CN108467968B - 一种铅蓄电池板栅合金的制备方法 - Google Patents
一种铅蓄电池板栅合金的制备方法 Download PDFInfo
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- CN108467968B CN108467968B CN201810116166.8A CN201810116166A CN108467968B CN 108467968 B CN108467968 B CN 108467968B CN 201810116166 A CN201810116166 A CN 201810116166A CN 108467968 B CN108467968 B CN 108467968B
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- alloy
- lead
- preparation
- aluminium
- lanthanum
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- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- 239000001999 grid alloy Substances 0.000 title claims abstract description 27
- 238000003860 storage Methods 0.000 title claims abstract description 22
- 239000000956 alloy Substances 0.000 claims abstract description 118
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 117
- -1 aluminium-lanthanum-cerium Chemical compound 0.000 claims abstract description 36
- 229910001122 Mischmetal Inorganic materials 0.000 claims abstract description 28
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 28
- 239000011575 calcium Substances 0.000 claims abstract description 23
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 22
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- 229910052718 tin Inorganic materials 0.000 claims abstract description 21
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011135 tin Substances 0.000 claims abstract description 18
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims description 46
- 238000002844 melting Methods 0.000 claims description 26
- 230000008018 melting Effects 0.000 claims description 26
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- 229910052684 Cerium Inorganic materials 0.000 claims description 20
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910052746 lanthanum Inorganic materials 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 238000005266 casting Methods 0.000 claims description 16
- 239000003792 electrolyte Substances 0.000 claims description 15
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 15
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 15
- 239000004411 aluminium Substances 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 8
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 6
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 6
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 238000003723 Smelting Methods 0.000 claims description 2
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 2
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 claims description 2
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 claims description 2
- 229910000967 As alloy Inorganic materials 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 38
- 150000002910 rare earth metals Chemical class 0.000 abstract description 23
- 239000000126 substance Substances 0.000 abstract description 9
- 239000012535 impurity Substances 0.000 abstract description 8
- 239000004615 ingredient Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010931 gold Substances 0.000 abstract description 3
- 229910052737 gold Inorganic materials 0.000 abstract description 3
- 238000004886 process control Methods 0.000 abstract description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 24
- 238000012360 testing method Methods 0.000 description 16
- 238000004458 analytical method Methods 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002893 slag Substances 0.000 description 11
- 239000013078 crystal Substances 0.000 description 10
- 239000002184 metal Substances 0.000 description 9
- 238000005275 alloying Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 229910018540 Si C Inorganic materials 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 5
- 241000251468 Actinopterygii Species 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910002975 Cd Pb Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910020187 CeF3 Inorganic materials 0.000 description 3
- 229910001128 Sn alloy Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 229910052747 lanthanoid Inorganic materials 0.000 description 3
- 150000002602 lanthanoids Chemical class 0.000 description 3
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- 208000032953 Device battery issue Diseases 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000013475 authorization Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- 229910000612 Sm alloy Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- UZQSJWBBQOJUOT-UHFFFAOYSA-N alumane;lanthanum Chemical compound [AlH3].[La] UZQSJWBBQOJUOT-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- DPDORTBBLUCNJG-UHFFFAOYSA-N calcium tin Chemical compound [Ca].[Sn] DPDORTBBLUCNJG-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000002142 lead-calcium alloy Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000002706 plastid Anatomy 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C11/00—Alloys based on lead
- C22C11/06—Alloys based on lead with tin as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/36—Alloys obtained by cathodic reduction of all their ions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/68—Selection of materials for use in lead-acid accumulators
- H01M4/685—Lead alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/73—Grids for lead-acid accumulators, e.g. frame plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
La | Ce | Al | Fe | Si | C | Cu | Ag | Sb |
39.2 | 37.1 | 22.3 | 0.08 | 0.02 | 0.01 | 0.002 | 0.0004 | 0.001 |
La | Ce | Al | Fe | Si | C | Cu | Ag | Sb |
49.8 | 36.2 | 12.5 | 0.06 | 0.02 | 0.02 | 0.001 | 0.0003 | 0.001 |
La | Ce | Al | Fe | Si | C | Cu | Ag | Sb |
28.1 | 27.3 | 43.1 | 0.07 | 0.01 | 0.02 | 0.002 | 0.0005 | 0.001 |
La | Ce | Al | Na | Fe | Si | C |
3.38 | 3.29 | 1.76 | 3.44 | 0.008 | 0.002 | 0.001 |
Cu | Ag | Bi | Zn | Sb | Pb | - |
0.0002 | 0.0003 | 0.003 | 0.0003 | 0.0008 | 余量 | - |
La | Ce | Al | Na | Fe | Si | C |
4.96 | 3.68 | 1.23 | 4.88 | 0.006 | 0.002 | 0.002 |
Cu | Ag | Bi | Zn | Sb | Pb | - |
0.0003 | 0.0004 | 0.002 | 0.0003 | 0.0007 | 余量 | - |
Sn | Ca | La | Ce | Al | Na | Bi | Cu |
1.92 | 0.055 | 0.032 | 0.032 | 0.015 | 0.033 | 0.005 | 0.001 |
As | Ag | Zn | Ni | Sb | Fe | Cd | Pb |
0.001 | 0.005 | 0.0005 | 0.0002 | 0.001 | 0.0005 | 0.0002 | 余量 |
Sn | Ca | La | Ce | Al | Na | Bi | Cu |
1.53 | 0.073 | 0.048 | 0.036 | 0.011 | 0.046 | 0.005 | 0.001 |
As | Ag | Zn | Ni | Sb | Fe | Cd | Pb |
0.001 | 0.005 | 0.0005 | 0.0002 | 0.001 | 0.0005 | 0.0002 | 余量 |
Sn | Ca | La | Ce | Al | Na | Bi | Cu |
1.13 | 0.092 | 0.022 | 0.021 | 0.036 | 0.021 | 0.005 | 0.001 |
As | Ag | Zn | Ni | Sb | Fe | Cd | Pb |
0.001 | 0.005 | 0.0005 | 0.0002 | 0.001 | 0.0005 | 0.0002 | 余量 |
Sn | Ca | La | Ce | Al | Na | Bi | Cu |
1.223 | 0.076 | 0.026 | 0.027 | 0.025 | 0.032 | 0.004 | 0.001 |
As | Ag | Zn | Ni | Sb | Fe | Cd | Pb |
0.001 | 0.005 | 0.0005 | 0.0002 | 0.001 | 0.0005 | 0.0002 | 余量 |
合金 | 初始高度/mm | 循环后高度/mm | 高度增长量/mm | 高度变化率 |
对比例1 | 136.12 | 137.58 | 1.46 | 1.07% |
对比例2 | 136.15 | 137.46 | 1.31 | 0.96% |
实施例7 | 136.13 | 136.76 | 0.63 | 0.46% |
Claims (10)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810116166.8A CN108467968B (zh) | 2018-02-06 | 2018-02-06 | 一种铅蓄电池板栅合金的制备方法 |
DE112018007020.4T DE112018007020T5 (de) | 2018-02-06 | 2018-10-26 | Verfahren für die herstellung einer gitterlegierung einer bleibatterie |
PCT/CN2018/112133 WO2019153795A1 (zh) | 2018-02-06 | 2018-10-26 | 一种铅蓄电池板栅合金的制备方法 |
BR112020015587-0A BR112020015587B1 (pt) | 2018-02-06 | 2018-10-26 | Método para preparar liga de grade de bateria de chumbo |
US16/965,770 US11851732B2 (en) | 2018-02-06 | 2018-10-26 | Method for preparing grid alloy of lead battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810116166.8A CN108467968B (zh) | 2018-02-06 | 2018-02-06 | 一种铅蓄电池板栅合金的制备方法 |
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CN108467968A CN108467968A (zh) | 2018-08-31 |
CN108467968B true CN108467968B (zh) | 2019-07-23 |
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CN201810116166.8A Active CN108467968B (zh) | 2018-02-06 | 2018-02-06 | 一种铅蓄电池板栅合金的制备方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US11851732B2 (zh) |
CN (1) | CN108467968B (zh) |
BR (1) | BR112020015587B1 (zh) |
DE (1) | DE112018007020T5 (zh) |
WO (1) | WO2019153795A1 (zh) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108467968B (zh) | 2018-02-06 | 2019-07-23 | 天能电池集团股份有限公司 | 一种铅蓄电池板栅合金的制备方法 |
CN110165149A (zh) * | 2019-06-05 | 2019-08-23 | 天能电池(芜湖)有限公司 | 蓄电池板栅节能固化工艺 |
CN111349812B (zh) * | 2020-02-20 | 2021-08-06 | 江苏海瑞电源有限公司 | 一种节能环保型铅基合金 |
CN111659733A (zh) * | 2020-06-08 | 2020-09-15 | 宁夏天元锰材料技术开发有限公司 | 一种电解锰阳极板板栅及其制作方法 |
CN111705337B (zh) * | 2020-06-23 | 2022-02-08 | 超威电源集团有限公司 | 一种熔盐原电池法制备铅钙母合金的方法 |
CN112159993B (zh) * | 2020-09-24 | 2022-03-29 | 江西江钨浩运科技有限公司 | 含钇的混合稀土金属、稀土储氢合金及其制备方法 |
US11740328B2 (en) * | 2020-12-16 | 2023-08-29 | DC-001, Inc. | Methods and systems for processing radar signals |
CN113097573B (zh) * | 2021-03-25 | 2022-08-12 | 北京阳光鸿志电气工程技术有限公司 | 一种快速充电全密封免维护铅酸蓄电池 |
CN113106534B (zh) * | 2021-04-13 | 2022-07-05 | 山西百一机械设备制造有限公司 | 铅合金电极板、制备方法以及阳极板 |
CN114335445A (zh) * | 2021-08-27 | 2022-04-12 | 漳州市华威电源科技有限公司 | 一种高循环性能铅酸电池的电池极板制备工艺 |
CN115772614B (zh) * | 2022-11-01 | 2024-03-29 | 天能集团贵州能源科技有限公司 | 一种蓄电池正板栅合金及其制备方法 |
CN115772610A (zh) * | 2022-11-23 | 2023-03-10 | 华宇新能源科技有限公司 | 一种耐腐蚀蓄电池板栅及其制备方法 |
CN116287858B (zh) * | 2023-03-30 | 2023-11-28 | 巨江电源科技有限公司 | 铅酸蓄电池负极板栅用铅基钡钠铝合金及其制备方法和应用 |
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IN153954B (zh) * | 1981-03-03 | 1984-09-01 | Chloride India Limited | |
CN1208860C (zh) * | 2003-04-03 | 2005-06-29 | 复旦大学 | 用作铅蓄电池正极板栅的铅-稀土多元合金及其制备方法 |
CN1259456C (zh) * | 2004-01-08 | 2006-06-14 | 包头铝业股份有限公司 | 熔盐电解法直接制备铝铈中间合金的方法 |
JP5087950B2 (ja) * | 2007-02-27 | 2012-12-05 | 新神戸電機株式会社 | 鉛蓄電池 |
CN100588729C (zh) * | 2007-08-08 | 2010-02-10 | 株洲冶炼集团股份有限公司 | 铅合金及其应用和制造方法 |
CN102660697B (zh) * | 2012-04-27 | 2014-01-08 | 天能电池集团有限公司 | 一种动力用铅酸蓄电池板栅合金 |
CN103762369B (zh) | 2014-01-10 | 2016-08-17 | 江苏海宝电池科技有限公司 | 一种铅酸蓄电池正极板栅用稀土铅合金 |
CN106684391A (zh) | 2016-12-21 | 2017-05-17 | 河南超威电源有限公司 | 一种铅酸蓄电池用稀土板栅合金及其生产方法 |
CN107146890B (zh) | 2017-03-24 | 2019-10-29 | 淄博火炬能源有限责任公司 | 高温型阀控铅酸蓄电池及其制备方法 |
CN108467968B (zh) * | 2018-02-06 | 2019-07-23 | 天能电池集团股份有限公司 | 一种铅蓄电池板栅合金的制备方法 |
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BR112020015587B1 (pt) | 2023-11-28 |
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