CN110526574A - A kind of preparation method of crystal wine bottle cover - Google Patents
A kind of preparation method of crystal wine bottle cover Download PDFInfo
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- CN110526574A CN110526574A CN201910983450.XA CN201910983450A CN110526574A CN 110526574 A CN110526574 A CN 110526574A CN 201910983450 A CN201910983450 A CN 201910983450A CN 110526574 A CN110526574 A CN 110526574A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
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Abstract
The present invention relates to bottles to pack manufacturing field, and the present invention provides a kind of preparation methods of crystal wine bottle cover；The method of the present invention includes ingredient, melting, press, carries out fiery throwing, anneal and post-treating and other steps；A kind of crystal wine bottle cover disclosed by the invention has the sparkling and crystal-clear sense of crystal, and the appearance is beautiful and elegant, very helpful for the class for promoting wine product packaging；The crystal material that crystal bottle cap of the invention uses has very high transparency and refractive index and intensity, so that the collection of wine product and ornamental value are sharply promoted.
Description
Technical field
The present invention relates to bottles to pack manufacturing field, particularly with regard to a kind of preparation method of crystal wine bottle cover.
Background technique
Worldwide spirits culture is all extremely important, particularly in China wine mean it is critically important be particular about, drink and help
It is emerging, set off happy expression atmosphere by contrast, the bottle of high quality and beauty means class and grade, and great has reserve value.
For the clarifying process for accelerating glass, a small amount of clarifying agent is often added in batch.The effect of clarifying agent is had nothing in common with each other,
Most of clarifying agents itself can vaporize or decompose to give off gas at high temperature, so that the partial pressure of gas is greater than equilibrium-like in glass metal
In state in minute bubbles gas partial pressure, to make the balance between kiln gas, glass metal and minute bubbles three be broken, in glass metal
Bubble enter in minute bubbles, so that minute bubbles is become air pocket and be discharged, to reach clarification.
With the increase of China's rare earth yield, rare earth in glass production using increasingly extensive, especially cerium oxide
Clarification is better than the clarification of white arsenic.In the glass production in China, adopt always for a long time severe toxicity white arsenic make it is clear
Clear agent, seriously pollutes environment, is detrimental to health, and makees clarifying agent using cerium oxide, can thoroughly eradicate environmental pollution, and can be with
Stabilize and increase glass product quality.
Due to Rare-Earth Ce O2It is a kind of strong oxidizer, it can be decomposed at high temperature generates Ce2O3, and release certain
O2, O2Into in the bubble of glass metal, the partial pressure in bubble is reduced, is allowed to continue to absorb gas, bubble volume is promoted to increase
Greatly, it accelerates, to achieve the purpose that glass clarifying.CeO21950 DEG C of fusion temperature, density 7.30g/cm3 is released
Oxygen ability is 4.65wt%.Its reaction equation are as follows:
CeO2Compared with As2O3With bigger chemical potential, make the Fe in glass than white arsenic decoloration using cerium oxide decoloration2+Conversion
Rate increases.But excessive CeO is added2It is in light yellow for making glass bulb again, and color is with CeO2The increase of dosage and deepen.
201821185310.5 disclosing a kind of crystal works formula red wine bottle plug, it is related to red wine bottle plug technology neck
Domain, including corking, the side of corking are fixedly connected with bottle stopper, and the side both ends of corking are fixedly connected to mandril, and the one of mandril
End offers notch, and the internal activity of notch is connected with switch block, and the side of switch block offers square groove, the internal activity connection of square groove
There is strut, the surface of strut has been fitted and connected torsionspring, and the other side of switch block is fixedly connected with fixture block, the side both ends of bottle stopper
Card slot is offered, the side of card slot offers threaded hole, and one end of threaded hole is arranged with circular groove, and the internal activity of threaded hole connects
It is connected to screw rod.The crystal works formula red wine bottle plug, strut can be such that switch block rotates in notch, and torsionspring can make fixture block
It automatically resets, card slot can be convenient for the disengaging of mandril, make to be easily installed or dismantle between corking and bottle stopper, and fixture block and screw rod are matched
Conjunction can be such that corking and bottle stopper fixes.
201020568719.2 are related to a kind of bottle, especially a kind of crystal decorative winebottle with reserve value, in bottle
Be provided with a groove on the outer wall of body, an engraving or draw have image, pattern transparent water crystal ornamental blocks with it is described recessed
The shape of slot is adapted, and fixation is inlaid in the groove.Transparent water crystal ornamental blocks by being embedded by the utility model
On the outer wall of bottle body, carves or draw a design, image according to the content in celebrating red-letter day in the transparent water crystal ornamental blocks, individual character
Commemorative blessing text, person image, enterprises and institutions' title, activity mark etc. are customized, makes bottle with more receipts
Hiding value and commemoration meaning.
200920129023.7 disclose a kind of flow control crystal wine bottle stopper, by finial, wine outlet sealing cover and wine outlet
Composition, wine outlet are the bottle stopper of a kind of water conservancy diversion and flow control, are equipped with the flow control baffle in one or more flow controls hole, In in wine channel out
Wine outlet top sets an anti-hook wine annular boss, sets multiple ring type seals on wine outlet lower outer layer surface.Wine outlet is close
It is sealed in the connecting hole of top and sets an annular chuck, be equipped with a ring packing column in wine outlet sealing cover lower part.Under finial
Portion central cylinder surface sets an annular recess.When pouring liquid, realize that flow control function is practical to realize by flow control hole
New design purpose.Shape is simple and beautiful, sufficiently maintains the sparkling and crystal-clear sense of crystal transparent head.
The wine bottle cover that the above patent and the prior art are announced all only has decorative performance, for the matter of crystal bottle cap
Amount, such as transparency, intensity etc. are all not fully up to expectations, influence very much the collection and ornamental value of wine product, individually use in industry
When pure zirconia cerium makees clarifying agent, it may appear that the phenomenon that " babysbreath ".Cerium oxide discharges the very capable of oxygen, between high temperature, short time
The interior a large amount of oxygen of release, and the diffusion velocity of oxygen in glass is very fast.So being easy to when under clarifying temp in glass
Glass bath surface instantaneously generates a large amount of foam, causes O2Discharge it is difficult, affect clarifying effect.To the transmitance of glass
Influence is produced with decoloration;Cerium oxide is Fe2+It has been oxidized to Fe3+, the optical density reduction of glass, transmitance increase；Continue to increase
The amount of big cerium oxide, glass sample generate coloring phenomenon, transmitance decline.This may be the Fe because excessive3+And Ce4+It is right
Glass is coloured, so that the optical density of glass increases, transmitance reduces.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of preparation methods of crystal wine bottle cover.
A kind of crystal wine bottle cover, the material of use include: 10-20 parts of glass；100-400 parts of quartz sand；70-90 parts
Soda ash；20-30 parts of potassium carbonate；4-9 parts of barium carbonate；50-80 parts of calcite；10-15 parts of borax；4-8 parts of nitre
Sour sodium；3-8 parts of prodan；2-7 parts of clarifying agent；4-8 parts of aluminium oxide；0.5-1.2 parts of antimony oxide；0.8-1.2 parts
Copper oxide；0.04-0.08 parts of cobalt oxide；0.01-0.09 parts of zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
According to mass fraction, 5-10 parts of rubidium oxide of rare earth oxide and 1-8 parts of cerium oxide are calcined into 5- after mixing
15min, then with 10-20 parts of fumed silica, 15-30 parts of bentonite, 0.01-0.5 parts of perfluoroalkyl monosilane
Base mica, 3-9 parts of prodan and 0.5-5 parts of nano zine oxide are uniformly mixed to obtain inoganic solids material, so
Afterwards by 0.3-2.6 parts of N, N- dimethyl disulfide is for formamide propane sulfonic acid sodium and 0.2-2.7 parts of cetyl trimethyl phosphorus
Acid dihydride ammonium, 0.05-0.9 parts of sodium triacetoxy borohydride are dissolved in 30-50 parts of purified water, and are added to inorganic solid
In body material, in 70-90 DEG C, 20-30min is mixed, is then dried with 150-200 DEG C, pulverizing, it is described to can be obtained
A kind of organic inorganic hybridization glass fining agent.
After the rare earth oxide is calcined at 600-800 DEG C in air atmosphere, anoxic object mutually changes, and generates
Oxygen-enriched object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400-1600 DEG C
Change, then 30-50h fusing, filtering discharges；
Step 3: press, material after thawing becomes crystal magma to 800-1000 DEG C by feeding machine constant temperature, is then pressed
Film molding, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750-850 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580-530 DEG C of first segment, second segment 530-500
DEG C, 500-470 DEG C of third section, the 5th section 430-400 DEG C, returns toughness, promotes crystal hardness by the 4th section 470-430 DEG C；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The technology of the present invention effect are as follows:
(1) a kind of preparation method of crystal wine bottle cover disclosed in the method for the present invention, a kind of crystal wine bottle cover tool disclosed by the invention
The sparkling and crystal-clear sense of standby crystal, the appearance is beautiful and elegant, very helpful for the class for promoting wine product packaging；It is moreover of the invention
The crystal material that uses of crystal bottle cap there is very high transparency and refractive index and intensity so that the collection and sight of wine product
Reward value is sharply promoted.
(2) in oxidation process, organic inorganic hybridization glass fining agent advantage is preferential right unlike arsenic trioxide
Selenium is aoxidized.Therefore, selenium still exists with zero valence state.Since the decolorizing effect of organic inorganic hybridization glass fining agent is more preferable,
It is not required to too much by physical decolorization agent, therefore dosage can about reduce 50%, and can be added without cobalt completely.In fusion process
In, organic inorganic hybridization glass fining agent needs to carry out atmosphere special control unlike arsenic trioxide, also unlike selenium,
The influence of arsenic trioxide and antimony like that vulnerable to kiln temperature fluctuation.The volatility of cerium is much lower, therefore dust and waste gas loss are less.
Organic inorganic hybridization glass fining agent had not only been used as decolorising agent but also had been used as clarifying agent that addition arsenic trioxide and antimony band is completely eliminated
The danger come.Organic inorganic hybridization glass fining agent can absorb ultraviolet light.
(3) organic inorganic hybridization glass fining agent is solved when in CeO2It is easy when under clarifying temp in glass melt surface
A large amount of foam is instantaneously generated, O is caused2Discharge it is difficult, the technical issues of affecting clarifying effect, perfluoroalkyl monosilane
Base mica provides gas-barrier layer, keeps the production quantity of oxygen stable and gentle, will not generate a large amount of foams.Triacetoxy borohydride hydrogen
Change the process that sodium has delayed cerium oxide Fe2+ to be oxidized to Fe3+, avoiding exclusive use cerium oxide generates glass sample
The shortcomings that coloring phenomenon, transmitance declines.The index of refraction of sample is up to 1.6602, and transmitance is up to 93.1%.
Detailed description of the invention
The Fourier infrared spectrum figure that the sample for the organic inorganic hybridization glass fining agent that Fig. 1 is prepared by embodiment 1 is done.
Specific embodiment
The invention is described further below by specific embodiment:
The index of refraction that sample preparation is measured at the glass gob of 10mm*20mm*5mm using abbe's refractometer to sample, using island
Transmitance of the saliva multifunctional optical instrument test glass in visible region.
Embodiment 1
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；10g borax；4g sodium nitrate；3g prodan；2g clarifying agent；4g aluminium oxide；0.5g
Antimony oxide；0.8g copper oxide；0.04g cobalt oxide；0.01g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 5g rubidium oxide and 1g cerium oxide are calcined into 5min under high temperature after mixing, after then obtaining calcining
Rare earth oxide and 10g fumed silica, 15g bentonite, 0.03g perfluoroalkyl silicyl mica, 3g prodan
And 0.5g nano zine oxide is uniformly mixed to obtain inoganic solids material, then by 3gN, N- dimethyl disulfide is for formamide
Propane sulfonic acid sodium and 0.8g cetyl trimethyl ammonium dihydrogen phosphate, the sodium triacetoxy borohydride of 0.3g are dissolved in 36g's
It in purified water, and is added in inoganic solids material, in 70 DEG C, 20min is mixed, then dries, pulverizes with 150 DEG C
A kind of organic inorganic hybridization glass fining agent can be obtained.
After the rare earth oxide is calcined at 600 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6571, transmitance 92.3%.
The Fourier infrared spectrum figure that Fig. 1 is done by ability strength organic inorganic hybridization glass fining agent.
As shown in Figure 1,780cm-1Nearby there are the absorption peak of silica, illustrate that fumed silica takes part in reaction；
745cm-1Nearby there are the absorption peak of prodan, illustrate that prodan takes part in reaction；452cm-1Nearby there are cerium oxide
Absorption peak illustrates that cerium oxide takes part in reaction；1414cm-1Nearby there are the absorption peaks of silicon-carbon, illustrate perfluoroalkyl silicyl
Mica takes part in reaction；1189cm-1Nearby there are P=O absorption peak of phosphate anion, 2916 and 2859cm-1Nearby there are carbon
The absorption peak of hydrogen illustrates that cetyl trimethyl ammonium dihydrogen phosphate takes part in reaction；1094cm-1Nearby there are the suctions of carbon nitrogen singly-bound
Receive peak, 1063cm-1Nearby there are the absorption peaks of sulfate ion, illustrate N, and N- dimethyl disulfide is joined for formamide propane sulfonic acid sodium
With react；1731cm-1Nearby there are the absorption peak of C=O, illustrate that sodium triacetoxy borohydride takes part in reaction.
Embodiment 2
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 15g glass；300g quartz sand；80g soda ash；25g
Potassium carbonate；7g barium carbonate；60g calcite；13g borax；6g sodium nitrate；5g prodan；5g clarifying agent；6g aluminium oxide；0.8g
Antimony oxide；1g copper oxide；0.06g cobalt oxide；0.05g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 8g rubidium oxide and 4g cerium oxide are calcined into 10min under high temperature after mixing, then will be calcined
Rare earth oxide and 15g fumed silica, 20g bentonite, 0.01g perfluoroalkyl silicyl mica, 6g fluosilicic acid afterwards
Sodium and 2.5g nano zine oxide are uniformly mixed to obtain inoganic solids material, and then by 5gN, N- dimethyl disulfide is for formyl
Amine propane sulfonic acid sodium and 2.6g cetyl trimethyl ammonium dihydrogen phosphate, the sodium triacetoxy borohydride of 0.05g are dissolved in 30g
Purified water in, and be added in inoganic solids material, in 80 DEG C, 25min be mixed, then dries, is ground into 180 DEG C
A kind of organic inorganic hybridization glass fining agent can be obtained in powder.
After the rare earth oxide is calcined at 700 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1500 DEG C, 40h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 900 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 800 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 550 DEG C of first segment, 520 DEG C of second segment, and third section
480 DEG C, the 4th section 450 DEG C, the 5th section 420 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6582, transmitance 92.8%.
Embodiment 3
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 15g glass；200g quartz sand；80g soda ash；25g
Potassium carbonate；6g barium carbonate；60g calcite；13g borax；6g sodium nitrate；5g prodan；5g clarifying agent；6g aluminium oxide；0.9g
Antimony oxide；1.2g copper oxide；0.08g cobalt oxide；0.09g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 10g rubidium oxide and 8g cerium oxide are calcined into 15min under high temperature after mixing, then will be calcined
Rare earth oxide and 20g fumed silica, 30g bentonite, 0.05g perfluoroalkyl silicyl mica, 9g fluosilicic acid afterwards
Sodium and 5g nano zine oxide are uniformly mixed to obtain inoganic solids material, and then by 8gN, N- dimethyl disulfide is for formamide
Propane sulfonic acid sodium and 3.6g cetyl trimethyl ammonium dihydrogen phosphate, the sodium triacetoxy borohydride of 0.9g are dissolved in 50g's
It in purified water, and is added in inoganic solids material, in 90 DEG C, 30min is mixed, then dries, pulverizes with 200 DEG C
A kind of organic inorganic hybridization glass fining agent can be obtained.
After the rare earth oxide is calcined at 800 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1600 DEG C,
50h fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 1000 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 850 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 530 DEG C of first segment, 500 DEG C of second segment, and third section
470 DEG C, the 4th section 430 DEG C, the 5th section 400 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6602, transmitance 93.1%.
Comparative example 1
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；4g sodium nitrate；3g prodan；2g clarifying agent；4g aluminium oxide；0.5g antimony oxide；
0.8g copper oxide；0.04g cobalt oxide；0.01g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 5g rubidium oxide and 1g cerium oxide are calcined into 5min under high temperature after mixing, after then obtaining calcining
Rare earth oxide and 10g fumed silica, 15g bentonite, 0.03g perfluoroalkyl silicyl mica, 3g prodan
And 0.5g nano zine oxide is uniformly mixed to obtain inoganic solids material, then by 0.8g cetyl trimethyl di(2-ethylhexyl)phosphate
Hydrogen ammonium, 0., 3g sodium triacetoxy borohydride are dissolved in the purified water of 36g, and are added in inoganic solids material, in 70
DEG C, 20min is mixed, is then dried with 150 DEG C, pulverizing, it is clear that a kind of organic inorganic hybridization glass can be obtained
Clear agent.
After the rare earth oxide is calcined at 600 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6171, transmitance 91.3%.
Comparative example 2
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；10g borax；4g sodium nitrate；3g prodan；4g aluminium oxide；0.5g antimony oxide；
0.8g copper oxide；0.04g cobalt oxide；0.01g zirconium oxide.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.5522, transmitance 87.4%.
Comparative example 3
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；10g borax；4g sodium nitrate；3g prodan；2g clarifying agent；4g aluminium oxide；0.5g
Antimony oxide；0.8g copper oxide；0.04g cobalt oxide；0.01g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 5g rubidium oxide and 1g cerium oxide are calcined into 5min under high temperature after mixing, after then obtaining calcining
Rare earth oxide and 10g fumed silica, 15g bentonite, 0.03g perfluoroalkyl silicyl mica, 3g prodan
And 0.5g nano zine oxide is uniformly mixed to obtain inoganic solids material, then by 3gN, N- dimethyl disulfide is for formamide
Propane sulfonic acid sodium, 0., 3g sodium triacetoxy borohydride are dissolved in the purified water of 36g, and are added to inoganic solids material
In, in 70 DEG C, 20min is mixed, is then dried with 150 DEG C, pulverizing, it is miscellaneous that a kind of organic-inorganic can be obtained
Change glass fining agent.
After the rare earth oxide is calcined at 600 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6124, transmitance 91.7%.
Comparative example 4
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；10g borax；4g sodium nitrate；2g clarifying agent；4g aluminium oxide；0.8g copper oxide；0.04g
Cobalt oxide；0.01g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 5g rubidium oxide and 1g cerium oxide are calcined into 5min under high temperature after mixing, after then obtaining calcining
Rare earth oxide and 10g fumed silica, 15g bentonite, 0.03g perfluoroalkyl silicyl mica, 3g prodan
And 0.5g nano zine oxide is uniformly mixed to obtain inoganic solids material, then by 3gN, N- dimethyl disulfide is for formamide
Propane sulfonic acid sodium and 0.8g cetyl trimethyl ammonium dihydrogen phosphate are dissolved in the purified water of 36g, and are added to inoganic solids
In material, in 70 DEG C, 20min is mixed, is then dried with 150 DEG C, pulverizes and a kind of organic nothing can be obtained
Machine hydridization glass fining agent.
After the rare earth oxide is calcined at 600 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6071, transmitance 88.7%.
Comparative example 5
A kind of crystal wine bottle cover, the material that the wine bottle cover uses includes: 10g glass；100g quartz sand；70g soda ash；20g
Potassium carbonate；4g barium carbonate；50g calcite；10g borax；4g sodium nitrate；3g prodan；2g clarifying agent；4g aluminium oxide；0.5g
Antimony oxide；0.8g copper oxide；0.04g cobalt oxide；0.01g zirconium oxide.
The clarifying agent is a kind of organic inorganic hybridization glass fining agent, and preparation method is as follows:
Rare earth oxide 5g rubidium oxide and 1g cerium oxide are calcined into 5min under high temperature after mixing, after then obtaining calcining
Rare earth oxide be stirred with 10g fumed silica, 15g bentonite, 3g prodan and 0.5g nano zine oxide
Inoganic solids material uniformly is obtained, then by 3gN, N- dimethyl disulfide is for formamide propane sulfonic acid sodium and 0.8g cetyl three
The sodium triacetoxy borohydride of methyl dihydrogen phosphate ammonium, 0.3g is dissolved in the purified water of 36g, and is added to inoganic solids object
In material, in 70 DEG C, 20min is mixed, is then dried with 150 DEG C, pulverizes and a kind of organic-inorganic can be obtained
Hydridization glass fining agent.
After the rare earth oxide is calcined at 600 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched
Object phase.
The quartz grains content of the quartz sand is up to 98% or more.
A kind of crystal wine bottle cover is prepared according to following scheme:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400 DEG C, 30h
Fusing, then discharges；
Step 3: press, material after thawing becomes crystal magma to 800 DEG C by feeding machine constant temperature, then carry out press mold at
Type, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580 DEG C of first segment, 530 DEG C of second segment, and third section
500 DEG C, the 4th section 470 DEG C, the 5th section 430 DEG C, toughness is returned, promotes crystal hardness；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
The index of refraction of sample is 1.6011, transmitance 86.5%.
Claims (5)
1. a kind of preparation method of crystal wine bottle cover, it is characterised in that the material that the wine bottle cover uses includes: 10-20 parts
Glass；100-400 parts of quartz sand；70-90 parts of soda ash；20-30 parts of potassium carbonate；4-9 parts of barium carbonate；50-80 parts
Calcite；10-15 parts of borax；4-8 parts of sodium nitrate；3-8 parts of prodan；2-7 parts of clarifying agent；4-8 parts of oxidation
Aluminium；0.5-1.2 parts of antimony oxide；0.8-1.2 parts of copper oxide；0.04-0.08 parts of cobalt oxide；0.01-0.09 parts of oxidation
Zirconium.
2. a kind of preparation method of crystal wine bottle cover according to claim 1, it is characterised in that: the clarifying agent is one
Kind organic inorganic hybridization glass fining agent, preparation method are as follows:
According to mass fraction, 5-10 parts of rubidium oxide of rare earth oxide and 1-8 parts of cerium oxide are calcined into 5- after mixing
15min, then with 10-20 parts of fumed silica, 15-30 parts of bentonite, 0.01-0.5 parts of perfluoroalkyl monosilane
Base mica, 3-9 parts of prodan and 0.5-5 parts of nano zine oxide are uniformly mixed to obtain inoganic solids material, so
Afterwards by 0.3-2.6 parts of N, N- dimethyl disulfide is for formamide propane sulfonic acid sodium and 0.2-2.7 parts of cetyl trimethyl phosphorus
Acid dihydride ammonium, 0.05-0.9 parts of sodium triacetoxy borohydride are dissolved in 30-50 parts of purified water, and are added to inorganic solid
In body material, in 70-90 DEG C, 20-30min is mixed, is then dried with 150-200 DEG C, pulverizing, it is described to can be obtained
A kind of organic inorganic hybridization glass fining agent.
3. a kind of preparation method of crystal wine bottle cover according to claim 2, it is characterised in that: the rare earth oxide
After calcining at 600-800 DEG C in air atmosphere, anoxic object mutually changes, and generates oxygen-enriched object phase.
4. a kind of preparation method of crystal wine bottle cover according to claim 1, it is characterised in that: the stone of the quartz sand
English clast content is up to 98% or more.
5. a kind of preparation method of crystal wine bottle cover according to claim 1, it is characterised in that: according to following scheme system
It is standby:
Step 1: ingredient will be put into mixing kettle according to the above formula after all batch weighings, blender is uniformly mixed；
Step 2: melting, is put into total oxygen furnace for uniformly mixed material or electric furnace melts, melted at 1400-1600 DEG C
Change, then 30-50h fusing, filtering discharges；
Step 3: press, material after thawing becomes crystal magma to 800-1000 DEG C by feeding machine constant temperature, is then pressed
Film molding, sizing；
Step 4: carrying out fiery throwing, temperature is controlled at 750-850 DEG C, crystal surface is polished and is slided；
Step 5: anneal, five sections of warm areas of degeneration furnace point are annealed, 580-530 DEG C of first segment, second segment 530-500
DEG C, 500-470 DEG C of third section, the 5th section 430-400 DEG C, returns toughness, promotes crystal hardness by the 4th section 470-430 DEG C；
Step 6: post-processing, including inspection, interior carving, deep processing and beautification finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112299713A (en) * | 2020-11-13 | 2021-02-02 | 郑州市华源玻璃制品有限公司 | Production process of beer bottle |
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| JPH09235126A (en) * | 1996-02-29 | 1997-09-09 | Toshiba Glass Co Ltd | Forming of nonspherical lens |
| JP2012232896A (en) * | 2012-07-17 | 2012-11-29 | Hoya Corp | Method of manufacturing glass optical device |
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