CN114736747A - Antibacterial soap solution containing natural plant components and preparation method thereof - Google Patents
Antibacterial soap solution containing natural plant components and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/02—Local antiseptics
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/04—Antibacterial agents
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/10—Antimycotics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Health & Medical Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Dermatology (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Communicable Diseases (AREA)
- Oncology (AREA)
- Inorganic Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention provides an antibacterial soap solution containing natural plant components and a preparation method thereof, and relates to the technical field of cleaning and antibiosis. The natural plant component antibacterial soap solution is prepared from the following materials in parts by weight: 15-25 parts of vegetable oil, 3-5 parts of alkali, 1-5 parts of humectant, 0.05-3 parts of plant extract, 0.1-2 parts of sodium chloride aqueous solution and 60-80 parts of purified water. The antibacterial agent disclosed by the invention adopts natural plant components, is free of any chemically synthesized antibacterial agent, is safe and non-irritant, acts for 2min on intestinal pathogenic bacteria, pyococcus, pathogenic yeast and common hospital infection bacteria with a dilution of 1:1 with water, and has a sterilization rate of over 90%.
Description
Technical Field
The invention relates to the technical field of cleaning and antibiosis, and particularly relates to an antibacterial soap solution containing natural plant components and a preparation method thereof.
Background
Modern research shows that many pathogens enter the body through hands or come into contact with nose, eyes and the like. Therefore, people pay more and more attention to the sanitary cleaning of hands. Particularly, hospitals are dense in pathogenic microorganisms, and medical staff sometimes have contact with infection, so that the hand hygiene of the medical staff is also important. With the increasing requirements of people on the efficacy of washing and caring products, the washing and caring products with the sterilization effect are certainly more popular among the public. Because the soap solution is superior to the common hand sanitizer, the soap solution is used for more and more sanitary cleaning of hands, but the soap solution on the market only has the function of cleaning and decontamination, and the soap solution which can sterilize and decontaminate is rarely available on the market, and especially the antibacterial soap solution added with natural plant components is rare. Some of the plant extracts have bactericidal active ingredients, are nonirritating to the skin, and are natural and harmless to hands, so people tend to use washing and care products containing natural plants.
Disclosure of Invention
Based on the technical problems, the invention provides an antibacterial soap solution containing natural plant components and a preparation method thereof. The invention adopts natural plant components, does not have any chemically synthesized antibacterial agent, is safe and non-irritant, and the diluent of the natural plant components and water in a ratio of 1:1 acts on intestinal pathogenic bacteria, pyogenic coccus, pathogenic yeast and common bacteria infected in hospitals for 2min, and the sterilization rate can reach more than 90%.
In order to achieve the purpose, the invention is realized by the following technical scheme:
an antibacterial soap solution containing natural plant components is prepared from the following materials in parts by weight: 15-25 parts of vegetable oil, 3-5 parts of alkali, 1-5 parts of humectant, 0.05-3 parts of plant extract, 0.1-2 parts of sodium chloride aqueous solution and 60-80 parts of purified water.
Further, the vegetable oil is one or more of soybean oil, olive oil and coconut oil.
Further, the alkali is one or more of sodium hydroxide, potassium hydroxide and aqueous solution thereof.
Further, the humectant is one or more of trehalose, vitamin E and aloe.
Further, the plant extract is polyphenol and alkaloid, and is one or more of caulis Fibraureae extract, herba Macleayae Cordatae extract, cortex Magnolia officinalis extract, flos Lonicerae extract, radix Sophorae Flavescentis extract, and herba Chelidonii extract.
Further, the mass fraction of the sodium chloride aqueous solution is 25%.
The preparation process of the antibacterial soap liquid containing natural plant components comprises the following specific steps
S1, weighing raw materials, adding part of purified water, alkali and vegetable oil into a synthesis tank, and heating for saponification;
s2, adding the rest purified water to dissolve the saponified soap base, controlling the temperature at 40-50 ℃, and then adding the humectant and the plant extract;
s3, adding a sodium chloride aqueous solution for thickening;
and S4, packaging.
Further, in step S1, the amount of purified water is 5% to 10% of the total weight of the purified water.
Further, in step S1, the saponification temperature is 90-100 ℃.
The invention has the following beneficial effects:
1. the soap solution containing natural plant components and having an antibacterial effect is safe and non-irritant because the antibacterial agent is made of natural plant components and is free of any chemically synthesized antibacterial agent, and the sterilizing rate of the soap solution and a 1:1 dilution of water on intestinal pathogenic bacteria, pyogenic coccus, pathogenic yeast and common bacteria infected in hospitals can reach more than 90%. The present invention selects natural plants from the aspects of antibacterial property, safety, etc. Wherein, the fibraurea recisa pierre extract has inhibitory action on various gram positive and negative bacteria, dysentery bacillus, colibacillus, streptococcus B and Asian influenza A virus, and 12 moulds with different degrees of inhibitory action. The extract of the macleaya cordata has strong inhibiting effect on various gram positive and negative bacteria and leptospira. The Magnolia bark extract has special and durable muscle relaxation effect and strong antibacterial effect. The honeysuckle extract has strong bacteriostatic power on streptococcus, staphylococcus, typhoid bacillus, dysentery bacillus, large intestine, pseudomonas aeruginosa, pneumococcus, pertussis bacillus, meningococcus and the like. The sophora flavescens extract has multiple effects of whitening, diminishing inflammation, resisting acne, resisting bacteria and the like, is used for beautifying and protecting skin for hundreds of years, and is a popular cosmetic raw material for various cosmeceutics. The herba Chelidonii extract can inhibit gram-positive bacteria, tubercle bacillus, fungi, etc.
2. The soap solution containing natural plant components and having the antibacterial effect, the vegetable oil and the soap base formed after saponification with alkali are mild and soft, green, healthier and more environment-friendly, and have the characteristics of rich foam, strong detergency, easiness in rinsing, no residue and the like.
3. The soap solution containing natural plant components and having antibacterial effect, humectant, and natural moisturizing factor can prevent water loss of skin, effectively protect skin, and prevent skin dryness.
4. The soap solution containing natural plant components and having antibacterial effect and sodium chloride water solution can improve product fluidity, avoid product drying and agglomeration, and improve product comfort.
Detailed Description
The invention provides a technical scheme that: an antibacterial soap solution containing natural plant components is prepared from the following materials in parts by weight: 15-25 parts of vegetable oil, 3-5 parts of alkali, 1-5 parts of humectant, 0.05-3 parts of plant extract, 0.1-2 parts of sodium chloride aqueous solution and 60-80 parts of purified water.
Vegetable oil: is one or more of soybean oil, olive oil and coconut oil, is natural, healthy, mild and soft. Humectant: is one or more of trehalose, vitamin E and aloe, and can protect hand skin and avoid irritation. Plant extracts: is polyphenol and alkaloids, and is one or more of caulis Fibraureae extract, herba Macleayae Cordatae extract, cortex Magnolia officinalis extract, flos Lonicerae extract, radix Sophorae Flavescentis extract, and herba Chelidonii extract. The polyphenol substances have strong antioxidation, the alkaloid antibacterial spectrum is wide, the antibacterial effect on strains including drug-resistant bacteria is good, the alkaloid not only has direct antibacterial effect, but also has synergistic antibacterial effect with other substances, and the polyphenol substances and the alkaloid substances exist simultaneously, so that the skin can be protected from stimulation while the antibacterial effect is improved. The natural plant components have no any chemically synthesized antibacterial agent, are safe and non-irritant, and have good antibacterial effect.
The soap solution with the antibacterial effect is added with the pure natural plant saponifiable matter, contains natural skin care factors, does not contain chemical components such as phosphorus, fluorescent agent, whitening agent and the like, has no irritation to the skin, and is safe and reliable; contains deep cleaning factors, has the characteristics of rich foam, strong detergency, easy flushing and the like; contains natural plant extract, wherein the plant extract contains a large amount of bactericidal active ingredients, has no irritation to skin, and is a natural hand-friendly bactericide; the antibacterial soap solution has obvious bactericidal effect on staphylococcus aureus, pseudomonas aeruginosa and candida albicans.
An antibacterial soap solution containing natural plant components comprises the following steps and specific embodiments:
example 1
An antibacterial soap solution containing natural plant components comprises the following steps:
s1, weighing raw materials according to 1kg of production, weighing 50g of purified water, 40g of potassium hydroxide and 200g of soybean oil, adding into a synthesis tank, and heating to 90 ℃ for saponification.
S2, adding 694g of the rest purified water, dissolving saponified soap base, controlling the temperature at 50 ℃, and then adding 7g of aloe, 3g of trehalose, 0.5g of fibraurea recisa extract and 0.5g of honeysuckle extract.
S3, adding 5g of sodium chloride aqueous solution for thickening.
And S4, packaging.
Example 2
An antibacterial soap solution containing natural plant components comprises the following steps:
s1, weighing raw materials according to 1kg of production, weighing 50g of purified water, 40g of potassium hydroxide, 180g of soybean oil and 20g of olive oil, adding into a synthesis tank, and heating to 90 ℃ for saponification.
S2, adding 694g of the rest purified water, dissolving saponified soap base, controlling the temperature at 40 ℃, and then adding 3g of aloe, 7g of vitamin E, 0.5g of macleaya cordata extract and 0.5g of radix sophorae flavescentis extract.
S3, adding 5g of sodium chloride aqueous solution for thickening.
And S4, packaging.
Example 3
An antibacterial soap solution containing natural plant components comprises the following steps:
s1, weighing raw materials according to 1kg of production, weighing 50g of purified water, 40g of potassium hydroxide, 180g of soybean oil and 20g of olive oil, adding into a synthesis tank, and heating to 100 ℃ for saponification.
S2, adding 694g of residual purified water, dissolving saponified soap base, controlling temperature at 40 deg.C, and adding 5g of Aloe, 5g of vitamin E, 0.5g of cortex Magnolia officinalis extract, and 0.5g of herba Chelidonii extract.
S3, adding 5g of sodium chloride aqueous solution for thickening.
And S4, packaging.
Example 4
An antibacterial soap solution containing natural plant components comprises the following steps:
s1, weighing raw materials according to 1kg of production, weighing 50g of purified water, 40g of sodium hydroxide, 180g of coconut oil and 20g of olive oil, adding into a synthesis tank, and heating to 100 ℃ for saponification.
S2, adding the rest 670g of purified water to dissolve saponified soap base, controlling the temperature at 40 ℃, and then adding 5g of aloe, 5g of vitamin E, 10g of magnolia bark extract and 20g of celandine extract.
S3, adding 5g of sodium chloride aqueous solution for thickening.
The examples were tested according to GB/T13173 appendix 2008 experimental method for surfactant detergents 8.1, disinfection specifications (2002 edition) 2.2.1.4, 2.1.1.6, 2.1.11.3, 2.3.3, GB/T34855 appendix 2017 hand sanitizer 5.3, cosmetic safety specifications (2015 edition) chapter IV, 4.6, 2.22, GB15979-2002 hygienic standards for Disposable hygiene (B, GB/T15818 appendix 2018 appendix F for testing biological degradability of surfactant.
The following conclusions are drawn through the tests:
1. the pH value of the product (aqueous solution with the mass ratio of 1: 10) is about 12.23.
2. After the sample is stored for 90 days at 37 ℃, the sample diluent (aqueous solution with the mass ratio of 1: 1) acts on the candida albicans for 2min, the sterilization rate is more than 90 percent, and the storage period of validity can be determined as 24 months.
3. Tests prove that the sample stock solution is stored for 24 hours at the temperature of (40 +/-2) DEG C and the temperature of (-5 +/-2) DEG C respectively, and is observed after being restored to the room temperature, so that the sample stock solution is not layered, turbid, precipitate and peculiar smell or color change, and meets the requirements of GB/T34855-2017 hand sanitizer.
4. The samples were found to have no detectable lead (<10mg/kg), no detectable mercury (<1mg/kg) and no detectable arsenic (<2mg/kg), and met the requirements of the technical safety standards for cosmetics (2015 edition).
5. The original formaldehyde content of the sample is less than 25mg/kg, and meets the requirements of GB/T34855-2017 hand sanitizer.
6. The total number of bacteria of the sample is less than 1CFU/mL, coliform bacteria are not detected, staphylococcus aureus is not detected, hemolytic streptococcus is not detected, pseudomonas aeruginosa is not detected, and the total number of fungus colonies is less than 1CFU/mL, thereby meeting the requirements of GB15979 & lt & gtBian & gt 2002 sanitary Standard for Disposable sanitary articles.
7. In a suspension quantitative sterilization experiment, DifcoTMD/E nutrient broth neutralizing agent and neutralizing agent products obtained by diluting natural plant antibacterial hand sanitizer (1:1 mass ratio aqueous solution) have no influence on growth of bacterial propagules and nutrient medium.
8. The sample diluent (aqueous solution with the mass ratio of 1: 1) acts on escherichia coli, staphylococcus aureus and pseudomonas aeruginosa for 2min, and the sterilization rate is more than 90%.
9. In a suspension quantitative sterilization experiment, DifcoTMD/E nutrient broth neutralizer and a neutralizer product thereof with a natural plant antibacterial hand sanitizer diluent (aqueous solution with the mass ratio of 1: 1) have no influence on growth and nutrient medium of Candida albicans.
10. The sample diluent (aqueous solution with the mass ratio of 1: 1) acts on Candida albicans for 2min, and the sterilization rate is more than 90%.
11. The biodegradability D7 of this sample at day 7 was 100%.
12. This sample was subjected to multiple complete skin irritation test evaluations, in accordance with the "Disinfection Specification" (2002 edition). Under the present test conditions, the results are as follows: the results of multiple complete skin irritation tests show that the sample has no irritation to the skin irritation strength of Japanese white rabbits with big ears according to the skin irritation strength grading of disinfection products, and meets the requirements of disinfection technical Specification (2002 edition).
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various changes and modifications can be made without departing from the inventive concept of the present invention, and these changes and modifications are all within the scope of the present invention.
Claims (10)
1. An antibacterial soap solution containing natural plant components is characterized by being prepared from the following materials in parts by weight: 15-25 parts of vegetable oil, 3-5 parts of alkali, 1-5 parts of humectant, 0.05-3 parts of plant extract, 0.1-2 parts of sodium chloride aqueous solution and 60-80 parts of purified water.
2. The natural plant component-containing antibacterial soap solution according to claim 1, wherein the vegetable oil is one or more of soybean oil, olive oil and coconut oil.
3. The natural plant component-containing antibacterial soap solution according to claim 1, wherein the alkali is one or more of sodium hydroxide, potassium hydroxide and aqueous solutions thereof.
4. The natural plant component-containing antibacterial soap solution as claimed in claim 1, wherein the humectant is one or more of trehalose, vitamin E and aloe.
5. The natural plant component-containing antibacterial soap solution according to claim 1, wherein the plant extract is polyphenols and/or alkaloids.
6. The natural plant component-containing antibacterial soap solution as claimed in claim 5, wherein the plant extract is one or more of a fibraurea stem extract, a macleaya cordata extract, a magnolia bark extract, a honeysuckle flower extract, a sophora flavescens extract and a celandine extract.
7. The natural plant component-containing antibacterial soap solution as claimed in claim 1, wherein the mass fraction of the sodium chloride aqueous solution is 25%.
8. The method for preparing the antibacterial soap solution containing natural plant components according to any one of the preceding claims, which is characterized by comprising the following steps:
s1, weighing the raw materials, adding part of purified water, alkali and vegetable oil into a synthesis tank, and heating and saponifying;
s2, adding the rest purified water to dissolve the saponified soap base, controlling the temperature at 40-50 ℃, and then adding the humectant and the plant extract;
s3, adding a sodium chloride aqueous solution for thickening;
and S4, packaging.
9. The method according to claim 8, wherein the purified water is used in an amount of 5 to 10% by weight based on the total weight of the purified water in step S1.
10. The method according to claim 8, wherein the saponification temperature in step S1 is 90-100 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210268345.XA CN114736747A (en) | 2022-03-18 | 2022-03-18 | Antibacterial soap solution containing natural plant components and preparation method thereof |
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| CN202210268345.XA CN114736747A (en) | 2022-03-18 | 2022-03-18 | Antibacterial soap solution containing natural plant components and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589535A (en) * | 2013-11-27 | 2014-02-19 | 骆志明 | Skin-care honeysuckle liquid soap |
| CN105193663A (en) * | 2015-10-23 | 2015-12-30 | 安徽师范大学 | Traditional Chinese medicinal liquid soap and preparation method thereof |
| CN107893002A (en) * | 2017-11-29 | 2018-04-10 | 山东卓健医疗科技有限公司 | A kind of natural antibacterial skin care soap lye and preparation method thereof |
| WO2019199255A2 (en) * | 2017-12-20 | 2019-10-17 | Evyap Sabun Yag Gliserin Sanayi Ve Ticaret Anonim Sirketi | Developing natural soap based antibacterial liquid soap formula |
-
2022
- 2022-03-18 CN CN202210268345.XA patent/CN114736747A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589535A (en) * | 2013-11-27 | 2014-02-19 | 骆志明 | Skin-care honeysuckle liquid soap |
| CN105193663A (en) * | 2015-10-23 | 2015-12-30 | 安徽师范大学 | Traditional Chinese medicinal liquid soap and preparation method thereof |
| CN107893002A (en) * | 2017-11-29 | 2018-04-10 | 山东卓健医疗科技有限公司 | A kind of natural antibacterial skin care soap lye and preparation method thereof |
| WO2019199255A2 (en) * | 2017-12-20 | 2019-10-17 | Evyap Sabun Yag Gliserin Sanayi Ve Ticaret Anonim Sirketi | Developing natural soap based antibacterial liquid soap formula |
Non-Patent Citations (1)
| Title |
|---|
| 范文昌等: "常用中药毒性研究进展及应用", vol. 1, 湖北科学技术出版社, pages: 567 - 568 * |
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