CN109097170A - 一种环保型低油烟雾金属压造润滑剂 - Google Patents

一种环保型低油烟雾金属压造润滑剂 Download PDF

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CN109097170A
CN109097170A CN201811104374.2A CN201811104374A CN109097170A CN 109097170 A CN109097170 A CN 109097170A CN 201811104374 A CN201811104374 A CN 201811104374A CN 109097170 A CN109097170 A CN 109097170A
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黄馨卉
陈瑀瑄
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Jiaxing Shuncheng Fine Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/41—Chlorine free or low chlorine content compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/50—Emission or smoke controlling properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

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  • Chemical & Material Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种环保型低油烟雾金属压造润滑剂，所述润滑剂由重量组分磷酸酯季铵盐0.5‑1％、胺类抗氧化剂0.2‑0.5％、硫化烯烃2‑5％、三羫甲基丙烷油酸酯10‑13％、硫化脂肪酸脂1.5‑4％、T154分散剂0.5‑1％、聚异丁烯0.5‑1％、表面活性剂0.2‑0.5％、150#基础油38‑42％、68#基础油38‑42％配制而成。同时还公开了该环保型低油烟雾金属压造润滑剂的配制方法。本发明的环保型低油烟雾金属压造润滑剂，适用于成型各种碳钢管件、深孔件、套筒件且具有束杆形状的金属非标准件，成型时可吸附大量的热量，油不易汽化，减少油烟雾生成，达到加工现场减烟的目的。且不使用氯化石蜡，防止游离氯造成危害。

Description

一种环保型低油烟雾金属压造润滑剂
技术领域
本发明属于润滑剂技术领域，具体涉及一种环保型低油烟雾金属压造润滑剂。
背景技术
碳钢管件、深孔件、套筒件等具有束杆形状的金属非标准件在成型过程中需要使用润滑剂。由于成型过程中产生大量热量，传统润滑剂受高温影响会产生大量的油烟雾，影响加工车间的生产环境。同时，传统润滑剂中含有的氯化石蜡，受高温后会随着油烟雾产生有害的游离氯，严重危害车间工作人员的身体健康。
发明内容
为解决上述技术问题，本发明采用的技术方案是：
一种环保型低油烟雾金属压造润滑剂，所述润滑剂由重量组分磷酸酯季铵盐0.5-1％、胺类抗氧化剂0.2-0.5％、硫化烯烃2-5％、三羫甲基丙烷油酸酯10-13％、硫化脂肪酸脂1.5-4％、T154分散剂0.5-1％、聚异丁烯0.5-1％、表面活性剂0.2-0.5％、150#基础油38-42％、68#基础油38-42％配制而成。
润滑剂由重量组分磷酸酯季铵盐1％、胺类抗氧化剂0.5％、硫化烯烃2％、三羫甲基丙烷油酸酯10％、硫化脂肪酸脂2％、T154分散剂1％、聚异丁烯0.5％、表面活性剂0.5％、150#基础油42％、68#基础油40.5％配制而成。
一种环保型低油烟雾金属压造润滑剂的配制方法，包括以下步骤：
1)在搅拌槽内放入68#基础油、150#基础油，加热搅拌，温度大于40℃；
2)依次加入胺类抗氧化剂、硫化烯烃、三羫甲基丙烷油酸酯、硫化脂肪酸脂、T154分散剂、聚异丁烯，持续搅拌30分钟；
3)加入表面活性剂、磷酸酯季铵盐，将搅拌槽升温至50℃并搅拌30分钟以上即得低油烟雾金属压造润滑剂。
本发明中：磷酸酯季铵盐起到润滑的作用；胺类抗氧化剂起到抗氧化的作用；硫化烯烃起到挤压润滑的作用；三羫甲基丙烷油酸酯起到增溶润滑的作用；硫化脂肪酸脂起润滑、提高附着力的作用；T154分散剂起到分散的作用；聚异丁烯起到减烟、增稠的作用；表面活性剂起到消泡的作用；150#基础油和68#基础油作为溶剂，也起到润滑的作用。
本发明的有益效果是：本发明的环保型低油烟雾金属压造润滑剂，适用于成型各种碳钢管件、深孔件、套筒件且具有束杆形状的金属非标准件，成型时可吸附大量的热量，油不易汽化，减少油烟雾生成，达到加工现场减烟的目的。且不使用氯化石蜡，防止游离氯造成危害。
具体实施方式
实施例1
一种环保型低油烟雾金属压造润滑剂，所述润滑剂由重量组分磷酸酯季铵盐1％、胺类抗氧化剂0.5％、硫化烯烃2％、三羫甲基丙烷油酸酯10％、硫化脂肪酸脂2％、T154分散剂1％、聚异丁烯0.5％、表面活性剂0.5％、150#基础油42％、68#基础油40.5％配制而成。
实施例2
一种环保型低油烟雾金属压造润滑剂，所述润滑剂由重量组分磷酸酯季铵盐0.5％、胺类抗氧化剂0.5％、硫化烯烃5％、三羫甲基丙烷油酸酯13％、硫化脂肪酸脂3.3％、T154分散剂0.5％、聚异丁烯1％、表面活性剂0.2％、150#基础油38％、68#基础油38配制而成。
实施例3
一种环保型低油烟雾金属压造润滑剂的配制方法，按照实施例1称量各组分，再依次进行下述步骤：
1)在搅拌槽内放入68#基础油、150#基础油，加热搅拌，温度大于40℃；
2)依次加入胺类抗氧化剂、硫化烯烃、三羫甲基丙烷油酸酯、硫化脂肪酸脂、T154分散剂、聚异丁烯，持续搅拌30分钟；
3)加入表面活性剂、磷酸酯季铵盐，将搅拌槽升温至50℃并搅拌30分钟以上即得低油烟雾金属压造润滑剂。
以上详细描述了本发明的较佳具体实施例，应当理解，本领域的普通技术人员无需创造性劳动就可以根据本发明的构思做出诸多修改和变化，因此，凡本技术领域中技术人员依本发明的构思在现有技术的基础上通过逻辑分析、推理或者有限的实验可以得到的技术方案，皆应在由权利要求书所确定的保护范围内。

Claims (3)

1.一种环保型低油烟雾金属压造润滑剂，其特征在于，所述润滑剂由重量组分磷酸酯季铵盐0.5-1％、胺类抗氧化剂0.2-0.5％、硫化烯烃2-5％、三羫甲基丙烷油酸酯10-13％、硫化脂肪酸脂1.5-4％、T154分散剂0.5-1％、聚异丁烯0.5-1％、表面活性剂0.2-0.5％、150#基础油38-42％、68#基础油38-42％配制而成。
2.如权利要求1所述的环保型低油烟雾金属压造润滑剂，其特征在于，所述润滑剂由重量组分磷酸酯季铵盐1％、胺类抗氧化剂0.5％、硫化烯烃2％、三羫甲基丙烷油酸酯10％、硫化脂肪酸脂2％、T154分散剂1％、聚异丁烯0.5％、表面活性剂0.5％、150#基础油42％、68#基础油40.5％配制而成。
3.一种如权利要求1所述的环保型低油烟雾金属压造润滑剂的配制方法，其特征在于，包括以下步骤：
1)在搅拌槽内放入68#基础油、150#基础油，加热搅拌，温度大于40℃；
2)依次加入胺类抗氧化剂、硫化烯烃、三羫甲基丙烷油酸酯、硫化脂肪酸脂、T154分散剂、聚异丁烯，持续搅拌30分钟；
3)加入表面活性剂、磷酸酯季铵盐，将搅拌槽升温至50℃并搅拌30分钟以上即得低油烟雾金属压造润滑剂。
CN201811104374.2A 2018-09-21 2018-09-21 一种环保型低油烟雾金属压造润滑剂 Pending CN109097170A (zh)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110229711A (zh) * 2019-06-24 2019-09-13 湖北诚祥科技有限公司 适用于高光加工工艺的镜面级高精密金属加工油及其制备方法
CN110408461A (zh) * 2019-08-23 2019-11-05 广州市联诺化工科技有限公司 一种低烟雾长寿命环保型强缩成型油及其制备方法
CN111808664A (zh) * 2020-07-09 2020-10-23 嘉兴顺诚精细化工有限公司 一种植物脂肪高黏度不锈钢无氯成型剂及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110229711A (zh) * 2019-06-24 2019-09-13 湖北诚祥科技有限公司 适用于高光加工工艺的镜面级高精密金属加工油及其制备方法
CN110408461A (zh) * 2019-08-23 2019-11-05 广州市联诺化工科技有限公司 一种低烟雾长寿命环保型强缩成型油及其制备方法
CN110408461B (zh) * 2019-08-23 2021-09-24 广州市联诺化工科技有限公司 一种低烟雾长寿命环保型强缩成型油及其制备方法
CN111808664A (zh) * 2020-07-09 2020-10-23 嘉兴顺诚精细化工有限公司 一种植物脂肪高黏度不锈钢无氯成型剂及其制备方法
CN111808664B (zh) * 2020-07-09 2022-08-16 嘉兴顺诚精细化工有限公司 一种植物脂肪高黏度不锈钢无氯成型剂及其制备方法

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