CN112997272A - 外延层和3d nand存储器的形成方法、退火设备 - Google Patents
外延层和3d nand存储器的形成方法、退火设备 Download PDFInfo
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- CN112997272A CN112997272A CN201880096615.5A CN201880096615A CN112997272A CN 112997272 A CN112997272 A CN 112997272A CN 201880096615 A CN201880096615 A CN 201880096615A CN 112997272 A CN112997272 A CN 112997272A
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- 238000000137 annealing Methods 0.000 title claims abstract description 125
- 238000000034 method Methods 0.000 title claims description 67
- 230000015654 memory Effects 0.000 title claims description 28
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 92
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 76
- 239000010703 silicon Substances 0.000 claims abstract description 76
- 239000000758 substrate Substances 0.000 claims abstract description 72
- 239000000203 mixture Substances 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 235000012431 wafers Nutrition 0.000 claims description 23
- 238000005530 etching Methods 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000013078 crystal Substances 0.000 claims description 20
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 20
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 17
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 17
- 239000006227 byproduct Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000003860 storage Methods 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- -1 silicon carbide nitride Chemical class 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 230000000149 penetrating effect Effects 0.000 claims description 5
- 230000007547 defect Effects 0.000 abstract description 18
- 239000007789 gas Substances 0.000 description 50
- 229910052799 carbon Inorganic materials 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000011800 void material Substances 0.000 description 9
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
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- 230000000694 effects Effects 0.000 description 3
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- 239000001301 oxygen Substances 0.000 description 3
- 239000002210 silicon-based material Substances 0.000 description 3
- 238000001039 wet etching Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000000407 epitaxy Methods 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 229910003828 SiH3 Inorganic materials 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- RJCRUVXAWQRZKQ-UHFFFAOYSA-N oxosilicon;silicon Chemical compound [Si].[Si]=O RJCRUVXAWQRZKQ-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02694—Controlling the interface between substrate and epitaxial layer, e.g. by ion implantation followed by annealing
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Abstract
一种外延层和3D NAND存储器的形成方法、退火设备,其中所述外延层的形成方法,先进行第一退火,以消除堆叠结构中产生的应力,在进行第一退火时,所述凹槽的侧壁和底部表面形成含硅的混合物,因而第一退火后,进行第二退火,进行第二退火,以去除所述凹槽侧壁和底部表面的含硅的混合物,使得后续在形成外延层时的生长界面为纯净的衬底材料界面,防止凹槽中形成的外延层中产生孔洞缺陷。
Description
PCT国内申请,说明书已公开。
Claims (23)
- PCT国内申请,权利要求书已公开。
Applications Claiming Priority (1)
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PCT/CN2018/116491 WO2020102990A1 (zh) | 2018-11-20 | 2018-11-20 | 外延层和3d nand存储器的形成方法、退火设备 |
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US (1) | US10741390B2 (zh) |
CN (1) | CN112997272B (zh) |
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WO (1) | WO2020102990A1 (zh) |
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CN111952317B (zh) * | 2020-08-04 | 2024-04-09 | 长江存储科技有限责任公司 | 三维存储器及其制备方法 |
CN113228279B (zh) * | 2021-03-31 | 2024-04-09 | 长江存储科技有限责任公司 | 用于形成半导体结构的方法 |
WO2023225199A1 (en) * | 2022-05-18 | 2023-11-23 | Applied Materials, Inc. | Epitaxial silicon channel growth |
US20230413569A1 (en) * | 2022-05-18 | 2023-12-21 | Applied Materials, Inc. | Epitaxial silicon channel growth |
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CN102800595A (zh) * | 2011-05-26 | 2012-11-28 | 中芯国际集成电路制造(上海)有限公司 | Nmos晶体管形成方法及对应cmos结构形成方法 |
CN103137462A (zh) * | 2011-11-25 | 2013-06-05 | 中芯国际集成电路制造(上海)有限公司 | 自对准金属硅化物的形成方法 |
CN103498196A (zh) * | 2008-09-29 | 2014-01-08 | 美格纳半导体有限会社 | 硅晶片的制造方法 |
CN107611130A (zh) * | 2017-08-23 | 2018-01-19 | 长江存储科技有限责任公司 | 一种3d nand闪存结构中硅外延生长的工艺 |
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KR100784860B1 (ko) * | 2005-10-31 | 2007-12-14 | 삼성전자주식회사 | 비휘발성 메모리 장치 및 그 제조 방법 |
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CN108807410B (zh) * | 2018-07-16 | 2021-02-05 | 长江存储科技有限责任公司 | 3d存储器件及其制造方法 |
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2018
- 2018-11-20 CN CN201880096615.5A patent/CN112997272B/zh active Active
- 2018-11-20 WO PCT/CN2018/116491 patent/WO2020102990A1/zh active Application Filing
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2019
- 2019-01-31 TW TW108103911A patent/TWI676273B/zh active
- 2019-01-31 TW TW108128012A patent/TWI693628B/zh active
- 2019-03-13 US US16/351,532 patent/US10741390B2/en active Active
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US20090004770A1 (en) * | 2007-06-26 | 2009-01-01 | Dongbu Hitek Co., Ltd. | Method for manufacturing vertical cmos image sensor |
CN103498196A (zh) * | 2008-09-29 | 2014-01-08 | 美格纳半导体有限会社 | 硅晶片的制造方法 |
CN102800595A (zh) * | 2011-05-26 | 2012-11-28 | 中芯国际集成电路制造(上海)有限公司 | Nmos晶体管形成方法及对应cmos结构形成方法 |
CN103137462A (zh) * | 2011-11-25 | 2013-06-05 | 中芯国际集成电路制造(上海)有限公司 | 自对准金属硅化物的形成方法 |
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US20200161131A1 (en) | 2020-05-21 |
WO2020102990A1 (zh) | 2020-05-28 |
TW202021099A (zh) | 2020-06-01 |
TWI676273B (zh) | 2019-11-01 |
US10741390B2 (en) | 2020-08-11 |
TW202020931A (zh) | 2020-06-01 |
TWI693628B (zh) | 2020-05-11 |
CN112997272B (zh) | 2024-03-29 |
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