CN109456688A - A kind of nano rare earth Wooden furniture paint and preparation method thereof - Google Patents

A kind of nano rare earth Wooden furniture paint and preparation method thereof Download PDF

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Publication number
CN109456688A
CN109456688A CN201811335905.9A CN201811335905A CN109456688A CN 109456688 A CN109456688 A CN 109456688A CN 201811335905 A CN201811335905 A CN 201811335905A CN 109456688 A CN109456688 A CN 109456688A
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rare earth
wooden furniture
nano rare
furniture paint
nano
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Inventor
周永富
吴才来
冯靖
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Guangdong Zhongsheng New Environmental Protection Technology Co Ltd
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Guangdong Zhongsheng New Environmental Protection Technology Co Ltd
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Priority to CN201811335905.9A priority Critical patent/CN109456688A/en
Publication of CN109456688A publication Critical patent/CN109456688A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention relates to a kind of nano rare earth Wooden furniture paints, it is characterized by: the nano rare earth Wooden furniture paint is made of following raw material and mass parts: the rare earth 0.5-1.5 of the little 150nm of partial size, polyurethane 65-85, levelling agent 0.2-0.4,12 6-8 of alcohol ester, thickener (TT-935) 2-6, defoaming agent 1-3, wax emulsion 6-8, mill base 6-8, pH adjusting agent (AMP-95) 1-3, tap water 10-12;The beneficial effects of the present invention are: a kind of nano rare earth Wooden furniture paint that quantitative rare earth element production is added, the nano rare earth Wooden furniture paint is not only free of formaldehyde, benzene class volatile matter, and there is formaldehyde, benzene, bacterium, the peculiar smell for removing the volatilizations such as metope, template, door and window in family room, can it is anti-radiation, generate far infrared beneficial to human health, it is without any side effects.

Description

A kind of nano rare earth Wooden furniture paint and preparation method thereof
Technical field
The present invention relates to coating, especially it is a kind of have except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate it is remote red A kind of nano rare earth Wooden furniture paint of the functions such as outside line and preparation method thereof.
Background technique
Wood furniture is the major product in furniture, is the important articles of people's daily life, and China is that wood furniture is raw Big country is produced, is ranked first in the world.Wood furniture is particularly significant to wood furniture development by coating protection and decoration, coating.With The improvement of people's living standards, the requirement to Wooden furniture paint is also higher and higher, needs environmental protection, durable, energy conservation and band There are some specific functionalities.Currently, Wooden furniture paint in the market only plays protection and decorative effect, most wood substantially The coating of device furniture, which contains, uses formaldehyde, benzene class volatile matter, and formaldehyde, benzene class volatile matter are carcinogens, and formaldehyde, benzene class volatile matter are few then Several years is more, and many decades constantly volatilize, and wood furniture is generally furnished in room or parlor, and formaldehyde, benzene class volatile matter are undoubtedly one kind The stealthy killer that the mankind can not get rid of.
Summary of the invention
The purpose of the present invention is to provide a kind of nano rare earth Wooden furniture paint that quantitative rare earth element production is added, The nano rare earth Wooden furniture paint is not only free of formaldehyde, benzene class volatile matter, but also has metope, the mould in removal family room Formaldehyde, benzene, bacterium, the peculiar smell of the volatilizations such as plate, door and window, can it is anti-radiation, generate far infrared beneficial to human health, it is no any secondary to make With.
For achieving the above object, The technical solution adopted by the invention is as follows:
A kind of nano rare earth Wooden furniture paint, it is characterised in that: the nano rare earth Wooden furniture paint by following raw material and Mass parts composition:
The rare earth 0.5-1.5 of the little 150nm of partial size
Polyurethane 65-85
Levelling agent 0.2-0.4
12 6-8 of alcohol ester
Thickener TT-935 2-6
Defoaming agent 1-3
Wax emulsion 6-8
Mill base 6-8
PH adjusting agent AMP-95 1-3
Tap water 10-12.
Preferably, a kind of nano rare earth Wooden furniture paint, it is characterised in that: the nano rare earth Wooden furniture paint by Following raw material and mass parts composition:
The rare earth 1 of the little 150nm of partial size
Polyurethane 75
Levelling agent 0.3
Alcohol ester 12
Thickener TT-935 5
Defoaming agent 2
Wax emulsion 7
Mill base 7
PH adjusting agent AMP-95 2
Tap water 11.
The rare earth refer to lanthanide series-lanthanum (La) in the periodic table of chemical element, cerium (Ce), praseodymium (Pr), neodymium (Nd), Hard iron (Pm), samarium (Sm), europium (Eu), gadolinium (Ga), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), And closely related two element-scandiums (Sc) and yttrium (Y) totally 17 kinds of elements, referred to as rare earth element with 15 elements of group of the lanthanides, Wherein rare earth element content ppm are as follows: La:242, Ce:549, Pr:60.9, Nd:222, Sm:43.5, Eu:1.17, Ga:30.3, Tb:5.42, Dy:31.0, Ho:6.11, Er:19.3, Tm:2.63, Yb:17.4, Lu:2.37, Sc:8.40, Y:154.
The rare earth is provided by Zhong Se rare earth Co., Ltd;
The film forming binder, pigment, filler, auxiliary agent raw material are commercially available.
The second object of the present invention is to provide a kind of preparation method of nano rare earth Wooden furniture paint, including walk as follows It is rapid:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare;
Step 2 prepares water-borne dispersions: tap water being added in polyurethane by the mass parts of setting and is stirred with 500-700r/min It mixes 30-50 minutes, adds defoaming agent later, levelling agent continues to stir, wax emulsion, alcohol ester 12 are added in whipping process, Rare earth of the spare partial size of step 1 no more than 150nm is stirring evenly and then adding into the above raw material to continue to stir, and is stirred evenly After add color paste toning, add pH adjusting agent AMP-95 for pH and be adjusted to 8, be then added thickener TT-935 adjust it is glutinous Finished product is crossed 300 meshes by degree, filling up to a kind of nano rare earth Wooden furniture paint.
Preferably, a kind of preparation method of nano rare earth Wooden furniture paint, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth powder, spare;
Step 2 prepares water-borne dispersions: tap water 11kg being added in polyurethane 75kg with 500-by the mass parts of setting 700r/min is stirred 40 minutes, adds defoaming agent 2kg later, levelling agent 0.3kg continues to stir, and wax is added in whipping process It is dilute no more than 150nm to be stirring evenly and then adding into the spare partial size of step 1 to the above raw material by lotion 7kg, 12 7kg of alcohol ester Native 1kg continues to stir, and is stirring evenly and then adding into mill base 7kg toning to the above raw material, adds pH adjusting agent (AMP-95) 2kg PH is adjusted to 8, thickener (TT-935) 5kg is then added and adjusts viscosity, finished product is crossed into 300 meshes, it is filling to be received up to one kind Rice rare earth Wooden furniture paint.
The beneficial effects of the present invention are: since above-mentioned nano rare earth Wooden furniture paint uses nano rare earth element, produce Product have the function of except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate far infrared etc. beneficial to human health, without any pair Effect.Rare earth element includes 15 lanthanide series and scandium, yttrium totally 17 metallic elements.Rare earth element is from 18 end of the centurys in succession by people Find since, be used widely in the industries such as metallurgy, ceramics, glass, petrochemical industry, printing and dyeing, agricultural.With science and technology Progress, the application range of rare earth constantly expand.Especially recent 20 years, rare earth have obtained fast in the application of high-technology field Hail exhibition.
Therefore present Wooden furniture paint product there are no it is any can have simultaneously except formaldehyde, except benzene, remove Bacterium eliminates the unusual smell, is anti-radiation, release far infrared light wave, and a kind of nano rare earth Wooden furniture paint product collection that the present invention develops Above-mentioned 6 functions in one, not only have degerming, except formaldehyde, except benzene, eliminate the unusual smell, improve indoor environment, but also be resistant to spoke It penetrates, discharge far infrared light wave, these are highly beneficial to human health.(1) the orderly light wave that rare earth element releases, when room temperature, can Far red light wave property is released, can reach the first for decomposing the volatilizations such as woodenware, template, door and window, furniture in removal family room The pernicious gases such as aldehyde, benzene, bacterium, peculiar smell;(2) due to the principle that orderly wave resists unordered wave has reached can be with electromagnetic radiation resistant Function;(3) the effect of room temperature release far infrared light wave reaches antibacterial.
Specific embodiment
Be given below a kind of nano rare earth Wooden furniture paint of the invention embodiment and a kind of Nano Rare of the invention Native Wooden furniture paint specific embodiment.
The raw material ratio (mass parts) of nano rare earth Wooden furniture paint embodiment 1-4 of the invention a kind of:
The formula table of embodiment 1 prepares a kind of preparation method of nano rare earth Wooden furniture paint, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth powder, spare;
Step 2 prepares water-borne dispersions: tap water 11kg being added in polyurethane 75kg with 600r/min by the mass parts of setting Stirring 40 minutes, adds defoaming agent 2kg, levelling agent 0.3kg continues to stir later, be added in whipping process wax emulsion 7kg, 12 7kg of alcohol ester, to the above raw material be stirring evenly and then adding into the spare partial size of step 1 no more than 150nm rare earth 1kg after Continuous stirring is stirring evenly and then adding into mill base 7kg toning to the above raw material, adds pH adjusting agent (AMP-95) 2kg for pH tune Then section is added thickener (TT-935) 5kg and adjusts viscosity, finished product is crossed 300 meshes, a kind of filling nano rare earth to obtain the final product to 8 Wooden furniture paint.
Embodiment 2 and embodiment 3 are compared except formula table is different from embodiment 1, and preparation method is identical.
The preparation method of embodiment 4, includes the following steps:
Tap water 11kg is added in polyurethane 75kg with 600r/min stirring 40 minutes by the mass parts of setting, is added later Defoaming agent 2kg, levelling agent 0.3kg continue to stir, and wax emulsion 7kg, 12 7kg of alcohol ester are added in whipping process, to above former Material is stirring evenly and then adding into mill base 7kg toning, adds pH adjusting agent (AMP-95) 2kg for pH and is adjusted to 8, is then added and increases Thick dose of (TT-935) 5kg adjusts viscosity, and finished product is crossed 300 meshes, filling up to a kind of nano rare earth Wooden furniture paint.
Experiment detection: the sample of embodiment 1 and the properties of sample detection comparison of embodiment 4 are as follows:
Laboratory test results analysis:
1, woodwork coating detection project of 1 sample of embodiment containing nano rare earth, formaldehyde removal rate 95.20%;4 sample of embodiment is not The detection project of woodwork coating containing nano rare earth, formaldehyde removal rate 0.
2, woodwork coating detection project of 1 sample of embodiment containing nano rare earth, benzene removal rate 98.33;4 sample of embodiment is not The detection project of woodwork coating containing nano rare earth, benzene removal rate 0.
3, woodwork coating detection project of 1 samples of embodiment containing nano rare earth, anti-radiation rate 99.1%;4 sample of embodiment Product are free of nano rare earth woodwork coating detection project, anti-radiation rate 0.9%.
4, woodwork coating detection project of 1 samples of embodiment containing nano rare earth, normal emittance 0.76.Embodiment 1 Sample compared with the sample of embodiment 2 and the sample function sexual valence of embodiment 3,1 sample of embodiment be better than embodiment 2 sample With the sample of embodiment 3.
In conclusion the present invention have the function of except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate far infrared etc., Significant effect.
Experiments have shown that: use nano rare earth element, product have except formaldehyde, except benzene, degerming, eliminate the unusual smell, it is anti-radiation, generate The functions such as far infrared are without any side effects beneficial to human health.
The embodiments of the present invention have been described in detail above, but content is only the preferred embodiment of the present invention, It should not be considered as limiting the scope of the invention.Any changes and modifications in accordance with the scope of the present application, It should still be within the scope of the patent of the present invention.

Claims (5)

1. a kind of nano rare earth Wooden furniture paint, it is characterised in that: the nano rare earth Wooden furniture paint is by following raw material And mass parts composition:
The rare earth 0.5-1.5 of the little 150nm of partial size
Polyurethane 65-85
Levelling agent 0.2-0.4
12 6-8 of alcohol ester
Thickener TT-935 2-6
Defoaming agent 1-3
Wax emulsion 6-8
Mill base 6-8
PH adjusting agent AMP-95 1-3
Tap water 10-12.
2. a kind of nano rare earth Wooden furniture paint according to claim 1, it is characterised in that: the nano rare earth woodenware man Tool coating is made of following raw material and mass parts:
The rare earth 1 of the little 150nm of partial size
Polyurethane 75
Levelling agent 0.3
Alcohol ester 12
Thickener TT-935 5
Defoaming agent 2
Wax emulsion 7
Mill base 7
PH adjusting agent AMP-95 2
Tap water 11.
3. rare earth according to claim 1 refers to lanthanide series-lanthanum (La) in the periodic table of chemical element, cerium (Ce), praseodymium (Pr), neodymium (Nd), hard iron (Pm), samarium (Sm), europium (Eu), gadolinium (Ga), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), and the two element-scandiums (Sc) closely related with 15 elements of group of the lanthanides and yttrium (Y) totally 17 kinds of elements, Referred to as rare earth element, wherein rare earth element content ppm are as follows: La:242, Ce:549, Pr:60.9, Nd:222, Sm:43.5, Eu: 1.17, Ga:30.3, Tb:5.42, Dy:31.0, Ho:6.11, Er:19.3, Tm:2.63, Yb:17.4, Lu:2.37, Sc:8.40, Y:154.
4. a kind of preparation method of nano rare earth Wooden furniture paint, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth, spare;
Step 2 prepares water-borne dispersions: tap water being added in polyurethane by the mass parts of setting and is stirred with 500-700r/min It mixes 30-50 minutes, adds defoaming agent later, levelling agent continues to stir, wax emulsion, alcohol ester 12 are added in whipping process, Rare earth of the spare partial size of step 1 no more than 150nm is stirring evenly and then adding into the above raw material to continue to stir, and is stirred evenly After add color paste toning, add pH adjusting agent AMP-95 for pH and be adjusted to 8, be then added thickener TT-935 adjust it is glutinous Finished product is crossed 300 meshes by degree, filling up to a kind of nano rare earth Wooden furniture paint.
5. a kind of preparation method of nano rare earth Wooden furniture paint according to claim 4, includes the following steps:
The grinding of step 1 rare earth: being placed in grinder fineness of grind partial size no more than 150nm for rare earth, obtain nano rare earth powder, spare;
Step 2 prepares water-borne dispersions: tap water 11kg being added in polyurethane 75kg with 500-by the mass parts of setting 700r/min is stirred 40 minutes, adds defoaming agent 2kg later, levelling agent 0.3kg continues to stir, and wax is added in whipping process It is dilute no more than 150nm to be stirring evenly and then adding into the spare partial size of step 1 to the above raw material by lotion 7kg, 12 7kg of alcohol ester Native 1kg continues to stir, and is stirring evenly and then adding into mill base 7kg toning to the above raw material, adds pH adjusting agent (AMP-95) 2kg PH is adjusted to 8, thickener (TT-935) 5kg is then added and adjusts viscosity, finished product is crossed into 300 meshes, it is filling to be received up to one kind Rice rare earth Wooden furniture paint.
CN201811335905.9A 2018-11-11 2018-11-11 A kind of nano rare earth Wooden furniture paint and preparation method thereof Pending CN109456688A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101260275A (en) * 2008-04-01 2008-09-10 徐州市三为水性漆科技有限公司 Water woodenware paint and preparation method thereof
KR20100125120A (en) * 2009-05-20 2010-11-30 주식회사 스카이벽지 Binder composition for wall paper having absorption property of electromagnetic waves
CN102643562A (en) * 2012-03-31 2012-08-22 北京展辰化工有限公司 Antibacterial latex paint containing natural jade powder and preparation method for same
CN106433280A (en) * 2015-08-06 2017-02-22 上海利民环保节能科技有限公司 Nanometer negative ion environmental-protection coating
CN106947348A (en) * 2017-04-06 2017-07-14 合肥欧克斯新型建材有限公司 A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof
CN107974155A (en) * 2018-01-08 2018-05-01 孟静 Anion environmental protection coating and preparation method thereof and construction method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101260275A (en) * 2008-04-01 2008-09-10 徐州市三为水性漆科技有限公司 Water woodenware paint and preparation method thereof
KR20100125120A (en) * 2009-05-20 2010-11-30 주식회사 스카이벽지 Binder composition for wall paper having absorption property of electromagnetic waves
CN102643562A (en) * 2012-03-31 2012-08-22 北京展辰化工有限公司 Antibacterial latex paint containing natural jade powder and preparation method for same
CN106433280A (en) * 2015-08-06 2017-02-22 上海利民环保节能科技有限公司 Nanometer negative ion environmental-protection coating
CN106947348A (en) * 2017-04-06 2017-07-14 合肥欧克斯新型建材有限公司 A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof
CN107974155A (en) * 2018-01-08 2018-05-01 孟静 Anion environmental protection coating and preparation method thereof and construction method

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Application publication date: 20190312