CN108049162A - 一种涤纶抗菌面料的制备工艺 - Google Patents
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Abstract
本发明涉及了一种涤纶抗菌面料的制备工艺，a、配置整理液，抗菌整理剂20‑40g/L，有机硅柔软剂4‑8g/L；b、浸轧抗菌整理液，浸渍温度20～30℃，时间10min；轧车轧液，轧液率90～100％；c、烘干，180℃，45‑60s。本发明采用聚氨酯、丙烯酸酯单体在改性后的纳米氧化锌粒子表面接枝的方法，使纳米材料抗菌物质限制在聚合物基体中，克服了纳米氧化锌稳定性差的缺点，实现了涤纶面料抗菌的安全、持久、高效性。
Description
技术领域
本发明涉及一种涤纶抗菌面料的制备工艺，属于功能纺织品制备技术领域。
背景技术
我们日常所使用的各种纺织品，如棉被、内衣裤、鞋袜等，都是微生物滋生繁衍的适宜场所。它们在人体适宜环境中的迅速繁殖，不仅会使纤维制品变色、发霉、脆化降解，而且还会对人体皮肤产生异常的刺激，诱发各种皮肤疾病，影响健康。纺织品上滋生的细菌，会以人体新陈代谢产物-汗水、脂肪质和皮屑等为营养，迅速繁殖。
随着生活水平的提高，人们对服用纺织品卫生性的要求正在逐渐提高，具有抗菌防臭功能的纺织产品市场也在逐步扩人。
发明内容
针对现有抗菌剂的不足，本发明所要解决的技术问题是提供一种涤纶抗菌面料的制备工艺，提高涤纶面料抗菌长效性。
为实现上述目的，本发明采用的技术方案为：
一种涤纶抗菌面料的制备工艺，
a、配置整理液
抗菌整理剂20-40g/L，有机硅柔软剂4-8g/L；
b、浸轧抗菌整理液
浸渍温度20～30℃，时间10min；轧车轧液，轧液率90～100％；
c、烘干
180℃，45-60s；
所述的抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一向反应釜中加入12份表面改性纳米氧化锌粉末、9份十二烷基苯磺酸钠、6份Span-20、48份端乙烯基聚氨酯乳液、124份去离子水，搅拌均匀，升温至75℃；以20份去离子水溶解0.6份过硫酸钠成引发剂水溶液；
步骤二缓慢地向反应釜中滴加12份苯乙烯、24份丙烯酸丁酯、86份去离子水、5份十二烷基苯磺酸钠、3份Span-20形成的乳化液、引发剂水溶液，滴加完后，在83℃保温反应2h；
步骤三降温至50℃以下，过200目筛，得抗菌整理剂。
所述表面改性纳米氧化锌的制备方法为：
10份纳米氧化锌加到盛有60份无水乙醇和20份水的广口瓶中，超声分散30分钟，升温至40℃，恒温匀速搅拌30分钟，盐酸调节pH值5.5，待搅拌稳定后通过滴管从瓶口加入由12份无水乙醇溶解的1份硅烷偶联剂KH-570，反应1小时后，取出过滤、洗涤、烘干、研磨，制得表面改性纳米氧化锌粉末。
本发明采用聚氨酯、丙烯酸酯单体在改性后的纳米氧化锌粒子表面接枝的方法，使纳米材料抗菌物质限制在聚合物基体中，克服了纳米氧化锌稳定性差的缺点，实现了涤纶面料抗菌的安全、持久、高效性。
具体实施方法：
下列实施方案，仅是举例说明，不是仅有的，所以，一切在本发明范围内或是做与本发明相似的改变均包含于本发明之内，基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一 向反应釜中加入12份表面改性纳米氧化锌粉末、9份十二烷基苯磺酸钠、6份Span-20、48份端乙烯基聚氨酯乳液、124份去离子水，搅拌均匀，升温至75℃；以20份去离子水溶解0.6份过硫酸钠成引发剂水溶液；
步骤二 缓慢地向反应釜中滴加12份苯乙烯、24份丙烯酸丁酯、86份去离子水、5份十二烷基苯磺酸钠、3份Span-20形成的乳化液、引发剂水溶液，滴加完后，在83℃保温反应2h；
步骤三 降温至50℃以下，过200目筛，得抗菌整理剂。
所述表面改性纳米氧化锌的制备方法为：
10份纳米氧化锌加到盛有60份无水乙醇和20份水的广口瓶中，超声分散30分钟，升温至40℃，恒温匀速搅拌30分钟，盐酸调节pH值5.5，待搅拌稳定后通过滴管从瓶口加入由12份无水乙醇溶解的1份硅烷偶联剂KH-570，反应1小时后，取出过滤、洗涤、烘干、研磨，制得表面改性纳米氧化锌粉末。
实施例2
一种涤纶抗菌面料的制备工艺，
a、配置整理液
抗菌整理剂20-40g/L，有机硅柔软剂4-8g/L；
b、浸轧抗菌整理液
浸渍温度20～30℃，时间10min；轧车轧液，轧液率90～100％；
c、烘干
180℃，45-60s。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (2)
1.一种涤纶抗菌面料的制备工艺，
a、配置整理液
抗菌整理剂20-40g/L
有机硅柔软剂4-8g/L；
b、浸轧抗菌整理液
浸渍温度20～30℃，时间10min；
轧车轧液，轧液率90～100％；
c、烘干
180℃，45-60s；
所述的抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一 向反应釜中加入12份表面改性纳米氧化锌粉末、9份十二烷基苯磺酸钠、6份Span-20、48份端乙烯基聚氨酯乳液、124份去离子水，搅拌均匀，升温至75℃；以20份去离子水溶解0.6份过硫酸钠成引发剂水溶液；
步骤二 缓慢地向反应釜中滴加12份苯乙烯、24份丙烯酸丁酯、86份去离子水、5份十二烷基苯磺酸钠、3份Span-20形成的乳化液、引发剂水溶液，滴加完后，在83℃保温反应2h；
步骤三 降温至50℃以下，过200目筛，得抗菌整理剂。
2.如权利要求1所述的一种涤纶抗菌面料的制备工艺，其特征在于：所述表面改性纳米氧化锌的制备方法为：
10份纳米氧化锌加到盛有60份无水乙醇和20份水的广口瓶中，超声分散30分钟，升温至40℃，恒温匀速搅拌30分钟，盐酸调节pH值5.5，待搅拌稳定后通过滴管从瓶口加入由12份无水乙醇溶解的1份硅烷偶联剂KH-570，反应1小时后，取出过滤、洗涤、烘干、研磨，制得表面改性纳米氧化锌粉末。
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108823965A (zh) * | 2018-07-09 | 2018-11-16 | 合肥洁诺医疗用品有限公司 | 一种擦拭纸用改性无纺布的制备方法 |
| CN113026361A (zh) * | 2021-02-26 | 2021-06-25 | 石家庄学院 | 一种戊二醛偶联聚六亚甲基盐酸盐制备长效抗菌聚酯纤维的方法及反应装置 |
| CN113668233A (zh) * | 2021-08-24 | 2021-11-19 | 江西服装学院 | 织物整理剂及使用其整理纯棉织物的方法 |
| CN114318639A (zh) * | 2021-12-22 | 2022-04-12 | 宁波狮丹努针织有限公司 | 一种锌离子抗菌针织面料及其制备工艺 |
| CN114622401A (zh) * | 2022-05-13 | 2022-06-14 | 江苏恒力化纤股份有限公司 | 一种聚酯织物功能化后整理的方法 |
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2017
- 2017-11-27 CN CN201711312144.0A patent/CN108049162A/zh active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108823965A (zh) * | 2018-07-09 | 2018-11-16 | 合肥洁诺医疗用品有限公司 | 一种擦拭纸用改性无纺布的制备方法 |
| CN113026361A (zh) * | 2021-02-26 | 2021-06-25 | 石家庄学院 | 一种戊二醛偶联聚六亚甲基盐酸盐制备长效抗菌聚酯纤维的方法及反应装置 |
| CN113026361B (zh) * | 2021-02-26 | 2022-12-30 | 石家庄学院 | 一种戊二醛偶联聚六亚甲基盐酸盐制备长效抗菌聚酯纤维的方法及反应装置 |
| CN113668233A (zh) * | 2021-08-24 | 2021-11-19 | 江西服装学院 | 织物整理剂及使用其整理纯棉织物的方法 |
| CN114318639A (zh) * | 2021-12-22 | 2022-04-12 | 宁波狮丹努针织有限公司 | 一种锌离子抗菌针织面料及其制备工艺 |
| CN114622401A (zh) * | 2022-05-13 | 2022-06-14 | 江苏恒力化纤股份有限公司 | 一种聚酯织物功能化后整理的方法 |
| CN114622401B (zh) * | 2022-05-13 | 2022-10-04 | 江苏恒力化纤股份有限公司 | 一种聚酯织物功能化后整理的方法 |
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