CN110343429A - A kind of nano rare earth dope for inner wall of architecture and preparation method thereof - Google Patents
A kind of nano rare earth dope for inner wall of architecture and preparation method thereof Download PDFInfo
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract
A kind of nano rare earth dope for inner wall of architecture of the present invention, the nano rare earth dope for inner wall of architecture is made of following raw material and mass parts: the rare earth 5-15 of the little 150nm of partial size, styrene-acrylic emulsion 200-350, partial size is not more than the anatase thpe white powder 180-250 of 800 mesh, partial size is not more than the kaolin 60-90 of 800 mesh, partial size is not more than the wollastonite 60-90 of 800 mesh, partial size is not more than the dicalcium powder 40-60 of 800 mesh, partial size is not more than the talcum powder 40-60, dispersing agent 6-10,12 8-12 of alcohol ester of 800 mesh, thickener 2-6, defoaming agent 1-3, pH adjusting agent 1-3, tap water 200-240；Beneficial effect is: the dope for inner wall of architecture not only has formaldehyde, benzene, bacterium, the peculiar smell of the volatilizations such as woodenware, template, door and window, the furniture in removal family room, but also anti-radiation, generation far infrared is beneficial to human health, without any side effects.
Description
Technical field
The present invention relates to coating, especially it is a kind of have except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate it is remote red
Nano rare earth dope for inner wall of architecture of the functions such as outside line and preparation method thereof.
Background technique
Coating is a kind of flowable or soluble mixture.After it is coated in building and structures surface, it can be formed
One layer of solid film can play the material of protection, decoration, mark or specific function to building and structures surface.It is one
The very big material of indispensable and dosage in kind daily life and ornament materials, as the improvement of people's living standards, to coating
Requirement it is also higher and higher, need environmental protection, it is durable, energy conservation and have some specific functionalities products.Currently, market
On dope for inner wall of architecture only play protection and decorative effect substantially.
Summary of the invention
The purpose of the present invention is to provide a kind of dope for inner wall of architecture that quantitative rare earth element production is added, in the rare earth
Wall coating not only has formaldehyde, benzene, bacterium, the peculiar smell of the volatilizations such as woodenware, template, door and window, the furniture in removal family room, but also
Anti-radiation, generation far infrared is without any side effects beneficial to human health.
For achieving the above object, The technical solution adopted by the invention is as follows:
A kind of nano rare earth dope for inner wall of architecture, it is characterised in that: the nano rare earth dope for inner wall of architecture by following raw material and
Mass parts composition:
The rare earth 5-15 of the little 150nm of partial size
Styrene-acrylic emulsion 200-350
Partial size is not more than the anatase thpe white powder 180-250 of 800 mesh
Partial size is not more than the kaolin 60-90 of 800 mesh
Partial size is not more than the wollastonite 60-90 of 800 mesh
Partial size is not more than the dicalcium powder 40-60 of 800 mesh
Partial size is not more than the talcum powder 40-60 of 800 mesh
5040 6-10 of dispersing agent
12 8-12 of alcohol ester
Thickener TT-935 2-6
Defoaming agent 1-3
PH adjusting agent AMP-95 1-3
Tap water 200-240.
Preferably, a kind of nano rare earth dope for inner wall of architecture, it is characterised in that: the nano rare earth dope for inner wall of architecture by
Following raw material and mass parts composition:
Partial size is not more than the rare earth 10 of 150nm
Styrene-acrylic emulsion 250
Partial size is not more than the anatase thpe white powder 200 of 800 mesh
Partial size is not more than the kaolin 80 of 800 mesh
Partial size is not more than the wollastonite 80 of 800 mesh
Partial size is not more than the dicalcium powder 50 of 800 mesh
Partial size is not more than the talcum powder 50 of 800 mesh
Dispersing agent 5,040 8
Alcohol ester 12
Thickener TT-935 4
Defoaming agent 2
PH adjusting agent AMP-95 2
Tap water 220.
The rare earth refer to lanthanide series-lanthanum (La) in the periodic table of chemical element, cerium (Ce), praseodymium (Pr), neodymium (Nd),
Hard iron (Pm), samarium (Sm), europium (Eu), gadolinium (Ga), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu),
And closely related two element-scandiums (Sc) and yttrium (Y) totally 17 kinds of elements, referred to as rare earth element with 15 elements of group of the lanthanides,
Wherein rare earth element content ppm are as follows: La:242, Ce:549, Pr:60.9, Nd:222, Sm:43.5, Eu:1.17, Ga:30.3,
Tb:5.42, Dy:31.0, Ho:6.11, Er:19.3, Tm:2.63, Yb:17.4, Lu:2.37, Sc:8.40, Y:154.
The rare earth is provided by Zhong Se rare earth Co., Ltd；
The film forming binder, pigment, filler, auxiliary agent raw material are commercially available.
The second object of the present invention is to provide a kind of preparation method of nano rare earth dope for inner wall of architecture, including walk as follows
It is rapid:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare；
Step 2 prepares water-borne dispersions: it is mixed evenly by the mass parts tap water, dispersing agent 5040, defoaming agent of setting,
Rare earth of the spare fineness partial size of addition step 1 no more than 150nm, partial size are not more than anatase thpe white powder, the partial size of 800 mesh
It is little no more than dicalcium powder, the partial size of 800 mesh no more than the wollastonite of 800 mesh, partial size no more than the kaolin of 800 mesh, partial size
It is spare to obtain homogeneous aqueous's dispersion with 1300-1700r/min high-speed stirred 15-30 minutes in the talcum powder of 800 mesh；
The preparation of step 3 finished product: styrene-acrylic emulsion (Styrene And Chloroalkyl Acrylates are added in the spare water-borne dispersions of step 2 under stiring
Ester lotion), it adds alcohol ester 12, thickener TT-935, pH adjusting agent AMP-95 and stirs 15-30 minutes to get a kind of white
Nano rare earth dope for inner wall of architecture；Or be added red, yellow and other color pigment as needed or colorant stir evenly to get
A kind of nano rare earth dope for inner wall of architecture of red color or yellow color and other colors.
Preferably, a kind of preparation method of nano rare earth dope for inner wall of architecture, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare；
Step 2 prepares water-borne dispersions: by the mass parts tap water 220kg of setting, dispersing agent (5040) 8kg, defoaming agent 2kg
It is mixed evenly, rare earth 10kg of the spare fineness partial size of step 1 no more than 150nm is added, partial size is not more than 800 purposes
Anatase thpe white powder 200kg, partial size are not more than wollastonite 80kg, the grain of 800 mesh no more than kaolin 80kg, the partial size of 800 mesh
Diameter is not more than the talcum powder 50kg of 800 mesh no more than dicalcium powder 50kg, the partial size of 800 mesh, with 1300-1700r/min high-speed stirrings
It mixes 30 minutes, it is spare to obtain homogeneous aqueous's dispersion；
The preparation of step 3 finished product: styrene-acrylic emulsion (Styrene And Chloroalkyl Acrylates are added in the spare water-borne dispersions of step 2 under stiring
Ester lotion) 250kg, it adds 12 10kg of alcohol ester, thickener (TT-935) 4kg, pH adjusting agent (AMP-95) 2kg and stirs 30 points
Clock is to get a kind of white nano rare earth dope for inner wall of architecture；Or red, yellow and other color pigment or coloring are added as needed
Agent stirs evenly the nano rare earth dope for inner wall of architecture to get a kind of red color or yellow color and other colors.
The beneficial effects of the present invention are: since above-mentioned nano rare earth dope for inner wall of architecture uses nano rare earth element, produce
Product have the function of except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate far infrared etc. beneficial to human health, without any pair
Effect.Rare earth element includes 15 lanthanide series and scandium, yttrium totally 17 metallic elements.Rare earth element is from 18 end of the centurys in succession by people
Find since, be used widely in the industries such as metallurgy, ceramics, glass, petrochemical industry, printing and dyeing, agricultural.With science and technology
Progress, the application range of rare earth constantly expand.Especially recent 20 years, rare earth have obtained fast in the application of high-technology field
Hail exhibition.
Therefore present dope for inner wall of architecture product there are no it is any can have simultaneously except formaldehyde, except benzene, remove
Bacterium, eliminate the unusual smell, be anti-radiation, release far infrared light wave, and the dope for inner wall of architecture product that the present invention develops collect above-mentioned 6 functions in
One, not only have degerming, except formaldehyde, except benzene, eliminate the unusual smell, improve indoor environment, but also can it is anti-radiation, release far red light
Wave, it is highly beneficial to human health.Its main feature is that: (1) it when rare earth element room temperature can release far red light wave property, can reach
Decompose the pernicious gases such as formaldehyde, benzene, bacterium, the peculiar smell of volatilizations such as woodenware, template, door and window, the furniture in removal family room；(2)
Due to the principle that orderly wave resists unordered wave has reached can be with the function of electromagnetic radiation resistant；(3) room temperature discharges far infrared light wave
The effect of reaching antibacterial.
Specific embodiment
Be given below a kind of nano rare earth dope for inner wall of architecture of the invention embodiment and a kind of Nano Rare of the invention
Native dope for inner wall of architecture specific embodiment.
The raw material ratio (mass parts) of nano rare earth dope for inner wall of architecture embodiment 1-4 of the invention a kind of:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Partial size is not more than the rare earth of 150nm | 10 | 5 | 15 | 0 |
| Styrene-acrylic emulsion | 250 | 200 | 350 | 250 |
| Partial size is not more than the anatase thpe white powder of 800 mesh | 220 | 180 | 250 | 220 |
| Partial size is not more than the kaolin of 800 mesh | 80 | 90 | 60 | 80 |
| Partial size is not more than the wollastonite of 800 mesh | 80 | 90 | 60 | 80 |
| Partial size is not more than the dicalcium powder of 800 mesh | 50 | 60 | 40 | 50 |
| Partial size is not more than the talcum powder of 800 mesh | 50 | 60 | 40 | 50 |
| Dispersing agent 5040 | 8 | 10 | 6 | 8 |
| Alcohol ester 12 | 10 | 8 | 12 | 10 |
| Thickener TT-935 | 4 | 2 | 6 | 4 |
| Defoaming agent | 2 | 1 | 3 | 2 |
| PH adjusting agent AMP-95 | 2 | 1 | 3 | 2 |
| Tap water | 220 | 200 | 240 | 220 |
A kind of preparation method of nano rare earth dope for inner wall of architecture of embodiment 1, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare；
Step 2 prepares water-borne dispersions: by the mass parts tap water 220kg of setting, dispersing agent (5040) 8kg, defoaming agent 2kg
It is mixed evenly, rare earth 10kg of the spare fineness partial size of step 1 no more than 150nm is added, partial size is not more than 800 purposes
Anatase thpe white powder 200kg, partial size are not more than wollastonite 80kg, the grain of 800 mesh no more than kaolin 80kg, the partial size of 800 mesh
Diameter is not more than the talcum powder 50kg of 800 mesh no more than dicalcium powder 50kg, the partial size of 800 mesh, with 1300-1700r/min high-speed stirrings
It mixes 30 minutes, it is spare to obtain homogeneous aqueous's dispersion；
The preparation of step 3 finished product: styrene-acrylic emulsion (Styrene And Chloroalkyl Acrylates are added in the spare water-borne dispersions of step 2 under stiring
Ester lotion) 250kg, it adds 12 10kg of alcohol ester, thickener (TT-935) 4kg, pH adjusting agent (AMP-95) 2kg and stirs 30 points
Clock is to get a kind of white nano rare earth dope for inner wall of architecture；Or red, yellow and other color pigment or coloring are added as needed
Agent stirs evenly the nano rare earth dope for inner wall of architecture to get a kind of red color or yellow color and other colors.
The preparation method of embodiment 2-3 is identical as the preparation method of embodiment 1.
A kind of preparation method of dope for inner wall of architecture of embodiment 4, includes the following steps:
Step 1 prepares water-borne dispersions: by the mass parts tap water 220kg of setting, dispersing agent (5040) 8kg, defoaming agent 2kg
It is mixed evenly, rare earth 10kg of the spare fineness partial size of step 1 no more than 150nm is added, partial size is not more than 800 purposes
Anatase thpe white powder 200kg, partial size are not more than wollastonite 80kg, the grain of 800 mesh no more than kaolin 80kg, the partial size of 800 mesh
Diameter is not more than the talcum powder 50kg of 800 mesh no more than dicalcium powder 50kg, the partial size of 800 mesh, with 1300-1700r/min high-speed stirrings
It mixes 30 minutes, it is spare to obtain homogeneous aqueous's dispersion；
The preparation of step 2 finished product: styrene-acrylic emulsion (Styrene And Chloroalkyl Acrylates are added in the spare water-borne dispersions of step 1 under stiring
Ester lotion) 250kg, it adds 12 10kg of alcohol ester, thickener (TT-935) 4kg, pH adjusting agent (AMP-95) 2kg and stirs 30 points
Clock is to get a kind of white nano rare earth dope for inner wall of architecture；Or red, yellow and other color pigment or coloring are added as needed
Agent stirs evenly the nano rare earth dope for inner wall of architecture to get a kind of red color or yellow color and other colors.
Experiment detection: the product of embodiment 1 and the product contrasting detection of embodiment 4 are as follows:
Laboratory test results analysis:
1, the product of embodiment 1 contains nano rare earth dope for inner wall of architecture detection project, formaldehyde removal rate 95.76%；Embodiment 4
Product be free of nano rare earth dope for inner wall of architecture detection project, formaldehyde removal rate 0.
2, the product of embodiment 1 contains nano rare earth dope for inner wall of architecture detection project, benzene removal rate 95.83%；Embodiment
4 product is free of the dope for inner wall of architecture detection project of nano rare earth, benzene removal rate 0.
3, the product of embodiment 1 contains nano rare earth dope for inner wall of architecture detection project, anti-radiation rate 98.2%；Embodiment 4
Product be free of nano rare earth dope for inner wall of architecture detection project, anti-radiation rate 1.8%.
4, the product of embodiment 1 contains nano rare earth dope for inner wall of architecture detection project, normal emittance 0.86；Embodiment
4 product is free of the dope for inner wall of architecture detection project of nano rare earth, normal emittance 0.
The product of embodiment 1 is compared with the product function sexual valence of embodiment 2 and embodiment 3, and the product of embodiment 1 is better than real
Apply the product of example 2 and embodiment 3.
In conclusion the present invention have the function of except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate far infrared etc.,
Significant effect.
Experiments have shown that: use nano rare earth element, product have except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate
The functions such as far infrared are without any side effects beneficial to human health.
The embodiments of the present invention have been described in detail above, but content is only the preferred embodiment of the present invention,
It should not be considered as limiting the scope of the invention.Any changes and modifications in accordance with the scope of the present application,
It should still be within the scope of the patent of the present invention.
Claims (5)
1. a kind of nano rare earth dope for inner wall of architecture, it is characterised in that: the nano rare earth dope for inner wall of architecture is by following raw material
And mass parts composition:
The rare earth 5-15 of the little 150nm of partial size
Styrene-acrylic emulsion 200-350
Partial size is not more than the anatase thpe white powder 180-250 of 800 mesh
Partial size is not more than the kaolin 60-90 of 800 mesh
Partial size is not more than the wollastonite 60-90 of 800 mesh
Partial size is not more than the dicalcium powder 40-60 of 800 mesh
Partial size is not more than the talcum powder 40-60 of 800 mesh
5040 6-10 of dispersing agent
12 8-12 of alcohol ester
Thickener TT-935 2-6
Defoaming agent 1-3
PH adjusting agent AMP-95 1-3
Tap water 200-240.
2. a kind of nano rare earth dope for inner wall of architecture according to claim 1, it is characterised in that: in nano rare earth building
Wall coating is made of following raw material and mass parts:
Partial size is not more than the rare earth 10 of 150nm
Styrene-acrylic emulsion 250
Partial size is not more than the anatase thpe white powder 200 of 800 mesh
Partial size is not more than the kaolin 80 of 800 mesh
Partial size is not more than the wollastonite 80 of 800 mesh
Partial size is not more than the dicalcium powder 50 of 800 mesh
Partial size is not more than the talcum powder 50 of 800 mesh
Dispersing agent 5,040 8
Alcohol ester 12
Thickener TT-935 4
Defoaming agent 2
PH adjusting agent AMP-95 2
Tap water 220.
3. rare earth according to claim 1 refers to lanthanide series-lanthanum (La) in the periodic table of chemical element, cerium (Ce), praseodymium
(Pr), neodymium (Nd), hard iron (Pm), samarium (Sm), europium (Eu), gadolinium (Ga), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium
(Yb), lutetium (Lu), and the two element-scandiums (Sc) closely related with 15 elements of group of the lanthanides and yttrium (Y) totally 17 kinds of elements,
Referred to as rare earth element, wherein rare earth element content ppm are as follows: La:242, Ce:549, Pr:60.9, Nd:222, Sm:43.5, Eu:
1.17, Ga:30.3, Tb:5.42, Dy:31.0, Ho:6.11, Er:19.3, Tm:2.63, Yb:17.4, Lu:2.37, Sc:8.40,
Y:154.
4. a kind of preparation method of nano rare earth dope for inner wall of architecture, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare；
Step 2 prepares water-borne dispersions: it is mixed evenly by the mass parts tap water, dispersing agent 5040, defoaming agent of setting,
Rare earth of the spare fineness partial size of addition step 1 no more than 150nm, partial size are not more than anatase thpe white powder, the partial size of 800 mesh
It is little no more than dicalcium powder, the partial size of 800 mesh no more than the wollastonite of 800 mesh, partial size no more than the kaolin of 800 mesh, partial size
It is spare to obtain homogeneous aqueous's dispersion with 1300-1700r/min high-speed stirred 15-30 minutes in the talcum powder of 800 mesh；
The preparation of step 3 finished product: styrene-acrylic emulsion, i.e. styrene-propene is added in the spare water-borne dispersions of step 2 under stiring
Acid esters lotion adds alcohol ester 12, thickener TT-935, pH adjusting agent AMP-95 and stirs 15-30 minutes to get a kind of white
Nano rare earth dope for inner wall of architecture；Or be added red, yellow and other color pigment as needed or colorant stir evenly to get
A kind of nano rare earth dope for inner wall of architecture of red color or yellow color and other colors.
5. a kind of preparation method of nano rare earth dope for inner wall of architecture according to claim 4, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare；
Step 2 prepares water-borne dispersions: mixed by the mass parts tap water 220kg, dispersing agent 5040:8kg, defoaming agent 2kg of setting
Conjunction stirs evenly, and it is sharp no more than 800 purposes no more than the rare earth 10kg of 150nm, partial size that the spare fineness partial size of step 1 is added
Titanium-type titanium dioxide 200kg, partial size are not more than wollastonite 80kg, the partial size of 800 mesh no more than kaolin 80kg, the partial size of 800 mesh
No more than the talcum powder 50kg that dicalcium powder 50kg, the partial size of 800 mesh are not more than 800 mesh, with 1300-1700r/min high-speed stirreds
30 minutes, it is spare to obtain homogeneous aqueous's dispersion；
The preparation of step 3 finished product: styrene-acrylic emulsion, Styrene And Chloroalkyl Acrylates are added in the spare water-borne dispersions of step 2 under stiring
Ester lotion: 250kg adds 12 10kg of alcohol ester, thickener TT-935:4kg, pH adjusting agent AMP-95:2kg and stirs 30 points
Clock is to get a kind of white nano rare earth dope for inner wall of architecture；Or red, yellow and other color pigment or coloring are added as needed
Agent stirs evenly the nano rare earth dope for inner wall of architecture to get a kind of red color or yellow color and other colors.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040569A (en) * | 2019-12-02 | 2020-04-21 | 安徽科创美涂料科技股份有限公司 | High-temperature-resistant epoxy stone-like paint coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422920A (en) * | 2002-12-31 | 2003-06-11 | 中国建筑材料科学研究院 | Multi-waveband photocatalytic material, preparation method thereof and air-purifying exposed wall coating composition |
| US20070208129A1 (en) * | 2006-03-02 | 2007-09-06 | Catherine Ann Finegan | Scrub and stain-resistant coating |
| CN106433280A (en) * | 2015-08-06 | 2017-02-22 | 上海利民环保节能科技有限公司 | Nanometer negative ion environmental-protection coating |
-
2018
- 2018-11-11 CN CN201811335918.6A patent/CN110343429A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422920A (en) * | 2002-12-31 | 2003-06-11 | 中国建筑材料科学研究院 | Multi-waveband photocatalytic material, preparation method thereof and air-purifying exposed wall coating composition |
| US20070208129A1 (en) * | 2006-03-02 | 2007-09-06 | Catherine Ann Finegan | Scrub and stain-resistant coating |
| CN106433280A (en) * | 2015-08-06 | 2017-02-22 | 上海利民环保节能科技有限公司 | Nanometer negative ion environmental-protection coating |
Non-Patent Citations (1)
| Title |
|---|
| 蒋鸿辉等: "《材料化学和无机非金属材料实验教程》", 31 May 2018, 冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040569A (en) * | 2019-12-02 | 2020-04-21 | 安徽科创美涂料科技股份有限公司 | High-temperature-resistant epoxy stone-like paint coating and preparation method thereof |
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