CN107938104A - High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof - Google Patents

High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof Download PDF

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Publication number
CN107938104A
CN107938104A CN201711040729.1A CN201711040729A CN107938104A CN 107938104 A CN107938104 A CN 107938104A CN 201711040729 A CN201711040729 A CN 201711040729A CN 107938104 A CN107938104 A CN 107938104A
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Prior art keywords
graphene oxide
fiber
daiamid
retardant
wool
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CN201711040729.1A
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Chinese (zh)
Inventor
黄旭
张炜栋
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Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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Priority to CN201711040729.1A priority Critical patent/CN107938104A/en
Priority to PCT/CN2017/116978 priority patent/WO2019085191A1/en
Publication of CN107938104A publication Critical patent/CN107938104A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses high antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof, the high antibacterial flame-retardant and anti-static carpet yarn of the graphene oxide includes graphene oxide daiamid-6 fiber and wool, and graphene oxide ratio is 0.3 0.8% in the graphene oxide daiamid-6 fiber.The ratio of graphene oxide daiamid-6 fiber and wool is：10‑90:90‑10.The antibiotic property of the high antibacterial flame-retardant and anti-static carpet uniqueness of the graphene oxide of the present invention does not produce allergy to human body；Dual characteristics with chemical fibre and wool, antibacterial is anti-insect, fire retardant, antistatic is good.Its rational technology, simple, suitable industrialized production.

Description

High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof
Technical field
The invention belongs to woven carpet production technical field, and in particular to a kind of high antibacterial flame-retardant and anti-static of graphene oxide Carpet and preparation method thereof.
Background technology
Graphene oxide daiamid-6 fiber, is by graphene oxide and the thermoplastic resin system containing amide group For a kind of complex fibre gone out.With high biocidal property, the features such as wearability is high, moisture absorption is breathed freely, superconduction is antistatic.Graphite oxide The material of main part of alkene daiamid-6 fiber is cut into slices for polyamide 6, using prefabricated master batch technique, graphene oxide is uniform It is dispersed in polyamide 6 section, through melt spinning, spinning handles to obtain the daiamid-6 fiber containing graphene oxide with after.So as to Graphite oxide olefinic functionality is introduced into daiamid-6 fiber.The graphene oxide daiamid-6 fiber and traditional daiamid-6 fiber phase Than being all significantly improved in bacteria resistance, ultraviolet-resistent property etc..
The carpet overwhelming majority does not have antibacterial functions at present, has the function of the carpet of antibacterial, using organic antibacterial agent or Inorganic heavy metal antiseptic, the slender cell space of harmful bacteria is killed, but at the same time metropolitan environments are caused with environmental pollution, and to using Person produces certain allergy effect.
In order to improve the security that carpet uses, it is improved on the yarn of woven carpet, carpet itself is had one Fixed antibacterial functions.Graphene oxide produces " graphite knife " effect, has good anti-microbial property, cytotoxicity very little is to human body Do not produce allergy.
The content of the invention
Goal of the invention：It is high antibacterial fire-retardant the present invention provides a kind of graphene oxide in order to solve the deficiencies in the prior art Antistatic carpet and preparation method thereof.
Technical solution：A kind of high antibacterial flame-retardant and anti-static carpet of graphene oxide, the carpet raw material is graphite oxide Alkene daiamid-6 fiber/wool blended yarn, the scribbled includes graphene oxide daiamid-6 fiber and wool, described Graphene oxide daiamid-6 fiber in graphene oxide ratio be 0.1-1%；Graphene oxide daiamid-6 fiber and wool Ratio be：10-90:90-10, the scribbled are differential imitative hair strong twisted yarn, 200-210 twists/m of the twist.
Further, the specification of the graphene oxide daiamid-6 fiber is：2.78dtex × 51mm, the oxidation stone The blending rate of black alkene daiamid-6 fiber and wool is selected from：10/90th, one in 40/60,50/50,60/40,65/35,90/10 Kind blending ratio.
Further, the graphene oxide daiamid-6 fiber is fibre in differentiation, its section configuration is triangle, three Leaf, oval, X-shaped or Y shape.
Further, the graphene oxide daiamid-6 fiber is fire-retardant anti-quiet by in-situ polymerization graphene oxide polyamide 6 Cutting piece is made by melt spinning, and graphene oxide content is 0.3-0.8%, which there is excellent antibacterial to hinder Fire antistatic property.
A kind of preparation method according to the high antibacterial flame-retardant and anti-static carpet of the graphene oxide, comprises the following steps： Weave-cut open suede-stamp-evaporating-and wash-arrange-be dehydrated-tentering drying-plucking-bristle-raising-cropping- Bound edge-packaging；
During the stamp, the stamp of flannelette blanket uses acid dyes stamp.
During the arrangement, one or more of organosilicon flexibles in DC-200, KF-96, GE-9981 are used Arrangement is rolled in agent, two leachings two, and pick-up rate 80-90%, 90-100 DEG C of drying, 150-180 DEG C bakes.
Beneficial effect：Graphene oxide daiamid-6 fiber in the present invention provides antibacterial, fire-retardant, antistatic, anti-insect work( Energy.Special-shaped graphene oxide daiamid-6 fiber reduces reflection, eliminates aurora, strengthens the feel of wool.Heavy twist makes mixed yarn have filoplume It is short, overcome the shortcomings that pure wool yarn pilling, antifungal gene, feel abundant.
The antibiotic property of the high antibacterial flame-retardant and anti-static carpet uniqueness of the graphene oxide of the present invention does not produce allergy to human body；Tool There are the dual characteristics of chemical fibre and wool, antibacterial is anti-insect, fire retardant, antistatic is good.Its rational technology, simple, suitable industry metaplasia Production.
Embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, so that the technology of this area Personnel can be better understood from advantages and features of the invention, so as to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only part of the embodiment of the present invention, instead of all the embodiments, based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained on the premise of creative work is not made Example, belongs to the scope of protection of the invention.
Embodiment 1
A kind of high antibacterial flame-retardant and anti-static carpet of graphene oxide, the carpet raw material is graphene oxide polyamide 6 Fiber/wool blended yarn, the scribbled include graphene oxide daiamid-6 fiber and wool, the oxidation stone Graphene oxide ratio is 0.1% in black alkene daiamid-6 fiber；The ratio of graphene oxide daiamid-6 fiber and wool is： 10:90, the scribbled is differential imitative hair strong twisted yarn, 200 twists/m of the twist.
The specification of the graphene oxide daiamid-6 fiber is：2.78dtex × 51mm, the graphene oxide polyamide The blending rate of 6 fibers and wool is selected from：10/90th, a kind of blending ratio in 40/60,50/50,60/40,65/35,90/10.
The graphene oxide daiamid-6 fiber is fibre in differentiation, its section configuration is triangle, trilobal, ellipse Shape, X-shaped or Y shape.
The graphene oxide daiamid-6 fiber by in-situ polymerization graphene oxide polyamide 6 flame-retardant and anti-static cut into slices by Melt spinning is made, and graphene oxide content is 0.3%, which has excellent antibacterial flame-retardant antistatic property.
A kind of preparation method according to the high antibacterial flame-retardant and anti-static carpet of the graphene oxide, comprises the following steps： Weave-cut open suede-stamp-evaporating-and wash-arrange-be dehydrated-tentering drying-plucking-bristle-raising-cropping- Bound edge-packaging；
The stamp of flannelette blanket uses acid dyes stamp.
During the arrangement, one or more of organosilicon flexibles in DC-200, KF-96, GE-9981 are used Arrangement is rolled in agent, two leachings two, and pick-up rate 80%, 90 DEG C of drying, 150 DEG C bake.
Embodiment 2
A kind of high antibacterial flame-retardant and anti-static carpet of graphene oxide, the carpet raw material is graphene oxide polyamide 6 Fiber/wool blended yarn, the scribbled include graphene oxide daiamid-6 fiber and wool, the oxidation stone Graphene oxide ratio is 1% in black alkene daiamid-6 fiber；The ratio of graphene oxide daiamid-6 fiber and wool is：90: 10, the scribbled is differential imitative hair strong twisted yarn, 210 twists/m of the twist.
The specification of the graphene oxide daiamid-6 fiber is：2.78dtex × 51mm, the graphene oxide polyamide The blending rate of 6 fibers and wool is selected from：10/90th, a kind of blending ratio in 40/60,50/50,60/40,65/35,90/10.
The graphene oxide daiamid-6 fiber is fibre in differentiation, its section configuration is triangle, trilobal, ellipse Shape, X-shaped or Y shape.
The graphene oxide daiamid-6 fiber by in-situ polymerization graphene oxide polyamide 6 flame-retardant and anti-static cut into slices by Melt spinning is made, and graphene oxide content is 0.8%, which has excellent antibacterial flame-retardant antistatic property.
A kind of preparation method according to the high antibacterial flame-retardant and anti-static carpet of the graphene oxide, comprises the following steps： Weave-cut open suede-stamp-evaporating-and wash-arrange-be dehydrated-tentering drying-plucking-bristle-raising-cropping- Bound edge-packaging；
The stamp of flannelette blanket uses acid dyes stamp.
During the arrangement, one or more of organosilicon flexibles in DC-200, KF-96, GE-9981 are used Arrangement is rolled in agent, two leachings two, and pick-up rate 90%, 100 DEG C of drying, 180 DEG C bake.
Embodiment 3
A kind of high antibacterial flame-retardant and anti-static carpet of graphene oxide, the carpet raw material is graphene oxide polyamide 6 Fiber/wool blended yarn, the scribbled include graphene oxide daiamid-6 fiber and wool, the oxidation stone Graphene oxide ratio is 0.7% in black alkene daiamid-6 fiber；The ratio of graphene oxide daiamid-6 fiber and wool is： 40:60, the scribbled is differential imitative hair strong twisted yarn, 207 twists/m of the twist.
The specification of the graphene oxide daiamid-6 fiber is：2.78dtex × 51mm, the graphene oxide polyamide The blending rate of 6 fibers and wool is selected from：10/90th, a kind of blending ratio in 40/60,50/50,60/40,65/35,90/10.
The graphene oxide daiamid-6 fiber is fibre in differentiation, its section configuration is triangle, trilobal, ellipse Shape, X-shaped or Y shape.
The graphene oxide daiamid-6 fiber by in-situ polymerization graphene oxide polyamide 6 flame-retardant and anti-static cut into slices by Melt spinning is made, and graphene oxide content is 0.6%, which has excellent antibacterial flame-retardant antistatic property.
A kind of preparation method according to the high antibacterial flame-retardant and anti-static carpet of the graphene oxide, comprises the following steps： Weave-cut open suede-stamp-evaporating-and wash-arrange-be dehydrated-tentering drying-plucking-bristle-raising-cropping- Bound edge-packaging；
The stamp of flannelette blanket uses acid dyes stamp.
During the arrangement, one or more of organosilicon flexibles in DC-200, KF-96, GE-9981 are used Arrangement is rolled in agent, two leachings two, and pick-up rate 84%, 96 DEG C of drying, 170 DEG C bake.
Graphene oxide daiamid-6 fiber in the present invention provides antibacterial, fire-retardant, antistatic, anti-insect function.Special-shaped oxygen Graphite alkene daiamid-6 fiber reduces reflection, eliminates aurora, strengthens the feel of wool.Heavy twist has mixed yarn, and filoplume is short, overcomes pure sheep The shortcomings that wool yarn line pilling, antifungal gene, feel are abundant.
The antibiotic property of the high antibacterial flame-retardant and anti-static carpet uniqueness of the graphene oxide of the present invention does not produce allergy to human body；Tool There are the dual characteristics of chemical fibre and wool, antibacterial is anti-insect, fire retardant, antistatic is good.Its rational technology, simple, suitable industry metaplasia Production.

Claims (5)

  1. A kind of 1. high antibacterial flame-retardant and anti-static carpet of graphene oxide, it is characterised in that：The carpet raw material is graphite oxide Alkene daiamid-6 fiber/wool blended yarn, the scribbled includes graphene oxide daiamid-6 fiber and wool, described Graphene oxide daiamid-6 fiber in graphene oxide ratio be 0.1-1%；Graphene oxide daiamid-6 fiber and wool Ratio be：10-90:90-10, the scribbled are differential imitative hair strong twisted yarn, 200-210 twists/m of the twist.
  2. 2. the high antibacterial flame-retardant and anti-static carpet of graphene oxide described in accordance with the claim 1, it is characterised in that：The oxidation stone The specification of black alkene daiamid-6 fiber is：2.78dtex × 51mm, the graphene oxide daiamid-6 fiber and wool it is blended Ratio is selected from：10/90th, a kind of blending ratio in 40/60,50/50,60/40,65/35,90/10.
  3. 3. the high antibacterial flame-retardant and anti-static carpet of graphene oxide described in accordance with the claim 1, it is characterised in that：The oxidation stone Black alkene daiamid-6 fiber is fibre in differentiation, its section configuration is triangle, trilobal, ellipse, X-shaped or Y shape.
  4. 4. the high antibacterial flame-retardant and anti-static carpet of graphene oxide described in accordance with the claim 1, it is characterised in that：The oxidation stone Black alkene daiamid-6 fiber is cut into slices by in-situ polymerization graphene oxide polyamide 6 flame-retardant and anti-static and is made by melt spinning, aoxidizes stone Black alkene content is 0.3-0.8%.
  5. 5. the preparation method of the high antibacterial flame-retardant and anti-static carpet of graphene oxide described in accordance with the claim 1, it is characterised in that： Comprise the following steps：Weave-cut open suede-stamp-evaporating-and wash-arrange-be dehydrated-tentering drying-plucking-bristle- Raising-cropping-bound edge-packaging；
    During the stamp, the stamp of flannelette blanket uses acid dyes stamp；
    During the arrangement, using one or more of silicone softening agents in DC-200, KF-96, GE-9981, two Arrangement is rolled in leaching two, and pick-up rate 80-90%, 90-100 DEG C of drying, 150-180 DEG C bakes.
CN201711040729.1A 2017-10-31 2017-10-31 High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof Pending CN107938104A (en)

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CN201711040729.1A CN107938104A (en) 2017-10-31 2017-10-31 High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof
PCT/CN2017/116978 WO2019085191A1 (en) 2017-10-31 2017-12-18 Highly bacteriostatic flame-retardant anti-static carpet with graphene oxide and method for preparing same

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CN201711040729.1A CN107938104A (en) 2017-10-31 2017-10-31 High antibacterial flame-retardant and anti-static carpet of a kind of graphene oxide and preparation method thereof

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CN108754786A (en) * 2018-07-16 2018-11-06 北京赛欧兰阻燃纤维有限公司 A kind of multifunctional flame-proof blanket and preparation method thereof
CN108924976A (en) * 2018-05-29 2018-11-30 湖南省农村科技发展中心 A kind of graphene electricity that suitable special population uses fever heating system
CN109267200A (en) * 2018-09-04 2019-01-25 江苏箭鹿毛纺股份有限公司 A kind of preparation method of the wool blended machine knitting yarn of graphene
CN111041630A (en) * 2019-12-24 2020-04-21 浙江博泰纺织有限公司 Biomass graphene spindle spinning knitting yarn and preparation method thereof
CN111109987A (en) * 2019-12-30 2020-05-08 戴明 Graphene far-infrared heating carpet

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CN110204897A (en) * 2019-06-21 2019-09-06 平顶山华邦工程塑料有限公司 A kind of flame-retardant and anti-static type polyamide compoiste material and preparation method thereof
CN112273750A (en) * 2020-09-25 2021-01-29 上海燕莎服饰有限公司 Double-faced woolen overcoat and manufacturing method thereof
CN112359465A (en) * 2020-10-29 2021-02-12 胡小雪 Preparation method of antibacterial and antiviral textile

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