CN113929997A - 一种环保型无机复合纳米抗菌防霉高分子母料及其制备方法与应用 - Google Patents
一种环保型无机复合纳米抗菌防霉高分子母料及其制备方法与应用 Download PDFInfo
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- CN113929997A CN113929997A CN202111023851.4A CN202111023851A CN113929997A CN 113929997 A CN113929997 A CN 113929997A CN 202111023851 A CN202111023851 A CN 202111023851A CN 113929997 A CN113929997 A CN 113929997A
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114874517A (zh) * | 2022-06-13 | 2022-08-09 | 安徽英科医疗用品有限公司 | 一种医用抗菌手套的制备工艺 |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07252378A (ja) * | 1994-03-16 | 1995-10-03 | Daiwa Kagaku Kogyo Kk | 熱可塑性プラスチックの抗菌防黴組成物 |
CN1461755A (zh) * | 2002-05-31 | 2003-12-17 | 中国科学院化学研究所 | 一种聚合物/无机纳米抗菌组合物水基微乳液的制备方法 |
CN101724284A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种抗菌热塑性塑料组合物及其制备方法 |
CN101720785A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种复合抗菌剂及其制备方法 |
CN102783498A (zh) * | 2011-05-16 | 2012-11-21 | 常州英中纳米科技有限公司 | 一种喷雾干燥生产纳米银复合抗菌剂的方法 |
CN105623218A (zh) * | 2016-03-15 | 2016-06-01 | 惠州市环美盛新材料有限公司 | 一种无机复合纳米抗菌耐热聚乳酸母料及其制备方法 |
US20160326670A1 (en) * | 2014-01-10 | 2016-11-10 | Nano, Future And Life, Inc. | Antibacterial fiber material, antibacterial fibers, master batch for manufacturing antibacterial fibers, and method for manufacturing antibacterial fibers |
CN106349663A (zh) * | 2016-08-29 | 2017-01-25 | 佛山市高明区尚润盈科技有限公司 | 一种聚乳酸抗菌防辐射母粒的制备方法 |
CN108841043A (zh) * | 2018-07-13 | 2018-11-20 | 广州广化塑料管道有限公司 | 聚氯乙烯材料用纳米化包覆改性复合阻燃剂及其制备方法 |
CN109535584A (zh) * | 2017-09-21 | 2019-03-29 | 博富科技股份有限公司 | 抗菌防霉pvc软胶粒及其制备方法 |
CN109705454A (zh) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | 一种抗菌防霉3d打印聚丙烯丝材及其制备方法 |
CN109705455A (zh) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | 一种抗菌防霉热塑性树脂组合物及其制备方法 |
CN111875883A (zh) * | 2020-07-25 | 2020-11-03 | 陈志益 | 一种纳米抗菌防污桌椅塑料颗粒及制备方法 |
CN112144132A (zh) * | 2019-06-26 | 2020-12-29 | 博富科技股份有限公司 | 改性纳米氧化锌抗菌剂、抗菌化学纤维母粒及其制备方法 |
CN112409698A (zh) * | 2020-11-10 | 2021-02-26 | 华南理工大学 | 纳米改性增强增韧抗菌无规共聚聚丙烯专用料及其制备方法 |
-
2021
- 2021-09-02 CN CN202111023851.4A patent/CN113929997B/zh active Active
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07252378A (ja) * | 1994-03-16 | 1995-10-03 | Daiwa Kagaku Kogyo Kk | 熱可塑性プラスチックの抗菌防黴組成物 |
CN1461755A (zh) * | 2002-05-31 | 2003-12-17 | 中国科学院化学研究所 | 一种聚合物/无机纳米抗菌组合物水基微乳液的制备方法 |
CN101724284A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种抗菌热塑性塑料组合物及其制备方法 |
CN101720785A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种复合抗菌剂及其制备方法 |
CN102783498A (zh) * | 2011-05-16 | 2012-11-21 | 常州英中纳米科技有限公司 | 一种喷雾干燥生产纳米银复合抗菌剂的方法 |
US20160326670A1 (en) * | 2014-01-10 | 2016-11-10 | Nano, Future And Life, Inc. | Antibacterial fiber material, antibacterial fibers, master batch for manufacturing antibacterial fibers, and method for manufacturing antibacterial fibers |
CN105623218A (zh) * | 2016-03-15 | 2016-06-01 | 惠州市环美盛新材料有限公司 | 一种无机复合纳米抗菌耐热聚乳酸母料及其制备方法 |
CN106349663A (zh) * | 2016-08-29 | 2017-01-25 | 佛山市高明区尚润盈科技有限公司 | 一种聚乳酸抗菌防辐射母粒的制备方法 |
CN109535584A (zh) * | 2017-09-21 | 2019-03-29 | 博富科技股份有限公司 | 抗菌防霉pvc软胶粒及其制备方法 |
CN109705454A (zh) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | 一种抗菌防霉3d打印聚丙烯丝材及其制备方法 |
CN109705455A (zh) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | 一种抗菌防霉热塑性树脂组合物及其制备方法 |
CN108841043A (zh) * | 2018-07-13 | 2018-11-20 | 广州广化塑料管道有限公司 | 聚氯乙烯材料用纳米化包覆改性复合阻燃剂及其制备方法 |
CN112144132A (zh) * | 2019-06-26 | 2020-12-29 | 博富科技股份有限公司 | 改性纳米氧化锌抗菌剂、抗菌化学纤维母粒及其制备方法 |
CN111875883A (zh) * | 2020-07-25 | 2020-11-03 | 陈志益 | 一种纳米抗菌防污桌椅塑料颗粒及制备方法 |
CN112409698A (zh) * | 2020-11-10 | 2021-02-26 | 华南理工大学 | 纳米改性增强增韧抗菌无规共聚聚丙烯专用料及其制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114874517A (zh) * | 2022-06-13 | 2022-08-09 | 安徽英科医疗用品有限公司 | 一种医用抗菌手套的制备工艺 |
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