CN1282762A - High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process - Google Patents
High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Download PDFInfo
- Publication number
- CN1282762A CN1282762A CN99113932A CN99113932A CN1282762A CN 1282762 A CN1282762 A CN 1282762A CN 99113932 A CN99113932 A CN 99113932A CN 99113932 A CN99113932 A CN 99113932A CN 1282762 A CN1282762 A CN 1282762A
- Authority
- CN
- China
- Prior art keywords
- impact
- abs
- flowability
- resistant
- electrically conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 40
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title claims abstract description 31
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title description 2
- 239000006229 carbon black Substances 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 36
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 12
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 12
- 239000004609 Impact Modifier Substances 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 230000005611 electricity Effects 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000035939 shock Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- ZUROCNHARMFRKA-UHFFFAOYSA-N 4,5-dibromo-1h-pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC(Br)=C(Br)N1 ZUROCNHARMFRKA-UHFFFAOYSA-N 0.000 description 1
- 101100431668 Homo sapiens YBX3 gene Proteins 0.000 description 1
- 102100022221 Y-box-binding protein 3 Human genes 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/919—Thermal treatment of the stream of extruded material, e.g. cooling using a bath, e.g. extruding into an open bath to coagulate or cool the material
Landscapes
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
Component concentration (weight part) | ?????1???????2???????3 |
The HYTREL4533 of ABS Du Pont carbon black oxidation inhibitor UV light stabilizing agent adds up to | ????600?????620?????650 ????200?????180?????150 ????200?????200?????200 ?????2???????2???????2 ?????2???????2???????2 ????1004????1004????1004 |
Performance | ??????1???????????2????????3 |
Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | ?????1.8????????2.2?????1.6 ?????32?????????32.4????33.8 ????12.3???????11.8?????9.1 ?????34?????????34.2????36.5 ????2100????????2110?????2280 ???10 5~10 7????10 5~107?10 5~10 7???0.9~1.0????0.9?????0.9 |
Component concentration (weight part) | ?????1??????2??????3 |
ABS thermoplastic polyurethane TPU carbon black oxidation inhibitor UV light stabilizing agent adds up to | ????600????620????650 ????200????180????150 ????200????200????200 ?????2??????2??????2 ?????2??????2??????2 ????1004???1004???1004 |
Performance | ??????1???????????2????????3 |
Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | ?????3.8????????3.2?????2.6 ????36.4???????39.8????43.8 ????14.3???????13.8????15.1 ????32.5???????33.2????34.5 ?????2000????????2010?????2080 ???10 5~10 7??10 5~10 7?10 5~10 7???0.9~1.0????0.9?????0.9 |
Component concentration (weight part) | ?????1??????2 |
The grafts MBS carbon black oxidation inhibitor UV light stabilizing agent of ABS nucleocapsid structure adds up to | ????600????650 ????200????150 ????200????200 ?????2??????2 ?????2??????2 ????1004???1004 |
Performance | ??????1?????????2 |
Molten (10g/min) hot strength (MPa) simply supported beam notched Izod impact strength (MPa) bending strength (MPa) bending modulus (MPa) surface resistivity (Ω) molding shrinkage (%) that refers to | ????1.8??????1.2 ???38.4?????40.1 ???12.7?????11.8 ???34.5?????36.2 ????2100??????2210 ??10 5~10 7??10 5~10 7????0.8??????0.7 |
Claims (5)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991139321A CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
PCT/CN2000/000154 WO2001009241A1 (en) | 1999-07-29 | 2000-06-12 | High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof |
AU53865/00A AU5386500A (en) | 1999-07-29 | 2000-06-12 | High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof |
JP2001514039A JP2003529626A (en) | 1999-07-29 | 2000-06-12 | High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991139321A CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1282762A true CN1282762A (en) | 2001-02-07 |
CN1160409C CN1160409C (en) | 2004-08-04 |
Family
ID=5277070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB991139321A Expired - Lifetime CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP2003529626A (en) |
CN (1) | CN1160409C (en) |
AU (1) | AU5386500A (en) |
WO (1) | WO2001009241A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102002206A (en) * | 2010-12-21 | 2011-04-06 | 四川大学 | High-glossiness high-toughness scratch resistant molding composition |
CN102585429A (en) * | 2011-01-11 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
CN102582188A (en) * | 2012-02-16 | 2012-07-18 | 仙居县一远静电科技有限公司 | Antistatic ABS (Acrylonitrile Butadiene Styrene) laminated board |
CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002256125A (en) * | 2001-02-28 | 2002-09-11 | Daicel Chem Ind Ltd | Conductive resin composition |
KR101860388B1 (en) | 2017-03-10 | 2018-05-24 | (주)티엘씨코리아 | ABS composition for 3D printer filament having excellent discoloration resistance and low shrinkage and filament manufactured therefrom |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52124043A (en) * | 1976-04-13 | 1977-10-18 | Kokoku Rubber Ind | Electrical conductive resin composition for plating |
JPS5950259B2 (en) * | 1980-11-17 | 1984-12-07 | 住友ベークライト株式会社 | Resin composition for plating |
JPS58222135A (en) * | 1982-06-19 | 1983-12-23 | Nippon Steel Chem Co Ltd | Electrically conductive resin composition |
JPH072885B2 (en) * | 1986-10-14 | 1995-01-18 | 東レ株式会社 | Thermoplastic resin composition |
JP2917049B2 (en) * | 1990-07-23 | 1999-07-12 | 住化エイビーエス・ラテックス株式会社 | Method for producing filler-containing resin composition |
JPH0657153A (en) * | 1992-08-10 | 1994-03-01 | Daicel Chem Ind Ltd | Antistatic resin composition |
JPH0665508A (en) * | 1992-08-18 | 1994-03-08 | Daicel Chem Ind Ltd | Antistatic resin composition |
JP3465340B2 (en) * | 1994-04-01 | 2003-11-10 | Jsr株式会社 | Thermoplastic resin composition |
US5989723A (en) * | 1997-05-16 | 1999-11-23 | Far Eastern Textile Ltd. | Conductive polyester-based alloy sheet |
-
1999
- 1999-07-29 CN CNB991139321A patent/CN1160409C/en not_active Expired - Lifetime
-
2000
- 2000-06-12 JP JP2001514039A patent/JP2003529626A/en active Pending
- 2000-06-12 AU AU53865/00A patent/AU5386500A/en not_active Abandoned
- 2000-06-12 WO PCT/CN2000/000154 patent/WO2001009241A1/en active Application Filing
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102002206A (en) * | 2010-12-21 | 2011-04-06 | 四川大学 | High-glossiness high-toughness scratch resistant molding composition |
CN102585429A (en) * | 2011-01-11 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
CN102585429B (en) * | 2011-01-11 | 2015-02-25 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
CN102582188A (en) * | 2012-02-16 | 2012-07-18 | 仙居县一远静电科技有限公司 | Antistatic ABS (Acrylonitrile Butadiene Styrene) laminated board |
CN103360718A (en) * | 2013-07-14 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging ABS-TPU plastic alloy |
CN103360718B (en) * | 2013-07-14 | 2015-11-18 | 上海秋橙新材料科技有限公司 | anti-aging ABS-TPU plastic alloy |
Also Published As
Publication number | Publication date |
---|---|
AU5386500A (en) | 2001-02-19 |
CN1160409C (en) | 2004-08-04 |
WO2001009241A1 (en) | 2001-02-08 |
JP2003529626A (en) | 2003-10-07 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SHANGHAI GENIUS NEW MATERIALS (GROUP) CO., LTD. Free format text: FORMER NAME: SHANGHAI GENIUS NEW MATERIALS CO., LTD. |
|
CP03 | Change of name, title or address |
Address after: 201109, No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee after: Shanghai Genius Advanced Material (Group) Co., Ltd. Address before: 201109 Shanghai City North Town Minhang District North Pine Road Zhugang Bridge No. 1 Patentee before: Jieshijie New Materials Co., Ltd., Shanghai |
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ASS | Succession or assignment of patent right |
Owner name: HEFEI GENIUS NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI GENIUS ADVANCED MATERIAL (GROUP) CO., LTD. Effective date: 20110324 |
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C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 201109 NO. 800, BEISONG ROAD, BEIQIAO TOWN, MINHANG DISTRICT, SHANGHAI TO: 230601 NO. 2388, LIANHUA ROAD, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT ZONE, HEFEI CITY, ANHUI PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20110324 Address after: 230601 No. 2388 Lianhua Road, Hefei Economic Development Zone, Anhui, China Patentee after: Hefei Genius New Materials Co., Ltd. Address before: 201109, No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee before: Shanghai Genius Advanced Material (Group) Co., Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Effective date of registration: 20150810 Granted publication date: 20040804 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20161121 Granted publication date: 20040804 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process Effective date of registration: 20161124 Granted publication date: 20040804 Pledgee: CITIC Bank Hefei branch Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000085 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20171020 Granted publication date: 20040804 Pledgee: CITIC Bank Hefei branch Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2016340000085 |
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