CN110799354B - 包括至少一种作为无机增强填料的二氧化硅的橡胶组合物 - Google Patents

包括至少一种作为无机增强填料的二氧化硅的橡胶组合物 Download PDF

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Publication number: CN110799354B
Authority: CN; China
Prior art keywords: ctab; silica; weight; specific surface; surface area
Prior art date: 2017-05-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

CN201880042725.3A

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English (en)

Chinese (zh)

Other versions

CN110799354A (zh

Inventor

A·帕夫拉克

E·阿兰奈曼

S·巴代尔

C·法约勒

P·加尔贝

L·居伊

S·内沃

F·斯托克卢瑟

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Compagnie Generale des Etablissements Michelin SCA

Original Assignee

Compagnie Generale des Etablissements Michelin SCA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2017-05-05

Filing date

2018-05-03

Publication date

2021-03-30

2018-05-03 Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA

2020-02-14 Publication of CN110799354A publication Critical patent/CN110799354A/zh

2021-03-30 Application granted granted Critical

2021-03-30 Publication of CN110799354B publication Critical patent/CN110799354B/zh

Status Active legal-status Critical Current

2038-05-03 Anticipated expiration legal-status Critical

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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 474
239000000377 silicon dioxide Substances 0.000 title claims abstract description 238
239000000203 mixture Substances 0.000 title claims abstract description 210
229920001971 elastomer Polymers 0.000 title claims abstract description 188
239000005060 rubber Substances 0.000 title claims abstract description 79
239000012763 reinforcing filler Substances 0.000 title abstract description 10
239000000806 elastomer Substances 0.000 claims abstract description 109
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 61
229910052782 aluminium Inorganic materials 0.000 claims abstract description 57
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 45
238000004062 sedimentation Methods 0.000 claims abstract description 37
239000002245 particle Substances 0.000 claims abstract description 28
238000009826 distribution Methods 0.000 claims abstract description 26
239000011265 semifinished product Substances 0.000 claims abstract description 22
238000004132 cross linking Methods 0.000 claims abstract description 21
230000008878 coupling Effects 0.000 claims abstract description 20
238000010168 coupling process Methods 0.000 claims abstract description 20
238000005859 coupling reaction Methods 0.000 claims abstract description 20
230000003014 reinforcing effect Effects 0.000 claims description 86
239000011256 inorganic filler Substances 0.000 claims description 81
229910003475 inorganic filler Inorganic materials 0.000 claims description 80
229920003244 diene elastomer Polymers 0.000 claims description 62
238000000034 method Methods 0.000 claims description 61
230000008569 process Effects 0.000 claims description 32
239000003795 chemical substances by application Substances 0.000 claims description 31
238000004519 manufacturing process Methods 0.000 claims description 24
239000006229 carbon black Substances 0.000 claims description 21
239000004411 aluminium Substances 0.000 claims description 16
238000004898 kneading Methods 0.000 claims description 12
239000012766 organic filler Substances 0.000 claims description 11
238000001816 cooling Methods 0.000 claims description 9
239000011717 all-trans-retinol Substances 0.000 claims description 2
239000007822 coupling agent Substances 0.000 abstract description 24
239000000243 solution Substances 0.000 description 144
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 111
239000012429 reaction media Substances 0.000 description 72
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 48
239000002253 acid Substances 0.000 description 48
239000000523 sample Substances 0.000 description 48
-1 vinyl aromatic compounds Chemical class 0.000 description 38
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 36
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
239000004115 Sodium Silicate Substances 0.000 description 34
125000000524 functional group Chemical group 0.000 description 34
229910052911 sodium silicate Inorganic materials 0.000 description 33
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 33
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 32
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RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 31
229920001577 copolymer Polymers 0.000 description 29
239000000725 suspension Substances 0.000 description 24
OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 23
150000001399 aluminium compounds Chemical class 0.000 description 20
235000019241 carbon black Nutrition 0.000 description 20
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 17
238000005096 rolling process Methods 0.000 description 17
238000002360 preparation method Methods 0.000 description 16
238000003756 stirring Methods 0.000 description 16
238000005259 measurement Methods 0.000 description 15
DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 14
229920001021 polysulfide Polymers 0.000 description 14
239000003981 vehicle Substances 0.000 description 14
239000005062 Polybutadiene Substances 0.000 description 13
239000000945 filler Substances 0.000 description 13
239000005077 polysulfide Substances 0.000 description 13
150000008117 polysulfides Polymers 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 12
239000012065 filter cake Substances 0.000 description 12
229910044991 metal oxide Inorganic materials 0.000 description 12
150000004706 metal oxides Chemical class 0.000 description 12
238000004073 vulcanization Methods 0.000 description 12
238000004458 analytical method Methods 0.000 description 11
150000001993 dienes Chemical class 0.000 description 11
239000000126 substance Substances 0.000 description 11
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 10
125000004432 carbon atom Chemical group C* 0.000 description 10
239000003792 electrolyte Substances 0.000 description 10
TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 10
229910052717 sulfur Inorganic materials 0.000 description 10
238000012360 testing method Methods 0.000 description 10
238000005303 weighing Methods 0.000 description 10
238000004497 NIR spectroscopy Methods 0.000 description 9
230000009477 glass transition Effects 0.000 description 9
239000004014 plasticizer Substances 0.000 description 9
239000000047 product Substances 0.000 description 9
229920005989 resin Polymers 0.000 description 9
239000011347 resin Substances 0.000 description 9
235000012239 silicon dioxide Nutrition 0.000 description 9
239000011734 sodium Substances 0.000 description 9
239000007787 solid Substances 0.000 description 9
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
125000000217 alkyl group Chemical group 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 8
125000003636 chemical group Chemical group 0.000 description 8
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238000009472 formulation Methods 0.000 description 8
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239000011159 matrix material Substances 0.000 description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
238000005299 abrasion Methods 0.000 description 7
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 7
239000003963 antioxidant agent Substances 0.000 description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
230000006870 function Effects 0.000 description 7
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 7
238000002347 injection Methods 0.000 description 7
239000007924 injection Substances 0.000 description 7
239000000463 material Substances 0.000 description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
150000003254 radicals Chemical class 0.000 description 7
229910001388 sodium aluminate Inorganic materials 0.000 description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
230000003078 antioxidant effect Effects 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
125000004122 cyclic group Chemical group 0.000 description 6
238000001035 drying Methods 0.000 description 6
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230000014509 gene expression Effects 0.000 description 6
239000000178 monomer Substances 0.000 description 6
229910000077 silane Inorganic materials 0.000 description 6
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 6
125000005372 silanol group Chemical group 0.000 description 6
229910052710 silicon Inorganic materials 0.000 description 6
229910052938 sodium sulfate Inorganic materials 0.000 description 6
238000001179 sorption measurement Methods 0.000 description 6
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
150000003512 tertiary amines Chemical class 0.000 description 6
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 5
125000003277 amino group Chemical group 0.000 description 5
238000000889 atomisation Methods 0.000 description 5
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229920002857 polybutadiene Polymers 0.000 description 5
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230000002829 reductive effect Effects 0.000 description 5
150000004756 silanes Chemical class 0.000 description 5
238000004448 titration Methods 0.000 description 5
229920002554 vinyl polymer Polymers 0.000 description 5
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 4
KZTCAXCBXSIQSS-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-4-n-phenylbenzene-1,4-diamine Chemical compound C=1C=C(N)C=CC=1N(C(C)CC(C)C)C1=CC=CC=C1 KZTCAXCBXSIQSS-UHFFFAOYSA-N 0.000 description 4
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
239000005642 Oleic acid Substances 0.000 description 4
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
235000021355 Stearic acid Nutrition 0.000 description 4
229930006000 Sucrose Natural products 0.000 description 4
235000019486 Sunflower oil Nutrition 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000012512 characterization method Methods 0.000 description 4
229910052681 coesite Inorganic materials 0.000 description 4
229910052906 cristobalite Inorganic materials 0.000 description 4
230000007423 decrease Effects 0.000 description 4
125000002897 diene group Chemical group 0.000 description 4
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
239000012530 fluid Substances 0.000 description 4
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
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QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
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239000000376 reactant Substances 0.000 description 4
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WRTFVQOWILDODC-UHFFFAOYSA-N silane triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound [SiH4].CCO[Si](CCCSSSSCCC[Si](OCC)(OCC)OCC)(OCC)OCC WRTFVQOWILDODC-UHFFFAOYSA-N 0.000 description 4
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QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
239000007832 Na2SO4 Substances 0.000 description 3
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238000010539 anionic addition polymerization reaction Methods 0.000 description 3
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230000001588 bifunctional effect Effects 0.000 description 3
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FBELJLCOAHMRJK-UHFFFAOYSA-L disodium;2,2-bis(2-ethylhexyl)-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCC(CC)CC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CC(CC)CCCC FBELJLCOAHMRJK-UHFFFAOYSA-L 0.000 description 3
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CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 3
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MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
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AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
WITDFSFZHZYQHB-UHFFFAOYSA-N dibenzylcarbamothioylsulfanyl n,n-dibenzylcarbamodithioate Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)C(=S)SSC(=S)N(CC=1C=CC=CC=1)CC1=CC=CC=C1 WITDFSFZHZYQHB-UHFFFAOYSA-N 0.000 description 2
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238000000113 differential scanning calorimetry Methods 0.000 description 2
125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 2
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TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 2
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BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
239000004570 mortar (masonry) Substances 0.000 description 2
IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
125000004433 nitrogen atom Chemical group N* 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
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239000011148 porous material Substances 0.000 description 2
KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
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Classifications

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- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/22—Oxides; Hydroxides of metals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/36—Silica
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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CN201880042725.3A 2017-05-05 2018-05-03 包括至少一种作为无机增强填料的二氧化硅的橡胶组合物 Active CN110799354B (zh)

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FR1753968A FR3065960B1 (fr)	2017-05-05	2017-05-05	Composition de caoutchouc comprenant au moins une silice en tant que charge renforcante inorganique
FR1753968		2017-05-05
PCT/FR2018/051099 WO2018203002A1 (fr)	2017-05-05	2018-05-03	Composition de caoutchouc comprenant au moins une silice en tant que charge renforcante inorganique

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US (1)	US11111360B2 (ko)
EP (1)	EP3619051B1 (ko)
JP (1)	JP6796216B2 (ko)
KR (1)	KR102128918B1 (ko)
CN (1)	CN110799354B (ko)
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CN111289731A (zh) *	2020-03-07	2020-06-16	深圳天溯计量检测股份有限公司	无转子硫化仪及其使用方法
CN113736155B (zh) *	2021-09-02	2023-01-24	赛轮集团股份有限公司	抗湿滑橡胶组合物、其混炼方法和应用

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2017
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- 2018-05-03 JP JP2019560636A patent/JP6796216B2/ja active Active
- 2018-05-03 EP EP18728214.0A patent/EP3619051B1/fr active Active
- 2018-05-03 CN CN201880042725.3A patent/CN110799354B/zh active Active
- 2018-05-03 KR KR1020197032588A patent/KR102128918B1/ko active IP Right Grant
- 2018-05-03 US US16/610,685 patent/US11111360B2/en active Active
- 2018-05-03 WO PCT/FR2018/051099 patent/WO2018203002A1/fr active Application Filing

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US20200165419A1 (en)	2020-05-28
WO2018203002A1 (fr)	2018-11-08
FR3065960A1 (fr)	2018-11-09
US11111360B2 (en)	2021-09-07
CN110799354A (zh)	2020-02-14
JP6796216B2 (ja)	2020-12-02
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2021-03-30	GR01	Patent grant
2021-03-30	GR01	Patent grant

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