CN110328221A - A kind of incineration of refuse flyash mineralization treatment method - Google Patents
A kind of incineration of refuse flyash mineralization treatment method Download PDFInfo
- Publication number
- CN110328221A CN110328221A CN201910765404.2A CN201910765404A CN110328221A CN 110328221 A CN110328221 A CN 110328221A CN 201910765404 A CN201910765404 A CN 201910765404A CN 110328221 A CN110328221 A CN 110328221A
- Authority
- CN
- China
- Prior art keywords
- mineralizer
- incineration
- treatment method
- flying dust
- fine powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000010881 fly ash Substances 0.000 title claims abstract description 16
- 230000033558 biomineral tissue development Effects 0.000 title claims abstract description 15
- 239000000428 dust Substances 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 22
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910000632 Alusil Inorganic materials 0.000 claims abstract description 12
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010427 ball clay Substances 0.000 claims abstract description 12
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 11
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 10
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- 239000002699 waste material Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000008187 granular material Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 4
- 239000004035 construction material Substances 0.000 claims abstract description 3
- 239000000470 constituent Substances 0.000 claims description 10
- 239000003638 chemical reducing agent Substances 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 201000008827 tuberculosis Diseases 0.000 abstract description 4
- 230000002427 irreversible effect Effects 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 238000005245 sintering Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 3
- 238000004056 waste incineration Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
A kind of incineration of refuse flyash mineralization treatment method; mineralizer and aqueous solvent are added to the flying dust that waste incinerator generates; mixture is formed, spherical solid granulates will be made in mixture merging particle machinery, and spherical solid granulates are returned in waste incinerator and carry out secondary clacining;Mineralizer includes potassium feldspar fine powder, spodumene fine powder, magnesia, land plaster, ball clay and Alusil;The present invention wraps flying dust using the extra specific surface area feature of Alusil, harmful substance is prevented to be precipitated, spodumene promotes Alusil and flying dust to generate tuberculosis under high temperature action, potassium feldspar reduces the dry of tuberculosis and shrinks and deform, ball clay is as the matrix bonded with flying dust, the sintering of auxiliary at high temperature, the addition of land plaster, magnesia, effectively the bonding to ball clay and flying dust it can carry out normal temperature cure, irreversible reaction is generated after hot setting, following processed flying dust can be used as construction material use.
Description
Technical field
The present invention relates to a kind of incineration of refuse flyash mineralization treatment methods, belong to dangerous waste processing field of engineering technology.
Background technique
Existing more than 100 years history of incineration treatment of garbage, incineration method processing house refuse are to realize that minimizing most fast has
The technical method of effect not only thoroughly eliminates harmful bacteria and virus, and recoverable energy is secondary promotes the well-being of mankind, but waste incineration
Also secondary pollution problem is produced;Secondary pollution is mainly in the flying dust of waste incineration generation comprising dioxin contamination
The heavy metal pollution problems such as cd.AS.Hg.rb cause the flying dust excluded that cannot efficiently use;But due to containing pollution in flying dust,
Therefore, national clear stipulaties flying dust category dangerous waste object must not be discharged arbitrarily, after this just carries out carry out chelation treatment to flying dust, taken and filled out
The processing modes such as bury, but this Landfill occupies a large amount of soil, pre-processing is up to standard, but whether the later period generates two
The secondary all bad control of pollution, in addition, China's conventional garbage incinerator has broken through 1000, generates a large amount of flying dust every year, therefore,
It needs that technological means is taken to carry out secondary use to flying dust and makes place mat, in the hope of effecting a permanent cure.
For the secondary use for realizing flying dust, the more method handled flying dust and material exists in the prior art,
But there is complex process, operating difficulties, problem with high costs in these methods, and need to carry out needle using specific environment more
The product that technology is unable to drive garbage burning factory can not be brought up in the defect of garbage burning factory treatment in situ, these problems to property processing
Polarity, though lead to have technological means, the predicament that can not effectively promote.
Summary of the invention
For the defect for solving the prior art, the present invention provides a kind of flyash treatment method of simple process, and the present invention only needs
Flying dust is stirred and processing to flying dust can be realized in local use waste incinerator secondary clacining, and be made it is subsequent can benefit
Material, it is low in cost.
To achieve the above object, the invention adopts the following technical scheme: a kind of incineration of refuse flyash mineralization treatment method, right
Mineralizer and aqueous solvent is added in the flying dust that waste incinerator generates, and forms mixture, will be made in mixture merging particle machinery
Spherical solid granulates, and spherical solid granulates are returned in waste incinerator and carry out secondary clacining;
The mineralizer includes potassium feldspar fine powder, spodumene fine powder, magnesia, land plaster, ball clay and Alusil.
Preferably, with mineralizer poidometer, the weight ratio of mineralizer constituent is respectively potassium feldspar fine powder 5-15%, lithium
Pyroxene fine powder 5-15%, magnesia 2-8%, land plaster 5-15%, ball clay 10-25%, Alusil 35-55%.
Preferably, with mineralizer poidometer, the weight ratio of mineralizer constituent is respectively potassium feldspar fine powder 10%, lithium brightness
Stone fine powder 10%, magnesia 5%, land plaster 10%, ball clay 18%, Alusil 47%.
Preferably, aqueous solvent includes emulsifier and water-reducing agent, and the emulsifier and water-reducing agent using commercial emulsifier and subtract
Aqua.
Preferably, with flying dust poidometer, the weight ratio of aqueous solvent constituent is emulsifier 0.05-0.3%, water-reducing agent
0.1-0.4%。
Preferably, with flying dust poidometer, the weight ratio of aqueous solvent constituent is emulsifier 0.1%, water-reducing agent 0.15%.
Preferably, the partial size of potassium feldspar fine powder and spodumene fine powder is 50 μm of micro mists and Ultramicro-powder below.
Preferably, with flying dust poidometer, the mineralizer accounts for the 5-15% of flying dust total weight.
Compared with prior art, it is special using the extra specific surface area of Alusil that the beneficial effects of the present invention are: the present invention
Point wraps flying dust, and the harmful substance in flying dust is prevented to be precipitated, and promotes Alusil and flying dust to make in high temperature by spodumene
With lower generation tuberculosis, while reducing the dry of tuberculosis using the high viscosity feature of potassium feldspar and shrinking and deformation, ball clay as with
The matrix of flying dust bonding, assists sintering at high temperature, the addition of land plaster, magnesia can be effectively to ball clay and flying dust
Bonding carry out normal temperature cure, obtain some strength at normal temperature, irreversible reaction, subsequent warp generated after mixture high temperature mineralising
Processing flying dust can be used as construction material use.
Specifically embodiment
The flying dust 60KG for taking waste incinerator to generate, and be put into Particle mixer, the mineralizer of following components: potassium is added
Feldspar fine powder 0.6KG, spodumene fine powder 0.6KG, magnesia 0.3KG, land plaster 0.6KG, ball clay 1KG, Alusil 2.8KG,
It carries out dry-mixed, stirs, aqueous solvent odium stearate 0.06KG and naphthalene sulfonate water-reducing agent 0.09KG is added, is sufficiently stirred
Uniformly, the orbicule of 3 centimetres or so of diameter is made, orbicule is subjected to static solidification in 24 hours, is then sent to waste incineration
It is sintered in furnace, sintered flying dust is mineralized object package, is discharged with clinker, as can built again using material
It is used in field as raw material.
In the above-described embodiments, the partial size of spodumene and potassium feldspar is smaller, and raw material obtained will have better effect.
It is clear that above embodiment is only one of demonstration example of the invention, it is any provided by the present invention
Simple modifications in structure or principle will fall into protection scope of the present invention.
Claims (10)
1. a kind of incineration of refuse flyash mineralization treatment method, it is characterised in that mineralizer is added to the flying dust that waste incinerator generates
And aqueous solvent, mixture is formed, spherical solid granulates will be made in mixture merging particle machinery, and spherical solid granulates are returned
It returns in waste incinerator and carries out secondary clacining, form available construction material;
The mineralizer includes potassium feldspar fine powder, spodumene fine powder and Alusil.
2. a kind of incineration of refuse flyash mineralization treatment method according to claim 1, it is characterised in that with mineralizer weight
Meter, the weight ratio of mineralizer constituent is respectively potassium feldspar fine powder 5-15%, spodumene fine powder 5-15%, Alusil 35-55%.
3. a kind of incineration of refuse flyash mineralization treatment method according to claim 2, it is characterised in that with mineralizer weight
Meter, the weight ratio of mineralizer constituent is respectively potassium feldspar fine powder 10%, spodumene fine powder 10%, Alusil 47%.
4. a kind of incineration of refuse flyash mineralization treatment method according to claim 1, it is characterised in that the mineralizer is also
Including magnesia, land plaster, ball clay.
5. a kind of incineration of refuse flyash mineralization treatment method according to claim 4, it is characterised in that with mineralizer weight
Meter, the weight ratio of mineralizer constituent is respectively magnesia 2-8%, land plaster 5-15%, ball clay 10-25%.
6. a kind of incineration of refuse flyash mineralization treatment method according to claim 4, it is characterised in that with mineralizer weight
Meter, the weight ratio of mineralizer constituent is respectively magnesia 5%, land plaster 10%, ball clay 18%.
7. a kind of incineration of refuse flyash mineralization treatment method according to claim 1 or 2 or 3, it is characterised in that aqueous solvent
Including emulsifier and water-reducing agent.
8. a kind of incineration of refuse flyash mineralization treatment method according to claim 4, it is characterised in that with flying dust poidometer,
The weight ratio of aqueous solvent constituent is emulsifier 0.05-0.3%, water-reducing agent 0.1-0.4%.
9. a kind of incineration of refuse flyash mineralization treatment method according to claim 5, it is characterised in that with flying dust poidometer,
The weight ratio of aqueous solvent constituent is emulsifier 0.1%, water-reducing agent 0.15%.
10. a kind of incineration of refuse flyash mineralization treatment method according to claim 5, it is characterised in that potassium feldspar fine powder and
The partial size of spodumene fine powder is 50 μm of micro mists and Ultramicro-powder below.
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CN201910765404.2A CN110328221B (en) | 2019-08-19 | 2019-08-19 | Method for mineralizing and treating fly ash generated by burning garbage |
Applications Claiming Priority (1)
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CN201910765404.2A CN110328221B (en) | 2019-08-19 | 2019-08-19 | Method for mineralizing and treating fly ash generated by burning garbage |
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Publication Number | Publication Date |
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CN110328221A true CN110328221A (en) | 2019-10-15 |
CN110328221B CN110328221B (en) | 2022-04-05 |
Family
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CN201910765404.2A Active CN110328221B (en) | 2019-08-19 | 2019-08-19 | Method for mineralizing and treating fly ash generated by burning garbage |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115093143A (en) * | 2022-06-24 | 2022-09-23 | 上海康恒环境股份有限公司 | Method for collecting and recycling carbon dioxide in flue gas through synergistic treatment of fly ash and leachate and recycling product |
CN115611653A (en) * | 2021-07-16 | 2023-01-17 | 润泰精密材料股份有限公司 | Method for producing lightweight porous material particles |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115611653A (en) * | 2021-07-16 | 2023-01-17 | 润泰精密材料股份有限公司 | Method for producing lightweight porous material particles |
CN115093143A (en) * | 2022-06-24 | 2022-09-23 | 上海康恒环境股份有限公司 | Method for collecting and recycling carbon dioxide in flue gas through synergistic treatment of fly ash and leachate and recycling product |
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CN110328221B (en) | 2022-04-05 |
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