CN114012098B - 一种易激活的非蒸散型锆石墨吸气材料 - Google Patents
一种易激活的非蒸散型锆石墨吸气材料 Download PDFInfo
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- CN114012098B CN114012098B CN202111294988.3A CN202111294988A CN114012098B CN 114012098 B CN114012098 B CN 114012098B CN 202111294988 A CN202111294988 A CN 202111294988A CN 114012098 B CN114012098 B CN 114012098B
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- 239000000463 material Substances 0.000 title claims abstract description 45
- 229910052845 zircon Inorganic materials 0.000 title claims abstract description 23
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 title claims abstract description 23
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 79
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 58
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 57
- 239000002131 composite material Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 30
- 238000002156 mixing Methods 0.000 claims abstract description 28
- 238000005245 sintering Methods 0.000 claims abstract description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 17
- 239000011733 molybdenum Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000003825 pressing Methods 0.000 claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 54
- 239000000243 solution Substances 0.000 claims description 48
- 239000000017 hydrogel Substances 0.000 claims description 26
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 24
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 24
- 239000007864 aqueous solution Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000002243 precursor Substances 0.000 claims description 21
- 239000003153 chemical reaction reagent Substances 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 18
- 239000006260 foam Substances 0.000 claims description 18
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 14
- 239000004202 carbamide Substances 0.000 claims description 14
- FTXJFNVGIDRLEM-UHFFFAOYSA-N copper;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O FTXJFNVGIDRLEM-UHFFFAOYSA-N 0.000 claims description 14
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 229930003268 Vitamin C Natural products 0.000 claims description 12
- 229910052786 argon Inorganic materials 0.000 claims description 12
- 238000000713 high-energy ball milling Methods 0.000 claims description 12
- 235000019154 vitamin C Nutrition 0.000 claims description 12
- 239000011718 vitamin C Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 8
- 238000000498 ball milling Methods 0.000 claims description 6
- 238000000502 dialysis Methods 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- 238000007710 freezing Methods 0.000 claims description 6
- 230000008014 freezing Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000002161 passivation Methods 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000010257 thawing Methods 0.000 claims description 6
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
- 239000012498 ultrapure water Substances 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims 1
- 239000004964 aerogel Substances 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 abstract description 4
- 238000005247 gettering Methods 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract 3
- 239000010439 graphite Substances 0.000 abstract 3
- 238000000465 moulding Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910000628 Ferrovanadium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZPZCREMGFMRIRR-UHFFFAOYSA-N molybdenum titanium Chemical compound [Ti].[Mo] ZPZCREMGFMRIRR-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1003—Use of special medium during sintering, e.g. sintering aid
- B22F3/1007—Atmosphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/043—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
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CN202111294988.3A CN114012098B (zh) | 2021-11-03 | 2021-11-03 | 一种易激活的非蒸散型锆石墨吸气材料 |
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CN202111294988.3A CN114012098B (zh) | 2021-11-03 | 2021-11-03 | 一种易激活的非蒸散型锆石墨吸气材料 |
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CN114012098A CN114012098A (zh) | 2022-02-08 |
CN114012098B true CN114012098B (zh) | 2023-11-14 |
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Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1580304A (zh) * | 2003-07-30 | 2005-02-16 | 北京有色金属研究总院 | 纳米级锆基非蒸散型吸气材料制备工艺 |
CN101721969A (zh) * | 2009-12-21 | 2010-06-09 | 北京有色金属研究总院 | 一种以钛为基的烧结型吸气材料及其制备方法 |
CN105271212A (zh) * | 2015-11-30 | 2016-01-27 | 航天特种材料及工艺技术研究所 | 一种石墨烯气凝胶材料及其制备方法 |
CN107418513A (zh) * | 2017-07-21 | 2017-12-01 | 大连理工大学 | 一种石墨烯泡沫负载纳米Fe3O4磁性粒子复合吸波材料及其制备方法 |
CN110305635A (zh) * | 2019-07-19 | 2019-10-08 | 天津工业大学 | 一种成形储热材料及其制备方法 |
WO2019195374A1 (en) * | 2018-04-03 | 2019-10-10 | Nanotek Instruments, Inc. | Metallized graphene foam having high through-plane conductivity |
CN110452667A (zh) * | 2019-08-27 | 2019-11-15 | 国科瑞华(天津)材料科技有限公司 | 石墨烯增强相变材料制备方法和石墨烯增强相变材料 |
CN111101020A (zh) * | 2019-12-31 | 2020-05-05 | 南京华东电子真空材料有限公司 | 一种锆石墨烯吸气材料及其制备方法 |
WO2020130499A2 (ko) * | 2018-12-21 | 2020-06-25 | 한국과학기술원 | 다공성 구조체 기반 그래핀 폼 및 그 제조방법 |
CN111359584A (zh) * | 2020-04-22 | 2020-07-03 | 湖南二零八先进科技有限公司 | 一种石墨烯基吸气剂及其制作方法 |
CN111359582A (zh) * | 2020-03-23 | 2020-07-03 | 成都新柯力化工科技有限公司 | 一种石墨烯复合气凝胶除甲醛材料及制备方法 |
CN111842917A (zh) * | 2020-07-27 | 2020-10-30 | 安徽有研吸气材料有限公司 | 一种高性能吸气合金的成分及其加工方法 |
-
2021
- 2021-11-03 CN CN202111294988.3A patent/CN114012098B/zh active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1580304A (zh) * | 2003-07-30 | 2005-02-16 | 北京有色金属研究总院 | 纳米级锆基非蒸散型吸气材料制备工艺 |
CN101721969A (zh) * | 2009-12-21 | 2010-06-09 | 北京有色金属研究总院 | 一种以钛为基的烧结型吸气材料及其制备方法 |
CN105271212A (zh) * | 2015-11-30 | 2016-01-27 | 航天特种材料及工艺技术研究所 | 一种石墨烯气凝胶材料及其制备方法 |
CN107418513A (zh) * | 2017-07-21 | 2017-12-01 | 大连理工大学 | 一种石墨烯泡沫负载纳米Fe3O4磁性粒子复合吸波材料及其制备方法 |
WO2019195374A1 (en) * | 2018-04-03 | 2019-10-10 | Nanotek Instruments, Inc. | Metallized graphene foam having high through-plane conductivity |
WO2020130499A2 (ko) * | 2018-12-21 | 2020-06-25 | 한국과학기술원 | 다공성 구조체 기반 그래핀 폼 및 그 제조방법 |
CN110305635A (zh) * | 2019-07-19 | 2019-10-08 | 天津工业大学 | 一种成形储热材料及其制备方法 |
CN110452667A (zh) * | 2019-08-27 | 2019-11-15 | 国科瑞华(天津)材料科技有限公司 | 石墨烯增强相变材料制备方法和石墨烯增强相变材料 |
CN111101020A (zh) * | 2019-12-31 | 2020-05-05 | 南京华东电子真空材料有限公司 | 一种锆石墨烯吸气材料及其制备方法 |
CN111359582A (zh) * | 2020-03-23 | 2020-07-03 | 成都新柯力化工科技有限公司 | 一种石墨烯复合气凝胶除甲醛材料及制备方法 |
CN111359584A (zh) * | 2020-04-22 | 2020-07-03 | 湖南二零八先进科技有限公司 | 一种石墨烯基吸气剂及其制作方法 |
CN111842917A (zh) * | 2020-07-27 | 2020-10-30 | 安徽有研吸气材料有限公司 | 一种高性能吸气合金的成分及其加工方法 |
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Address after: 234300 Tanghe Road South Dangtu Road West, Development Zone Management Committee of Sixian County, Suzhou City, Anhui Province Patentee after: Anhui Youyan Aspiration New Materials Co.,Ltd. Country or region after: China Address before: 234300 Factory Building 3 #, Chuanggu Industrial Park, Sixian Development Zone, Suzhou City, Anhui Province Patentee before: Anhui Youyan inspiratory Materials Co.,Ltd. Country or region before: China |