CN113896422B - Kiln transition blue glaze, preparation method thereof and glaze firing method - Google Patents
Kiln transition blue glaze, preparation method thereof and glaze firing method Download PDFInfo
- Publication number
- CN113896422B CN113896422B CN202111369226.5A CN202111369226A CN113896422B CN 113896422 B CN113896422 B CN 113896422B CN 202111369226 A CN202111369226 A CN 202111369226A CN 113896422 B CN113896422 B CN 113896422B
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- blue
- kiln
- water white
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to a kiln blue glaze, a preparation method and a glaze firing method thereof. According to the invention, green glass, cobalt oxide and basic copper sulfate are used as coloring raw materials, the silicon-aluminum content ratio in the blue glaze of the kiln is controlled through fluorite tailings with high silicon, low aluminum and high calcium and water white with high silicon, low aluminum and high calcium, calcium phosphate in beta-cristobalite and bovine bone ash and anorthite crystal bundles mainly formed by the water white and fluorite tailings in glaze firing are used for promoting the generation of blue-white phase opalescence phenomenon, and meanwhile, proper amount of iron contained in the water white, trace amount of titanium dioxide and tin dioxide are used together to play roles of assisting color development and enriching decoration, and the synergetic effect of each component is realized.
Description
Technical Field
The invention belongs to the technical field of artistic glaze, and particularly relates to a transmutation blue glaze, a preparation method thereof and a glaze firing method.
Background
The kiln-transition glaze, as the name implies, has unexpected glaze color effect in the firing process of ceramic products. Because the kiln contains various coloring elements, the porcelain can show unexpected glaze color effect after coming out of the kiln through oxidation or reduction.
Chinese patent publication (CN 102249738A) discloses a transmutation glaze dolomite pottery, comprising a dolomite pottery body and a glaze layer applied Yu Baiyun on the surface of the pottery body, the glaze layer comprising a base glaze directly applied on the surface of the dolomite pottery body and an overglaze applied on the surface of the base glaze; the overglaze comprises, by weight, 85-90 parts of low-temperature lead-free frit, 2-5 parts of zinc oxide, 2-5 parts of titanium oxide, 0-2 parts of coloring oxide and 5-6 parts of kaolin. The sintering temperature is 1080-1100 ℃, the single-batch sintering time is 8-12 hours, the sintering temperature is low, the time is short, and the low-temperature efficient light-weight white cloud ceramic kiln transformation glaze production process is realized, and the energy is saved and the environment is protected.
The Chinese published patent document (CN 111233520A) discloses a sky blue kiln transformation glaze which is applied to sanitary ceramics and comprises 1-4wt% of zirconium silicate, 22-30wt% of quartz, 18-28wt% of potassium feldspar, 6-12wt% of albite, 5-12wt% of heavy calcium carbonate, 6-15wt% of calcium metasilicate, 5-10wt% of Huizhou water washing clay, 3-10wt% of calcined zinc oxide, 5-10wt% of high-temperature frit, 2-6wt% of titanium pigment, 1-3wt% of cobalt oxide and 0.2-0.5wt% of methylcellulose. The color-developing substances in the overglaze formula are titanium dioxide, cobalt oxide and zirconium silicate, and the blue-white effect is represented in the sintering process; in addition, stable blue spinel is formed by CoO and Al2O3 in the overglaze at high temperature, and black spots are formed by the overglaze and the ground glaze after permeation and sedimentation, so that the sky blue kiln transformation glaze effect is finally realized.
With the continuous improvement of the living standard of people, the appreciation level and the requirements of people are greatly changed. In the ceramic industry, in order to meet various requirements, new modeling and decorating methods are continuously developed, a rich and colorful kiln transformation glaze formula is provided, the method is an important ring in the ceramic manufacturing process, and huge commercial value can be brought to ceramic products.
Disclosure of Invention
The invention aims to provide a transmutation blue glaze prepared from resource waste.
In order to achieve the aim of the invention, the invention adopts the following technical scheme:
the kiln transition blue glaze consists of the following components in parts by weight: 30-35 parts of beta-cristobalite, 20-25 parts of potassium feldspar, 10-15 parts of water white, 5-10 parts of fluorite tailings, 5-10 parts of Jiangxi talcum, 1.5-2.5 parts of zinc white, 1-3 parts of bovine bone ash, 8-12 parts of green glass, 1-2 parts of cobalt oxide, 0.2-0.3 part of basic copper sulfate, 0.1-0.15 part of titanium dioxide and 0.1-0.2 part of tin dioxide.
The invention also provides a preparation method of the kiln blue glaze, which comprises the steps of weighing raw materials according to a formula, putting beta-cristobalite, potassium feldspar, water white, fluorite tailings, jiangxi talcum, zinc white, bovine bone ash, titanium dioxide and tin dioxide into a ball mill for the first time, sieving with a 100-150 mesh sieve, adding green glass, cobalt oxide and basic copper sulfate into the sieved glaze slurry for the second time, and carrying out ball milling and sieving, wherein the fineness is 20-50 microns, the grain diameter is 65% -75%, and the specific gravity of the glaze slurry is controlled to be 1.7g/cm < 3 > -1.8 g/cm < 3 >.
The invention further provides a glaze firing method of the transmutation blue glaze, which comprises the steps of firstly dipping titanium flower base glaze with the thickness of 0.4mm-0.6mm on a biscuit, spraying the transmutation blue glaze with the thickness of 0.1mm-0.2mm after the titanium flower base glaze is dried, and then firing in a kiln.
The kiln-entering firing process specifically comprises the following steps: slowly heating to 800-850 ℃ at a speed of 3.5-4 ℃/min under an oxidizing atmosphere, then quickly heating to 1000-1020 ℃ at a speed of 8-10 ℃/min, converting into reducing flame, slowly heating to strong reduction slow burning at a speed of 0.8-1 ℃/min, finally converting into a heating speed of 0.5-0.8 ℃/min when heating to 1100 ℃, carrying out weak reduction slow burning to 1060-1080 ℃, and cooling.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, green glass, cobalt oxide and basic copper sulfate are used as coloring raw materials, the silicon-aluminum content ratio in the blue glaze of the kiln is controlled through fluorite tailings with high silicon, low aluminum and high calcium and water white with high silicon, low aluminum and high calcium, calcium phosphate in beta-cristobalite and bovine bone ash and anorthite crystal bundles mainly formed by the water white and fluorite tailings in glaze firing are used for promoting the generation of blue-white phase opalescence phenomenon, and meanwhile, proper amount of iron contained in the water white, trace amount of titanium dioxide and tin dioxide are used together to play roles of assisting color development and enriching decoration, and the synergetic effect of each component is realized; the Jiangxi talcum not only plays a role of reducing the firing temperature by synergizing with the potassium feldspar, but also improves the opalescence blue phenomenon together with the zinc white and the zinc dioxide; meanwhile, fluorite tailings are selected for use, so that waste materials are utilized, and the method is energy-saving and environment-friendly.
Detailed Description
Example 1
The embodiment provides a kiln transition blue glaze which comprises the following components in parts by weight: 32 parts of beta-cristobalite, 20 parts of potassium feldspar, 12 parts of water white, 10 parts of fluorite tailings, 8 parts of Jiangxi talcum, 2.5 parts of zinc white, 1 part of bovine bone ash, 12 parts of green glass, 2 parts of cobalt oxide, 0.25 part of basic copper sulfate, 0.1 part of titanium dioxide and 0.12 part of tin dioxide.
The preparation method of the kiln transition blue glaze comprises the steps of respectively weighing raw materials according to a formula, firstly putting beta-cristobalite, potassium feldspar, water white, fluorite tailings, jiangxi talcum, zinc white, bovine bone ash, titanium dioxide and tin dioxide into a ball mill for the first time, ball milling, sieving with a 150-mesh sieve, then adding green glass, cobalt oxide and basic copper sulfate into the sieved glaze slurry for the second time, ball milling and sieving, wherein the fineness is 20-50 microns, the grain diameter is 70%, and the specific gravity of the glaze slurry is controlled to be 1.7g/cm < 3 >.
The glaze firing method of the transmutation blue glaze comprises the steps of firstly dipping titanium flower base glaze with the thickness of 0.6mm on a biscuit, spraying the transmutation blue glaze with the thickness of 0.15mm after the titanium flower base glaze is dried, and firing in a kiln, wherein the method specifically comprises the following steps: slowly heating to 800 ℃ at a speed of 4 ℃/min under an oxidizing atmosphere, then quickly heating to 1020 ℃ at a speed of 10 ℃/min, converting into reducing flame, slowly heating to perform strong reduction slow burning at a speed of 1 ℃/min, and finally converting into a heating rate of 0.6 ℃/min when heating to 1100 ℃ for weak reduction slow burning to 1080 ℃, and cooling.
Example 2
The embodiment provides a kiln transition blue glaze which comprises the following components in parts by weight: 35 parts of beta-cristobalite, 22 parts of potassium feldspar, 10 parts of water white, 8 parts of fluorite tailings, 10 parts of Jiangxi talcum, 2 parts of zinc white, 1.5 parts of bovine bone ash, 10 parts of green glass, 1 part of cobalt oxide, 0.2 part of basic copper sulfate, 0.12 part of titanium dioxide and 0.1 part of tin dioxide.
The preparation method of the kiln transition blue glaze comprises the steps of respectively weighing raw materials according to a formula, firstly putting beta-cristobalite, potassium feldspar, water white, fluorite tailings, jiangxi talcum, zinc white, bovine bone ash, titanium dioxide and tin dioxide into a ball mill for the first time, ball milling, sieving by a 100-mesh sieve, then adding green glass, cobalt oxide and basic copper sulfate into the sieved glaze slurry for the second time, ball milling and sieving, wherein the fineness is 20-50 microns, the grain diameter is 75%, and the specific gravity of the glaze slurry is controlled to be 1.75g/cm < 3 >.
The glaze firing method of the transmutation blue glaze comprises the steps of firstly dipping titanium flower base glaze with the thickness of 0.5mm on a biscuit, spraying the transmutation blue glaze with the thickness of 0.2mm after the titanium flower base glaze is dried, and firing in a kiln, wherein the method specifically comprises the following steps: slowly heating to 850 ℃ at a speed of 4 ℃/min under an oxidizing atmosphere, then quickly heating to 1000 ℃ at a speed of 8 ℃/min, converting into reducing flame, slowly heating to strong reduction slow combustion at a speed of 0.8 ℃/min, and finally converting into 0.5 ℃/min heating rate when heating to 1100 ℃ to perform weak reduction slow combustion to 1060 ℃, and cooling.
Example 3
The embodiment provides a kiln transition blue glaze which comprises the following components in parts by weight: 35 parts of beta-cristobalite, 25 parts of potassium feldspar, 15 parts of water white, 5 parts of fluorite tailings, 5 parts of Jiangxi talcum, 1.5 parts of zinc white, 3 parts of bovine bone ash, 8 parts of green glass, 1.5 parts of cobalt oxide, 0.3 part of basic copper sulfate, 0.15 part of titanium dioxide and 0.2 part of tin dioxide.
The preparation method of the kiln transition blue glaze comprises the steps of weighing raw materials according to a formula, firstly putting beta-cristobalite, potassium feldspar, water white, fluorite tailings, jiangxi talcum, zinc white, bovine bone ash, titanium dioxide and tin dioxide into a ball mill for the first time, ball milling, sieving with a 150-mesh sieve, adding green glass, cobalt oxide and basic copper sulfate into the sieved glaze slurry for the second time, ball milling and sieving, wherein the fineness is 20-50 microns, the grain diameter is 65%, and the specific gravity of the glaze slurry is controlled to be 1.8g/cm < 3 >.
The glaze firing method of the transmutation blue glaze comprises the steps of firstly immersing titanium flower base glaze with the thickness of 0.4mm on a biscuit, spraying the transmutation blue glaze with the thickness of 0.1mm after the titanium flower base glaze is dried, and firing in a kiln, wherein the method specifically comprises the following steps: slowly heating to 820 ℃ at a speed of 3.5 ℃/min under an oxidizing atmosphere, then quickly heating to 1000 ℃ at a speed of 8 ℃/min, converting into reducing flame, slowly heating to strong reduction slow burning at a speed of 0.8 ℃/min, and finally converting into 0.6 ℃/min heating rate when heating to 1100 ℃ for weak reduction slow burning to 1065 ℃, and cooling.
While the basic principles and main features of the invention and advantages of the invention have been shown and described, it will be understood by those skilled in the art that the present invention is not limited by the foregoing embodiments, which are described in the foregoing description merely illustrate the principles of the invention, and various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined in the appended claims and their equivalents.
Claims (4)
1. The transmutation blue glaze is characterized by comprising the following components in parts by weight: 30-35 parts of beta-cristobalite, 20-25 parts of potassium feldspar, 10-15 parts of water white, 5-10 parts of fluorite tailings, 5-10 parts of Jiangxi talcum, 1.5-2.5 parts of zinc white, 1-3 parts of bovine bone ash, 8-12 parts of green glass, 1-2 parts of cobalt oxide, 0.2-0.3 part of basic copper sulfate, 0.1-0.15 part of titanium dioxide and 0.1-0.2 part of tin dioxide;
the preparation method of the transmutation blue glaze comprises the following steps: the raw materials are respectively weighed according to the formula, firstly, the beta-cristobalite, the potassium feldspar, the water white, the fluorite tailings, the Jiangxi talcum, the zinc white, the bovine bone ash, the titanium dioxide and the tin dioxide are put into a ball mill for the first time to be ball-milled, and pass through a 100-150-mesh sieve, then green glass, cobalt oxide and basic copper sulfate are added into the sieved glaze slurry for the second time to be ball-milled and sieved, the fineness is 20-50 microns, the grain diameter is 65-75 percent, and the specific gravity of the glaze slurry is controlled to be 1.7g/cm 3 ～1.8g/cm 3 ；
The glaze firing method of the kiln transition blue glaze comprises the following steps: firstly, dipping titanium flower base enamel on a biscuit, wherein the thickness of the titanium flower base enamel is 0.4-0.6 mm, spraying the kiln-transition blue enamel prepared by the preparation method after the titanium flower base enamel is dried, spraying the enamel with the thickness of 0.1-0.2 mm, and then firing in a kiln;
the kiln-entering firing process specifically comprises the following steps: slowly heating to 800-850 ℃ at a speed of 3.5-4 ℃/min under an oxidizing atmosphere, then quickly heating to 1000-1020 ℃ at a speed of 8-10 ℃/min, converting into reducing flame, slowly heating to strong reduction slow burning at a speed of 0.8-1 ℃/min, finally converting into a cooling speed of 0.5-0.8 ℃/min when heating to 1100 ℃ for weak reduction slow burning to 1060-1080 ℃, and cooling.
2. The transmutation blue glaze of claim 1, wherein: the composite material consists of the following components in parts by weight: 32 parts of beta-cristobalite, 20 parts of potassium feldspar, 12 parts of water white, 10 parts of fluorite tailings, 8 parts of Jiangxi talcum, 2.5 parts of zinc white, 1 part of bovine bone ash, 12 parts of green glass, 2 parts of cobalt oxide, 0.25 part of basic copper sulfate, 0.1 part of titanium dioxide and 0.12 part of tin dioxide.
3. The transmutation blue glaze of claim 1, wherein: the composite material consists of the following components in parts by weight: 35 parts of beta-cristobalite, 22 parts of potassium feldspar, 10 parts of water white, 8 parts of fluorite tailings, 10 parts of Jiangxi talcum, 2 parts of zinc white, 1.5 parts of bovine bone ash, 10 parts of green glass, 1 part of cobalt oxide, 0.2 part of basic copper sulfate, 0.12 part of titanium dioxide and 0.1 part of tin dioxide.
4. The transmutation blue glaze of claim 1, wherein: the composite material consists of the following components in parts by weight: 35 parts of beta-cristobalite, 25 parts of potassium feldspar, 15 parts of water white, 5 parts of fluorite tailings, 5 parts of Jiangxi talcum, 1.5 parts of zinc white, 3 parts of bovine bone ash, 8 parts of green glass, 1.5 parts of cobalt oxide, 0.3 part of basic copper sulfate, 0.15 part of titanium dioxide and 0.2 part of tin dioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111369226.5A CN113896422B (en) | 2021-11-18 | 2021-11-18 | Kiln transition blue glaze, preparation method thereof and glaze firing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111369226.5A CN113896422B (en) | 2021-11-18 | 2021-11-18 | Kiln transition blue glaze, preparation method thereof and glaze firing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113896422A CN113896422A (en) | 2022-01-07 |
| CN113896422B true CN113896422B (en) | 2023-05-09 |
Family
ID=79194776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111369226.5A Active CN113896422B (en) | 2021-11-18 | 2021-11-18 | Kiln transition blue glaze, preparation method thereof and glaze firing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113896422B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115215547B (en) * | 2022-07-12 | 2023-09-08 | 德化恒瀚艺品有限公司 | Low-temperature kiln-transition glaze and processing technology thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103964900B (en) * | 2014-05-12 | 2015-10-21 | 成都朋和科技有限公司 | A kind of sky blue furnace transmutation glaze formula and preparation method thereof |
| CN107601898B (en) * | 2017-09-28 | 2020-06-26 | 禹州市正玉钧窑有限公司 | Preparation method of Jun porcelain blue glaze |
| CN107522403A (en) * | 2017-10-16 | 2017-12-29 | 禹州市锦丰源瓷业有限公司 | A kind of blue chun glaze |
| CN107540223A (en) * | 2017-10-17 | 2018-01-05 | 禹州市锦丰源瓷业有限公司 | A kind of pottery jewel blue glaze of high rigidity and preparation method thereof |
| CN109293237A (en) * | 2018-09-18 | 2019-02-01 | 禹州市元丰钧陶瓷有限公司 | A kind of roe Bluepoint shape pottery glaze and preparation method thereof |
| CN109293337B (en) * | 2018-12-01 | 2020-07-17 | 景德镇陶瓷大学 | Preparation method of celadon porcelain |
| CN109987842A (en) * | 2019-04-18 | 2019-07-09 | 大宋官窑股份有限公司 | A kind of pottery celeste glaze and its preparation process |
| KR20210061824A (en) * | 2019-11-20 | 2021-05-28 | 정용무 | A ceramic glaze composition |
| CN111233520B (en) * | 2020-04-14 | 2020-09-29 | 佛山市东鹏陶瓷有限公司 | Starry sky blue transmutation glaze, preparation method thereof and sanitary ceramic using glaze |
| CN112279515A (en) * | 2020-12-01 | 2021-01-29 | 禹州市神器钧窑有限公司 | Jun porcelain sky blue glaze and preparation method thereof |
-
2021
- 2021-11-18 CN CN202111369226.5A patent/CN113896422B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN113896422A (en) | 2022-01-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111233520B (en) | Starry sky blue transmutation glaze, preparation method thereof and sanitary ceramic using glaze | |
| CN101759441B (en) | Ceramic glaze and preparation process thereof | |
| CN102249739B (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
| CN106396638B (en) | Low temperature lightweight lime gradual change glaze ceramics and its manufacture craft | |
| CN105753322A (en) | Medium-temperature plum green glaze and medium-temperature plum green Longquan celadon | |
| WO2015054805A1 (en) | High whiteness underglaze multicolored low-temperature porcelain and preparation method | |
| CN111960801B (en) | Low-temperature once-fired ceramic with opaque glaze and preparation method thereof | |
| CN106242285A (en) | One draws blue or green reddish brown glaze and ceramic material | |
| CN107216127A (en) | Dehua pearl white porcelain and its preparation technology | |
| CN115159970B (en) | Overglaze sky blue glaze ceramic vase and preparation process thereof | |
| CN113754404B (en) | High-light-transmittance daily fine porcelain and preparation method thereof | |
| CN105669161A (en) | Method of reductive firing of ceramic at medium temperature (1190-1260 DEG C) | |
| CN111548012A (en) | Low-temperature environment-friendly shallow brown white furnace transmutation glazed porcelain and preparation process thereof | |
| CN105272153A (en) | Preparation method of blue-and-white Nixing ceramic | |
| CN113896422B (en) | Kiln transition blue glaze, preparation method thereof and glaze firing method | |
| CN107721179B (en) | Preparation method of Jun porcelain bluish-blue glaze | |
| CN105218167A (en) | A kind of preparation method of blue and white material decoration Nixing pottery | |
| CN100369841C (en) | Method for preparing glaze in bright red for ceramics at intermediate temperature | |
| CN105272152A (en) | Novel combination method of cobalt blue material and Nixing ceramic | |
| CN105294058A (en) | Preparation method for novel nixing ceramic decorated with blue-and-white material | |
| CN110342823B (en) | Fertilizer Bai Youtao porcelain and preparation method thereof | |
| CN111908792A (en) | Glaze mixture of metal glaze, metal glaze product and preparation process of metal glaze product | |
| CN105254274A (en) | Method for combining cobalt blue material with Nixing ceramics | |
| CN107601898B (en) | Preparation method of Jun porcelain blue glaze | |
| CN113233766B (en) | Three-dimensional fancy glaze for feldspar porcelain decoration and application method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |