CN111187482B - 耐白化性优异的聚丙烯树脂组合物及其制备方法、以及由其模制的成型品 - Google Patents

耐白化性优异的聚丙烯树脂组合物及其制备方法、以及由其模制的成型品 Download PDF

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CN111187482B
CN111187482B CN201911103017.9A CN201911103017A CN111187482B CN 111187482 B CN111187482 B CN 111187482B CN 201911103017 A CN201911103017 A CN 201911103017A CN 111187482 B CN111187482 B CN 111187482B
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ethylene
resin composition
propylene
polypropylene resin
polypropylene
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CN111187482A (zh
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金奉奭
林承薰
全龙成
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Hanwha TotalEnergies Petrochemical Co Ltd
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Hanwha Total Petrochemicals Co Ltd
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6423—Component of C08F4/64 containing at least two different metals
    • C08F4/6425—Component of C08F4/64 containing at least two different metals containing magnesium
    • C—CHEMISTRY; METALLURGY
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    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
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    • C08L2203/00—Applications
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    • C—CHEMISTRY; METALLURGY
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    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)
CN201911103017.9A 2018-11-14 2019-11-12 耐白化性优异的聚丙烯树脂组合物及其制备方法、以及由其模制的成型品 Active CN111187482B (zh)

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KR10-2018-0139836 2018-11-14
KR1020180139836A KR102124702B1 (ko) 2018-11-14 2018-11-14 내백화성이 우수한 폴리프로필렌 수지 조성물, 그 제조방법 및 그로부터 제조된 성형품

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Publication number Priority date Publication date Assignee Title
KR102494537B1 (ko) * 2020-12-03 2023-02-06 에쓰대시오일 주식회사 폴리프로필렌 수지 조성물, 그 제조방법 및 상기 폴리프로필렌 수지 조성물의 유변물성 측정방법

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001288330A (ja) * 2000-04-06 2001-10-16 Idemitsu Petrochem Co Ltd ポリプロピレン樹脂組成物及びそれを用いたレトルト食品包装用フィルム
KR20020077893A (ko) * 2000-01-26 2002-10-14 쇼와 덴코 플라스틱 프로덕츠 가부시키가이샤 프로필렌계 중합체 조성물, 그 필름 및 다층적층체
CN103145902A (zh) * 2013-02-28 2013-06-12 浙江大学 一种高乙丙橡胶含量的多相聚丙烯共聚物及其制备方法
KR20150145016A (ko) * 2014-06-18 2015-12-29 한화토탈 주식회사 이축연신 필름용 폴리프로필렌 수지
KR20160039406A (ko) * 2014-10-01 2016-04-11 한화토탈 주식회사 고충격 고강성 폴리프로필렌 수지 조성물, 이의 제조방법 및 이로 제조된 성형품
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
CN108329590A (zh) * 2018-02-08 2018-07-27 贵州省材料产业技术研究院 一种双峰结晶聚丙烯复合材料及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09104729A (ja) * 1995-06-26 1997-04-22 Showa Denko Kk プロピレンブロック共重合体およびその製造方法ならびにそれを用いたプロピレン樹脂組成物
JP3479163B2 (ja) * 1995-06-26 2003-12-15 昭和電工株式会社 ポリプロピレンフィルムおよびシート
US6844078B2 (en) * 2002-02-06 2005-01-18 Toray Plastics (America) Inc. Polyolefin oil resistant film using high isotactic content polypropylene
JP4571790B2 (ja) * 2003-09-11 2010-10-27 株式会社プライムポリマー 長繊維強化樹脂ペレット及びその成形体
US7863368B2 (en) * 2006-11-17 2011-01-04 Mitsui Chemicals, Inc. Propylene resin composition, process for producing propylene resin composition, propylene polymer composition, shaped article produced of the propylene resin composition, and electric wire
KR101298417B1 (ko) 2011-05-16 2013-08-20 삼성토탈 주식회사 내백화성, 내충격성 및 투명성이 우수한 폴리프로필렌 수지 및 이의 필름
KR101501835B1 (ko) * 2013-08-13 2015-03-12 삼성토탈 주식회사 내백화성 및 내충격성이 우수한 폴리프로필렌 수지 조성물
CN104558816B (zh) * 2013-10-12 2018-01-23 中国石油化工股份有限公司 一种聚丙烯组合物及其制备方法
KR101598715B1 (ko) 2014-11-12 2016-02-29 한화토탈 주식회사 폴리프로필렌 수지 조성물 및 이것으로 제조된 필름
KR101862917B1 (ko) * 2016-01-04 2018-05-30 한화토탈 주식회사 폴리프로필렌 수지 조성물 및 이것으로 제조된 성형품

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020077893A (ko) * 2000-01-26 2002-10-14 쇼와 덴코 플라스틱 프로덕츠 가부시키가이샤 프로필렌계 중합체 조성물, 그 필름 및 다층적층체
JP2001288330A (ja) * 2000-04-06 2001-10-16 Idemitsu Petrochem Co Ltd ポリプロピレン樹脂組成物及びそれを用いたレトルト食品包装用フィルム
CN103145902A (zh) * 2013-02-28 2013-06-12 浙江大学 一种高乙丙橡胶含量的多相聚丙烯共聚物及其制备方法
CN105899599A (zh) * 2014-01-15 2016-08-24 埃克森美孚化学专利公司 基于丙烯的抗冲共聚物
KR20150145016A (ko) * 2014-06-18 2015-12-29 한화토탈 주식회사 이축연신 필름용 폴리프로필렌 수지
KR20160039406A (ko) * 2014-10-01 2016-04-11 한화토탈 주식회사 고충격 고강성 폴리프로필렌 수지 조성물, 이의 제조방법 및 이로 제조된 성형품
CN108329590A (zh) * 2018-02-08 2018-07-27 贵州省材料产业技术研究院 一种双峰结晶聚丙烯复合材料及其制备方法

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KR20200056523A (ko) 2020-05-25
JP6910407B2 (ja) 2021-07-28
KR102124702B1 (ko) 2020-06-19
JP2020084176A (ja) 2020-06-04
CN111187482A (zh) 2020-05-22

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