CN108651482A - A kind of composition pesticide containing bronopol and benziothiazolinone - Google Patents
A kind of composition pesticide containing bronopol and benziothiazolinone Download PDFInfo
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- CN108651482A CN108651482A CN201810423261.2A CN201810423261A CN108651482A CN 108651482 A CN108651482 A CN 108651482A CN 201810423261 A CN201810423261 A CN 201810423261A CN 108651482 A CN108651482 A CN 108651482A
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- bronopol
- benziothiazolinone
- composition pesticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing bronopol and benziothiazolinone, effective active composition are made of bronopol and benziothiazolinone, and the weight part ratio of bronopol and benziothiazolinone in composition pesticide is 30:1~1:10.The composition pesticide of the present invention is used to prevent the bacterial diseases such as bacterial wilt, bacterial angular leaf spot, canker and the soft rot on crops, and excellent, the lasting period is long, to Crop securify.There is significant synergistic function after bronopol and benziothiazolinone compounding, Pesticide use amount can be reduced, reduce use cost, mitigate the pollution to environment, delay the generation of pathogen drug resistance, increase the Pesticide use service life.
Description
Technical field
The present invention relates to pesticide complex composition and its application fields, are specifically effective with bronopol and benziothiazolinone
The binary complex of active constituent compounding, is mainly used in the prevention of bacterial disease on crops.
Background technology
Bronopol (bronopol) is mainly used for industrial circulating water, paper making pulp, coating, plastics, cosmetics, timber, cold
But the sterilizing, be mould proof of water circulation system and industrial use, anti-corrosion, algae removal etc., while it also has various plants pathogenetic bacteria
Good bactericidal effect.
Benziothiazolinone (benziothiazolinone) belongs to isothiazole heterocyclic compound, be it is a kind of efficiently, low toxicity, broad spectrum activity kill
Microbial inoculum, mechanism of action are：It is reacted with the anion binding of the cell membrane surface of bacterium, mould or with sulfydryl, destroys protein
Pathogen cell metabolism is interfered, its physiologic derangement is made to inhibit bacterium, mould breeding with the synthesis system of cell membrane,
Cause pathogen dead.The compound is to rot disease, canker, anthracnose, scab, leaf spot, the downy mildew on crops
Etc. diseases have good control effect, and it is fool proof to crops.
The long-time of pesticide single variety is used continuously, and easy tos produce resistance risk and dosage increases risk, and then increase
Cost and carrying capacity of environment, and the compounded combination of notable synergistic function is provided by the compound screening of different pesticide species
Object can not only reduce Pesticide use amount, reduce use cost, reduce resistance risk, moreover it is possible to reduce potential environmental risk, increase
The Pesticide use service life.
The present inventor is furtheing investigate bronopol and during benziothiazolinone compounded formula, surprisingly bronopol
It is compounded with benziothiazolinone, to the bacterial blight of rice on crops, paddy bacterial item within the scope of certain compound proportion
Pinta, Characters of Erwinia chrysanthemi pv. zeae, paddy bacterial brown spot, corn bacterial stem rot, soft rot of Chinese cabbage, the soft corruption of green vegetables
Disease, wild cabbage soft rot, radish soft rot, cauliflower soft rot, celery soft rot, romaine lettuce soft rot, taro soft rot, ginger rot,
Cabbage black rot, radish black rot, cauliflower black rot, bacterial wilt of tomato, eggplant bacterial wilt, pepper ralstonia solanacearum, potato blueness are withered
Disease, bacterial spot of tomato, bacterial blight of soybean, cucumber bacterial angular leaf spot, watermelon bacterial angular leaf spot, sponge gourd are thin
Bacterium property angular leaf spot, cucumber Bacterial Leaf Blight, watermelon Bacterial Leaf Blight, bacterial fruit blotch of watermelon, muskmelon bacterial fruit blotch
Disease, common bacterial blight of bean, bacterial spot of pepper, Apple crown gall, peach crown gall, pear tree crown gall, Lee
Crown gall, persimmon crown gall, citrus bacterial canker disease, fire blight of pear, peach bacterial shot hole, wildfire, cigarette
The bacterial diseases such as careless bacterial wilt have synergistic function, especially to bacterial wilt, bacterial angular leaf spot, canker and soft corruption
The synergistic function of disease is more notable, after further study, completes the present invention.
Invention content
The purpose of the present invention is to provide a kind of component is reasonable, obvious synergy, bactericidal effect be outstanding, the lasting period
It is long, drug cost is low, pathogen can be delayed to develop immunity to drugs, and to a kind of containing bronopol and benziothiazolinone of Crop securify
Composition pesticide.
Another object of the present invention is to provide the purposes of above-mentioned composition pesticide bacterial disease on prevention crops.
The bacterial disease is that bacterial blight of rice, bacterial leaf streak of rice, Characters of Erwinia chrysanthemi pv. zeae, rice are thin
Bacterium property brown spot, corn bacterial stem rot, soft rot of Chinese cabbage, green vegetables soft rot, wild cabbage soft rot, radish soft rot, flower coconut palm
Dish soft rot, celery soft rot, romaine lettuce soft rot, taro soft rot, ginger rot, cabbage black rot, radish black rot, cauliflower
Black rot, bacterial wilt of tomato, eggplant bacterial wilt, pepper ralstonia solanacearum, potato bacterial wilt, bacterial spot of tomato, soybean are thin
Bacterium property spot disease, cucumber bacterial angular leaf spot, watermelon bacterial angular leaf spot, sponge gourd bacterial angular leaf spot, the bacillary leaf of cucumber are withered
Disease, watermelon Bacterial Leaf Blight, bacterial fruit blotch of watermelon, muskmelon Acidovorax Avenae Subsp. Citrulli, common bacterial blight of bean, capsicum scab
Disease, Apple crown gall, peach crown gall, pear tree crown gall, Lee's crown gall, the bacillary crown gall of persimmon
Disease, citrus bacterial canker disease, fire blight of pear, peach bacterial shot hole, wildfire, tobacco bacterial wilt etc..
Technical scheme of the present invention：To achieve the above object, the present invention provides a kind of agriculture containing bronopol and benziothiazolinone
Drug composition, effective active composition are made of bronopol and benziothiazolinone, the weight of bronopol and benziothiazolinone in composition pesticide
Portion rate is 30:1~1:10, the weight percent of bronopol and benziothiazolinone weight summation in composition pesticide is 0.1%-
85%, remaining is that can receive and allow the auxiliary element used on pesticide.
Further, bronopol and the preferred weight portion rate of benziothiazolinone are 15:1~1:1, most preferably weight part ratio is 5:
1。
Composition pesticide of the present invention can be prepared into the arbitrary dosage form used in suitable agricultural production, and relatively good dosage form has
Suspending agent, aqueous emulsion, microemulsion, water dispersible granules etc..
Further include in pesticide other than effective active composition when various application forms prepared by composition pesticide of the present invention
Allow to use and the various auxiliary elements of acceptable.
The auxiliary element includes but not limited to solvent, emulsifier, wetting agent, dispersant, stabilizer, antifreezing agent, increasing
Thick dose, antifoaming agent, synergist, preservative and filler etc., be all to commonly use in pesticidal preparations or allow the ingredient used, have no especially
It limits, specific ingredient and dosage are according to the recipe requirements determined by the test.
The production technology of the various application forms of the composition pesticide belongs to existing known technology, and details are not described herein.
Compared with the prior art, the advantages of the present invention are as follows：
1, bronopol and benziothiazolinone compounding have significant synergistic function, are significantly improved compared with single dose exclusive use
To the control effect of bacterial disease on crops.
2, bronopol and benziothiazolinone two kinds of active components compounding, reduce Pesticide use amount, reduce use cost, mitigate
Pollution to environment.
3, bronopol and benziothiazolinone two kinds of active components compounding, the mechanism of action is different, and action site increases, and delays
The generation of pathogen drug resistance increases the service life of pesticide.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of that invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
Embodiment one
Following substance is weight percentage：Bronopol 20%, benziothiazolinone 4%, double naphthalenesulfonate formaldehyde condensation compounds
5%, alkyl phenol formaldehyde resin polyoxyethylene ether 3%, xanthans 1%, sodium benzoate 0.5%, silicone compound 0.5%, third
Triol 3%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, is uniformly dispersed through high speed shear, sand in sand mill
After mill, you can 24% bronopol benziothiazolinone suspending agent is made.
Using above-mentioned 24% bronopol benziothiazolinone suspending agent for preventing cucumber bacterial angular leaf spot：24% bronopol
Benziothiazolinone suspending agent carries out first time dispenser by 30g a.i./ha dosages in cucumber bacterial angular leaf spot early period of origination, and 7d is laggard
Second of dispenser of row, 14d is 93.46% to the preventive effect of cucumber bacterial angular leaf spot after second of dispenser；20% bronopol is outstanding
Floating agent carries out first time dispenser by 30g a.i./ha dosages in cucumber bacterial angular leaf spot early stage, is carried out after 7d second
Dispenser, 14d is 41.69% to the preventive effect of cucumber bacterial angular leaf spot after second of dispenser；4% benziothiazolinone suspending agent presses 30g
A.i./ha dosages carry out first time dispenser in cucumber bacterial angular leaf spot early stage, second of dispenser are carried out after 7d, second
14d is 63.75% to the preventive effect of cucumber bacterial angular leaf spot after secondary dispenser.As it can be seen that being assisted after bronopol and benziothiazolinone binary built
Notable with synergistic effect, the lasting period is long, and the preventive effect of cucumber bacterial angular leaf spot is used alone significantly better than each single dose, meanwhile,
Do not find that 24% bronopol benziothiazolinone suspending agent generates poisoning to cucumber during the test.
Embodiment two
Following substance is weight percentage：Bronopol 30%, benziothiazolinone 2%, triphenoethyl benzene phenol polyethenoxy ether
Phosphate 10%, sec-Butyl Acetate 10%, the solvent naphtha (trade mark：S-150) 8%, butylated hydroxy anisole 3%, ethylene glycol 2%,
Organobentonite 1%, C10-20Saturated fat acids compound 0.2%, sodium benzoate 0.3%, deionized water supplies 100%.It will
Above-mentioned material mixes in proportion, after high shear agitation is uniform, you can 32% bronopol benziothiazolinone aqueous emulsion is made.
Control of plant bacterial wilt is used for using above-mentioned 32% bronopol benziothiazolinone aqueous emulsion：32% bronopol benziothiazolinone
Aqueous emulsion carries out first time dispenser by 30g a.i./ha dosages in bacterial wilt of tomato early period of origination, and second of dispenser is carried out after 7d,
14d is 86.77% to the preventive effect of bacterial wilt of tomato after second of dispenser；30% bronopol aqueous emulsion is used by 30g a.i./ha
Amount carries out first time dispenser in bacterial wilt of tomato early stage, carries out second of dispenser after 7d, after second of dispenser 14d to kind
The preventive effect of bacterial wilt of eggplant is 45.96%；2% benziothiazolinone aqueous emulsion presses 30g
A.i./ha dosages carry out first time dispenser in bacterial wilt of tomato early stage, carry out second of dispenser after 7d, the
14d is 65.06% to the preventive effect of bacterial wilt of tomato after secondary dispenser.Increase as it can be seen that being cooperateed with after bronopol and benziothiazolinone binary built
Effect effect is notable, and the lasting period is long, and the preventive effect of bacterial wilt of tomato is used alone significantly better than each single dose, meanwhile, in experiment process
In do not find 32% bronopol benziothiazolinone aqueous emulsion to tomato generate poisoning.
Embodiment three
Following substance is weight percentage：Bronopol 20%, benziothiazolinone 20%, calcium dodecyl benzene sulfonate 3%, benzene
Ethyl -phenol polyoxyethylene poly-oxygen propylene aether 7%, isopropanol 3%, sec-Butyl Acetate 10%, the solvent naphtha (trade mark：S-180) 5%,
Glycerine 3%, C10-20Saturated fat acids compound 0.2%, triphenyl phosphite 3%, deionized water supplies 100%.It will be upper
It states material to mix in proportion, after high shear agitation is uniform, you can 40% bronopol benziothiazolinone microemulsion is made.
Using above-mentioned 40% bronopol benziothiazolinone microemulsion for preventing soft rot of Chinese cabbage：40% bronopol thiophene is mould
Ketone microemulsion carries out first time dispenser by 30g a.i./ha dosages in soft rot of Chinese cabbage early period of origination, is carried out after 7d second
Dispenser, 14d is 90.63% to the preventive effect of soft rot of Chinese cabbage after second of dispenser；20% bronopol water microemulsion presses 30g
A.i./ha dosages carry out first time dispenser at soft rot of Chinese cabbage initial stage, second of dispenser are carried out after 7d, after second of dispenser
14d is 41.53% to the preventive effect of soft rot of Chinese cabbage；20% benziothiazolinone microemulsion is soft in Chinese cabbage by 30g a.i./ha dosages
Maize ear rot initial stage carries out first time dispenser, carries out second of dispenser after 7d, 14d prevents soft rot of Chinese cabbage after second of dispenser
Effect is 69.33%.As it can be seen that obvious synergy after bronopol and benziothiazolinone binary built, the lasting period is long, soft to Chinese cabbage
The preventive effect of maize ear rot is used alone significantly better than each single dose, meanwhile, do not find that 40% bronopol benziothiazolinone is micro- during the test
Emulsion generates poisoning to Chinese cabbage.
Example IV
Following substance is weight percentage：Bronopol 50%, benziothiazolinone 5%, polyoxyethylene polyoxypropylene base ether are embedding
Section copolymer 1 0%, Nonyl pheno base ether 5%, ammonium sulfate 10%, attapulgite supplies 100%.Above-mentioned material is pressed
Ratio mixes, and is uniformly mixed through air-flow crushing, kneading is granulated, after dry screening, you can 55% bronopol benziothiazolinone water is made
Dispersible granule.
Using above-mentioned 55% bronopol benziothiazolinone water dispersion granule for preventing citrus bacterial canker disease：55% bronopol thiophene
Mould ketone water dispersible granules carry out first time dispenser by 20mg a.i./kg dosages in citrus bacterial canker disease early period of origination, and the is carried out after 7d
Secondary dispenser, 14d is 88.07% to the preventive effect of citrus bacterial canker disease after second of dispenser；50% bronopol water dispersible granules are pressed
20mga.i./kg dosages carry out first time dispenser in citrus bacterial canker disease early stage, and second of dispenser is carried out after 7d, at second
14d is 47.96% to the preventive effect of citrus bacterial canker disease after dispenser；5% benziothiazolinone water dispersion granule exists by 20mg a.i./kg dosages
Citrus bacterial canker disease early stage carries out first time dispenser, and second of dispenser is carried out after 7d, and 14d bursts to citrus after second of dispenser
The preventive effect of ulcer disease is 68.36%.As it can be seen that obvious synergy after bronopol and benziothiazolinone binary built, the lasting period is long, right
The preventive effect of citrus bacterial canker disease is used alone significantly better than each single dose, meanwhile, do not find 55% bronopol thiophene during the test
Mould ketone water dispersible granules generate poisoning to citrus.
Embodiment five：Bronopol and benziothiazolinone compound the indoor toxicity determination test to cucumber bacterial angular leaf spot pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.16-2008》, using turbidity method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
1 bronopol of table and benziothiazolinone compound the The Toxicity Determination result to cucumber bacterial angular leaf spot pathogen
| Medicament title and proportioning (weight ratio) | EC50(mg/L) | ATI | TTI | CTC |
| Bronopol | 3.02 | 100.00 | ||
| Benziothiazolinone | 1.56 | 193.59 | ||
| Bronopol：Benziothiazolinone (40:1) | 2.61 | 115.71 | 102.28 | 113.13 |
| Bronopol：Benziothiazolinone (30:1) | 1.95 | 154.87 | 103.02 | 150.33 |
| Bronopol：Benziothiazolinone (20:1) | 1.57 | 192.36 | 104.46 | 184.15 |
| Bronopol：Benziothiazolinone (15:1) | 1.23 | 245.53 | 105.85 | 231.96 |
| Bronopol：Benziothiazolinone (10:1) | 1.04 | 290.38 | 108.51 | 267.61 |
| Bronopol：Benziothiazolinone (5:1) | 0.88 | 343.18 | 115.60 | 296.87 |
| Bronopol：Benziothiazolinone (1:1) | 0.97 | 311.34 | 146.80 | 212.08 |
| Bronopol：Benziothiazolinone (1:5) | 1.01 | 299.01 | 177.99 | 167.99 |
| Bronopol：Benziothiazolinone (1:10) | 1.13 | 267.26 | 185.08 | 144.40 |
| Bronopol：Benziothiazolinone (1:15) | 1.46 | 206.85 | 187.74 | 110.18 |
As it can be seen from table 1 bronopol and benziothiazolinone are 30:1~1:When being compounded in the range of 10 (by weight), poison is altogether
Number (CTC) is all higher than 120, illustrates to show synergistic function to cucumber bacterial angular leaf spot pathogen；Bronopol and thiophene are mould
Ketone is 15:1~1:When being compounded in the range of 1 (by weight), synergistic function is more notable, and co-toxicity coefficient (CTC) is 200
More than.As it can be seen that bronopol and benziothiazolinone compounding have reasonability and feasibility.
Embodiment six：Bronopol and benziothiazolinone compound the indoor toxicity determination test to tomato bacterial wilt pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.16-2008》, using turbidity method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
2 bronopol of table and benziothiazolinone compound the The Toxicity Determination result to tomato bacterial wilt pathogen
| Medicament title and proportioning (weight ratio) | EC50(mg/L) | ATI | TTI | CTC |
| Bronopol | 3.87 | 100.00 | ||
| Benziothiazolinone | 1.39 | 278.42 | ||
| Bronopol：Benziothiazolinone (40:1) | 3.17 | 122.08 | 104.35 | 116.99 |
| Bronopol：Benziothiazolinone (30:1) | 2.44 | 158.61 | 105.76 | 149.97 |
| Bronopol：Benziothiazolinone (20:1) | 1.86 | 208.06 | 108.50 | 191.76 |
| Bronopol：Benziothiazolinone (15:1) | 1.42 | 272.54 | 111.15 | 245.20 |
| Bronopol：Benziothiazolinone (10:1) | 1.26 | 307.14 | 116.22 | 264.27 |
| Bronopol：Benziothiazolinone (5:1) | 1.03 | 375.73 | 129.74 | 289.60 |
| Bronopol：Benziothiazolinone (1:1) | 0.87 | 444.83 | 189.21 | 235.10 |
| Bronopol：Benziothiazolinone (1:5) | 0.93 | 416.13 | 248.68 | 167.34 |
| Bronopol：Benziothiazolinone (1:10) | 1.11 | 348.65 | 262.20 | 132.97 |
| Bronopol：Benziothiazolinone (1:15) | 1.39 | 278.42 | 267.27 | 104.17 |
From table 2 it can be seen that bronopol and benziothiazolinone are 30:1~1:When being compounded in the range of 10 (by weight), poison is altogether
Number (CTC) is all higher than 120, illustrates to show synergistic function to tomato bacterial wilt pathogen；Bronopol and benziothiazolinone are 15:
1~1:When being compounded in the range of 1 (by weight), synergistic function is more notable, and co-toxicity coefficient (CTC) is 200 or more.It can
See, bronopol and benziothiazolinone compounding have reasonability and feasibility.
In conclusion a kind of composition pesticide containing bronopol and benziothiazolinone of the present invention, synergistic function
Significantly, each single dose is compared to be used alone, preventive effect significantly improves, can effectively prevent bacterial wilt on crops, bacterial angular leaf spot,
The bacterial diseases such as canker and soft rot, the lasting period is long, to Crop securify, is worth promoting and applying in agricultural production.
Claims (7)
1. a kind of composition pesticide containing bronopol and benziothiazolinone, it is characterised in that：Effective active composition is by bronopol and thiophene
Mould ketone composition, the weight part ratio of bronopol and benziothiazolinone in composition pesticide are 30:1~1:10, bronopol and benziothiazolinone
Weight percent of the weight summation in composition pesticide is 0.1%-85%.
2. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 1, it is characterised in that：Bronopol
It is 15 with weight part ratio of the benziothiazolinone in composition pesticide:1~1:1.
3. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 1, it is characterised in that：Bronopol
It is 5 with weight part ratio of the benziothiazolinone in composition pesticide:1.
4. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 1, it is characterised in that：Its agent
Type is one kind in suspending agent, aqueous emulsion, microemulsion, water dispersible granules.
5. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 1, it is characterised in that：The agriculture
When suspending agent is made in drug composition, each component weight percent is：Bronopol 20%, benziothiazolinone 4%, the contracting of double naphthalene sulphonate formaldehydes
Close object 5%, alkyl phenol formaldehyde resin polyoxyethylene ether 3%, xanthans 1%, sodium benzoate 0.5%, silicone compound
0.5%, glycerine 3%, deionized water supply 100%.
6. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 1 is for preventing crops
The purposes of bacterial disease.
7. a kind of composition pesticide containing bronopol and benziothiazolinone according to claim 6, it is characterised in that：Described
Bacterial disease is bacterial wilt, bacterial angular leaf spot, canker and soft rot.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114868746A (en) * | 2022-04-01 | 2022-08-09 | 顺毅股份有限公司 | Bactericidal composition containing bronopol of alkaloid and alkaloid analogue |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103619174A (en) * | 2011-05-13 | 2014-03-05 | Isp投资公司 | Aqueous solutions of 1,2-benzisothiazolin-3-one |
| CN107736357A (en) * | 2017-11-13 | 2018-02-27 | 江苏艾津农化有限责任公司 | A kind of agricultural chemicals suspension agent anticorrosive composite and its application method |
-
2018
- 2018-05-05 CN CN201810423261.2A patent/CN108651482A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103619174A (en) * | 2011-05-13 | 2014-03-05 | Isp投资公司 | Aqueous solutions of 1,2-benzisothiazolin-3-one |
| CN107736357A (en) * | 2017-11-13 | 2018-02-27 | 江苏艾津农化有限责任公司 | A kind of agricultural chemicals suspension agent anticorrosive composite and its application method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114868746A (en) * | 2022-04-01 | 2022-08-09 | 顺毅股份有限公司 | Bactericidal composition containing bronopol of alkaloid and alkaloid analogue |
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Application publication date: 20181016 |