CN108102571A - Solar double-glass photovoltaic module laminating edge sealing and adhesive reducing adhesive tape and preparation method thereof - Google Patents

Solar double-glass photovoltaic module laminating edge sealing and adhesive reducing adhesive tape and preparation method thereof Download PDF

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Publication number
CN108102571A
CN108102571A CN201711192716.6A CN201711192716A CN108102571A CN 108102571 A CN108102571 A CN 108102571A CN 201711192716 A CN201711192716 A CN 201711192716A CN 108102571 A CN108102571 A CN 108102571A
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CN
China
Prior art keywords
edge sealing
photovoltaic module
glass photovoltaic
solar energy
adhesive tape
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711192716.6A
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Chinese (zh)
Inventor
祝怀瑞
王建斌
陈田安
解海华
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Yantai Darbond Technology Co Ltd
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Yantai Darbond Technology Co Ltd
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Priority to CN201711192716.6A priority Critical patent/CN108102571A/en
Publication of CN108102571A publication Critical patent/CN108102571A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/322Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/006Presence of polyolefin in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

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  • Laminated Bodies (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention belongs to the technical field of solar double-glass photovoltaic modules, and particularly relates to a laminating edge sealing and viscosity reducing adhesive tape for a solar double-glass photovoltaic module and a preparation method of the laminating edge sealing and viscosity reducing adhesive tape. The prepared adhesive tape for laminating and edge sealing of the solar double-glass photovoltaic module is not crosslinked at normal temperature, has high initial adhesion and good conformability, has no adhesive residue when being peeled after heating and laminating, is easy to peel and not to break, and solves the problem that the construction adhesive tape is easy to warp under the low temperature condition. The adhesive tape disclosed by the invention has no burrs during processing and slitting, the viscosity is reduced during peeling of the adhesive tape after high-temperature lamination, the adhesive tape is easy to peel without residual adhesive, and the fracture condition is avoided.

Description

Double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of a kind of solar energy and preparation method thereof
Technical field
The invention belongs to the double glass photovoltaic module technical fields of solar energy more particularly to a kind of double glass photovoltaic module layers of solar energy Press seal side visbreaking adhesive tape and preparation method thereof.
Background technology
In the production process of photovoltaic cell component, the protection of tradition lamination technique edges edge is generally consolidated by aluminum alloy frame Fixed, silica gel or adhesive tape are bonded and sealed, complex procedures, low production efficiency;Solar double-glass assemblies replace backboard, ultra-thin double glass with photovoltaic glass Assembly property advantage highlights, and slowly becomes the main product of photovoltaic market.
At present, it is common silica gel high temperature gummed tape edge sealing adhesive band to be previously mentioned in Chinese patent CN105957911A, with silicon The rise in price of raw material and environmental protection pressure, common silica gel adhesive tape will be replaced progressively by the product of more economical environmental protection.Chinese patent The high temperature resistance for the high temperature resistant acrylate pressure sensitive adhesive invented in CN106589434A is good, but Tg higher, and winter temperature is relatively low In the case of adhesive tape it is just viscous poor, construct edge sealing when easily warp, and nylon cloth and glass-fiber-fabric price height, production cost pressure is big, no It goes into operation beneficial to extensive.Therefore need a kind of to produce simple and environmentally-friendly, inexpensive functional adhesive tape to meet new markets demand.
The content of the invention
The present invention in view of the deficiency of the prior art, provides a kind of double glass photovoltaic module lamination edge sealing of solar energy and subtracts Adhesive tape and preparation method thereof.
The technical solution that the present invention solves above-mentioned technical problem is as follows:A kind of double glass photovoltaic module lamination edge sealing of solar energy subtract Adhesive tape, including Acrylic Pressure Sensitive Adhesive layer 20- 50-60 μm of flexible substrate layer and volume on the inside of flexible substrate layer 30μm;
Wherein, the flexible substrate layer is the composite membrane of resistance to 150 DEG C bakings;The Acrylic Pressure Sensitive Adhesive Layer reduces by more than 50% acrylate for viscosity after 150 DEG C of baking 30min.
Based on the above technical solutions, the present invention can also be improved as follows.
The flexible substrate layer is polyester film and polyolefin film composite membrane, and the thickness of the polyester film is 25-30 μm, The thickness of the polyolefin film is 25-30 μm.
The Acrylic Pressure Sensitive Adhesive layer includes 100 parts of acrylate, 0-1 parts of common cross-linking agents and 3-5 parts high Temperature deblocking crosslinking agent.
The common cross-linking agent is TDI-TMP.
Described high temperature deblocking crosslinking agent is the S-510 of Nantong Xin Naxi green woods, the S-610 of Nantong Xin Naxi green woods or on One or two kinds of mixing of the UN-7038 of Hai Youen chemical industry.
The double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, are followed successively by acrylate pressure-sensitive adhesive and glue from the inside to the outside Oxidant layer, polyester film and polyolefin film.
Second object of the present invention is the system for providing the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy Preparation Method, step are as follows:
(1) the polyester film surface of flexible substrate layer is made into sided corona treatment, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of acrylate, 0-1 parts of common cross-linking agents and 3-5 parts of high temperature deblocking crosslinking agents are mixed to prepare acrylic acid Ester pressure-sensitive adhesive layer is coated on the polyester layer of flexible substrate layer, 20-30 μm of thickness, drying;
(3) winding tension is controlled, from the inside to the outside according to the suitable of Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin film Sequence is superimposed, and winds to obtain the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy.
Wherein, the drying condition described in step (2) is:2~3min is dried at a temperature of 80~90 DEG C.
Winding tension described in step (3) is 80-150N.
The beneficial effects of the invention are as follows:
1st, the present invention is using flexible substrate, and for the composite membrane used without release, preparation is used for the double glass photovoltaics of solar energy Component lamination edge sealing visbreaking adhesive tape is not crosslinked at normal temperatures, just viscous height, and docile property is good, residual without glue when adhesive tape is removed after heating lamination It stays, adhesive tape is easily peelable not broken, solves the problems, such as that construction adhesive tape easily warps under cryogenic conditions.
2nd, adhesive tape of the invention does not have flash when processing and cutting, and viscosity reduces when adhesive tape is removed after high temperature lamination, easily Easily peelable no residue glue, is not in crack conditions, compared with common silica gel High temperature-resistanadhesive adhesive tape, reduces production cost, improves life Produce efficiency.
Description of the drawings
Fig. 1 is the structure diagram of edge sealing adhesive band of the present invention;
In figure, 1, flexible substrate layer;1-1, polyester film;1-2, polyolefin film;2nd, Acrylic Pressure Sensitive Adhesive layer.
Specific embodiment
The principle of the present invention and feature are described below in conjunction with example, the given examples are served only to explain the present invention, and It is non-to be used to limit the scope of the present invention.
The acrylate Y-1150W purchases used in the embodiment of the present invention are from peace assistant chemistry, the acrylate CF- used 62E is bought from Weifang Fuller new material.
Embodiment 1
The double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of a kind of solar energy, including flexible substrate layer and volume in flexibility base Acrylic Pressure Sensitive Adhesive layer on the inside of material layer;
Wherein, the flexible substrate layer is polyester film and polyolefin film composite membrane, and the thickness of the polyester film is 12 μ M, the thickness of the polyolefin film is 38 μm;
The thickness of the Acrylic Pressure Sensitive Adhesive layer is 25 μm, including 100 parts of CF-62E, 1 part of common cross-linking agent TDI-TMP and 3 part of high temperature unseals crosslinking aid S -610.
The preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, step are as follows:
(1) the polyester film surface of flexible substrate layer is made into sided corona treatment, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of CF-62E, 1 part of common cross-linking agent TDI-TMP and 3 parts of high temperature deblocking crosslinking aid Ss -610 are mixed to prepare Acrylic Pressure Sensitive Adhesive layer is coated on the polyester layer of flexible substrate layer, is dried at a temperature of 25 μm, 80~90 DEG C of thickness 2~3min;
(3) winding tension is controlled as 90N, from the inside to the outside according to Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin The laminated structure of film winds to obtain the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy.
Edge sealing adhesive band obtained is tested for the property, test result is shown in Table 1.
Embodiment 2
The double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of a kind of solar energy, including flexible substrate layer and volume in flexibility base Acrylic Pressure Sensitive Adhesive layer on the inside of material layer;
Wherein, the flexible substrate layer is polyester film and polyolefin film composite membrane, and the thickness of the polyester film is 25 μ M, the thickness of the polyolefin film is 25 μm;
The thickness of the Acrylic Pressure Sensitive Adhesive layer is 25 μm, including 100 parts of Y-1150W, 1 part of common cross-linking agent TDI-TMP and 3 part of high temperature unseals crosslinking aid S -610.
The preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, step are as follows:
(1) the polyester film surface of flexible substrate layer is made into sided corona treatment, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of Y-1150W, 1 part of common cross-linking agent TDI-TMP and 3 parts of high temperature deblocking crosslinking aid Ss -610 are mixed into system Acrylic Pressure Sensitive Adhesive layer is obtained, is coated on the polyester layer of flexible substrate layer, is dried at a temperature of 25 μm, 80~90 DEG C of thickness Dry 2~3min;
(3) winding tension is controlled as 100N, from the inside to the outside according to Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin The laminated structure of film winds to obtain the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy.
Edge sealing adhesive band obtained is tested for the property, test result is shown in Table 1.
Embodiment 3
The double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of a kind of solar energy, including flexible substrate layer and volume in flexibility base Acrylic Pressure Sensitive Adhesive layer on the inside of material layer;
Wherein, the flexible substrate layer is polyester film and polyolefin film composite membrane, and the thickness of the polyester film is 12 μ M, the thickness of the polyolefin film is 38 μm;
The thickness of the Acrylic Pressure Sensitive Adhesive layer is 25 μm, is handed over including 100 parts of Y-1150W, 3 parts of high temperature deblockings Join agent S-610 and 1 part of high temperature deblocking crosslinking agent UN-7038.
The preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, step are as follows:
(1) the polyester film surface of flexible substrate layer is made into sided corona treatment, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of Y-1150W, 3 parts of high temperature deblocking crosslinking aid Ss -610 and 1 part of high temperature deblocking crosslinking agent UN-7038 are mixed It closes and Acrylic Pressure Sensitive Adhesive layer is made, be coated on the polyester layer of flexible substrate layer, 25 μm of thickness, 80~90 DEG C of temperature 2~3min of lower drying;
(3) winding tension is controlled as 130N, from the inside to the outside according to Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin The laminated structure of film winds to obtain the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy.
Edge sealing adhesive band obtained is tested for the property, test result is shown in Table 1.
For difference with the prior art of the present invention is better described, following comparative example is now enumerated.
Comparative example 1
A kind of edge sealing adhesive band, including Acrylic Pressure Sensitive Adhesive layer substrate layer and volume on the inside of substrate layer;
Wherein, the substrate layer is PET single-sided parting films, and the thickness of the PET single-sided parting films is 50 μm;
The thickness of the Acrylic Pressure Sensitive Adhesive layer is 25 μm, including 100 parts of CF-62E, 1 part of common cross-linking agent TDI-TMP and 5 part of high temperature deblocking crosslinking agent UN-7038.
The preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, step are as follows:
(1) sided corona treatment is made into the PET single-sided parting films face of substrate layer, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of CF-62E, 1 part of common cross-linking agent TDI-TMP and 5 parts of high temperature deblocking crosslinking agent UN-7038 are mixed into system Acrylic Pressure Sensitive Adhesive layer is obtained, is coated on substrate layer, 2~3min is dried at a temperature of 25 μm, 80~90 DEG C of thickness;
(3) winding tension is controlled as 90N, from the inside to the outside according to Acrylic Pressure Sensitive Adhesive layer and PET single-sided parting films Laminated structure, wind to obtain edge sealing adhesive band.
Edge sealing adhesive band obtained is tested for the property, test result is shown in Table 1.
Comparative example 2
A kind of edge sealing adhesive band, including Acrylic Pressure Sensitive Adhesive layer substrate layer and volume on the inside of substrate layer;
Wherein, the substrate layer is PET single-sided parting films, and the thickness of the PET single-sided parting films is 50 μm;
The thickness of the Acrylic Pressure Sensitive Adhesive layer is 25 μm, including 100 parts of Y-1150W, 1 part of common cross-linking agent TDI-TMP and 5 part of high temperature deblocking crosslinking agent UN-7038.
The preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of above-mentioned solar energy, step are as follows:
(1) sided corona treatment is made into the PET single-sided parting films face of substrate layer, polyester layer surface corona value is 38 dynes after processing More than;
(2) 100 parts of Y-1150W, 1 part of common cross-linking agent TDI-TMP and 5 parts of high temperature deblocking crosslinking agent UN-7038 are mixed Acrylic Pressure Sensitive Adhesive layer is made, is coated on substrate layer, 2~3min is dried at a temperature of 25 μm, 80~90 DEG C of thickness;
(3) winding tension is controlled as 90N, from the inside to the outside according to Acrylic Pressure Sensitive Adhesive layer and PET single-sided parting films Laminated structure, wind to obtain edge sealing adhesive band.
Edge sealing adhesive band obtained is tested for the property, test result is shown in Table 1.
Table 1
By embodiment 1-3 with the edge sealing adhesive that comparative example 1-2 is prepared with rewinding into 100m long, cut into the small of 30mm wide It rolls up, solar double-glass assemblies edge is coated on after uncoiling and carries out high temperature resistant experiment, cooling is taken out after 150 DEG C of heating 30min, observes and remove glue Band without residue glue, warp, it is easily peelable not broken.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and Within principle, any modifications, equivalent replacements and improvements are made should all be included in the protection scope of the present invention.

Claims (9)

1. the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of a kind of solar energy, which is characterized in that including flexible substrate layer 50-60 μm and Acrylic Pressure Sensitive Adhesive layer 20-30 μm of the volume on the inside of flexible substrate layer;
Wherein, the flexible substrate layer is the composite membrane of resistance to 150 DEG C bakings;The Acrylic Pressure Sensitive Adhesive layer is Viscosity reduces by more than 50% acrylate after 150 DEG C of baking 30min.
2. the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy according to claim 1, which is characterized in that described Flexible substrate layer is polyester film and polyolefin film composite membrane, and the thickness of the polyester film is 25-30 μm, the polyolefin film Thickness is 25-30 μm.
3. the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy according to claim 1, which is characterized in that described Acrylic Pressure Sensitive Adhesive layer includes 100 parts of acrylate, 0-1 parts of common cross-linking agents and 3-5 parts of high temperature deblocking crosslinking agents.
4. the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy according to claim 3, which is characterized in that described Common cross-linking agent is TDI-TMP.
5. the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy according to claim 3, which is characterized in that described High temperature deblocking crosslinking agent is one or two kinds of mixing of S-510, S-610 or UN-7038.
6. the double glass photovoltaic modulies lamination edge sealing visbreaking adhesive tapes of solar energy according to claim 2, which is characterized in that by it is interior extremely It is followed successively by Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin film outside.
7. a kind of preparation method of the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of any one of the claim 1-6 solar energy, It is characterized in that, step is as follows:
(1) the polyester film surface of flexible substrate layer is made into sided corona treatment, polyester layer surface corona value is 38 dynes or more after processing;
(2) 100 parts of acrylate, 0-1 parts of common cross-linking agents and 3-5 parts of high temperature deblocking crosslinking agents are mixed to prepare acrylate pressure Sensitive adhesive layer is coated on the polyester layer of flexible substrate layer, 20-30 μm of thickness, drying;
(3) winding tension is controlled, is folded from the inside to the outside according to the order of Acrylic Pressure Sensitive Adhesive layer, polyester film and polyolefin film Add, wind to obtain the double glass photovoltaic module lamination edge sealing visbreaking adhesive tapes of solar energy.
8. preparation method according to claim 7, which is characterized in that the drying condition described in step (2) is:80~ 2~3min is dried at a temperature of 90 DEG C.
9. preparation method according to claim 7, which is characterized in that the winding tension described in step (3) is 80- 150N。
CN201711192716.6A 2017-11-24 2017-11-24 Solar double-glass photovoltaic module laminating edge sealing and adhesive reducing adhesive tape and preparation method thereof Pending CN108102571A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796901A (en) * 2019-01-23 2019-05-24 浙江耀阳新材料科技有限公司 A kind of adhesive and its adhesive tape
CN112549730A (en) * 2020-11-06 2021-03-26 杭州福斯特应用材料股份有限公司 Double-glass photovoltaic module lamination positioning structure

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Publication number Priority date Publication date Assignee Title
JPH07331219A (en) * 1994-06-15 1995-12-19 Sekisui Chem Co Ltd Adhesive composition
CN1494580A (en) * 2000-12-01 2004-05-05 3M Crosslinked pressure sensitive adhesive compositions, and adhesive articles based thereon, useful in high temp. applications
JP2007284576A (en) * 2006-04-17 2007-11-01 Nitto Denko Corp Pressure-sensitive adhesive sheet and method for processing adherend by using the same
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Publication number Priority date Publication date Assignee Title
JPH07331219A (en) * 1994-06-15 1995-12-19 Sekisui Chem Co Ltd Adhesive composition
CN1494580A (en) * 2000-12-01 2004-05-05 3M Crosslinked pressure sensitive adhesive compositions, and adhesive articles based thereon, useful in high temp. applications
JP2007284576A (en) * 2006-04-17 2007-11-01 Nitto Denko Corp Pressure-sensitive adhesive sheet and method for processing adherend by using the same
CN105086913A (en) * 2014-05-09 2015-11-25 霓达株式会社 Adhesive composition
CN107163869A (en) * 2017-06-26 2017-09-15 东莞市明信高分子科技有限公司 A kind of hot shear-thinning type adhesive tape and preparation method thereof

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Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796901A (en) * 2019-01-23 2019-05-24 浙江耀阳新材料科技有限公司 A kind of adhesive and its adhesive tape
CN112549730A (en) * 2020-11-06 2021-03-26 杭州福斯特应用材料股份有限公司 Double-glass photovoltaic module lamination positioning structure

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Application publication date: 20180601