CN106278350A - A kind of alkaline residue building waste water-permeable brick and preparation method thereof - Google Patents

A kind of alkaline residue building waste water-permeable brick and preparation method thereof Download PDF

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Publication number
CN106278350A
CN106278350A CN201610653328.2A CN201610653328A CN106278350A CN 106278350 A CN106278350 A CN 106278350A CN 201610653328 A CN201610653328 A CN 201610653328A CN 106278350 A CN106278350 A CN 106278350A
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China
Prior art keywords
building waste
water
alkaline residue
permeable brick
parts
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CN201610653328.2A
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Chinese (zh)
Inventor
杨卓舒
张军华
段晓
马春羽
史红彬
蔡世楷
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Zhuoda New Material Technology Group Weihai Co Ltd
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Zhuoda New Material Technology Group Weihai Co Ltd
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Priority to CN201610653328.2A priority Critical patent/CN106278350A/en
Publication of CN106278350A publication Critical patent/CN106278350A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/243Mixtures thereof with activators or composition-correcting additives, e.g. mixtures of fly ash and alkali activators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of alkaline residue building waste water-permeable brick belonging to construction material preparing technical field and preparation method thereof.It is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 200 800 parts, silicon ash 28 parts, cement 5 15 parts, alkali-activator 2 7.5 parts, 18 40 parts of water.The raw material of the present invention uses industrial residue and building waste, and solid waste utilization rate is high, production cost is low;Forming method is compressing, and technique is simple, it is not necessary to high-temperature calcination, and low-carbon (LC), environmental protection, energy consumption are low;Binder Materials uses alkali-activated carbonatite alkaline residue Binder Materials, has the advantages such as high intensity, high water-permeability, low hydration heat, anti-carbonation, good endurance with its water-permeable brick prepared.

Description

A kind of alkaline residue building waste water-permeable brick and preparation method thereof
Technical field
The invention belongs to construction material preparing technical field, be specifically related to a kind of alkaline residue building waste water-permeable brick and preparation thereof Method.
Background technology
Along with developing rapidly of China's economy and greatly developing of urbanization, greenery patches originally is by large-scale ground pavement Replace, " the city desert " of formation considerably increases Permeable stratum area so that urban rainwater can not back to nature, its result is city City's subsoil water reduces in a large number, has the danger that urban architecture is sunk;And meeting heavy rain when city is prominent, its rainwater on road surface cannot quickly ooze Leakage, causes to municipal drainage facility and bears greatly and easily send out into urban waterlogging.Meanwhile, its large-area road of mating formation Face weakens the respiratory function in city, can cause " tropical island effect ", reduces city comfort level and causes urban ecological system unbalance. Therefore, water-permeable brick starts increasingly to be received publicity as a kind of good water permeable paving material.
On the other hand, along with industrialization, the acceleration of urbanization process, building industry is the most fast-developing, with this together be to build Building refuse is increasing, and a large amount of building wastes not only occupy soil, and bring severe contamination to human habitat. According to statistics, the every annual meeting of China increases building waste more than 4,000 ten thousand tons newly, and the quantity of building waste has accounted for municipal refuse total amount More than 1/3, wherein concrete construction rubbish has accounted for again more than the 40% of building waste.This phenomenon has been obtained for the whole society Extensive concern.Land resource is not only wasted in storing up for a long time of building waste, easily produces potential safety hazard, and be unfavorable for resource can Sustainable development and the recycling of resource;And the heap of building waste is released and can be polluted water resource, has influence on air Quality, and then directly influence the living environment of the mankind.
At present, it is caused to fail to be widely used in practice because water-permeable brick cost is the highest, simultaneously saturating on current market The comprcssive strength of water brick, anti-wear performance and coefficient of permeability fail to reach active balance, therefore, how to ensure water-permeable brick performance Reduce water-permeable brick cost great to the market application value improving water-permeable brick simultaneously.
Patent CN201510406551 discloses the preparation method of a kind of ecological ceramic water-permeable brick.Include following steps: 1) by following components and constituent content feeding, percentage by weight meter: building waste micropowder 5%-10%, building waste fine aggregate 5%-15%, building waste coarse aggregate 30%-45%, dewatered sludge 15%-20%, modified mud 15%-40%, Alumen 0.075%-0.2%, Borax 0.5%-1%;2) compression moulding method will be used after each raw material mix homogeneously to be shaped to have wedge shape The half-blind hole test block of structure, briquetting pressure is 10-20Mpa, and after molding, natural drying 48h is dried in 80 ± 20 DEG C of environment again, It is warming up to 300 DEG C-350 DEG C, at 300-350 DEG C after constant temperature 2.5h-3.5h, then with 3-8 DEG C/min with the speed of 2-3 DEG C/min Speed be warming up to 1050 DEG C-1150 DEG C, sintering 3h-4h after lower the temperature.The ecological ceramic water-permeable brick production cost that the method prepares High;Ecological ceramic water-permeable brick is formed by high-temperature calcination, while consuming building waste, increases energy consumption, aggravates greenhouse effect, right Environment causes certain harm.
Summary of the invention
It is an object of the invention to provide a kind of alkaline residue building waste water-permeable brick and preparation method thereof.
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 200-800 part, silicon ash 2-8 part, cement 5-15 part, alkali-activator 2-7.5 part, water 18-40 part.
Described alkaline residue specific surface area >=350cm2/g。
Described alkali-activator be Calx, sodium silicate, sodium sulfate one or more.
Described building waste is one or more in waste concrete, useless brick, waste marble and waste mortar.
Described building waste includes the component of following percentage by weight: 0.15mm-0.60mm building waste 10-25%, 0.60mm-4.75mm building waste 15-35%, 4.75mm-8mm building waste 45-70%.
Described cement is 42.5 Portland cements.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is sequentially added into stirring according to water, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Machine stirs 3-5min;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 7-28 days, water-permeable brick is prepared.
Beneficial effects of the present invention: raw material of the present invention uses industrial residue and building waste, solid waste utilization rate is high, produce into This is low;Forming method is compressing, and technique is simple, it is not necessary to high-temperature calcination, and low-carbon (LC), environmental protection, energy consumption are low;Binder Materials uses alkali Excite alkaline residue Binder Materials, with its water-permeable brick prepared, there is high intensity, high water-permeability, low hydration heat, anti-carbonation, good endurance Etc. advantage.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 500 Part, silicon ash 5 parts, cement 10 parts, alkali-activator 5 parts, 25 parts of water.Described alkaline residue specific surface area >=350cm2/g.Described alkalescence Exciting agent is that Calx, sodium silicate, sodium sulfate are mixed according to mass ratio 1:1:1.Described building waste is waste concrete, gives up Brick, waste marble and waste mortar are mixed according to mass ratio 1:1:1:1.Described building waste includes following percentage by weight Component: 0.15mm-0.60mm building waste 15%, 0.60mm-4.75mm building waste 30%, 4.75mm-8mm building waste 55%.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is sequentially added into stirring according to water, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Machine stirs 4min;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 16 days, water-permeable brick is prepared.
Water-permeable brick prepared by the present embodiment, meets JC/T 945-2005 " water-permeable brick " standard;Comprcssive strength can reach 44Mpa;Low hydration heat, good endurance.
Embodiment 2
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 200 Part, silicon ash 2 parts, cement 5 parts, alkali-activator 2 parts, 18 parts of water.Described alkaline residue specific surface area >=350cm2/g.Described alkalescence swashs Sending out agent is that Calx, sodium silicate, sodium sulfate are mixed according to mass ratio 1:1:1.Described building waste is waste concrete, gives up Brick, waste marble and waste mortar are mixed according to mass ratio 1:1:1:1.Described building waste includes following percentage by weight Component: 0.15mm-0.60mm building waste 25%, 0.60mm-4.75mm building waste 15%, 4.75mm-8mm building waste 60%.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is sequentially added into stirring according to water, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Machine stirs 3min;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 7 days, water-permeable brick is prepared.
Water-permeable brick prepared by the present embodiment, meets JC/T 945-2005 " water-permeable brick " standard;Comprcssive strength can reach 43Mpa;Low hydration heat, good endurance.
Embodiment 3
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 800 Part, silicon ash 8 parts, cement 15 parts, alkali-activator 7.5 parts, 40 parts of water.Described alkaline residue specific surface area >=350cm2/g.Described alkali Property exciting agent is that Calx, sodium silicate, sodium sulfate are mixed according to mass ratio 1:1:1.Described building waste be waste concrete, Useless brick, waste marble and waste mortar are mixed according to mass ratio 1:1:1:1.Described building waste includes following percentage by weight Component: 0.15mm-0.60mm building waste 10%, 0.60mm-4.75mm building waste 20%, 4.75mm-8mm building waste 70%.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is sequentially added into stirring according to water, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Machine stirs 5min;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 28 days, water-permeable brick is prepared.
Water-permeable brick prepared by the present embodiment, meets JC/T 945-2005 " water-permeable brick " standard;Comprcssive strength can reach 43Mpa;Low hydration heat, good endurance.
Embodiment 4
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 500 Part, silicon ash 5 parts, cement 10 parts, 2 parts of Quercus acutissima powder, alkali-activator 5 parts, 25 parts of water.Described alkaline residue specific surface area >=350cm2/ g.Described alkali-activator is that Calx, sodium silicate, sodium sulfate are mixed according to mass ratio 1:1:1.Described building waste is Waste concrete, useless brick, waste marble and waste mortar are mixed according to mass ratio 1:1:1:1.Described building waste includes as follows The component of percentage by weight: 0.15mm-0.60mm building waste 15%, 0.60mm-4.75mm building waste 30%, 4.75mm- 8mm building waste 55%.The preparation method of described Quercus acutissima powder is: collects the bark of Quercus acutissima, dries, clay into power, and crosses 200 mesh sieves Make.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is added successively according to water, Quercus acutissima powder, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Enter stirring 4min in blender;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 16 days, water-permeable brick is prepared.
Water-permeable brick prepared by the present embodiment, meets JC/T 945-2005 " water-permeable brick " standard;Comprcssive strength can reach 53Mpa;Low hydration heat, good endurance.
Embodiment 5
A kind of alkaline residue building waste water-permeable brick, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 500 Part, silicon ash 5 parts, 2 parts of Elaeocarpus decipiens powder, cement 10 parts, alkali-activator 5 parts, 25 parts of water.Described alkaline residue specific surface area >=350cm2/ g.Described alkali-activator is that Calx, sodium silicate, sodium sulfate are mixed according to mass ratio 1:1:1.Described building waste is Waste concrete, useless brick, waste marble and waste mortar are mixed according to mass ratio 1:1:1:1.Described building waste includes as follows The component of percentage by weight: 0.15mm-0.60mm building waste 15%, 0.60mm-4.75mm building waste 30%, 4.75mm- 8mm building waste 55%.The preparation method of described Elaeocarpus decipiens powder is: receives the bark of Elaeocarpus decipiens tree, dries, clay into power, and crosses 200 mesh sieves Make.
The preparation method of above-mentioned alkaline residue building waste water-permeable brick, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing Machine is pulverized, with multi-layer grading sieve screening be 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-8mm building waste;
(2) material is added successively according to water, Elaeocarpus decipiens powder, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Enter stirring 4min in blender;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 16 days, water-permeable brick is prepared.
Water-permeable brick prepared by the present embodiment, meets JC/T 945-2005 " water-permeable brick " standard;Comprcssive strength can reach 56Mpa;Low hydration heat, good endurance.

Claims (7)

1. an alkaline residue building waste water-permeable brick, it is characterised in that be made up of the material of following parts by weight: alkaline residue 100 parts, build Building refuse 200-800 part, silicon ash 2-8 part, cement 5-15 part, alkali-activator 2-7.5 part, water 18-40 part.
Alkaline residue building waste water-permeable brick the most according to claim 1, it is characterised in that described alkaline residue specific surface area >=350cm2/ g。
Alkaline residue building waste water-permeable brick the most according to claim 1, it is characterised in that described alkali-activator is Calx, sodium Waterglass, sodium sulfate one or more.
Alkaline residue building waste water-permeable brick the most according to claim 1, it is characterised in that described building waste be waste concrete, One or more in useless brick, waste marble and waste mortar.
Alkaline residue building waste water-permeable brick the most according to claim 1, it is characterised in that described building waste includes following weight The component of percentage ratio: 0.15mm-0.60mm building waste 10-25%, 0.60mm-4.75mm building waste 15-35%, 4.75mm-8mm building waste 45-70%.
Alkaline residue building waste water-permeable brick the most according to claim 1, it is characterised in that described cement is 42.5 normal silicates Cement.
7. the preparation method of alkaline residue building waste water-permeable brick described in claim 1, it is characterised in that carry out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then enters with stone crusher Row is pulverized, and is 0.15mm-0.60mm building waste, 0.60mm-4.75mm building waste and 4.75mm-with multi-layer grading sieve screening 8mm building waste;
(2) material is sequentially added in blender according to water, silicon ash, cement, alkaline residue, building waste, the order of alkali-activator Stirring 3-5min;
(3) the mixing material brick machine after stirring is carried out mechanical pressing, prepare adobe;
(4), after the frequent replenishing vital QI with drugs of warm nature of adobe after molding protects 7-28 days, water-permeable brick is prepared.
CN201610653328.2A 2016-08-10 2016-08-10 A kind of alkaline residue building waste water-permeable brick and preparation method thereof Pending CN106278350A (en)

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CN106927769A (en) * 2017-04-10 2017-07-07 燕山大学 A kind of alkaline residue pervious concrete and preparation method thereof
CN107488014A (en) * 2017-10-12 2017-12-19 贺州学院 Rotten Marble Powder concrete permeable brick and preparation method thereof
CN107721270A (en) * 2017-10-24 2018-02-23 上海老港废弃物处置有限公司 A kind of method that non-sintered water-permeable brick is prepared using municipal sludge
CN109265083A (en) * 2017-07-17 2019-01-25 浙江兆联智能科技有限公司 A kind of cement prefabricated product and its production technology of building waste production
CN115286425A (en) * 2022-07-29 2022-11-04 广东简一(集团)陶瓷有限公司 Lightweight brick prepared from waste residues at low temperature and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106927769A (en) * 2017-04-10 2017-07-07 燕山大学 A kind of alkaline residue pervious concrete and preparation method thereof
CN109265083A (en) * 2017-07-17 2019-01-25 浙江兆联智能科技有限公司 A kind of cement prefabricated product and its production technology of building waste production
CN107488014A (en) * 2017-10-12 2017-12-19 贺州学院 Rotten Marble Powder concrete permeable brick and preparation method thereof
CN107488014B (en) * 2017-10-12 2020-04-10 贺州学院 Modified marble powder concrete water permeable brick and preparation method thereof
CN107721270A (en) * 2017-10-24 2018-02-23 上海老港废弃物处置有限公司 A kind of method that non-sintered water-permeable brick is prepared using municipal sludge
CN107721270B (en) * 2017-10-24 2020-05-19 上海老港废弃物处置有限公司 Method for preparing non-sintered water permeable brick by using municipal sludge
CN115286425A (en) * 2022-07-29 2022-11-04 广东简一(集团)陶瓷有限公司 Lightweight brick prepared from waste residues at low temperature and preparation method thereof

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Application publication date: 20170104