CN109763335A - A kind of nylon spinning oil and preparation method thereof - Google Patents
A kind of nylon spinning oil and preparation method thereof Download PDFInfo
- Publication number
- CN109763335A CN109763335A CN201910029903.5A CN201910029903A CN109763335A CN 109763335 A CN109763335 A CN 109763335A CN 201910029903 A CN201910029903 A CN 201910029903A CN 109763335 A CN109763335 A CN 109763335A
- Authority
- CN
- China
- Prior art keywords
- finish
- spinning oil
- nylon
- nylon spinning
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of nylon spinning oils and preparation method thereof, are related to spinning process aid technical field.Be characterized in that: nylon spinning oil includes finish solution and auxiliary agent, the mass ratio of the finish solution and auxiliary agent is 100:(2.5-4.5), the finish solution includes basic finish and ultrapure water, and the basis finish includes the component of following mass percent: lubricating oil in esters 63-67%；Non-ionic surfactant 10-14%；Teepol 14-16%；Antistatic agent 4-6%；Antioxidant 2-4%；The auxiliary agent includes the component of following mass percent: amine salt of alkyl phosphate 52-57%；Polyoxyethylene alkyl ether 43-48%.Finish greasy property of the invention is good, excellent adsorption, convergence are good, reduces the white powder that nylon yarn production process is generated by friction；The viscosity of finish is affected by temperature small, is not likely to produce oil smoke after heated, few in the coking that heating roller surface generates, and easy cleaning, and nylon filament drafting is uniform, stay in grade.
Description
Technical field
The present invention relates to spinning process aid technical field, more specifically, it relates to a kind of nylon spinning oil and its
Preparation method.
Background technique
Textile finish oil is a kind of important textile auxiliary, it is possible to reduce between fiber and the friction of fiber and machine, is increased
Add the flatness and convergence between fiber, to meet the requirement of spin-drawing and post-processing procedure, improve product quality and
Yield rate.
Commercially available nylon spinning oil mainly has lubricant, surfactant and antistatic agent, and surfactant is mainly
Polyethers.Existing nylon spinning oil has the disadvantage in that the viscous temperature of many polyether monomers, to glue dense characteristic ideal not enough, single
Body molecular weight is excessive, and viscosity is big under low temperature, causes to oil irregular, and viscosity is small under high temperature, and the finish on fiber is in centrifugation masterpiece
It can be splashed on hot-rolling under, the heated formation for being easy to cause coke-like object, gently then influences the heat conduction efficiency of heater, lead for a long time
Cause strand tensile uneven, it is heavy then increase lousiness and broken end, it influences to produce.And monomer molecule amount is smaller, generally there is viscosity
Jumping phenomenon, causes the viscosity fluctuation range during high speed spinning excessive, can equally cause to oil irregular, nylon yarn and equipment
Friction posterior surface generates white powder, influences the quality of silk.
Summary of the invention
In view of the deficienciess of the prior art, the purpose of the present invention one is to provide a kind of nylon spinning oil, have
Oiling, uniform, coefficient of friction is low, improves the advantages of nylon yarn quality.
The purpose of the present invention two is to provide a kind of preparation method of nylon spinning oil, with performance stabilization, friction
The low advantage of coefficient.
To achieve the above object one, the present invention provides the following technical scheme that
The mass ratio of a kind of nylon spinning oil, including finish solution and auxiliary agent, the finish solution and auxiliary agent is 100:(2.5-
4.5), the finish solution includes basic finish and ultrapure water, and the basis finish includes the component of following mass percent:
Lubricating oil in esters 63-67%；
Non-ionic surfactant 10-14%；
Teepol 14-16%；
Antistatic agent 4-6%；
Antioxidant 2-4%；
The auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 52-57%；
Polyoxyethylene alkyl ether 43-48%.
By using above-mentioned technical proposal, lubricating oil in esters forms one layer of continuous oil between nylon yarn and the contacting surface of equipment
Film, to reduce friction.But oil-film stabilization how to be allowed to be uniformly adhered to nylon yarn surface, this is long-standing problem this field skill
The problem of art personnel.Applicant after study and practice, is compounded using non-ionic surfactant and teepol,
And amine salt of alkyl phosphate and polyoxyethylene alkyl ether is added, so as to improve oil film adhesion, uniformity.Finish when in use,
Can uniform adhesion at nylon yarn surface, nylon yarn high-speed motion, be also not easy to separate with finish；The viscosity of finish is by temperature shadow
Sound is small, and high/low temperature will not make its viscosity that larger fluctuation occur；Finish temperature tolerance is good, is not likely to produce oil smoke after heated, is heating
The coking that roller surface generates is few, and easy cleaning.The effect of antistatic agent is to increase nylon in nylon yarn high speed texturing process
The hygroscopicity of silk, improves the conductivity of nylon yarn, reduces the generation and accumulation of electrostatic, and guarantee goes on smoothly spinning.Antioxidant energy
Enough antioxygenic property of the enhancing finish in frictional heating.
Further preferably, the mass percent of basic finish is 8-13% in the finish solution.
By using above-mentioned technical proposal, basic finish is too many, and the oil of nylon yarn surface adhesion thickens, both caused waste or
It is easy to generate splashing because of centrifugal force, basic finish is very little, and the oil of nylon yarn surface adhesion is very little, and greasy property is bad.
Further preferably, the lubricating oil in esters includes the component of following mass percent:
Dodecylphosphoric acid monoesters 30-60%；
Polyalphaolefin 20-40%；
Tricarboxymethyl propane oleate complements to 100%.
By using above-mentioned technical proposal, dodecylphosphoric acid monoesters is cheap, viscosity index (VI) is high, biological degradability
Height, but low temperature flow is poor, so being not suitable for separately as base oil；Polyalphaolefin has high thermo oxidative stability, (thermostabilization
Property refers to being able to maintain good viscosity index (VI) in wide in range temperature range), because the particularity of synthetic oil minor structure makes
It can possess higher flowing and penetrability (and mineral oil compares).Its chemical stability refers to synthetic oil in spinning
Any chemical change (for example, oxidation) for destroying its service performance will not occur in journey, pour point is more much lower than mineral oil, viscosity
Index is high, that is to say, that the variation of viscosity and little under the variation of temperature；Its also have volatility is low, hydrolysis stability is good,
The good advantage with mineral oil compatibility.
Tricarboxymethyl propane oleate belongs to polyol ester, and polyol ester is since ester group is more, so polarity is strong, evaporation loss
Low, lubricity is good.Polyol ester has excellent thermal oxidation stability and low vapo(u)rability, than work of the dibasic acid esters at high 50-100 DEG C
At a temperature of use, but it is expensive, arrange in pairs or groups dodecylphosphoric acid monoesters and polyalphaolefin use, reduce cost and keep preferable
Lubricant effect.
Further preferably, the non-ionic surfactant includes the component of following mass percent:
Laruyl alcohol 20-40%；
Fatty acid methyl ester ethoxylate 1-5%；
Sorbitan ester complements to 100%.
By using above-mentioned technical proposal, after above-mentioned non-ionic surfactant is used cooperatively, the surface of finish is reduced
Power improves the penetration of finish, and finish is enable to sprawl rapidly in the every fiber with rapid osmotic to fiber on nylon yarn surface,
It oils rapid and uniform, is conducive to high speed spinning, guarantee spinning quality.
Further preferably, the teepol is selected from sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl
At least one of benzene sulfonic acid sodium salt, Aerosol OT.
By using above-mentioned technical proposal, above-mentioned interfacial agent is soluble easily in water, and foam is easy to disappear, and has excellent profit
Wet, infiltration and emulsification performance, chemical property are stablized, and will not all decompose in acid or alkaline medium and under heating condition.
Further preferably, the antistatic agent is selected from ethoxylated alkyl ammonium sulfate, stearine, lauramide
At least one of propyl betaine.
By using above-mentioned technical proposal, ethoxylated alkyl ammonium sulfate, stearine all have antistatic property,
Lauroylamidopropyl betaine belongs to the extremely low amphoteric surfactant of irritation, can be with cation, anion, nonionic table
Face active ingredient has antistatic and bactericidal effect, and has good viscosity-adjusting agent to act on.Above-mentioned antistatic agent is compound
In use, effect is best, it ensure that the heat resistance of finish and all there is good antistatic effect under the conditions of different moisture levels.
Further preferably, the antioxidant is selected from 2,6- di-tert-butyl-4-methy phenol, four (β-(3,5- bis- tertiary fourths
Base -4- hydroxy phenyl) propionic acid) pentaerythritol ester, 4, at least one of 4 ' methylene bis (2,6- DI-tert-butylphenol compounds).
By using above-mentioned technical proposal, enhance antioxygenic property of the finish in frictional heating.
To achieve the above object two, the present invention provides the following technical scheme that
A kind of preparation method of nylon spinning oil, comprising the following steps:
Step 1 takes conductivity in 1us/cm ultrapure water below, is added in container；
Step 2, each component of basic finish is uniformly mixed, and basic finish is slowly added into container, is uniformly mixed,
Obtain finish solution；
The component of auxiliary agent is uniformly mixed by step 3, is slowly added to auxiliary agent into finish solution, is uniformly mixed, standing disappears
Bubble removing；
Step 4 is filtered to remove impurity, obtains nylon spinning oil.
By using above-mentioned technical proposal, using ultrapure water, avoids introducing salt impurity, improve the stability of finish, match
It is slowly added to each component when setting, can be avoided and generate a large amount of bubbles.
Further preferably, the temperature of the ultrapure water is 30-33 DEG C.
By using above-mentioned technical proposal, under heating conditions, is conducive to each component and quickly dissolves.
Further preferably, the speed that basic finish is added in the step 2 is 10-15L/min, and mixing speed exists
20rpm or less.
It by using above-mentioned technical proposal, avoids generating a large amount of bubbles, the long period need to be stood to eliminate bubble.
In conclusion compared with prior art, the invention has the following advantages:
(1) it is compounded using non-ionic surfactant and teepol, and amine salt of alkyl phosphate and polyoxy is added
Vinyl alkyl ether, finish when in use, can uniform adhesion at nylon yarn surface, nylon yarn high-speed motion, be also not easy with oil
Agent separation reduces the white powder that nylon yarn production process is generated by friction；
(2) viscosity of finish is affected by temperature small, and high/low temperature will not make its viscosity that larger fluctuation occur, and finish temperature tolerance is good, warp
Oil smoke is not likely to produce after heating, it is few in the coking that heating roller surface generates, and easy cleaning.
Specific embodiment
Below with reference to embodiment, the present invention will be described in detail.
Embodiment 1: a kind of nylon spinning oil, including finish solution and auxiliary agent, the quality of the finish solution and auxiliary agent
Than for 100:2.5, finish solution includes basic finish and ultrapure water, and the mass percent of basic finish is 8% in finish solution.
Basic finish includes the component of following mass percent:
Lubricating oil in esters 67%；
Non-ionic surfactant 10%；
Teepol 16%；
Antistatic agent 5%；
Antioxidant 2%；
Wherein, lubricating oil in esters includes the component of following mass percent:
Dodecylphosphoric acid monoesters 30%；
Polyalphaolefin 40%；
Tricarboxymethyl propane oleate complements to 100%.
Non-ionic surfactant includes the component of following mass percent:
Laruyl alcohol 20%；
Fatty acid methyl ester ethoxylate 5%；
Sorbitan ester complements to 100%.
Teepol is sodium sulfate of polyethenoxy ether of fatty alcohol, and antistatic agent is ethoxylated alkyl sulfates
Ammonium, antioxidant are selected from 2,6- di-tert-butyl-4-methy phenol.
Auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 52%；
Polyoxyethylene alkyl ether 48%.
A kind of preparation method of nylon spinning oil, comprising the following steps:
Step 1 takes conductivity in 1us/cm ultrapure water below, is added in container, and the temperature for controlling ultrapure water is 30 DEG C；
Step 2, each component of basic finish is uniformly mixed, and basic finish is slowly added into container, is uniformly mixed,
The speed of basic finish is 10L/min, and mixing speed is in 20rpm hereinafter, obtaining finish solution；
The component of auxiliary agent is uniformly mixed by step 3, is slowly added to auxiliary agent into finish solution, is uniformly mixed, standing disappears
Bubble removing；
Step 4 is filtered to remove impurity by 120 mesh stainless steel wave schlieren filter devices, obtains nylon spinning oil.
Embodiment 2: a kind of nylon spinning oil, difference from example 1 is that, basic finish includes following quality
The component of percentage:
Lubricating oil in esters 63%；
Non-ionic surfactant 14%；
Teepol 14%；
Antistatic agent 6%；
Antioxidant 3%；
The auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 57%；
Polyoxyethylene alkyl ether 43%.
Embodiment 3: a kind of nylon spinning oil, difference from example 1 is that, basic finish includes following quality
The component of percentage:
Lubricating oil in esters 65%；
Non-ionic surfactant 12%；
Teepol 15%；
Antistatic agent 5%；
Antioxidant 3%.
Auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 55%；
Polyoxyethylene alkyl ether 45%.
Embodiment 4: a kind of nylon spinning oil, difference from example 1 is that, basic finish includes following quality
The component of percentage:
Lubricating oil in esters 63%；
Non-ionic surfactant 13%；
Teepol 16%；
Antistatic agent 4%；
Antioxidant 4%.
The auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 55%；
Polyoxyethylene alkyl ether 45%.
Embodiment 5: a kind of nylon spinning oil, difference from example 1 is that, the quality of finish solution and auxiliary agent
Than for 100:3.5, the mass percent of basic finish is 10.5% in finish solution.
Embodiment 6: a kind of nylon spinning oil, difference from example 1 is that, the quality of finish solution and auxiliary agent
Than for 100:4.5, the mass percent of basic finish is 13% in finish solution.
Embodiment 7: a kind of nylon spinning oil, difference from example 1 is that, lubricating oil in esters includes following matter
Measure the component of percentage:
Dodecylphosphoric acid monoesters 45%；
Polyalphaolefin 30%；
Tricarboxymethyl propane oleate complements to 100%.
Embodiment 8: a kind of nylon spinning oil, difference from example 1 is that, lubricating oil in esters includes following matter
Measure the component of percentage:
Dodecylphosphoric acid monoesters 60%；
Polyalphaolefin 20%；
Tricarboxymethyl propane oleate complements to 100%.
Embodiment 9: a kind of nylon spinning oil, difference from example 1 is that, non-ionic surfactant includes
The component of following mass percent:
Laruyl alcohol 30%；
Fatty acid methyl ester ethoxylate 3%；
Sorbitan ester complements to 100%.
Embodiment 10: a kind of nylon spinning oil, difference from example 1 is that, non-ionic surfactant packet
Include the component of following mass percent:
Laruyl alcohol 40%；
Fatty acid methyl ester ethoxylate 1%；
Sorbitan ester complements to 100%.
Embodiment 11: a kind of nylon spinning oil, difference from example 1 is that, teepol is
Neopelex.
Embodiment 12: a kind of nylon spinning oil, difference from example 1 is that, teepol is
Mass ratio is the neopelex of 1:1 and the mixture of Aerosol OT.
Embodiment 13: a kind of nylon spinning oil, difference from example 1 is that, antistatic agent is glyceryl stearate
Acid esters.
Embodiment 14: a kind of nylon spinning oil, difference from example 1 is that, antistatic agent is that mass ratio is
The stearine of 1:1 and the mixture of lauroylamidopropyl betaine.
Embodiment 15: a kind of nylon spinning oil, difference from example 1 is that, antioxidant is four (β-(3,5-
Di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.
Embodiment 16: a kind of nylon spinning oil, difference from example 1 is that, antioxidant is that mass ratio is 1:1
Four (β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol esters and 4,4 ' methylene bis (2,6- DI-tert-butylphenol compounds)
Mixture.
A kind of embodiment 17: preparation method of nylon spinning oil, comprising the following steps:
Step 1 takes conductivity in 1us/cm ultrapure water below, is added in container, and the temperature for controlling ultrapure water is 32 DEG C；
Step 2, each component of basic finish is uniformly mixed, and basic finish is slowly added into container, is uniformly mixed,
The speed of basic finish is 12L/min, and mixing speed is in 20rpm hereinafter, obtaining finish solution；
The component of auxiliary agent is uniformly mixed by step 3, is slowly added to auxiliary agent into finish solution, is uniformly mixed, standing disappears
Bubble removing；
Step 4 is filtered to remove impurity by 120 mesh stainless steel wave schlieren filter devices, obtains nylon spinning oil.
A kind of embodiment 18: preparation method of nylon spinning oil, comprising the following steps:
Step 1 takes conductivity in 1us/cm ultrapure water below, is added in container, and the temperature for controlling ultrapure water is 33 DEG C；
Step 2, each component of basic finish is uniformly mixed, and basic finish is slowly added into container, is uniformly mixed,
The speed of basic finish is 15L/min, and mixing speed is in 20rpm hereinafter, obtaining finish solution；
The component of auxiliary agent is uniformly mixed by step 3, is slowly added to auxiliary agent into finish solution, is uniformly mixed, standing disappears
Bubble removing；
Step 4 is filtered to remove impurity by 120 mesh stainless steel wave schlieren filter devices, obtains nylon spinning oil.
Comparative example 1: a kind of nylon spinning oil, difference from example 1 is that, auxiliary agent is only with alkyl phosphate
Amine salt.
Comparative example 2: a kind of nylon spinning oil, difference from example 1 is that, auxiliary agent is only with polyoxyethylene alkane
Base ether.
Comparative example 3: a kind of nylon spinning oil, difference from example 1 is that, it is not added with auxiliary agent.
Comparative example 4: using common commercially available polyethers nylon spinning oil.
Performance test
Test method: the spinning oil in embodiment 1-18 and comparative example 1-4 is sent to the ceramic nozzle tip passed through to Tynex, note
Record the silk that floats, broken end, greasy dirt and the white powder phenomenon in Tynex production process.
Float silk: the individuals fibers of Tynex, which are broken, to be generated；Broken end: Tynex is broken in coiling；Greasy dirt: it is stained with
The weight of the Tynex of greasy dirt accounts for the ratio of total output；White powder: white powder is stained on ceramic nozzle tip.
Test result: test result is as shown in table 1.As shown in Table 1, compared with commercially available spinning oil, using the present invention
Finish solution and auxiliary agent after, thread number decline of floaing, broken end number decline, the weight for being stained with the Tynex of greasy dirt accounts for total yield
The ratio of amount declines；From oil nozzle white powder, white powder can obviously reduce using spinning oil of the invention or elimination white powder is existing
As.
1 test result of table
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment,
All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of nylon spinning oil, which is characterized in that including finish solution and auxiliary agent, the quality of the finish solution and auxiliary agent
Than for 100:(2.5-4.5), the finish solution includes basic finish and ultrapure water, and the basis finish includes following quality hundred
Divide the component of ratio:
Lubricating oil in esters 63-67%；
Non-ionic surfactant 10-14%；
Teepol 14-16%；
Antistatic agent 4-6%；
Antioxidant 2-4%；
The auxiliary agent includes the component of following mass percent:
Amine salt of alkyl phosphate 52-57%；
Polyoxyethylene alkyl ether 43-48%.
2. a kind of nylon spinning oil according to claim 1, which is characterized in that basic finish in the finish solution
Mass percent is 8-13%.
3. a kind of nylon spinning oil according to claim 1, which is characterized in that the lubricating oil in esters includes following matter
Measure the component of percentage:
Dodecylphosphoric acid monoesters 30-60%；
Polyalphaolefin 20-40%；
Tricarboxymethyl propane oleate complements to 100%.
4. a kind of nylon spinning oil according to claim 1, which is characterized in that the non-ionic surfactant includes
The component of following mass percent:
Laruyl alcohol 20-40%；
Fatty acid methyl ester ethoxylate 1-5%；
Sorbitan ester complements to 100%.
5. a kind of nylon spinning oil according to claim 1, which is characterized in that the teepol is selected from
At least one of sodium sulfate of polyethenoxy ether of fatty alcohol, neopelex, Aerosol OT.
6. a kind of nylon spinning oil according to claim 1, which is characterized in that the antistatic agent is selected from ethoxylation
At least one of alkylsurfuric acid ammonium, stearine, lauroylamidopropyl betaine.
7. the preparation method of nylon spinning oil according to claim 1, which is characterized in that the antioxidant is selected from 2,6-
Di-tert-butyl-4-methy phenol, four (β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol esters, 4,4 ' methylene bis
At least one of (2,6- DI-tert-butylphenol compounds).
8. a kind of preparation method of nylon spinning oil, which comprises the following steps:
Step 1 takes conductivity in 1us/cm ultrapure water below, is added in container；
Step 2, each component of basic finish is uniformly mixed, and basic finish is slowly added into container, is uniformly mixed,
Obtain finish solution；
The component of auxiliary agent is uniformly mixed by step 3, is slowly added to auxiliary agent into finish solution, is uniformly mixed, standing disappears
Bubble removing；
Step 4 is filtered to remove impurity, obtains nylon spinning oil.
9. the preparation method of nylon spinning oil according to claim 8, which is characterized in that the temperature of the ultrapure water is
30-33℃。
10. the preparation method of nylon spinning oil according to claim 8, which is characterized in that be added in the step 2
The speed of basic finish is 10-15L/min, and mixing speed is in 20rpm or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910029903.5A CN109763335B (en) | 2019-01-12 | 2019-01-12 | Nylon spinning oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910029903.5A CN109763335B (en) | 2019-01-12 | 2019-01-12 | Nylon spinning oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109763335A true CN109763335A (en) | 2019-05-17 |
| CN109763335B CN109763335B (en) | 2021-03-02 |
Family
ID=66453920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910029903.5A Active CN109763335B (en) | 2019-01-12 | 2019-01-12 | Nylon spinning oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109763335B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110747538A (en) * | 2019-11-20 | 2020-02-04 | 杭州锦尔迪科技有限公司 | Preparation method of antioxidant antistatic ATY oil |
| WO2021014662A1 (en) * | 2019-07-24 | 2021-01-28 | 竹本油脂株式会社 | Treatment agent for synthetic fibers, and synthetic fibers |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158295A (en) * | 1981-03-25 | 1982-09-30 | Teijin Ltd | Spinning lubricant for synthetic fiber |
| JPH07252727A (en) * | 1994-03-11 | 1995-10-03 | Asahi Chem Ind Co Ltd | High speed-spun polyamide multifilament |
| CN1242451A (en) * | 1998-07-17 | 2000-01-26 | 张晏境 | Polyamide cord high speed spinning oil solution |
| CN101353860A (en) * | 2008-07-31 | 2009-01-28 | 苏州华绸科技有限公司 | Consolidation oil agent for producing core-spun yarn |
| CN101929069A (en) * | 2009-06-19 | 2010-12-29 | 朱寅 | Polyester oiling agent |
| CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN103451929A (en) * | 2013-08-20 | 2013-12-18 | 苏州晟德竹科技发展有限公司 | Polyarmide fiber oiling agent |
| CN106149375A (en) * | 2016-08-05 | 2016-11-23 | 苏州锦超服饰有限公司 | A kind of reduction frictional static fibre finishing |
| CN106930104A (en) * | 2017-03-01 | 2017-07-07 | 烟台锐泽化学品有限公司 | A kind of polyurethane fiber dry spinning oil agent without organosilicon and preparation method thereof |
| CN106939514A (en) * | 2017-04-25 | 2017-07-11 | 上海新浦特种助剂有限公司 | A kind of terylene FDY spinning oil |
| CN108252098A (en) * | 2017-12-18 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of polyester fiber spinning oil and preparation method thereof |
-
2019
- 2019-01-12 CN CN201910029903.5A patent/CN109763335B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158295A (en) * | 1981-03-25 | 1982-09-30 | Teijin Ltd | Spinning lubricant for synthetic fiber |
| JPH07252727A (en) * | 1994-03-11 | 1995-10-03 | Asahi Chem Ind Co Ltd | High speed-spun polyamide multifilament |
| CN1242451A (en) * | 1998-07-17 | 2000-01-26 | 张晏境 | Polyamide cord high speed spinning oil solution |
| CN101353860A (en) * | 2008-07-31 | 2009-01-28 | 苏州华绸科技有限公司 | Consolidation oil agent for producing core-spun yarn |
| CN101929069A (en) * | 2009-06-19 | 2010-12-29 | 朱寅 | Polyester oiling agent |
| CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
| CN103147168A (en) * | 2013-03-06 | 2013-06-12 | 常州市灵达化学品有限公司 | Spinning finish and preparation method thereof |
| CN103451929A (en) * | 2013-08-20 | 2013-12-18 | 苏州晟德竹科技发展有限公司 | Polyarmide fiber oiling agent |
| CN106149375A (en) * | 2016-08-05 | 2016-11-23 | 苏州锦超服饰有限公司 | A kind of reduction frictional static fibre finishing |
| CN106930104A (en) * | 2017-03-01 | 2017-07-07 | 烟台锐泽化学品有限公司 | A kind of polyurethane fiber dry spinning oil agent without organosilicon and preparation method thereof |
| CN106939514A (en) * | 2017-04-25 | 2017-07-11 | 上海新浦特种助剂有限公司 | A kind of terylene FDY spinning oil |
| CN108252098A (en) * | 2017-12-18 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of polyester fiber spinning oil and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021014662A1 (en) * | 2019-07-24 | 2021-01-28 | 竹本油脂株式会社 | Treatment agent for synthetic fibers, and synthetic fibers |
| JP2021021150A (en) * | 2019-07-24 | 2021-02-18 | 竹本油脂株式会社 | Synthetic fiber treatment agent and synthetic fiber |
| CN112543827A (en) * | 2019-07-24 | 2021-03-23 | 竹本油脂株式会社 | Treating agent for synthetic fiber and synthetic fiber |
| TWI796547B (en) * | 2019-07-24 | 2023-03-21 | 日商竹本油脂股份有限公司 | Treatment agent for synthetic fiber and synthetic fiber |
| CN110747538A (en) * | 2019-11-20 | 2020-02-04 | 杭州锦尔迪科技有限公司 | Preparation method of antioxidant antistatic ATY oil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109763335B (en) | 2021-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103981712B (en) | The anti-DTY finish and preparation method thereof that splashes of a kind of polyamide fibre | |
| JP5659597B2 (en) | Oil composition for carbon fiber precursor acrylic fiber, carbon fiber precursor acrylic fiber bundle and method for producing the same | |
| CN109763335A (en) | A kind of nylon spinning oil and preparation method thereof | |
| CN101849063A (en) | Oil agent composition for carbon fiber precursor acrylic fiber, carbon fiber precursor acrylic fiber bundle, and method for producing the same | |
| CN101235592A (en) | Terylene FDY nano spinning oil and preparation method thereof | |
| KR20130124581A (en) | Carbon-fiber-precursor acrylic fiber bundle with oil composition adhering thereto, process for producing same, oil composition for carbon-fiber-precursor acrylic fiber, and oil composition dispersion for carbon-fiber-precursor acrylic fiber | |
| CN105803766A (en) | Superfine filament spinning oil agent and preparation method | |
| JP2011099167A (en) | Oil agent composition for carbon fiber precursor acrylic fiber, carbon fiber precursor acrylic fiber bundle, and method for producing the same | |
| CN108624995A (en) | A kind of preparation method of polyamide spinning finisher | |
| CN108505342A (en) | It is a kind of continuously to spin viscose filament yarn finish and its preparation method and application | |
| KR100662775B1 (en) | Hydrophilic polypropylene staple fiber, method for preparing the same, and hydrophilic polypropylene spunlace nonwoven prepared therefrom | |
| JP4917991B2 (en) | Oil agent composition for carbon fiber precursor acrylic fiber | |
| US2803565A (en) | Processing of fibres | |
| CN110725025B (en) | Oiling agent for carbon fiber precursor | |
| CN105274846B (en) | Polypropylene fibre spin-drawing finish | |
| CN103437186A (en) | Preparation method of high-speed polyester POY (Pre-Oriented Yarn) spinning oil agent | |
| CN104562664A (en) | Environment-friendly acrylic spinning oil | |
| JPWO2009098845A1 (en) | Fiber treatment agent and method for producing synthetic fiber | |
| JP2018159138A (en) | Oil solution composition for carbon fiber precursor acrylic fiber, carbon fiber precursor acrylic fiber bundle, carbon fiber, and method for producing carbon fiber precursor acrylic fiber bundle and carbon fiber | |
| JP2688719B2 (en) | Oil agent for fiber processing | |
| CN102619084B (en) | Polypropylene spinning oil composition for cigarette and preparation method thereof | |
| CN114892405A (en) | Polyester-nylon composite oiling agent for FDY spinning | |
| JP2012251266A (en) | Carbon fiber precursor acrylic fiber bundle | |
| CN102277732B (en) | Treating agent for regenerative synthetic fibers and method thereof for treating regenerative synthetic fibers | |
| JPH1161646A (en) | Treating agent for synthetic fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |