CN110526574B - Preparation method of crystal wine bottle cap - Google Patents
Preparation method of crystal wine bottle cap Download PDFInfo
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- CN110526574B CN110526574B CN201910983450.XA CN201910983450A CN110526574B CN 110526574 B CN110526574 B CN 110526574B CN 201910983450 A CN201910983450 A CN 201910983450A CN 110526574 B CN110526574 B CN 110526574B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
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Abstract
The invention relates to the field of wine bottle package manufacturing, and provides a preparation method of a crystal wine bottle cap; the method comprises the steps of material preparation, melting, pressing, fire polishing, annealing in an annealing furnace, post-treatment and the like; the crystal wine bottle cap disclosed by the invention has crystal glittering and translucent feeling and attractive and elegant appearance, and is very helpful for improving the grade of wine product packaging; the crystal material adopted by the crystal bottle cap has high transparency, refractive index and strength, so that the collection and viewing values of wine products are improved sharply.
Description
Technical Field
The invention relates to the field of wine bottle packaging and manufacturing, in particular to a preparation method of a crystal wine bottle cap.
Background
Wine culture is very important in the world, and especially Chinese wine means very important introduction, wine drinking is helpful, delightful atmosphere is created, high-quality and beautiful wine bottles mean grade and grade, and have collection value.
To speed up the fining process of the glass, small amounts of fining agents are often added to the batch materials. The effects of the clarifying agents are different, most of the clarifying agents can vaporize or decompose to release gas at high temperature, so that the partial pressure of the gas in the glass liquid is greater than that of the gas in the small bubbles in a balanced state, the balance among the kiln gas, the glass liquid and the small bubbles is broken, the bubbles in the glass liquid enter the small bubbles, the small bubbles are changed into large bubbles and are discharged, and the clarification is achieved.
Along with the increase of rare earth yield in China, the application of rare earth in glass production is increasingly wide, and particularly, the clarification effect of cerium oxide is superior to that of white arsenic. In the glass production of China, arsenic trioxide with high toxicity is used as a clarifier for a long time, so that the environment is seriously polluted and the health of human bodies is harmed, and cerium oxide is used as the clarifier, so that the environmental pollution can be thoroughly eradicated, and the quality of glass products can be stabilized and improved.
Due to rare earth Ce O2Is a strong oxidant which can be decomposed at high temperature to generate Ce2O3And release a certain amount of O2, O2And the glass enters the bubbles of the molten glass, so that the partial pressure of gas in the bubbles is reduced, the bubbles continuously absorb the gas, the volume of the bubbles is increased, the rising is accelerated, and the purpose of clarifying the glass is achieved. CeO (CeO)2Has a melting temperature of 1950 deg.C, a density of 7.30g/cm3, and an oxygen release capacity of 4.65 wt%. The reaction equation is as follows:
CeO2as in comparison2O3Has larger chemical potential, and uses cerium oxide for decoloring than white arsenic for decoloring Fe in glass2+The conversion rate of (a) is increased. But adding an excess of CeO2The glass shell is light yellow and the color of the glass shell is changed with that of CeO2The dosage is increased and becomes deeper.
201821185310.5 discloses a quartzy handicraft formula red wine bottle mouth stopper, relate to red wine bottle mouth stopper technical field, including the gag, one side fixedly connected with bottle plug of gag, the equal fixedly connected with ejector pin in one side both ends of gag, the notch has been seted up to the one end of ejector pin, the inside swing joint of notch has the turning block, the square groove has been seted up to one side of turning block, the inside swing joint in square groove has the vaulting pole, the laminating of the surface of vaulting pole is connected with torsion spring, the opposite side fixedly connected with fixture block of turning block, the draw-in groove has all been seted up at one side both ends of bottle plug, the screw hole has been seted up to one side of draw-in groove, the one end card of screw hole is equipped with the circular slot, the inside swing joint of screw hole has the screw rod. This quartzy handicraft formula red wine bottle mouth stopper, vaulting pole can make the commentaries on classics piece rotate at the notch, and torsion spring can make fixture block automatic re-setting, and the business turn over of ejector pin can be convenient for to the draw-in groove makes the installation or dismantle be convenient for between gag and the bottle plug, and the fixture block can make gag and bottle plug fixed with the cooperation of screw rod.
201020568719.2 relates to a wine bottle, especially a crystal decorative wine bottle with collection value, a groove is arranged on the outer wall of the bottle body, a transparent crystal decorative block carved or painted with images and patterns is adapted to the shape of the groove and is fixedly embedded in the groove. The utility model discloses a through decorating the piece with transparent crystal and imbedding on the outer wall of bottle, transparent crystal decorates the piece and carves or draw pattern, image according to the content of celebration festival, and personalized customization has commemorative blessing characters, personage image, enterprise and public institution name, activity sign etc. makes the beverage bottle more have collection value and commemorative meaning.
200920129023.7 discloses a flow-control crystal wine bottle plug, which comprises a decorative head, a wine outlet sealing cover and a wine outlet, wherein the wine outlet is a flow-guide and flow-control bottle plug, one or more flow-control baffle plates for controlling flow holes are arranged in a wine outlet channel, an anti-hooking annular boss is arranged at the upper part of the wine outlet, and a plurality of annular sealing rings are arranged on the outer surface of the lower part of the wine outlet. The wine outlet sealing cover is internally provided with an annular clamping table in the top connecting hole, and the lower part of the wine outlet sealing cover is provided with an annular sealing column. The surface of the central cylinder at the lower part of the decorative head is provided with an annular groove. When empting liquid, thereby realize through accuse discharge orifice that accuse flows the function and realize the utility model relates to a purpose. The appearance is simple and beautiful, and the glittering and translucent feeling of the crystal transparent head is fully maintained.
The wine bottle caps disclosed by the above patents and the prior art only have decorative performance, the quality of the crystal bottle caps, such as transparency, strength and the like, is unsatisfactory, the collection and ornamental value of wine products are greatly influenced, and the phenomenon of 'starry sky' can occur when pure cerium oxide is used as a clarifying agent in the industry alone. Cerium oxide has a strong ability to release oxygen, releases a large amount of oxygen at high temperature in a short time, and has a very fast diffusion rate in glass. Therefore, when at the fining temperature, a large amount of foam is easily instantaneously generated on the surface of the glass melt, resulting in O2The discharge is difficult, and the clarification effect is influenced. Has influence on the transmittance and decolorization of glass, and the cerium oxide is Fe2+Is oxidized into Fe3+The optical density of the glass is reduced, and the transmittance is increased; when the amount of cerium oxide is continuously increased, the glass sample is colored and the transmittance is decreased. This may be due to excessive Fe3+And Ce4+The glass is colored so that the optical density of the glass increases and the transmittance decreases.
Disclosure of Invention
In order to solve the problems, the invention provides a preparation method of a crystal wine bottle cap.
A crystal wine bottle cap is made of the following materials: 10-20 parts of glass; 100-400 parts of quartz sand; 70-90 parts of soda ash; 20-30 parts of potassium carbonate; 4-9 parts of barium carbonate; 50-80 parts of calcite; 10-15 parts of borax; 4-8 parts of sodium nitrate; 3-8 parts of sodium fluosilicate; 2-7 parts of a clarifying agent; 4-8 parts of alumina; 0.5-1.2 parts of antimony oxide; 0.8-1.2 parts of copper oxide; 0.04-0.08 parts of cobalt oxide; 0.01-0.09 parts of zirconium oxide.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
according to the mass portion, 5-10 portions of rubidium oxide and 1-8 portions of cerium oxide are evenly mixed and then calcined for 5-15min, then evenly stirred and mixed with 10-20 portions of fumed silica, 15-30 portions of bentonite, 0.01-0.5 portion of perfluoroalkyl silyl mica, 3-9 portions of sodium fluosilicate and 0.5-5 portions of nano zinc oxide to obtain inorganic solid material, then 0.3-2.6 portions of sodium N, N-dimethyl dithioformamide propane sulfonate, 0.2-2.7 portions of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.05-0.9 portion of sodium triacetoxyborohydride are dissolved in 30-50 portions of purified water and added into the inorganic solid material, mixed and stirred for 20-30min at 70-90 ℃, and then dried with 150-phase at 200 ℃, grinding into powder to obtain the organic-inorganic hybrid glass clarifying agent.
After the rare earth oxide is calcined at the temperature of 600-800 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400-1600 ℃, melting for 30-50h, filtering, and then discharging;
step three, a press machine, wherein the melted materials are subjected to constant temperature of 800-;
step four, performing fire polishing, controlling the temperature at 750-850 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing is carried out in the degradation furnace by five sections of temperature zones, namely a first section of 580-;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The invention has the technical effects that:
(1) the crystal wine bottle cap disclosed by the invention has crystal glittering and translucent feeling, is attractive and elegant in appearance, and is very helpful for improving the grade of wine product packaging; moreover, the crystal material adopted by the crystal bottle cap has high transparency, refractive index and strength, so that the collection and viewing values of wine products are improved sharply.
(2) The organic-inorganic hybrid glass fining agent has the advantage of not preferentially oxidizing selenium as arsenic trioxide during the oxidation process. Thus, selenium is still present in the zero-valent state. Because the decolouring effect of the organic-inorganic hybrid glass clarifier is better, the decolouring agent does not need to depend on physical decolouring agent too much, the dosage can be reduced by about 50 percent, and cobalt can not be added completely. In the melting process, the organic-inorganic hybrid glass refining agent does not need to specially control the atmosphere like arsenic trioxide, and is not easily influenced by the fluctuation of the kiln temperature like selenium, arsenic trioxide and antimony. Cerium is much less volatile and therefore has less dust and off-gas losses. The organic-inorganic hybrid glass clarifier can be used as both a decoloring agent and a clarifying agent to completely eliminate the danger caused by adding arsenic trioxide and antimony. The organic-inorganic hybrid glass clarifier can absorb ultraviolet rays.
(3) The organic-inorganic hybrid glass clarifying agent solves the problem that CeO is present2A great deal of foam is easily generated on the surface of the glass melt instantly at the clarification temperature, which causes O2The perfluoroalkyl silyl mica provides a gas barrier layer to stabilize and smooth the generation of oxygen without generating a large amount of foam. Sodium triacetoxyborohydride delays the process of oxidizing Fe2+ into Fe3+ by cerium oxide, and avoids the defects of coloring of a glass sample and reduction of transmittance caused by single use of cerium oxide. The refractive index of the sample can reach 1.6602,the transmittance can reach 93.1%.
Drawings
FIG. 1 is a Fourier infrared spectrum of a sample of the organic-inorganic hybrid glass fining agent prepared in example 1.
Detailed Description
The invention is further illustrated by the following specific examples:
the sample is prepared into a glass small block with the thickness of 10mm 20mm 5mm, the refractive index of the sample is measured by an Abbe refractometer, and the transmittance of the glass in a visible light region is measured by an Shimadzu multifunctional optical instrument.
Example 1
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 10g of borax; 4g of sodium nitrate; 3g of sodium fluosilicate; 2g of a clarifying agent; 4g of alumina; 0.5g of antimony oxide; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 5g of rubidium oxide and 1g of cerium oxide, calcining at high temperature for 5min, then uniformly stirring and mixing the obtained calcined rare earth oxide with 10g of fumed silica, 15g of bentonite, 0.03g of perfluoroalkyl silyl mica, 3g of sodium fluosilicate and 0.5g of nano zinc oxide to obtain an inorganic solid material, then dissolving 3g of N, N-dimethyl dithioformamide propane sodium sulfonate, 0.8g of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.3g of sodium triacetoxyborohydride in 36g of purified water, adding the inorganic solid material into the inorganic solid material, mixing and stirring for 20min at 70 ℃, then drying at 150 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 600 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6571, and the transmittance was 92.3%.
FIG. 1 is a Fourier infrared spectrum of a practical organic-inorganic hybrid glass fining agent.
As can be seen from FIG. 1, 780cm-1An absorption peak of silicon dioxide exists nearby, which indicates that the fumed silicon dioxide participates in the reaction; 745cm-1An absorption peak of sodium fluosilicate exists nearby, which indicates that the sodium fluosilicate participates in the reaction; 452cm-1An absorption peak of cerium oxide exists nearby, which indicates that the cerium oxide participates in the reaction; 1414cm-1An absorption peak of silicon carbon exists nearby, which indicates that the perfluoroalkyl silyl mica participates in the reaction; 1189cm-1Nearby P = O absorption peaks of phosphate ion, 2916 and 2859cm-1An absorption peak of hydrocarbon exists nearby, which indicates that hexadecyl trimethyl ammonium dihydrogen phosphate participates in the reaction; 1094cm-1An absorption peak of a carbon-nitrogen single bond is present nearby, 1063cm-1An absorption peak of sulfate ions exists nearby, which indicates that N, N-dimethyl dithioformamide propane sodium sulfonate participates in the reaction; 1731cm-1An absorption peak of C = O exists nearby, which indicates that sodium triacetoxyborohydride participates in the reaction.
Example 2
A crystal wine bottle cap is made of the following materials: 15g of glass; 300g of quartz sand; 80g of soda ash; 25g of potassium carbonate; 7g of barium carbonate; 60g of calcite; 13g of borax; 6g of sodium nitrate; 5g of sodium fluosilicate; 5g of a clarifying agent; 6g of alumina; 0.8g of antimony oxide; 1g of copper oxide; 0.06g of cobalt oxide; 0.05g of zirconium oxide.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 8g of rubidium oxide and 4g of cerium oxide, calcining at high temperature for 10min, then uniformly stirring and mixing the obtained calcined rare earth oxide with 15g of fumed silica, 20g of bentonite, 0.01g of perfluoroalkyl silyl mica, 6g of sodium fluosilicate and 2.5g of nano zinc oxide to obtain an inorganic solid material, then dissolving 5g of N, N-dimethyl dithioformamide propane sodium sulfonate, 2.6g of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.05g of sodium triacetoxyborohydride in 30g of purified water, adding the inorganic solid material into the inorganic solid material, mixing and stirring for 25min at 80 ℃, then drying at 180 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 700 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1500 ℃, melting for 40 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 900 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 800 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone of 550 ℃, a second zone of 520 ℃, a third zone of 480 ℃, a fourth zone of 450 ℃ and a fifth zone of 420 ℃, so that the toughness is removed and the hardness of the crystal is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6582, and the transmittance was 92.8%.
Example 3
A crystal wine bottle cap is made of the following materials: 15g of glass; 200g of quartz sand; 80g of soda ash; 25g of potassium carbonate; 6g of barium carbonate; 60g of calcite; 13g of borax; 6g of sodium nitrate; 5g of sodium fluosilicate; 5g of a clarifying agent; 6g of alumina; 0.9g of antimony oxide; 1.2g of copper oxide; 0.08g of cobalt oxide; 0.09g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
the preparation method comprises the steps of uniformly mixing 10g of rubidium oxide and 8g of cerium oxide, calcining at high temperature for 15min, then uniformly mixing the obtained calcined rare earth oxide with 20g of fumed silica, 30g of bentonite, 0.05g of perfluoroalkyl silyl mica, 9g of sodium fluosilicate and 5g of nano zinc oxide by stirring to obtain an inorganic solid material, then dissolving 8g of N, N-dimethyl dithioformamide propane sodium sulfonate, 3.6g of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.9g of sodium triacetoxyborohydride in 50g of purified water, adding the inorganic solid material into the inorganic solid material, mixing and stirring for 30min at 90 ℃, then drying at 200 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 800 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1600 ℃, melting for 50 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at the constant temperature of 1000 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature to be 850 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 530 ℃, a second zone 500 ℃, a third zone 470 ℃, a fourth zone 430 ℃ and a fifth zone 400 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6602, and the transmittance was 93.1%.
Comparative example 1
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 4g of sodium nitrate; 3g of sodium fluosilicate; 2g of a clarifying agent; 4g of alumina; 0.5g of antimony oxide; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 5g of rubidium oxide and 1g of cerium oxide, calcining at high temperature for 5min, then uniformly stirring and mixing the obtained calcined rare earth oxide with 10g of fumed silica, 15g of bentonite, 0.03g of perfluoroalkyl silyl mica, 3g of sodium fluosilicate and 0.5g of nano zinc oxide to obtain an inorganic solid material, then dissolving 0.8g of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.3g of sodium triacetoxyborohydride in 36g of purified water, adding the mixture into the inorganic solid material, mixing and stirring at 70 ℃ for 20min, then drying at 150 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 600 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6171, and the transmittance was 91.3%.
Comparative example 2
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 10g of borax; 4g of sodium nitrate; 3g of sodium fluosilicate; 4g of alumina; 0.5g of antimony oxide; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.5522, and the transmittance was 87.4%.
Comparative example 3
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 10g of borax; 4g of sodium nitrate; 3g of sodium fluosilicate; 2g of a clarifying agent; 4g of alumina; 0.5g of antimony oxide; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 5g of rubidium oxide and 1g of cerium oxide, calcining at high temperature for 5min, then uniformly stirring and mixing the obtained calcined rare earth oxide with 10g of fumed silica, 15g of bentonite, 0.03g of perfluoroalkyl silyl mica, 3g of sodium fluosilicate and 0.5g of nano zinc oxide to obtain an inorganic solid material, then dissolving 3g of N, N-dimethyl dithioformamide propane sodium sulfonate and 0.3g of sodium triacetoxyborohydride in 36g of purified water, adding the mixture into the inorganic solid material, mixing and stirring at 70 ℃ for 20min, then drying at 150 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 600 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6124, and the transmittance was 91.7%.
Comparative example 4
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 10g of borax; 4g of sodium nitrate; 2g of a clarifying agent; 4g of alumina; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 5g of rubidium oxide and 1g of cerium oxide, calcining at high temperature for 5min, then uniformly stirring and mixing the obtained calcined rare earth oxide with 10g of fumed silica, 15g of bentonite, 0.03g of perfluoroalkyl silyl mica, 3g of sodium fluosilicate and 0.5g of nano zinc oxide to obtain an inorganic solid material, then dissolving 3g of N, N-dimethyl dithioformamide propane sodium sulfonate and 0.8g of hexadecyl trimethyl ammonium dihydrogen phosphate in 36g of purified water, adding the mixture into the inorganic solid material, mixing and stirring at 70 ℃ for 20min, then drying at 150 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 600 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6071, and the transmittance was 88.7%.
Comparative example 5
A crystal wine bottle cap is made of the following materials: 10g of glass; 100g of quartz sand; 70g of soda ash; 20g of potassium carbonate; 4g of barium carbonate; 50g of calcite; 10g of borax; 4g of sodium nitrate; 3g of sodium fluosilicate; 2g of a clarifying agent; 4g of alumina; 0.5g of antimony oxide; 0.8g of copper oxide; 0.04g of cobalt oxide; 0.01g of zirconia.
The clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
uniformly mixing 5g of rubidium oxide and 1g of cerium oxide, calcining at high temperature for 5min, uniformly stirring and mixing the obtained calcined rare earth oxide with 10g of fumed silica, 15g of bentonite, 3g of sodium fluosilicate and 0.5g of nano zinc oxide to obtain an inorganic solid material, dissolving 3g of sodium N, N-dimethyldithioformamide propane sulfonate, 0.8g of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.3g of sodium triacetoxyborohydride in 36g of purified water, adding the mixture into the inorganic solid material, mixing and stirring at 70 ℃ for 20min, drying at 150 ℃, and grinding into powder to obtain the organic-inorganic hybrid glass clarifier.
After the rare earth oxide is calcined at 600 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
The quartz chip content of the quartz sand reaches more than 98 percent.
The crystal wine bottle cap is prepared according to the following scheme:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400 ℃, melting for 30 hours, and then discharging;
step three, a press, namely, keeping the temperature of the melted materials at 800 ℃ by a feeding machine to obtain crystal soft blocks, and then performing film pressing forming and shaping;
step four, performing fire polishing, controlling the temperature at 750 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing furnace is used for annealing in five temperature zones, namely a first zone 580 ℃, a second zone 530 ℃, a third zone 500 ℃, a fourth zone 470 ℃ and a fifth zone 430 ℃, so that the toughness is removed and the crystal hardness is improved;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
The refractive index of the sample was 1.6011, and the transmittance was 86.5%.
Claims (4)
1. The preparation method of the crystal wine bottle cap is characterized in that the wine bottle cap is made of the following materials: 10-20 parts of glass; 100-400 parts of quartz sand; 70-90 parts of soda ash; 20-30 parts of potassium carbonate; 4-9 parts of barium carbonate; 50-80 parts of calcite; 10-15 parts of borax; 4-8 parts of sodium nitrate; 3-8 parts of sodium fluosilicate; 2-7 parts of a clarifying agent; 4-8 parts of alumina; 0.5-1.2 parts of antimony oxide; 0.8-1.2 parts of copper oxide; 0.04-0.08 parts of cobalt oxide; 0.01-0.09 parts of zirconium oxide;
the clarifying agent is an organic-inorganic hybrid glass clarifying agent, and the preparation method comprises the following steps:
according to the mass portion, 5-10 portions of rubidium oxide and 1-8 portions of cerium oxide are evenly mixed and then calcined for 5-15min, then evenly stirred and mixed with 10-20 portions of fumed silica, 15-30 portions of bentonite, 0.01-0.5 portion of perfluoroalkyl silyl mica, 3-9 portions of sodium fluosilicate and 0.5-5 portions of nano zinc oxide to obtain inorganic solid material, then 0.3-2.6 portions of sodium N, N-dimethyl dithioformamide propane sulfonate, 0.2-2.7 portions of hexadecyl trimethyl ammonium dihydrogen phosphate and 0.05-0.9 portion of sodium triacetoxyborohydride are dissolved in 30-50 portions of purified water and added into the inorganic solid material, mixed and stirred for 20-30min at 70-90 ℃, and then dried at the temperature of 150 and 200 ℃, grinding into powder to obtain the organic-inorganic hybrid glass clarifying agent.
2. The preparation method of the crystal wine bottle cap according to claim 1, wherein the method comprises the following steps: after the rare earth oxide is calcined at the temperature of 600-800 ℃ in the air atmosphere, an oxygen-deficient phase is transformed to generate an oxygen-rich phase.
3. The preparation method of the crystal wine bottle cap according to claim 1, wherein the method comprises the following steps: the quartz chip content of the quartz sand reaches more than 98 percent.
4. The preparation method of the crystal wine bottle cap according to claim 1, wherein the method comprises the following steps: the preparation method comprises the following steps:
step one, batching, namely weighing all the batchings according to the formula, putting the batchings into a mixing kettle, and uniformly mixing the batchings in a stirrer;
step two, melting, namely putting the uniformly mixed materials into a total oxygen furnace or an electric furnace for melting, melting at 1400-1600 ℃, melting for 30-50h, filtering, and then discharging;
step three, a press machine, wherein the melted materials are subjected to constant temperature of 800-;
step four, performing fire polishing, controlling the temperature at 750-850 ℃, and polishing the surface of the crystal to be smooth;
annealing in an annealing furnace, wherein the annealing is carried out in the degradation furnace by five sections of temperature zones, namely a first section of 580-;
and step six, post-treatment, including inspection, inner carving, deep processing and finished product beautification.
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