CN114517135A - Environment-friendly low-foam degreasing agent for polyester fabric and preparation method thereof - Google Patents
Environment-friendly low-foam degreasing agent for polyester fabric and preparation method thereof Download PDFInfo
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- CN114517135A CN114517135A CN202210198433.7A CN202210198433A CN114517135A CN 114517135 A CN114517135 A CN 114517135A CN 202210198433 A CN202210198433 A CN 202210198433A CN 114517135 A CN114517135 A CN 114517135A
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- polyoxyethylene ether
- foam
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- friendly low
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- 239000006260 foam Substances 0.000 title claims abstract description 28
- 239000004744 fabric Substances 0.000 title claims abstract description 24
- 239000013527 degreasing agent Substances 0.000 title claims abstract description 23
- 238000005237 degreasing agent Methods 0.000 title claims abstract description 22
- 229920000728 polyester Polymers 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 30
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 30
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims abstract description 11
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 7
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims abstract description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940069096 dodecene Drugs 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 31
- 238000000034 method Methods 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 5
- -1 polyoxyethylene Polymers 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229930182478 glucoside Natural products 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000012208 gear oil Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000012224 working solution Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a low-foam degreasing agent, in particular to an environment-friendly low-foam degreasing agent for polyester fabrics and a preparation method thereof. The preparation method comprises the following raw materials in parts by mass: 20-25% of dodecene glycol polyoxyethylene ether, 10-15% of methyl laurate polyoxyethylene ether sulfonate, 5-10% of straight chain lauryl alcohol polyoxyethylene ether and the balance of deionized water. The emulsifying and dispersing performance of the oil removing agent can be enhanced, and the oil removing effect of the oil removing agent is improved.
Description
Technical Field
The invention relates to a low-foam degreasing agent, in particular to an environment-friendly low-foam degreasing agent for polyester fabrics and a preparation method thereof.
Background
The polyester fiber is continuously rubbed in the spinning and weaving process, so that a large amount of static electricity is easily generated, and the textile processing is influenced. In order to eliminate static electricity generated by fiber friction and reduce the end breakage rate, proper oil agents are required to be added, and the oil agents mainly comprise spindle oil, gear oil, white mineral oil, black engine oil and the like. The addition of the oil agent is unfavorable for the subsequent dyeing and finishing process of the fiber, the oil agent and oil stain are required to be thoroughly removed when the fabric is degreased, otherwise, the subsequent dyeing and finishing process is greatly damaged, and the fabric has the problems of color spots, color defects and the like.
When the polyester fabric is subjected to an intermittent oil removing process, the internal part of the overflow machine is high in temperature and pressure, and the working solution continuously circularly flows and impacts the cylinder wall to generate a large amount of foam, so that the following problems are caused:
(1) greasy dirt, impurities and the like removed from the working solution are easy to float in the foam and cause rewetting after contacting with the fabric.
(2) When too much foam is generated, the overflow machine is easy to generate 'empty suction', so that the fabric blocks the cylinder.
In the prior patent, a method of adding a defoaming agent is mostly adopted for reducing the foam of the auxiliary agent, but most of the defoaming agent is organic silicon, and under the conditions of high temperature and high pressure of an intermittent oil removal process, the organic silicon component in the defoaming agent is extremely unstable, is easy to break emulsion and separate out stained fabrics, and generates silicon spots.
The Chinese patent with publication number CN109370795B, entitled "oil removing agent for continuous processing of polyester/ammonia and polyamide-ammonia blended knitted fabric and preparation method thereof" discloses an oil removing agent for continuous processing prepared by polyoxyethylene type nonionic surfactant, chelating agent, fluorocarbon surfactant, organic fluorine finishing agent and other surfactants, which has good oil removal property, emulsifying dispersion property, anti-sticking property and rapid permeability, but the organic fluorine in the components is not beneficial to environmental protection.
The Chinese patent with the publication number of CN110527601A and the name of 'a low-temperature degreasing agent for chemical fiber fabrics and a preparation method thereof' discloses a low-temperature degreasing agent which takes fatty alcohol-polyoxyethylene ether containing alkyl glucoside, fatty alcohol-polyoxyethylene ether phosphate containing alkyl glucoside and fatty alcohol-polyoxyethylene ether sulfonate containing alkyl glucoside as main components, and has good decontamination property, degreasing property and dispersibility, but the degreasing agent has high foam, and impurities such as oil stains and the like removed in a degreasing process are easy to float in the foam and cause back staining and even cylinder blocking after contacting with fabrics.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides an environment-friendly low-foam degreasing agent for polyester fabrics and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the environment-friendly low-foam degreasing agent for the polyester fabric comprises the following preparation raw materials in parts by mass:
20-25% of dodecene glycol polyoxyethylene ether, 10-15% of methyl laurate polyoxyethylene ether sulfonate, 5-10% of straight chain lauryl alcohol polyoxyethylene ether and the balance of deionized water.
Preferably, the EO number of dodecenyldiol polyoxyethylene ether is 12, the EO number of methyl laurate polyoxyethylene ether sulfonate is 7, and the EO number of linear dodecanol polyoxyethylene ether is 9.
The preparation method of the environment-friendly low-foam degreasing agent for the polyester fabric comprises the following steps of:
(1) converting the mass percent of the components of the oil removing agent into specific mass and weighing the raw materials;
(2) adding methyl laurate polyethenoxy ether sulfonate and straight chain lauryl polyethenoxy ether into deionized water, and stirring and mixing uniformly;
(3) and (3) adding dodecenyl diol polyoxyethylene ether into the mixed solution obtained in the step (2), and then stirring and mixing uniformly to obtain the finished environment-friendly low-foam degreasing agent.
According to the preparation method of the environment-friendly low-foam oil removing agent for the polyester fabric, the anionic surfactant and the nonionic surfactant are compounded and synergized, the dodecene glycol polyoxyethylene ether has extremely low dynamic surface tension, and in the intermittent oil removing process of the polyester fabric, the foam can be effectively inhibited under the dynamic condition without adding a defoaming agent, so that oil stains and impurities are prevented from floating in the foam to cause adhesion return; the silicon spot problem of the defoaming agent is avoided; and the unsaturated alkynyl contained in the oil remover can enhance the emulsification and dispersion performance of the oil remover and improve the oil removing effect of the oil remover.
Detailed Description
The invention is further described below by means of specific embodiments.
Example 1: converting the mass percent of the components of the oil removing agent into specific mass, adding 10g of methyl laurate polyoxyethylene ether sulfonate and 10g of straight-chain lauryl alcohol polyoxyethylene ether into 60g of deionized water, and stirring and mixing uniformly; and adding 20g of dodecenyldiol polyoxyethylene ether into the mixed solution, and then stirring and mixing uniformly to obtain the finished environment-friendly low-foam degreasing agent.
Example 2: converting the mass percent of the components of the oil removing agent into specific mass, adding 15g of methyl laurate polyoxyethylene ether sulfonate and 10g of straight-chain lauryl alcohol polyoxyethylene ether into 50g of deionized water, and stirring and mixing uniformly; and adding 25g of dodecene glycol polyoxyethylene ether into the mixed solution, and then stirring and mixing uniformly to obtain the finished environment-friendly low-foam degreasing agent.
Example 3: converting the mass percent of the components of the oil removing agent into specific mass, adding 15g of methyl laurate polyoxyethylene ether sulfonate and 10g of straight-chain lauryl alcohol polyoxyethylene ether into 55g of deionized water, and stirring and mixing uniformly; and adding 20g of dodecenyldiol polyoxyethylene ether into the mixed solution, and then stirring and mixing uniformly to obtain the finished environment-friendly low-foam degreasing agent.
Comparative example:
domestic M: high-efficiency refined degreaser M-105B (Hangzhou Meigaohua Yiyi chemical Co., Ltd.);
An inlet F: the high-efficiency degreasing agent FORYL HY-E (Kokai Fine chemical engineering (Shanghai) Co., Ltd.) is prepared.
The experimental method comprises the following steps:
(I) application technique
1. Preparing test oil: firstly, mixing No. 10 white mineral oil, gear oil and black engine oil in a ratio of 1:1:1 uniformly to obtain the special oil.
2. Manufacturing the tarpaulin: shearing 5g of polyester knitted fabric (after deoiling), respectively dripping 0.1 ml of test oil at the center of the fabric, and after the oil is wetted and boiled, shaping for 45 seconds at 175 ℃ by using a high-temperature shaping machine.
3. The oil removal liquid is proportioned as follows:
degreasing agent 1g/L
Liquid caustic soda (32% NaOH) 5g/L
Bath ratio of 1:20
The process flow comprises the following steps: heating to 100 deg.C at a speed of 2.0 deg.C/min, keeping the temperature for 30min, cooling to 40 deg.C at a speed of 3 deg.C/min, washing with water, and oven drying.
(II) testing indexes and methods:
1. emulsibility:
preparing the degreasing agent into 1g/L aqueous solution, placing 30mL aqueous solution and 30mL special oil in a 100mL high-leg beaker, homogenizing at the rotating speed of 1000r/min for 60s by a homogenizer, standing in a 100mL measuring cylinder, and recording the time required for the lower layer to be layered into 5mL aqueous phase. The longer the time. The stronger the emulsifying power.
2. Foaming property: preparing 10g/L aqueous solution from the degreasing agent, pouring 20mL of the aqueous solution into a 100mL measuring cylinder with a plug (a printing paper scale with a millimeter scale is stuck on the cylinder body of the measuring cylinder with the plug), covering, forcibly shaking up and down for 20 times, placing on a flat table, recording the foam height, and recording the foam height again after 1 min.
3. Removing oil:
according to GB/T251-.
(III) application effect:
table 1 application test results
Results of the experiment
According to the data, the oil removal property, the emulsifying property and the foaming property of the polyester fabric in the embodiments of the invention are superior to those of the market sample comparative example; finally, it should be noted that the above embodiments are merely representative examples of the present invention. Obviously, the technical solution of the present invention is not limited to the above-described embodiments, and many variations are possible. All modifications which come within the meaning and range of equivalency of the claims are to be embraced within their scope.
Claims (3)
1. The environment-friendly low-foam degreasing agent for the polyester fabric is characterized by comprising the following components in parts by weight: the preparation method comprises the following raw materials in parts by mass:
20-25% of dodecene glycol polyoxyethylene ether, 10-15% of methyl laurate polyoxyethylene ether sulfonate, 5-10% of straight chain lauryl alcohol polyoxyethylene ether and the balance of deionized water.
2. The environment-friendly low-foam oil remover for polyester fabrics as claimed in claim 1, is characterized in that: the EO number of the dodecene glycol polyoxyethylene ether is 12, the EO number of the methyl laurate polyoxyethylene ether sulfonate is 7, and the EO number of the straight-chain lauryl alcohol polyoxyethylene ether is 9.
3. The preparation method of the environment-friendly low-foam oil remover for polyester fabrics according to claims 1 and 2, which is characterized by comprising the following steps of:
(1) converting the mass percent of the components of the oil removing agent into specific mass and weighing the raw materials;
(2) adding methyl laurate polyethenoxy ether sulfonate and straight chain lauryl polyethenoxy ether into deionized water, and stirring and mixing uniformly;
(3) and (3) adding dodecenylene glycol polyoxyethylene ether into the mixed solution obtained in the step (2), and then stirring and mixing uniformly to obtain the finished environment-friendly low-foam degreasing agent.
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CN111996803A (en) * | 2020-09-02 | 2020-11-27 | 多恩生物科技有限公司 | Novel environment-friendly low-foam low-temperature degreasing agent and preparation method thereof |
CN113583763A (en) * | 2021-08-16 | 2021-11-02 | 奥仕集团有限公司 | Preparation method of efficient fabric oil removing agent |
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2022
- 2022-03-02 CN CN202210198433.7A patent/CN114517135A/en not_active Withdrawn
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CN103194324A (en) * | 2013-04-01 | 2013-07-10 | 马永才 | Chemical fiber degreaser and preparation method thereof |
CN105463849A (en) * | 2015-11-19 | 2016-04-06 | 杭州美高华颐化工有限公司 | A phosphorus-free scouring agent used for nylon fabric and a preparing method |
CN105483726A (en) * | 2015-11-30 | 2016-04-13 | 武汉奥克特种化学有限公司 | Efficient low-foam normal-temperature phosphorous-free oil removing liquid |
CN111910451A (en) * | 2020-07-20 | 2020-11-10 | 纳派化学(上海)有限公司 | Wide-temperature range deoiling refining agent and preparation method thereof |
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