CN111910451B - Wide-temperature deoiling refining agent and preparation method thereof - Google Patents
Wide-temperature deoiling refining agent and preparation method thereof Download PDFInfo
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- CN111910451B CN111910451B CN202010699524.XA CN202010699524A CN111910451B CN 111910451 B CN111910451 B CN 111910451B CN 202010699524 A CN202010699524 A CN 202010699524A CN 111910451 B CN111910451 B CN 111910451B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention relates to the field of textile printing and dyeing auxiliaries, in particular to a wide-temperature deoiling refining agent and a preparation method thereof. The deoiling refining agent comprises, by weight, 20-25 parts of alcohol-modified heterogeneous decaalcohol polyoxyethylene ether, 20-25 parts of acid-modified heterogeneous decaalcohol polyoxyethylene ether, 10 parts of heterogeneous tridecanol polyoxyethylene ether, 10 parts of fatty alcohol polyoxyethylene ether, 5-10 parts of a high-molecular dispersing agent, 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 2-5 parts of an environment-friendly chelating dispersing agent and 10-20 parts of a solvent. The deoiling refining agent provided by the invention takes modified isomeric dodecyl alcohol polyoxyethylene ether and the like as main components, can be used for deoiling and refining at 30-130 ℃ under the synergistic effect of several substances, is suitable for all fibers, can meet various requirements in the industry, and has a good application prospect.
Description
Technical Field
The invention relates to the field of textile printing and dyeing auxiliaries, in particular to a wide-temperature deoiling refining agent and a preparation method thereof.
Background
The chemical fiber is inevitably stained with spinning oil in the processes of melt-blowing and wire-drawing, and other oil stains such as spindle oil, black machine oil, gear oil, white mineral oil and lubricating oil are possibly stained in the processes of later weaving, dyeing and finishing, transportation and storage; cellulose fibers are obtained from nature and inevitably contain impurities such as wax and pectin. The blended fabric of chemical fiber and cellulose fiber on the market is comparatively everywhere, need deoiling and refine together to go on, and the refining mode of deoiling that is widely used on the market at present mainly has two kinds: 1) A dissolving method, in which a fabric is soaked by using an organic solvent (common volatile solvents such as diethyl ether, carbon tetrachloride, benzene and derivatives thereof, trichloroethylene and the like), and the surface of the fabric is rinsed by using a small brush, so that small greasy dirt on the surface of the fabric can be cleaned, but the production efficiency is low, large-area greasy dirt cannot be effectively removed, and the large-scale industrial application is difficult; 2) The washing method utilizes high-efficiency detergent (such as degreasing agent, stain remover and the like) to wash the fabric for multiple times, although the method can clean massive greasy dirt on the surface of the fabric, the degreasing temperature is generally higher, the process flow is longer at about 100 ℃, the cost is higher, the problems of energy consumption, wastewater discharge and the like exist, and the method is still to be perfected. The prior market often requires low oil removal temperature and is suitable for oil removal refining agents of all fibers. Cotton and other cellulosic fibers are typically dyed at temperatures around 60 ℃. The printing and dyeing mill generally heats up to about 100 ℃ to remove oil, discharges liquid, cools to 60 ℃ to dye, and has long working procedure and high energy consumption. Therefore, the customers put forward the oil removal at the temperature of below 60 ℃ without discharging liquid, and then the temperature is raised to 60 ℃ for dyeing, thereby saving water and time and reducing energy consumption.
In China, research and development personnel continuously research low-temperature oil removal in recent years, in patent publication No. CN110527601A, alkyl glycoside fatty alcohol polyoxyethylene ether, alkyl glycoside polyoxyethylene ether phosphate and alkyl glycoside polyoxyethylene ether sulfonate are used as low-temperature oil removal components of chemical fiber fabrics, and the alkyl glycoside and oil stain components in the chemical fiber fabrics are well combined, so that oil stains can be adsorbed easily, and can be uniformly dispersed in water, and the oil removal agent is very suitable for removing oil in the temperature range of 70-80 ℃ of the chemical fiber fabrics. In patent publication No. CN105002022A, fatty amine polyoxyethylene ether, secondary alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and isomeric deca-alcohol polyoxyethylene ether are used as low-temperature deoiling components, and are particularly suitable for low-temperature deoiling of spandex fabrics, and because the system is a nonionic surfactant with medium and low ethylene oxide number, the deoiling agent has low cloud point and is suitable for deoiling at 40-80 ℃.
In conclusion, the application temperature range of the existing oil removal refining agent is narrow, and the oil removal refining agent with wider application range needs to be invented to meet different industrial requirements.
Disclosure of Invention
The invention provides a product suitable for oil removal refining at 30-130 ℃, and solves the problem that the existing oil removal refining agent has a narrow application temperature range.
On the basis of summarizing the existing research and development experience, the applicant of the invention simultaneously combines the application practice of a dye house, develops a product suitable for oil removal refining at the temperature of 30-130 ℃ through a large amount of innovative labor, is suitable for all fibers, and can be selected by customers according to the processing requirements.
Specifically, the technical scheme of the invention is as follows:
the invention discloses a deoiling refining agent in a first aspect, which comprises the following components in parts by weight:
preferably, the alcohol-modified isomeric decaalcohol polyoxyethylene ether is prepared by carrying out etherification reaction on propylene glycol or dipropylene glycol and isomeric decaalcohol polyoxyethylene ether; preferably, the EO number of the isomeric decahydric alcohol polyoxyethylene ether is 7.
EO in the invention is English abbreviation of ethylene oxide, the ring-opening polymerization of the ethylene oxide is changed into polyoxyethylene ether, fatty alcohol participates in the reaction and is changed into fatty alcohol-polyoxyethylene ether, and the larger the EO number, the better the hydrophilicity. In some embodiments of the present invention, the method for preparing alcohol-modified isomeric polyoxyethylene decaalcohol comprises: adding propylene glycol, dipropylene glycol and isomeric deca-alcohol polyoxyethylene ether (EO = 7) into a four-neck reaction flask, starting stirring, adding concentrated sulfuric acid, introducing nitrogen, heating to 95 ℃, keeping the temperature for reaction for 6 hours at 95-100 ℃, cooling to below 50 ℃, and discharging to obtain the alcohol-modified isomeric deca-alcohol polyoxyethylene ether.
Preferably, the acid modified isomeric decaalcohol polyoxyethylene ether is prepared by esterification reaction of 5 (or 6) -carboxyl-4-hexyl-2-cyclohexene-1-octanoic acid and isomeric decaalcohol polyoxyethylene ether; preferably, the EO number of the isomeric polyoxyethylene decacarbonate is 9. In some preferred embodiments of the invention, the 5 (or 6) -carboxy-4-hexyl-2-cyclohexene-1-octanoic acid is Cas:53980-88-4.
In some preferred embodiments of the present invention, the method for preparing the acid-modified isomeric polyoxyethylene decacarbinol ether comprises: adding 5 (or 6) -carboxyl-4-hexyl-2-cyclohexene-1-octanoic acid and isomeric decyl alcohol polyoxyethylene ether (EO = 9) into a four-neck reaction flask, starting stirring, adding concentrated sulfuric acid, introducing nitrogen, heating to 150 ℃, reacting for 6 hours at 150-155 ℃, cooling to below 50 ℃, turning off the nitrogen, discharging, and preparing the acid modified isomeric decyl alcohol polyoxyethylene ether.
Preferably, the isomeric polyoxyethylene decacarbonate is one or more selected from the group consisting of isomeric polyoxyethylene decacarbonate (EO number = 3), isomeric polyoxyethylene decacarbonate (EO number = 5), isomeric polyoxyethylene decacarbonate (EO number = 6), isomeric polyoxyethylene decacarbonate (EO number = 7), isomeric polyoxyethylene decacarbonate (EO number = 8), and isomeric polyoxyethylene decacarbonate (EO number = 9).
Preferably, the fatty alcohol-polyoxyethylene ether is selected from one or more of AEO-3, AEO-5, AEO-6, AEO-7, AEO-8 and AEO-9.
Preferably, the polymeric dispersant is selected from one or more of CP-6, CP-9, CP-12S and HP-56K of BASF company in Germany.
Preferably, the environment-friendly chelating dispersant is selected from one or any combination of sodium polyaspartate and tetrasodium iminodisuccinate.
Preferably, the solvent is selected from one or more of methanol, ethanol, isopropanol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether and isoprene glycol.
In a second aspect of the invention, a method for preparing the deoiling refining agent is disclosed, which comprises the following steps: adding alcohol-modified heterogeneous decaalcohol polyoxyethylene ether, acid-modified heterogeneous decaalcohol polyoxyethylene ether, heterogeneous tridecanol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, a high-molecular dispersing agent, 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, an environment-friendly chelating dispersing agent and a solvent into a mixing device in no sequence, and stirring for 30-50 minutes at 50-60 ℃ to obtain the deoiling refining agent.
The third aspect of the invention discloses the application of the deoiling refining agent in the field of textile printing and dyeing auxiliaries.
On the basis of the common general knowledge in the field, the above-mentioned preferred conditions can be combined arbitrarily without departing from the concept and the protection scope of the invention.
The isomeric deca-ethanol polyoxyethylene ether in the formula has excellent low-temperature penetration and deoiling effect, and can reduce foams after reacting with propylene glycol or dipropylene glycol; the 5 (Or 6) -carboxyl-4-hexyl-2-cyclohexene-1-caprylic acid is a low-temperature soaping oil-removing raw material, is a new deoiling agent raw material with functions of permeation, emulsification, dispersion and low foaming after reacting with isomeric deca-ethanol polyoxyethylene ether, and has excellent comprehensive performance; the isomeric tridecanol polyoxyethylene ether has excellent penetration and deoiling effects, and the cost can be properly reduced by compounding the isomeric tridecanol polyoxyethylene ether with the fatty alcohol polyoxyethylene ether; 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether has extremely low interfacial tension, quickly permeates into the fiber and has a certain defoaming effect; the macromolecular dispersing agent of the German BASF company has stronger dispersing ability than small-molecular fatty alcohol-polyoxyethylene ether, avoids oil stain agglomeration and improves continuous processability. The environment-friendly chelating dispersant poly-sodium aspartate and the like can avoid the adverse effect of water quality on the oil removal effect and can disperse oil stains. The solvent mainly solves the problem that part of fatty alcohol ether is insoluble in water, can be dissolved by adding a hydrophilic solvent, ensures the stability of a finished product, does not float oil, and has better deoiling effect. The raw materials are compounded according to a certain proportion, so that the wide-temperature degreaser with negative and non-ionic characteristics can be prepared, can be used for degreasing and refining at the temperature of 30-130 ℃, is suitable for all fibers, and is a product with strong competitiveness.
Compared with the prior art, the invention has the following remarkable advantages and effects:
(1) The deoiling refining agent provided by the invention takes alcohol-modified heterogeneous decaalcohol polyoxyethylene ether, acid-modified heterogeneous decaalcohol polyoxyethylene ether, heterogeneous tridecanol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, a high-molecular dispersing agent, 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether and an environment-friendly chelating dispersing agent as main components, and through the synergistic effect of the substances, the deoiling refining agent prepared by the method has the advantages that deoiling refining can be carried out at 30-130 ℃, the deoiling refining agent is suitable for all fibers, various requirements in the industry can be met, and the deoiling refining agent has a good application prospect.
(2) The deoiling refining agent disclosed by the invention is low in raw material cost, simple in process, suitable for large-scale industrial application and high in practicability.
Detailed Description
The technical solutions of the present invention are described in detail below with reference to examples, but the present invention is not limited to the scope of the examples.
The experimental methods without specifying specific conditions in the following examples were selected according to the conventional methods and conditions, or according to the commercial instructions. The reagents and starting materials used in the present invention are commercially available.
Example 1
Preparing alcohol modified isomeric decaalcohol polyoxyethylene ether: adding 38 g of propylene glycol, 67 g of dipropylene glycol and 466 g of isomeric deca-alcohol polyoxyethylene ether (7 EO) into a four-neck reaction flask, starting stirring, adding 1.2 g of concentrated sulfuric acid, introducing nitrogen, heating to 95 ℃, carrying out heat preservation reaction for 6 hours at the temperature of 95-100 ℃, cooling to below 50 ℃, and discharging to obtain alcohol-modified isomeric deca-alcohol polyoxyethylene ether;
preparing acid modified isomeric deca-alcohol polyoxyethylene ether: 352 g of 5 (or 6) -carboxyl-4-hexyl-2-cyclohexene-1-octanoic acid and 554 g of isomeric deca-ethanol polyoxyethylene ether (9 EO) are added into a reaction four-neck flask, stirring is started, 1.5 g of concentrated sulfuric acid is added, nitrogen is introduced, the temperature is raised to 150 ℃, the reaction is carried out for 6 hours at the temperature of 150-155 ℃, the temperature is reduced to below 50 ℃, the nitrogen is closed, and the acid modified isomeric deca-ethanol polyoxyethylene ether is prepared after discharging.
Example 2
20 g of alcohol modified isomeric dodecyl alcohol polyoxyethylene ether, 25 g of acid modified isomeric dodecyl alcohol polyoxyethylene ether, 10 g of isomeric dodecyl alcohol polyoxyethylene ether (3 EO), 10 g of isomeric tridecyl alcohol polyoxyethylene ether (1310), 5 g of AEO-3, 5 g of AEO-9, 5 g of CP-6, 5 g of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 2 g of sodium polyaspartate and 18 g of methanol which are all added into a mixing kettle in sequence, stirring is carried out, heat preservation is carried out for 30-50 minutes at 50-60 ℃, uniform mixing of materials is guaranteed, the appearance is transparent, and the deoiling refining agent is prepared.
The isomeric decahydric alcohol polyoxyethylene is of the Passion XL series, for example the XL-90 series represents isomeric decahydric alcohol polyoxyethylene ether (9 EO), the isomeric tridecanol polyoxyethylene ether is of the Passion TO series, for example the TO-5 series represents isomeric tridecanol polyoxyethylene ether (5 EO).
Example 3
21 g of alcohol modified isomeric decyl alcohol polyoxyethylene ether, 24 g of acid modified isomeric decyl alcohol polyoxyethylene ether, 10 g of isomeric decyl alcohol polyoxyethylene ether (5 EO), 10 g of isomeric tridecyl alcohol polyoxyethylene ether (1310), 10 g of AEO-5, 6 g of CP-9, 4 g of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 3 g of iminodisuccinic acid tetrasodium and 20 g of ethanol in example 1 are added into a mixing kettle in sequence, stirring is started, heat preservation is carried out for 30-50 minutes at 50-60 ℃, uniform mixing of materials is guaranteed, the appearance is transparent, and the deoiling refining agent is prepared.
Example 4
22 g of alcohol modified isomeric decyl alcohol polyoxyethylene ether, 23 g of acid modified isomeric decyl alcohol polyoxyethylene ether, 10 g of isomeric decyl alcohol polyoxyethylene ether (6 EO), 10 g of isomeric tridecyl alcohol polyoxyethylene ether (1310), 10 g of AEO-6, 7 g of CP-12S, 3 g of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 4 g of sodium polyaspartate and 15 g of isopropanol which are all added into a mixing kettle in sequence, stirring is started, heat preservation is carried out for 30-50 minutes at 50-60 ℃, uniform mixing of materials is guaranteed, the appearance is transparent, and the deoiling refining agent is prepared.
Example 5
23 g of alcohol modified isomeric dodecyl alcohol polyoxyethylene ether, 22 g of acid modified isomeric dodecyl alcohol polyoxyethylene ether, 10 g of isomeric dodecyl alcohol polyoxyethylene ether (7 EO), 10 g of isomeric tridecyl alcohol polyoxyethylene ether (1310), 10 g of AEO-7, 8 g of HP-56K, 2 g of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 5 g of iminodisuccinic acid tetrasodium and 12 g of ethylene glycol monobutyl ether in the example 1 are added into a mixing kettle in sequence, stirring is started, the temperature is kept at 50-60 ℃ for 30-50 minutes, the materials are uniformly mixed, the appearance is transparent, and the deoiling refining agent is prepared.
Example 6
25 g of alcohol modified isomeric dodecyl alcohol polyoxyethylene ether, 20 g of acid modified isomeric dodecyl alcohol polyoxyethylene ether, 10 g of isomeric dodecyl alcohol polyoxyethylene ether (8 EO), 10 g of isomeric tridecyl alcohol polyoxyethylene ether (1310), 10 g of AEO-8, 10 g of CP-9, 2 g of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, 3 g of sodium polyaspartate and 10 g of isoprene glycol in the example 1 are added into a mixing kettle in sequence, stirring is started, heat preservation is carried out for 30-50 minutes at 50-60 ℃, uniform mixing of materials is guaranteed, the appearance is transparent, and the deoiling refining agent is prepared.
Example 7
The degreasing refining agents prepared in examples 2 to 6 were evaluated for degreasing refining effect as follows:
fabric: terylene/viscose blended white gray cloth
Deoiling and refining process: 1g/L of deoiling refining agent is prepared into 200 g of aqueous solution, 5 g of cloth is added, the temperature is increased to a specified temperature, the temperature is kept for 30 minutes, the whiteness of the cloth surface is tested by a Datacolor color measuring instrument, and the capillary effect of the fabric is tested for 30 minutes according to the method in sections 6.4 and 6.5.3 in FZ/T4447-2012 textile capillary effect experiment method. The results are shown in Table 1.
TABLE 1 Effect of oil refining agent applied at different temperatures
As can be seen from Table 1, the degreasing refining agent prepared in the embodiments 2-6 is suitable for being used at the temperature of 30-130 ℃, the wool effect can be greatly improved by using 1g/L of degreasing refining agent, the whiteness of the fabric is improved, and the degreasing refining effect is slightly good but is not changed greatly along with the temperature rise.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (7)
1. The deoiling refining agent is characterized by comprising the following components in parts by weight:
20-25 parts of alcohol modified isomeric decaalcohol polyoxyethylene ether
20-25 parts of acid modified heterogeneous deca-alcohol polyoxyethylene ether
10 parts of isomeric deca-alcohol polyoxyethylene ether
10 parts of isomeric tridecanol polyoxyethylene ether
10 parts of fatty alcohol-polyoxyethylene ether
5-10 parts of macromolecular dispersant
2-5 parts of 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether
2-5 parts of environment-friendly chelating dispersant
10-20 parts of solvent
The alcohol modified isomeric deca-alcohol polyoxyethylene ether is prepared by carrying out etherification reaction on propylene glycol or dipropylene glycol and isomeric deca-alcohol polyoxyethylene ether with EO number of 7;
the acid modified isomeric deca-ethanol polyoxyethylene ether is prepared by esterification reaction of 5-carboxyl-4-hexyl-2-cyclohexene-1-octanoic acid or 6-carboxyl-4-hexyl-2-cyclohexene-1-octanoic acid and isomeric deca-ethanol polyoxyethylene ether with EO number of 9;
the fatty alcohol-polyoxyethylene ether is selected from one or more of AEO-3, AEO-5, AEO-6, AEO-7, AEO-8 and AEO-9.
2. The oil refining agent of claim 1, wherein the isomeric polyoxyethylene decacarbonate is one or more selected from the group consisting of isomeric polyoxyethylene decacarbonate with EO number =3, isomeric polyoxyethylene decacarbonate with EO number =5, isomeric polyoxyethylene decacarbonate with EO number =6, isomeric polyoxyethylene decacarbonate with EO number =7, isomeric polyoxyethylene decacarbonate with EO number =8, and isomeric polyoxyethylene decacarbonate with EO number = 9.
3. The oil-removing refining agent as defined in claim 1, wherein the polymeric dispersant is one or more selected from CP-6, CP-9, CP-12S, HP-56K from BASF corporation, germany.
4. The oil removal refining agent of claim 1, wherein the environmentally friendly chelating dispersant is selected from one or any combination of sodium polyaspartate and tetrasodium iminodisuccinate.
5. The oil-removing refining agent as defined in claim 1, wherein the solvent is one or more selected from methanol, ethanol, isopropanol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, and isoprene glycol.
6. A process for preparing a deoiling refiner of any one of claims 1 to 5, comprising: adding alcohol modified heterogeneous deca-alcohol polyoxyethylene ether, acid modified heterogeneous deca-alcohol polyoxyethylene ether, heterogeneous tridecanol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, a high-molecular dispersing agent, 2,5,8, 11-tetramethyl-6-dodecyne-5, 8-diol polyoxyethylene ether, an environment-friendly chelating dispersing agent and a solvent into a mixing device in no sequence, and stirring for 30-50 minutes at 50-60 ℃ to obtain the deoiling refining agent.
7. Use of a deoiling refining agent according to any of claims 1 to 5 in the field of textile printing and dyeing auxiliaries.
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