CN1160409C - High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process - Google Patents
High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Download PDFInfo
- Publication number
- CN1160409C CN1160409C CNB991139321A CN99113932A CN1160409C CN 1160409 C CN1160409 C CN 1160409C CN B991139321 A CNB991139321 A CN B991139321A CN 99113932 A CN99113932 A CN 99113932A CN 1160409 C CN1160409 C CN 1160409C
- Authority
- CN
- China
- Prior art keywords
- impact
- abs
- resistant
- butadiene
- flowability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 38
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000006229 carbon black Substances 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000005516 engineering process Methods 0.000 claims abstract description 6
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 12
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 12
- 239000004609 Impact Modifier Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- 229920001897 terpolymer Polymers 0.000 abstract 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 230000005611 electricity Effects 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 6
- 230000035939 shock Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- ZUROCNHARMFRKA-UHFFFAOYSA-N 4,5-dibromo-1h-pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC(Br)=C(Br)N1 ZUROCNHARMFRKA-UHFFFAOYSA-N 0.000 description 1
- 101100431668 Homo sapiens YBX3 gene Proteins 0.000 description 1
- 102100022221 Y-box-binding protein 3 Human genes 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/919—Thermal treatment of the stream of extruded material, e.g. cooling using a bath, e.g. extruding into an open bath to coagulate or cool the material
Landscapes
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The present invention relates to a high-fluidity impact-resistant conductive acrylonitrile-butadiene-styrene terpolymer (ABS) material and a preparation technology thereof. The material comprises the formula of the following weight percentage: 60 to 65 wt% of ABS, 15 to 25 wt% of carbon black, 15 to 20 wt% of impact-resistant modifying agent, 0.1 to 0.2 wt% of antioxidant and 0.2 to 0.3 wt% of ultraviolet absorbent. The components with the content are mixed by putting into a high mixer; then, the mixture is put into a double-screw extruder and is extruded; the extruded material is cooled by water and is granulated, and the material granules are dried to obtain the terpolymer material. Compared with the prior art, the terpolymer material of the present invention has the advantages of high fluidity, high impact resistance, conductivity, etc.
Description
The present invention relates to a kind of engineering plastic materials and preparation technology thereof, relate in particular to a kind of high-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and preparation technology thereof.
Acrylonitrile-butadiene-styrene terpolymer (ABS) resin is widely used in the parts such as shell of making phone, computer, televisor etc. owing to have good mechanical property and surface luster in household electric appliances such as electronics, communication.Yet because common ABS resin is an insulating material, its volume and surface resistivity are all higher, therefore the surface of goods is easily because of former thereby generation static charges such as frictions, can make the easy dust suction of product surface so on the one hand and influence outward appearance, thereby the static charge of gathering on the other hand can produce the works better that spark discharge influences semiconductor integrated circuit, and is serious even the person of manipulating is got shocked.In addition, extraneous interference hertzian wave passes insulating ABS shell easily and influences the works better of internal circuitry, on the other hand, thereby the signals such as hertzian wave that system such as computer, phone produces when work also can disturb the works better of other electronics Circuits System on every side to external irradiation, even influence the physiological well-being of human body.After giving the ABS resin certain electric conductivity, can eliminate on the one hand the harm of static charge that product surface gathers to human body, can play the effect of shielding electromagnetic wave on the other hand, effectively prevent of the interference of external electromagnetic ripple to circuitry system works better.
At present, countries in the world mainly are electroconductive stuffings such as filler metal powder, fiber and graphite, carbon black, carbon fiber in the ABS resin matrix about the development and production of conduction ABS.But metal-powder, fiber have easily oxidation of surface, are difficult for processing, and weight is big, to shortcomings such as the mechanical mechanics property deterioration of material are serious, have seriously restricted its application.In addition, the resistance of graphite is bigger, and electroconductibility is relatively poor, and the price of carbon fiber is more expensive, these factor affecting they in industrial widespread use.At present, carbon black filled ABS is a kind of method commonly used, still, because the adhesive property of carbon black and ABS matrix is relatively poor, can cause the shock resistance and the flowing property of carbon black filled back matrix material sharply to reduce, have a strong impact on the final result of use of Drawing abillity and goods.
Purpose of the present invention is exactly to provide a kind of preparation with conduction ABS material of good processing flowability energy and shock resistance for the defective that overcomes above-mentioned prior art existence.
Purpose of the present invention can realize in the following manner:
A kind of high-flowability, impact-resistant and electrically conductive acrylonitrile-butadiene-styrene terpolymer (ABS) material is characterized in that: described material prescription following (weight percentage):
ABS 60～65
Carbon black 15～25
Impact modifier 15～20
Oxidation inhibitor 0.1～0.2
UV light absorber 0.2～0.3
Described impact modifier is a thermoplastic polyester elastomer.
Described impact modifier is thermoplastic polyurethane TPU.
Described impact modifier is the grafts MBS of nucleocapsid structure.
A kind of preparation technology of high-flowability, impact-resistant and electrically conductive ABS material, it is characterized in that: above-mentioned each component was placed high-speed mixer and mixing 1～2 minute, then material is placed the hopper of twin screw extruder, the screw zones temperature is 210～240 ℃, screw speed is 300rpm, and the material of extruding obtains product after water-cooled, pelletizing, drying.
Compared with prior art, difference of the present invention is to adopt graphitized carbon black as conductive filler material, and at ABS---correctly selected several classes and ABS resin to have the polymer impact modifier of excellent compatibility in the carbon black system, as thermoplastic polyester elastomer, thermoplastic polyurethane TPU, grafts MBS with nucleocapsid structure is as toughner, improved the shock resistance of carbon black filled ABS matrix material on the one hand, improve the processing flowability of this matrix material on the other hand greatly, satisfied the needs of making the big parts goods of complex construction.
Below in conjunction with embodiment, the present invention is described in further detail:
Embodiment 1～3:
With ABS is base-material, and this ABS resin is the high fluent material of high tenacity.(MI=3～4g/10min), the simply supported beam notched Izod impact strength is 25～35kJ/m to melting index
2, tensile strength is 40～60MPa.With the thermoplastic polyester elastomer is toughner, and this elastomerics is the HYTREL4533 of Du Pont, and its fracture tensile strength is 30MPa, and elongation at break is 600%, and the Izod notch shock is continuous.Melt and refer to 8.5g/10min, 193 ℃ of fusing points, 158 ℃ of Vicat softening points.As electroconductive stuffing, this carbon black specific surface is 254m with carbon black
2/ g, particle diameter are 30 μ m, and the DBPA value reaches 188cm
3/ 100g, density 97g/l.Each composition component content of its blend is listed in the table one.Each component of above-mentioned content was placed high-speed mixer and mixing 1～2 minute, then material is placed the hopper of twin screw extruder, the screw zones temperature is 210～240 ℃.Screw speed is 300rpm.Material after extruding is through water-cooled, and pelletizing obtains product after the drying.This particulate product is injection molded into the standard batten for performance test, and test result is listed in the table two.
Table one high-impact, the high component concentration that flows, conducts electricity the ABS material
| Component concentration (weight part) | 1 2 3 |
| The HYTREL4533 of ABS Du Pont carbon black oxidation inhibitor UV light stabilizing agent adds up to | 600 620 650 200 180 150 200 200 200 2 2 2 2 2 2 1004 1004 1004 |
Table two high-impact, high electricity, the mechanical property that flows, conducts electricity the ABS material
| Performance | 1 2 3 |
| Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | 1.8 2.2 1.6 32 32.4 33.8 12.3 11.8 9.1 34 34.2 36.5 2100 2110 2280 10 5～10 7 10 5～10 7 10 5～10 7 0.9～1.0 0.9 0.9 |
Embodiment 4-6:
With ABS is base-material (material property is identical with embodiment 1), and thermoplastic polyurethane TPU is a toughner, and carbon black is as electroconductive stuffing (identical with embodiment 1), and each composition component content of its blend is listed in the table three.Each component of above-mentioned content was placed high-speed mixer and mixing 1～2 minute, then material is placed the hopper of twin screw extruder, the screw zones temperature is 210～240 ℃.Screw speed is 300rpm.Material after extruding is through water-cooled, and pelletizing obtains product after the drying.This particulate product is injection molded into the standard batten for performance test, and test result is listed in the table four.
Table three high-impact, the high component concentration that flows, conducts electricity the ABS material
| Component concentration (weight part) | 1 2 3 |
| ABS thermoplastic polyurethane TPU carbon black oxidation inhibitor UV light stabilizing agent adds up to | 600 620 650 200 180 150 200 200 200 2 2 2 2 2 2 1004 1004 1004 |
Table four high-impact, high electricity, the mechanical property that flows, conducts electricity the ABS material
| Performance | 1 2 3 |
| Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | 3.8 3.2 2.6 36.4 39.8 43.8 14.3 13.8 15.1 32.5 33.2 34.5 2000 2010 2080 10 5～10 7 10 5～10 7 10 5～10 7 0.9～1.0 0.9 0.9 |
Embodiment 7-8:
With ABS is base-material (material property is identical with embodiment 1), the grafts MBS of nuclear-shell structure (being U.S. ROHM HASS company product) is a toughner, carbon black is as electroconductive stuffing (identical with embodiment 1), and each composition component content of its blend is listed in the table five.Each component of above-mentioned content was placed high-speed mixer and mixing 1～2 minute, then material is placed the hopper of twin screw extruder, the screw zones temperature is 210～240 ℃.Screw speed is 300rpm.Material after extruding is through water-cooled, pelletizing, and drying obtains product.To be injection molded into the standard batten behind this particulate product for performance test, test result is listed in the table six.
Table five high-impact, the high component concentration that flows, conducts electricity the ABS material
| Component concentration (weight part) | 1 2 |
| The grafts MBS carbon black oxidation inhibitor UV light stabilizing agent of ABS nuclear-shell structure adds up to | 600 650 200 150 200 200 2 2 2 2 1004 1004 |
Table six high-impact, high electricity, the mechanical property that flows, conducts electricity the ABS material
| Performance | 1 2 |
| Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | 1.8 1.2 38.4 40.1 12.7 11.8 34.5 36.2 2100 2210 10 5～10 7 10 5～10 7 0.8 0.7 |
In a word, thermoplastic polyester elastomer, the thermoplastic polyurethane TPU of-hard segment structure soft to have, and the grafts MBS with nuclear-shell structure is as toughner, when keeping the material conductivity, improved the shock resistance of carbon black filled ABS matrix material on the one hand, improve the processing flowability of this matrix material on the other hand greatly, satisfied the needs of making the big parts goods of complex construction; In addition, product surface resistivity of the present invention is reduced to 10
5～10
7Ω reaches the antistatic requirement of material, is specially adapted to make miscellaneous parts such as televisor, computer, phone, printer casing and electronics Turnover Box.
Claims (2)
1. high-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer is characterized in that: described material weight umber prescription is as follows:
ABS 60～65
Carbon black 15～25
Impact modifier 15～20
Oxidation inhibitor 0.1～0.2
UV light absorber 0.2～0.3
Described impact modifier is a thermoplastic polyester elastomer, or thermoplastic polyurethane TPU, or the grafts MBS of nucleocapsid structure;
Described prescription does not contain metal-powder.
2. the preparation technology of a high-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer, it is characterized in that: the described material of claim 1 was placed high-speed mixer and mixing 1～2 minute, then material is placed the hopper of twin screw extruder, the screw zones temperature is 210～240 ℃, screw speed is 300rpm, and the material of extruding obtains product after water-cooled, pelletizing, drying.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991139321A CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
| JP2001514039A JP2003529626A (en) | 1999-07-29 | 2000-06-12 | High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same |
| AU53865/00A AU5386500A (en) | 1999-07-29 | 2000-06-12 | High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof |
| PCT/CN2000/000154 WO2001009241A1 (en) | 1999-07-29 | 2000-06-12 | High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991139321A CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1282762A CN1282762A (en) | 2001-02-07 |
| CN1160409C true CN1160409C (en) | 2004-08-04 |
Family
ID=5277070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991139321A Expired - Lifetime CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2003529626A (en) |
| CN (1) | CN1160409C (en) |
| AU (1) | AU5386500A (en) |
| WO (1) | WO2001009241A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002256125A (en) * | 2001-02-28 | 2002-09-11 | Daicel Chem Ind Ltd | Conductive resin composition |
| CN102002206A (en) * | 2010-12-21 | 2011-04-06 | 四川大学 | High-glossiness high-toughness scratch resistant molding composition |
| CN102585429B (en) * | 2011-01-11 | 2015-02-25 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
| CN102582188A (en) * | 2012-02-16 | 2012-07-18 | 仙居县一远静电科技有限公司 | Antistatic ABS (Acrylonitrile Butadiene Styrene) laminated board |
| CN103360718B (en) * | 2013-07-14 | 2015-11-18 | 上海秋橙新材料科技有限公司 | anti-aging ABS-TPU plastic alloy |
| KR101860388B1 (en) | 2017-03-10 | 2018-05-24 | (주)티엘씨코리아 | ABS composition for 3D printer filament having excellent discoloration resistance and low shrinkage and filament manufactured therefrom |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52124043A (en) * | 1976-04-13 | 1977-10-18 | Kokoku Rubber Ind | Electrical conductive resin composition for plating |
| JPS5950259B2 (en) * | 1980-11-17 | 1984-12-07 | 住友ベークライト株式会社 | Resin composition for plating |
| JPS58222135A (en) * | 1982-06-19 | 1983-12-23 | Nippon Steel Chem Co Ltd | Electrically conductive resin composition |
| JPH072885B2 (en) * | 1986-10-14 | 1995-01-18 | 東レ株式会社 | Thermoplastic resin composition |
| JP2917049B2 (en) * | 1990-07-23 | 1999-07-12 | 住化エイビーエス・ラテックス株式会社 | Method for producing filler-containing resin composition |
| JPH0657153A (en) * | 1992-08-10 | 1994-03-01 | Daicel Chem Ind Ltd | Antistatic resin composition |
| JPH0665508A (en) * | 1992-08-18 | 1994-03-08 | Daicel Chem Ind Ltd | Antistatic resin composition |
| JP3465340B2 (en) * | 1994-04-01 | 2003-11-10 | Ｊｓｒ株式会社 | Thermoplastic resin composition |
| US5989723A (en) * | 1997-05-16 | 1999-11-23 | Far Eastern Textile Ltd. | Conductive polyester-based alloy sheet |
-
1999
- 1999-07-29 CN CNB991139321A patent/CN1160409C/en not_active Expired - Lifetime
-
2000
- 2000-06-12 JP JP2001514039A patent/JP2003529626A/en active Pending
- 2000-06-12 AU AU53865/00A patent/AU5386500A/en not_active Abandoned
- 2000-06-12 WO PCT/CN2000/000154 patent/WO2001009241A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CN1282762A (en) | 2001-02-07 |
| AU5386500A (en) | 2001-02-19 |
| JP2003529626A (en) | 2003-10-07 |
| WO2001009241A1 (en) | 2001-02-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS59189142A (en) | Electrically conductive thermoplastic resin composition | |
| CN100406520C (en) | Environmental-friendly fire-retardant PC/PBT plastic alloy | |
| EP0099573A1 (en) | Improved conductive resinous composites | |
| JP2005510009A (en) | Conductive thermoplastic polymer composition | |
| CN102863788A (en) | Low-surface-resistance high-glass-fiber reinforced flame-retardant nylon resin composition and preparation method thereof | |
| CN113583396B (en) | PBT composition resistant to cyclic injection molding, preparation method and product thereof | |
| CN1160409C (en) | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process | |
| CN109897347B (en) | Military electric connector insulator and preparation method thereof | |
| CN111154248A (en) | High-rigidity toughened flame-retardant PC/ABS material and preparation method thereof | |
| DE112005000429T5 (en) | Impact modified mixtures | |
| US4596669A (en) | Flame retardant thermoplastic molding compositions of high electroconductivity | |
| JP2008150485A (en) | Fiber-reinforced resin composition for molding and fiber-reinforced resin molded article | |
| CN1315933C (en) | PP and ABS nano filler alloy and preparation method thereof | |
| CN103408909B (en) | A kind of resistance to electric arc of proof voltage ageing-resistant high-performance glass fiber reinforced PC composite material and its preparation method and application | |
| CN115109350B (en) | High-performance flame-retardant HIPS material and preparation method and application thereof | |
| CN102070824A (en) | Antistatic polypropylene composition and preparation method thereof | |
| JPH02242844A (en) | Resin composition | |
| CN112724586B (en) | High-toughness low-floating-fiber ABS resin composition and preparation method and application thereof | |
| KR20190030507A (en) | Preparing Method of Concentrated Conductive Resin and Polyamide Resin Composition Using the Same | |
| KR101411017B1 (en) | High modulus and impact composite for emi shielding | |
| JPH0450344B2 (en) | ||
| CN112724572A (en) | Heat-insulating matte polyester alloy and preparation method and application thereof | |
| JP2001261975A (en) | Electroconductive thermoplastic resin composition | |
| CA1194287A (en) | Flame retardant thermoplastic molding compositions of high electroconductivity | |
| JP2003529626A5 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: SHANGHAI GENIUS NEW MATERIALS (GROUP) CO., LTD. Free format text: FORMER NAME: SHANGHAI GENIUS NEW MATERIALS CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 201109, No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee after: Shanghai Genius Advanced Material (Group) Co., Ltd. Address before: 201109 Shanghai City North Town Minhang District North Pine Road Zhugang Bridge No. 1 Patentee before: Jieshijie New Materials Co., Ltd., Shanghai |
|
| ASS | Succession or assignment of patent right |
Owner name: HEFEI GENIUS NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI GENIUS ADVANCED MATERIAL (GROUP) CO., LTD. Effective date: 20110324 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 201109 NO. 800, BEISONG ROAD, BEIQIAO TOWN, MINHANG DISTRICT, SHANGHAI TO: 230601 NO. 2388, LIANHUA ROAD, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT ZONE, HEFEI CITY, ANHUI PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110324 Address after: 230601 No. 2388 Lianhua Road, Hefei Economic Development Zone, Anhui, China Patentee after: Hefei Genius New Materials Co., Ltd. Address before: 201109, No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee before: Shanghai Genius Advanced Material (Group) Co., Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Effective date of registration: 20150810 Granted publication date: 20040804 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20161121 Granted publication date: 20040804 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Effective date of registration: 20161124 Granted publication date: 20040804 Pledgee: CITIC Bank Hefei branch Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000085 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20171020 Granted publication date: 20040804 Pledgee: CITIC Bank Hefei branch Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000085 |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20040804 |