CN107418329A - A kind of interior wall coating and preparation method thereof - Google Patents

A kind of interior wall coating and preparation method thereof Download PDF

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Publication number
CN107418329A
CN107418329A CN201710467816.9A CN201710467816A CN107418329A CN 107418329 A CN107418329 A CN 107418329A CN 201710467816 A CN201710467816 A CN 201710467816A CN 107418329 A CN107418329 A CN 107418329A
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China
Prior art keywords
parts
interior wall
wall coating
powder
coalescents
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CN201710467816.9A
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Chinese (zh)
Inventor
俞克波
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Hefei Still Decoration Engineering Co Ltd
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Hefei Still Decoration Engineering Co Ltd
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Priority to CN201710467816.9A priority Critical patent/CN107418329A/en
Publication of CN107418329A publication Critical patent/CN107418329A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of interior wall coating and preparation method thereof, the interior wall coating includes following raw material:Acrylic resin, organosilicon acrylic resin, modified Nano bamboo charcoal powder, baryta feldspar powder, talcum powder, styrene-acrylic emulsion, diatomite, sierozem power, defoamer, wetting dispersing agent, coalescents, levelling agent and organic solvent.Its preparation method first will be added in a mixing bowl and stir and evenly mix except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent, obtain batch mixing;Batch mixing is ground by sand mill again, fineness≤10 μm of material after milling;Finally the material after milling and surplus stock are poured into homogenization is stirred in a mixing bowl.This kind of interior wall coating can effectively adsorb the pernicious gas in room air, real-time monitoring indoor humidity, improve indoor environment, and prepare simply, and cost is low, and paint film property is good, and covering power is strong.

Description

A kind of interior wall coating and preparation method thereof
Technical field
The present invention relates to building coating field, and in particular to a kind of interior wall coating and preparation method thereof.
Background technology
Interior wall coating is the important component of building and ornament materials, mostly by emulsion, deionized water, pigment and other Auxiliary agent is made.Chinese coating circle is more authoritative《Coating process》One book be defined as " coating is a kind of material, this material Material can be coated in object surface with different construction technologies, and it is firm, thin with some strength, continuous solid-state to form adhesion Film, also known as the film common name film so formed, paint film or coating." belong to organic chemical industry's macromolecular material, the film category formed In high-molecular compound type, the classification for the chemical products passed through according to the modern times, coating belongs to fine chemical product, modern painting Material progressively turns into a kind of multi-functional engineering material, is an important industry in chemical industry.
It is more and more extensive with house decorative material application, the present mankind initially enter using indoor pollution for indicate the Three generations pollutes period.It is the place maximum to public health harm to generally acknowledge indoor pollution in the world.And indoor environment changes at present Mainly there are following two aspects in kind direction:1) purifying formaldehyde, formaldehyde are carcinogenic and cause deformed material, are generally acknowledged allergy Source, and one of potential strong mutagen, even more cause one of hazards of child's leukaemia.It is miscellaneous according to the medical science of the country Will and pertinent literature report, harm of the indoor formaldehyde to health can be summarized as stimulation, toxic action and carcinogenesis; 2) regulating and controlling humidity, air humidity is one and produces closely related important ambient parameter with people's life, under low moisture environments, The respiratory system mucous membrane of people becomes drying, easily triggers respiratory disease, under high humidity environment, is easily caused the growth of mould, sternly Ghost image rings the life health of people, in the prior art, less to this report, and caused effect is not effectively obvious.
Modified Nano bamboo charcoal powder has excellent adsorption capacity, adjusting humidity and release anion, far infrared, electromagnetism Outside shielding action, moreover it is possible to noxious material such as ammonia, formaldehyde, phenol etc. of absorption are resolved into nontoxic carbon dioxide and water, And there is sterilization inhibitory action well to bacterium such as staphylococcus, Escherichia coli, the Candida albicans of absorption.
In the prior art, the report that modified Nano bamboo charcoal powder is used in building coating has been related to, but in practical application, Improving indoor environment and unobvious.Therefore, it is necessary to further improve.
The content of the invention
For problems of the prior art, the invention provides a kind of interior wall coating and preparation method thereof, in this kind Wall coating can effectively adsorb the pernicious gas in room air, real-time monitoring indoor humidity, improve indoor environment, and prepare letter Single, cost is low, and paint film property is good, and covering power is strong.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of interior wall coating, including following raw material by weight:Acrylic resin 35-45 parts, organosilicon acrylic resin 25-35 Part, modified Nano bamboo charcoal powder 18-22 parts, baryta feldspar powder 5-7 parts, talcum powder 8-12 parts, styrene-acrylic emulsion 10-20 parts, diatomite 6-10 parts, sierozem power 3-7 parts, defoamer 1-3 parts, wetting dispersing agent 2-4 parts, coalescents 2-4 parts, levelling agent 1-3 parts and have Solvent 20-30 parts;
The preparation method of the modified Nano bamboo charcoal powder is:Bamboo carbon powder is put into after soaking 3-5h in glacial acetic acid solution, taken Go out, filter, deionized water washing, then at 360-420 DEG C of calcining 1-2h, be then ground into nanometer powder and produce.
Further, the interior wall coating includes following raw material by weight:40 parts of acrylic resin, organosilicon acrylic resin 30 parts, 20 parts of modified Nano bamboo charcoal powder, 6 parts of baryta feldspar powder, 10 parts of talcum powder, 15 parts of styrene-acrylic emulsion, 8 parts of diatomite, grey calcium 25 parts of 5 parts of powder, 2 parts of defoamer, 3 parts of wetting dispersing agent, 3 parts of coalescents, 2 parts of levelling agent and organic solvent.
Preferably, the defoamer is one kind in dimethyl silicone polymer, benzyl carbinol oleate or polyoxypropylene.
Preferably, the wetting dispersing agent is Lignosite, alkyl aryl polyether or the sour sodium of glass amber acid di-isooctyl In one kind.
Preferably, the coalescents are two kinds of mixtures of 2,2,4- trimethyls -1 and 3- pentanediol diisobutyrates.
Preferably, the levelling agent is one kind or one in polyacrylic acid, carboxymethyl cellulose or dimethyl silicone polymer More than kind.
Preferably, the organic solvent is the one or more in ethanol, isobutanol, acetone or ethyl acetate.
A kind of preparation method of above-mentioned interior wall coating, is followed the steps below:
(1) required raw material is weighed by weight ratio;
(2) it will be added to stir in a mixing bowl except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent and mix It is even, obtain batch mixing;
(3) batch mixing is ground by sand mill, fineness≤10 μm of material after milling;
(4) finally the material after milling and surplus stock are poured into a mixing bowl and carries out being again stirring for homogenization, stirred Rotating speed is 300-500r/min, mixing time 1-2h, you can.
The present invention has following beneficial effect:
(1) interior wall coating raw material sources of the invention are extensive, and cost is cheap, and it prepares simple and convenient, and free from extraneous odour is without discharge Pollution, it is green;
(2) the problems such as interior wall coating paint film property of the invention is excellent, and good decorative property is not in sagging, out-of-flatness, hide Gai Liqiang, service life length;
(3) interior wall coating of the invention can effectively adsorb the pernicious gas in room air, real-time monitoring indoor humidity, Improve indoor environment, and also there is excellent heat preservation and soundproof.
Embodiment
The embodiment of the present invention is further described with reference to embodiment, following examples are only used for more Clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
Embodiment 1
A kind of interior wall coating, weigh following raw material:Acrylic resin 30kg, organosilicon acrylic resin 20kg, modified Nano bamboo charcoal powder 15kg, baryta feldspar powder 3kg, talcum powder 5kg, styrene-acrylic emulsion 8kg, diatomite 4kg, sierozem power 1kg, defoamer 1kg, wetting point Powder 2kg, coalescents 2kg, levelling agent 1kg and organic solvent 15kg;
The preparation method of above-mentioned modified Nano bamboo charcoal powder is:Take bamboo carbon powder 15kg to be put into glacial acetic acid solution and soak 3h Afterwards, take out, filtering, deionized water washing, then at 360 DEG C of calcining 1h, be then ground into nanometer powder and produce.
Wherein, above-mentioned defoamer uses dimethyl silicone polymer;Wetting dispersing agent uses Lignosite;Coalescents Using two kinds of mixtures of 2,2,4- trimethyls -1 and 3- pentanediol diisobutyrates, and mass ratio between the two is 1:1;Levelling Agent uses dimethyl silicone polymer;Organic solvent uses two kinds of mixtures of ethanol and isobutanol, and mass ratio between the two is 2:1。
A kind of preparation method of above-mentioned interior wall coating, is followed the steps below:
(1) first it will be added in a mixing bowl and stir except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent Mixed after 23min, speed of agitator 350r/min, obtain batch mixing;
(2) batch mixing is ground by sand mill, fineness≤10 μm of material after milling;
(3) finally the material after milling and surplus stock auxiliary agent are poured into a mixing bowl and carry out being again stirring for homogenization, Speed of agitator is 300r/min, mixing time 1h, that is, the interior wall coating of the present invention is made.
Embodiment 2
A kind of interior wall coating, weigh following raw material:Acrylic resin 40kg, organosilicon acrylic resin 30kg, modified Nano bamboo charcoal powder 20kg, baryta feldspar powder 6kg, talcum powder 10kg, styrene-acrylic emulsion 15kg, diatomite 8kg, sierozem power 5kg, defoamer 2kg, wetting Dispersant 3kg, coalescents 3kg, levelling agent 2kg and organic solvent 25kg;
The preparation method of above-mentioned modified Nano bamboo charcoal powder is:Take bamboo carbon powder 20kg to be put into glacial acetic acid solution and soak 4h Afterwards, take out, filtering, deionized water washing, then at 390 DEG C of calcining 1.5h, be then ground into nanometer powder and produce.
Wherein, above-mentioned defoamer uses benzyl carbinol oleate;Wetting dispersing agent uses alkyl aryl polyether;Coalescents Using two kinds of mixtures of 2,2,4- trimethyls -1 and 3- pentanediol diisobutyrates, and mass ratio between the two is 1:2;Levelling Agent uses two kinds of mixtures of polyacrylic acid and carboxymethyl cellulose, and mass ratio between the two is 1:2;Organic solvent is using different Two kinds of mixtures of butanol and acetone, and mass ratio between the two is 1:1.
A kind of preparation method of above-mentioned interior wall coating, is followed the steps below:
(1) first it will be added in a mixing bowl and stir except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent Mixed after 26min, speed of agitator 350r/min, obtain batch mixing;
(2) batch mixing is ground by sand mill, fineness≤10 μm of material after milling;
(3) finally the material after milling and surplus stock auxiliary agent are poured into a mixing bowl and carry out being again stirring for homogenization, Speed of agitator is 400r/min, mixing time 1.5h, that is, the interior wall coating of the present invention is made.
Embodiment 3
A kind of interior wall coating, weigh following raw material:Acrylic resin 50kg, organosilicon acrylic resin 40kg, modified Nano bamboo charcoal powder 25kg, baryta feldspar powder 10kg, talcum powder 16kg, styrene-acrylic emulsion 22kg, diatomite 12kg, sierozem power 10kg, defoamer 5kg, Wetting dispersing agent 6kg, coalescents 6kg, levelling agent 5kg and organic solvent 35kg;
The preparation method of above-mentioned modified Nano bamboo charcoal powder is:Take bamboo carbon powder 25kg to be put into glacial acetic acid solution and soak 5h Afterwards, take out, filtering, deionized water washing, then at 420 DEG C of calcining 2h, be then ground into nanometer powder and produce.
Wherein, above-mentioned defoamer uses polyoxypropylene;Wetting dispersing agent uses the sour sodium of glass amber acid di-isooctyl;Film forming Auxiliary agent uses two kinds of mixtures of 2,2,4- trimethyls -1 and 3- pentanediol diisobutyrates, and mass ratio between the two is 1:3; Levelling agent uses carboxymethyl cellulose;Organic solvent uses ethyl acetate.
A kind of preparation method of above-mentioned interior wall coating, is followed the steps below:
(1) first it will be added in a mixing bowl and stir except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent Mixed after 25min, speed of agitator 400r/min, obtain batch mixing;
(2) batch mixing is ground by sand mill, fineness≤10 μm of material after milling;
(3) finally the material after milling and surplus stock auxiliary agent are poured into a mixing bowl and carry out being again stirring for homogenization, Speed of agitator is 500r/min, mixing time 2h, that is, the interior wall coating of the present invention is made.
Performance detection
Interior wall coating and the commercially available common modified Nano bamboo charcoal powder interior wall paint of comparative example are made to above-described embodiment 1-3 Following related performance detection is carried out, the specific data that detect see the table below shown in 1;
Comparative example:Modified Nano bamboo charcoal powder interior wall paint includes modified Nano bamboo charcoal powder, and (preparation technology and the present invention are not Together), acrylic emulsion, polyester resin, coalescents, levelling agent.
Table 1
From upper table 1, interior wall coating of the invention compares commercially available modified Nano bamboo charcoal powder interior wall paint formaldehyde adsorption Effect is more preferable, and regulation and control indoor humidity is outstanding, and heat preservation and soundproof performance is more superior.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (8)

1. a kind of interior wall coating, it is characterised in that including following raw material by weight:Acrylic resin 35-45 parts, silicon third Resin 25-35 parts, modified Nano bamboo charcoal powder 18-22 parts, baryta feldspar powder 5-7 parts, talcum powder 8-12 parts, styrene-acrylic emulsion 10-20 Part, diatomite 6-10 parts, sierozem power 3-7 parts, defoamer 1-3 parts, wetting dispersing agent 2-4 parts, coalescents 2-4 parts, levelling agent 1-3 parts and organic solvent 20-30 parts;
The preparation method of the modified Nano bamboo charcoal powder is:Bamboo carbon powder is put into after soaking 3-5h in glacial acetic acid solution, taken out, mistake Filter, deionized water washing, then at 360-420 DEG C of calcining 1-2h, then it is ground into nanometer powder and produces.
2. a kind of interior wall coating according to claim 2, it is characterised in that including following raw material by weight:Third 40 parts of olefin(e) acid resin, 30 parts of organosilicon acrylic resin, 20 parts of modified Nano bamboo charcoal powder, 6 parts of baryta feldspar powder, 10 parts of talcum powder, phenylpropyl alcohol breast 15 parts of liquid, 8 parts of diatomite, 5 parts of sierozem power, 2 parts of defoamer, 3 parts of wetting dispersing agent, 3 parts of coalescents, 2 parts of levelling agent and have 25 parts of solvent.
A kind of 3. interior wall coating according to claim 1, it is characterised in that the defoamer be dimethyl silicone polymer, One kind in benzyl carbinol oleate or polyoxypropylene.
A kind of 4. interior wall coating according to claim 1, it is characterised in that the wetting dispersing agent be Lignosite, One kind in alkyl aryl polyether or the sour sodium of glass amber acid di-isooctyl.
5. a kind of interior wall coating according to claim 1, it is characterised in that the coalescents are 2,2,4- trimethyls -1 With two kinds of mixtures of 3- pentanediol diisobutyrates.
6. a kind of interior wall coating according to claim 1, it is characterised in that the levelling agent is polyacrylic acid, carboxymethyl One or more in cellulose or dimethyl silicone polymer.
7. a kind of interior wall coating according to claim 1, it is characterised in that the organic solvent is ethanol, isobutanol, third One or more in ketone or ethyl acetate.
8. the preparation method of a kind of interior wall coating as described in claim 1-7 any one, it is characterised in that including following step Suddenly:
(1) required raw material is weighed by weight ratio;
(2) it will be added in a mixing bowl and stir and evenly mix except defoamer, wetting dispersing agent, coalescents and the other raw materials of levelling agent, Obtain batch mixing;
(3) batch mixing is ground by sand mill, fineness≤10 μm of material after milling;
(4) finally the material after milling and surplus stock are poured into a mixing bowl and carries out being again stirring for homogenization, speed of agitator For 300-500r/min, mixing time 1-2h, you can.
CN201710467816.9A 2017-06-20 2017-06-20 A kind of interior wall coating and preparation method thereof Withdrawn CN107418329A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285709A (en) * 2018-01-23 2018-07-17 合肥达户电线电缆科技有限公司 A kind of environment-friendly type emulsion paint and preparation method thereof
CN109021751A (en) * 2018-07-03 2018-12-18 合肥华盖光伏科技有限公司 A kind of antibacterial inner wall paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003292876A (en) * 2002-04-04 2003-10-15 Nippon Paint Co Ltd Sealer for inorganic building material, its applying method and coated inorganic building material
CN102912686A (en) * 2012-09-25 2013-02-06 蚌埠凤凰滤清器有限责任公司 Filter paper for air filter containing modified nano bamboo charcoal powder
CN103242722A (en) * 2013-05-20 2013-08-14 佛山市伊思曼化工有限公司 Multifunctional composite inner wall thermal-insulating coating material and preparation method thereof
CN103923536A (en) * 2013-01-15 2014-07-16 佛山市康威涂料实业有限公司 Preparation method for ecological air-purifying humidity-regulating antibacterial interior wall paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003292876A (en) * 2002-04-04 2003-10-15 Nippon Paint Co Ltd Sealer for inorganic building material, its applying method and coated inorganic building material
CN102912686A (en) * 2012-09-25 2013-02-06 蚌埠凤凰滤清器有限责任公司 Filter paper for air filter containing modified nano bamboo charcoal powder
CN103923536A (en) * 2013-01-15 2014-07-16 佛山市康威涂料实业有限公司 Preparation method for ecological air-purifying humidity-regulating antibacterial interior wall paint
CN103242722A (en) * 2013-05-20 2013-08-14 佛山市伊思曼化工有限公司 Multifunctional composite inner wall thermal-insulating coating material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285709A (en) * 2018-01-23 2018-07-17 合肥达户电线电缆科技有限公司 A kind of environment-friendly type emulsion paint and preparation method thereof
CN109021751A (en) * 2018-07-03 2018-12-18 合肥华盖光伏科技有限公司 A kind of antibacterial inner wall paint and preparation method thereof

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