳化剂的乳状液。优选水的含量为约0.1%-约50%,更优选约0.1%-约30%,约0.1%-约20%,约0.1%-约10%,约0.1%-约5%,约0.1%-约1%。
明显地,本发明的方法不能使用为水洗方法开发的当前通用的自动洗衣机。而用于本方法的自动洗衣机可连接一个水源,为了实施通用的方法,这个连接只是为了供应任选有目的地加入的水。提供硅氧烷是必需的,优选将硅氧烷存储于在通用方法中使用的容器中,并且在自动家庭洗衣过程中,硅氧烷接触纺织品后返回(适当的清洗过程之后)到该容器中。
尽管具有所定义的适于非浸渍商业干洗方法的各种组分的装置(所述方法例如描述在2000年5月9日公布的美国专利6,059,845和2000年5月16日公布的美国专利6,063,135中所描述(两篇专利均全文引入本文作为参考)),如果加以改良以适于居住大小和消费者维护,该装置可用于实施本发明的方法,但对于本发明的非浸渍方法来说并不是优选的。原因包括与在家庭供应、储存和清洗大体积的硅氧烷有关的一些制约(相对于在这些专利中教导的商业干洗机的尺寸和操作而言)。
由于这些原因,高度优选较小体积方法如上文描述的那些利用均匀喷涂方法的方法,所述均匀喷涂方法利用较小体积的洗涤介质即可完全润湿纺织品。例如可考虑对传统的低水位洗涤器具进行改良以传递低含量的含硅氧烷的洗涤介质而不是含水的洗涤介质;这类传统的水洗涤器具在例如美国专利4,489,574;4,489,455;5,191,669;5,191,668;5,233,718;和5,671,494中进行描述,所有这些均全文引入本文作为参考。具有这种低体积方法用途的最优选的自动洗衣机在共同提交的、共同待决的专利申请宝洁公司案例8119P中详细地进行了描述,该专利申请全文引入本文作为参考。进一步优选的是这类自动洗衣机,即通过随机翻转后,间歇性的旋转和喷涂,直至已喷涂所有的洗涤介质,可保证用含硅氧烷的洗涤介质均匀地覆盖纺织品。还优选这类洗衣机,它通过紧接地再利用/再循环步骤,例如通过在将洗涤介质从纺织品中提取出来以后,将其通过颗粒去除过滤器,然后立即将其再喷涂到纺织品上而再利用该含硅氧烷的洗涤介质。
还优选适于实施本发明方法的自动洗衣机是为了在同一个装置内还可干燥纺织品而设计的自动洗衣机。这不仅赋予消费者不用处理湿纺织品的便利,还能够为了再利用或清洗而回收所有的硅氧烷。
还可想象按照消费者的愿望,适于清洗和/或处理纺织品的添加剂也可加入到该方法中。因此,自动洗衣机优选包括贮器来在理想的时间将这类添加剂,与洗涤介质一同或分开,接受和/或分配到自动洗衣过程中。包含这类添加剂的机筒(通过再充填或与添加剂一起购买),其可拆卸地安装到机器上,也是任选的实施方式。特别优选的添加剂是在当前自动家庭洗衣过程中,当与含硅氧烷的洗涤介质结合时,可充当一种抗静电剂的任何物质。
该自动洗衣机的另一个优选的特征是能够有多于一个自动洗衣步骤来净化和再利用硅氧烷。净化硅氧烷以多次使用的优选的工具是可替换的过滤器。这种过滤器应当优选包括过滤物质,其能去除并收集至少身体污垢,所述身体污垢是在自动家庭洗衣过程中从纺织品上去除的。活性炭、硅石、分子筛和/或疏水改性纸正好是这类过滤器的一些任选组分。优选用装置固定到自动洗衣机上,使得消费者每隔一定间隔可容易地替换它。
虽然已描述了本发明的具体实施方案,但对那些本领域的技术人员来说,明显地,在未脱离本发明的精神和范围条件下,可对本发明进行各种改变和修改。在后附的权利要求中,意图包含在本发明范围内的所有这类修改。
Claims (40)
1.一种织物护理组合物,其包含:
a)所述组合物重量的至少50%的一种亲脂性流体,选自全氟化胺,C6或更高级二醇,有机硅氧烷,多元醇酯,和它们的混合物;和
b)一种香料组合物;
其中所述组合物包含少于所述组合物重量的30%的水。
2.按照权利要求1的织物护理组合物,其中所述香料组合物包含一种持久香料成分,所述持久香料成分选自耐久香料成分,低气味检测阈香料成分和它们的混合物。
3.按照权利要求1的织物护理组合物,其中所述亲脂性流体包含一种线性硅氧烷。
4.按照权利要求3的织物护理组合物,其中所述亲脂性流体包含一种环状硅氧烷。
5.按照权利要求4的织物护理组合物,其中所述环状硅氧烷选自八甲基环四硅氧烷,十甲基环五硅氧烷,十二甲基环六硅氧烷和它们的混合物。
6.按照权利要求5的织物护理组合物,其中所述环状硅氧烷包含十甲基环五硅氧烷。
7.按照权利要求6的织物护理组合物,其中所述环状硅氧烷基本上不含八甲基环四硅氧烷。
8.按照权利要求7的织物护理组合物,其中所述环状硅氧烷包含少于所述十甲基环五硅氧烷重量的5%的八甲基环四硅氧烷。
9.按照权利要求2的织物护理组合物,其中所述香料组合物包含一种耐久香料成分。
10.按照权利要求9的织物护理组合物,其中所述耐久香料成分选自:环己基丙酸烯丙酯,黄葵内酯,苯甲酸戊酯,肉桂酸戊酯,戊基肉桂醛,戊基肉桂醛二甲缩醛,异水杨酸戊酯,羟基香茅醛-甲基邻氨基苯甲酸酯,二苯酮,水杨酸苄酯,异丁基喹啉,β-石竹烯,荜澄茄烯,雪松醇,乙酸柏木酯,甲酸柏木酯,肉桂酸肉桂酯,水杨酸环己酯,仙客来醛,二氢异茉莉酮酸酯,二苯甲烷,苯醚,十二内酯,1-(1,2,3,4,5,6,7,8-八氢-2,3,8,8-四甲基-2-萘基)-乙酮,巴西酸亚乙基酯,缩水甘油酸乙基甲基苯酯,十一烯酸乙酯,异丁子香酚,15-羟基十五烷酸内酯,1,3,4,6,7,8-六氢-4,6,6,7,8,8-六甲基环戊二烯并-γ-2-苯并吡喃,邻氨基苯甲酸香叶酯,十六醇一化物,水杨酸己烯酯,己基肉桂醛,水杨酸己酯,对-叔-丁基-α-甲基氢化肉桂醛,苯甲酸芳樟酯,2-甲氧基萘,肉桂酸甲酯,二氢茉莉酮酸甲酯,β-甲基·萘基酮,麝香2,3-二氢-2-茚酮,麝香酮,西藏麝香,肉豆蔻醚,δ-壬内酯,氧杂十六内酯-10,氧杂十六内酯-11,绿叶醇,5-乙酰基-1,1,2,3,3,6-六甲基茚满,苯甲酸苯乙酯,苯乙酸苯乙酯,苯庚醇,苯己醇,α-檀香醇,15-羟基十五烷酸,内酯,吐纳麝香,δ-十一内酯,γ-十一内酯,乙酸岩兰草酯,β-萘基甲基醚,苯氧乙酸烯丙酯,肉桂醇,肉桂醛,甲酸肉桂酯,香豆素,乙酸二甲基苄基原酯,肉桂酸乙酯,乙基香兰素(3-甲氧基-4-乙氧基苯甲醛),丁子香酚,乙酸丁子香酚酯,天芥菜精,吲哚醇,异丁子香酚,乙酰二异戊烯,甲基-β-萘酮,肉桂酸甲酯,二氢茉莉酮酸甲酯,β-甲基·萘基酮,甲基-n-甲基氨茴酸酯,δ-壬内酯,γ-壬内酯,对甲氧基乙酰苯(乙酰茴香醚),异丁酸苯氧基乙酯,丙酸苯氧基乙酯,胡椒醛,柠檬酸三乙酯,香兰素,甲基-N-甲基氨茴酸酯,丁酸苄酯,异戊酸苄酯,异丁酸香茅酯,丙酸香茅酯,δ-壬内酯,乙酸二甲基苄基原酯,十二醛,牻牛儿醇乙酸酯,异丁酸牻牛儿酯,γ-紫罗兰酮,对异丙基苯乙醛,顺茉莉酮,丁子香酚甲醚,羟基香茅醛,苯氧基乙醇,异戊酸苄酯,茴香醛,枯茗醇,顺茉莉酮,丁子香酚甲醚,和它们的混合物。
11.按照权利要求9的织物护理组合物,其中所述耐久香料成分具有240℃或更高的沸点。
12.按照权利要求11的织物护理组合物,其中所述耐久香料成分具有250℃或更高的沸点。
13.按照权利要求2的织物护理组合物,其中所述香料组合物包含一种低气味检测阈香料成分。
14.按照权利要求13的织物护理组合物,其中所述低气味检测阈香料成分选自戊基甘醇酸烯丙酯,降龙涎香醚,茴香脑,2-乙基-4-(2,2,3-三甲基-3-环戊烯-1-基)-2-丁烯-1-醇,苄基丙酮,水杨酸苄酯,邻氨基苯甲酸丁酯,calone,cetalox,肉桂醇,香豆素,cyclogalbanate,女贞醛,a-甲基-4-(1-甲基乙基)-苯丙醛,大马烯酮,α-二氢大马酮,4-癸烯醛,二氢异茉莉酸酮酯,γ-十二内酯,黑檀醇,邻氨基苯甲酸乙酯,乙基-2-甲基丁酸酯,缩水甘油酸乙基甲基苯酯,乙基香兰素,丁子香酚,3a,4,5,6,7,7a-六氢-8,8-二甲基-4,7-亚甲基-1H-茚-6-酚乙酸酯,花青醛,乙酸乙基甲基二噁茂烷酯,3a,4,5,6,7,7a-六氢-8,8-二甲基-4,7-亚甲基-1H-茚-6-酚丙酸酯,天芥菜精,3,3,5-三甲基环己基乙基醚,顺-3-己烯基水杨酸酯,吲哚,α-紫罗兰酮,β-紫罗兰酮,异环柠檬醛,异丁子香酚,α-异甲基紫罗兰酮,可翁酮,铃兰醛,里哪醇,2-羟基-2-甲基-6-(3,4-二氢环己醛),邻氨基苯甲酸甲酯,二氢茉莉酮酸甲酯,2-辛炔酸甲酯,四氢吡喃甲基异丁烯酯,甲基·β-萘基酮,甲基·壬基酮,β-萘甲醚,橙花醇,对-茴香醛,对-羟基苯基丁酮,苯乙醛,γ-十一内酯,十一烯醛和它们的混合物。
15.按照权利要求1的织物护理组合物,其中所述织物护理组合物包含所述组合物重量的0.01%-5%的所述香料组合物。
16.按照权利要求15的织物护理组合物,其中所述织物护理组合物包含所述组合物重量的0.1%-4%的所述香料组合物。
17.按照权利要求16的织物护理组合物,其中所述织物护理组合物包含所述组合物重量的0.3%-3%的所述香料组合物。
18.按照权利要求17的织物护理组合物,其中所述织物护理组合物包含所述组合物重量的0.4%-2%的所述香料组合物。
19.按照权利要求2的织物护理组合物,其中所述香料组合物包含所述香料组合物重量的至少25%的所述持久香料成分。
20.按照权利要求19的织物护理组合物,其中所述香料组合物包含所述香料组合物重量的至少40%的所述持久香料成分。
21.按照权利要求20的织物护理组合物,其中所述香料组合物包含所述香料组合物重量的至少60%的所述持久香料成分。
22.按照权利要求21的织物护理组合物,其中所述香料组合物包含所述香料组合物重量的至少75%的所述持久香料成分。
23.按照权利要求1的织物护理组合物,其中所述组合物包含所述组合物重量的0.0001%-0.2%的所述香料组合物。
24.按照权利要求23的织物护理组合物,其中所述组合物包含所述组合物重量的0.0002%-0.1%的所述香料组合物。
25.按照权利要求24的织物护理组合物,其中所述组合物包含所述组合物重量的0.003%-0.08%的所述香料组合物。
26.按照权利要求25的织物护理组合物,其中所述组合物包含所述组合物重量的0.005%-0.05%的所述香料组合物。
27.按照权利要求1的织物护理组合物,其中所述组合物包含所述组合物重量的至少50%或更多的所述亲脂性流体。
28.按照权利要求27的织物护理组合物,其中所述组合物包含所述组合物重量的50%-100%的所述亲脂性流体。
29.按照权利要求1的织物护理组合物,其中所述组合物包含所述组合物重量的0.1%-30%的水。
30.按照权利要求1的织物护理组合物,其中所述组合物进一步包含一种乳化剂。
31.一种将香料组合物传递给织物的方法,其包含用按照权利要求1的织物护理组合物接触所述织物,使得有效量的所述香料组合物被传递给所述织物。
32.一种香料传递体系,其包含:
a)所述体系重量的至少50%的一种亲脂性流体,选自全氟化胺,C6或更高级二醇,有机硅氧烷,多元醇酯,和它们的混合物;和
b)一种香料组合物;
其中所述香料组合物通过接触织物被传递给所述织物,
并且其中包含少于所述体系重量的30%的水。
33.一种香料传递体系,其包含:
a)所述体系重量的至少50%的一种亲脂性流体,选自全氟化胺,C6或更
高级二醇,有机硅氧烷,多元醇酯,和它们的混合物;和
b)一种香料组合物,其包含选自耐久香料成分、低气味检测阈香料成分
和它们的混合物的持久香料成分;
其中所述香料组合物通过接触织物被传递给所述织物,
并且其中包含少于所述体系重量的30%的水。
34.一种生产的制品,其包含按照权利要求1的织物护理组合物,其与使用所述织物护理组合物来处理需要处理的织物的用法说明书包装在一起,所述处理包含用所述织物护理组合物接触所述织物的步骤。
35.权利要求31的方法,其中所述织物由纤维制成,所述纤维选自天然纤维,合成纤维和它们的混合物。
36.权利要求31的方法,其中所述织物由纤维制成,所述纤维选自纤维素纤维,蛋白质纤维,合成纤维,长植物纤维和它们的混合物。
37.权利要求36的方法,其中所述纤维素纤维选自棉,人造丝,亚麻,Tencel,复/棉和它们的混合物;其中所述蛋白质纤维选自丝绸,羊毛和相关的哺乳动物纤维和它们的混合物;其中所述合成纤维选自聚酯,丙烯酸树脂,尼龙和它们的混合物;和其中所述长植物纤维选自黄麻,亚麻,苎麻,椰纤维,爪哇木棉,剑麻,灰叶剑麻,蕉麻,***,印度麻和它们的混合物。
38.权利要求31的方法,其中所述织物选自棉,人造丝,亚麻,聚酯/棉混合物,丝绸,羊毛,聚酯,丙烯酸树脂,尼龙,和它们的混合物。
39.权利要求31的方法,其中的接触步骤包含用该织物护理组合物的蒸汽相接触需要处理的织物的步骤。
40.权利要求31的方法,其中的接触步骤包含用该织物护理组合物接触需要处理的所述织物,使得当将所述织物护理组合物置于碰撞气体流时,其中的香料组合物被涂布到所述织物上。
Applications Claiming Priority (20)
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US20946800P | 2000-06-05 | 2000-06-05 | |
US20925000P | 2000-06-05 | 2000-06-05 | |
US20944400P | 2000-06-05 | 2000-06-05 | |
US20944300P | 2000-06-05 | 2000-06-05 | |
US60/209,468 | 2000-06-05 | ||
US60/209,250 | 2000-06-05 | ||
US60/209,443 | 2000-06-05 | ||
US60/209,444 | 2000-06-05 | ||
US24713500P | 2000-11-09 | 2000-11-09 | |
US60/247,135 | 2000-11-09 | ||
US09/849,893 | 2001-05-04 | ||
US09/849,842 US6828292B2 (en) | 2000-06-05 | 2001-05-04 | Domestic fabric article refreshment in integrated cleaning and treatment processes |
US09/849,839 US6840963B2 (en) | 2000-06-05 | 2001-05-04 | Home laundry method |
US09/849,844 US6670317B2 (en) | 2000-06-05 | 2001-05-04 | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
US09/849,893 US6691536B2 (en) | 2000-06-05 | 2001-05-04 | Washing apparatus |
US09/849,844 | 2001-05-04 | ||
US09/849,839 | 2001-05-04 | ||
US09/849,843 | 2001-05-04 | ||
US09/849,842 | 2001-05-04 | ||
US09/849,843 US6939837B2 (en) | 2000-06-05 | 2001-05-04 | Non-immersive method for treating or cleaning fabrics using a siloxane lipophilic fluid |
Publications (2)
Publication Number | Publication Date |
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CN1433461A CN1433461A (zh) | 2003-07-30 |
CN1254527C true CN1254527C (zh) | 2006-05-03 |
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CNB018107206A Expired - Fee Related CN1254527C (zh) | 2000-06-05 | 2001-06-05 | 在亲脂性流体处理过程中传递清洁清新气味的织物护理组合物和体系 |
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EP (1) | EP1290132B1 (zh) |
JP (1) | JP4828081B2 (zh) |
CN (1) | CN1254527C (zh) |
AT (1) | ATE393815T1 (zh) |
AU (2) | AU2001268214B2 (zh) |
BR (1) | BR0111401A (zh) |
CA (1) | CA2408936A1 (zh) |
CZ (1) | CZ20023983A3 (zh) |
DE (1) | DE60133813T2 (zh) |
MX (1) | MXPA02011958A (zh) |
WO (1) | WO2001094521A1 (zh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6734153B2 (en) | 2001-12-20 | 2004-05-11 | Procter & Gamble Company | Treatment of fabric articles with specific fabric care actives |
US7723417B2 (en) * | 2004-03-25 | 2010-05-25 | 3M Innovative Properties Company | Fluorochemical composition and method for treating a substrate therewith |
JP5557986B2 (ja) * | 2008-04-14 | 2014-07-23 | 花王株式会社 | 繊維製品処理剤組成物 |
EP2216394A1 (en) * | 2009-01-30 | 2010-08-11 | The Procter & Gamble Company | Method for perfuming fabrics |
WO2012037122A2 (en) * | 2010-09-13 | 2012-03-22 | Segetis, Inc. | Fabric softener compositions and methods of manufacture thereof |
WO2012082624A2 (en) * | 2010-12-17 | 2012-06-21 | Dow Global Technologies Llc | Ethylene acrylic acid copolymer aqueous dispersions for fragrance release in laundry detergents |
EP2708592B2 (en) | 2012-09-14 | 2022-03-16 | The Procter & Gamble Company | Fabric care composition |
GB201218447D0 (en) * | 2012-10-15 | 2012-11-28 | Givaudan Sa | Organic compounds |
JP2014136849A (ja) | 2013-01-18 | 2014-07-28 | Toray Opelontex Co Ltd | ポリウレタン繊維 |
EP2907913B1 (en) * | 2014-02-12 | 2016-09-14 | Sanflor S.r.l. | A perfuming element for garments usable in dry cleaning, and a relative dry-cleaning process |
CN106221911A (zh) * | 2016-08-03 | 2016-12-14 | 广州爱普香精香料有限公司 | 一种香味组合物及其应用 |
US11788918B2 (en) | 2020-06-18 | 2023-10-17 | Trevillyan Labs, Llc | Fluid detection fabric |
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DE3366382D1 (en) * | 1982-04-02 | 1986-10-30 | Hollygrange Ltd | Dry cleaning process |
DE3311642A1 (de) * | 1983-02-11 | 1984-10-11 | Dr. O. Martens & Co Nachf., 8021 Baierbrunn | Geruchsverbesserer, verfahren zu seiner herstellung und verwendung des geruchsverbesserers |
DE3739711A1 (de) * | 1987-11-24 | 1989-06-08 | Kreussler Chem Fab | Verwendung von polydialkylcyclosiloxanen als loesemittel fuer die chemischreinigung |
US5057240A (en) * | 1989-10-10 | 1991-10-15 | Dow Corning Corporation | Liquid detergent fabric softening laundering composition |
SU1705444A1 (ru) * | 1990-04-09 | 1992-01-15 | Омский технологический институт бытового обслуживания | Состав дл химической чистки одежды в среде органических растворителей |
JPH04311799A (ja) * | 1991-04-10 | 1992-11-04 | Nikko Kyodo Co Ltd | 石油系ドライクリ−ニング用溶剤 |
US5160494A (en) * | 1992-04-14 | 1992-11-03 | Dow Corning Corporation | Alkylmethylsiloxane containing perfume compositions |
CN1069064A (zh) * | 1992-05-29 | 1993-02-17 | 湖北省荆门市再生资源开发公司 | 织物喷雾干洗剂及其制法 |
US5630847A (en) * | 1995-03-30 | 1997-05-20 | The Procter & Gamble Company | Perfumable dry cleaning and spot removal process |
US5779933A (en) * | 1995-04-25 | 1998-07-14 | Chisso Corporation | Liquid crystal composition and liquid crystal display element |
DE29600628U1 (de) * | 1996-01-16 | 1997-05-15 | Oellig, Alexander, 66117 Saarbrücken | Verdampferflüssigkeit für Dampfbügeleisen |
CN1233282A (zh) * | 1996-08-19 | 1999-10-27 | 普罗格特-甘布尔公司 | 包含β-酮酯香料前体的洗衣洗涤剂组合物 |
US5942007A (en) * | 1997-08-22 | 1999-08-24 | Greenearth Cleaning, Llp | Dry cleaning method and solvent |
EP1075560A1 (en) * | 1998-04-27 | 2001-02-14 | The Procter & Gamble Company | Wrinkle and malodour reducing composition |
CA2330380A1 (en) * | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Wrinkle reducing composition |
CA2329663A1 (en) * | 1998-04-27 | 1999-11-04 | Toan Trinh | Fabric wrinkle control composition and method |
US6034051A (en) * | 1998-05-26 | 2000-03-07 | International Flavors & Fragrances Inc. | Three-dimensional expandable sponge article useful for (i) de-wrinkling and (ii) aromatizing and/or freshening clothing and/or linens, uses thereof and process for preparing same |
BR9914801A (pt) * | 1998-10-24 | 2001-07-10 | Procter & Gamble | Método para lavagem de roupas delicadas em uma máquina de lavar |
DE60011691T2 (de) * | 1999-03-31 | 2005-07-07 | General Electric Co. | Zusammensetzung und Verfahren zum Chemischreinigen |
US6310029B1 (en) * | 1999-04-09 | 2001-10-30 | General Electric Company | Cleaning processes and compositions |
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2001
- 2001-06-05 CZ CZ20023983A patent/CZ20023983A3/cs unknown
- 2001-06-05 BR BR0111401-8A patent/BR0111401A/pt not_active IP Right Cessation
- 2001-06-05 EP EP01946129A patent/EP1290132B1/en not_active Expired - Lifetime
- 2001-06-05 AU AU2001268214A patent/AU2001268214B2/en not_active Ceased
- 2001-06-05 CA CA002408936A patent/CA2408936A1/en not_active Abandoned
- 2001-06-05 MX MXPA02011958A patent/MXPA02011958A/es not_active Application Discontinuation
- 2001-06-05 AT AT01946129T patent/ATE393815T1/de not_active IP Right Cessation
- 2001-06-05 CN CNB018107206A patent/CN1254527C/zh not_active Expired - Fee Related
- 2001-06-05 WO PCT/US2001/018318 patent/WO2001094521A1/en active IP Right Grant
- 2001-06-05 DE DE60133813T patent/DE60133813T2/de not_active Expired - Lifetime
- 2001-06-05 AU AU6821401A patent/AU6821401A/xx active Pending
- 2001-06-05 JP JP2002502064A patent/JP4828081B2/ja not_active Expired - Fee Related
Also Published As
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DE60133813D1 (de) | 2008-06-12 |
AU2001268214B2 (en) | 2005-02-24 |
AU6821401A (en) | 2001-12-17 |
CZ20023983A3 (cs) | 2003-04-16 |
BR0111401A (pt) | 2003-06-03 |
DE60133813T2 (de) | 2009-06-25 |
WO2001094521A1 (en) | 2001-12-13 |
ATE393815T1 (de) | 2008-05-15 |
CN1433461A (zh) | 2003-07-30 |
JP4828081B2 (ja) | 2011-11-30 |
EP1290132A1 (en) | 2003-03-12 |
CA2408936A1 (en) | 2001-12-13 |
MXPA02011958A (es) | 2003-04-22 |
JP2003535987A (ja) | 2003-12-02 |
EP1290132B1 (en) | 2008-04-30 |
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