WO2019085191A1 - Highly bacteriostatic flame-retardant anti-static carpet with graphene oxide and method for preparing same - Google Patents

Highly bacteriostatic flame-retardant anti-static carpet with graphene oxide and method for preparing same Download PDF

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Publication number
WO2019085191A1
WO2019085191A1 PCT/CN2017/116978 CN2017116978W WO2019085191A1 WO 2019085191 A1 WO2019085191 A1 WO 2019085191A1 CN 2017116978 W CN2017116978 W CN 2017116978W WO 2019085191 A1 WO2019085191 A1 WO 2019085191A1
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graphene oxide
fiber
polyamide
flame
wool
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PCT/CN2017/116978
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French (fr)
Chinese (zh)
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黄旭
张炜栋
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江苏工程职业技术学院
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Publication of WO2019085191A1 publication Critical patent/WO2019085191A1/en

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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive

Definitions

  • the invention belongs to the technical field of textile carpet production, and particularly relates to a graphene oxide high antibacterial flame retardant antistatic carpet and a preparation method thereof.
  • Graphene oxide polyamide 6 fiber is a composite fiber prepared by blending graphene oxide with a thermoplastic resin containing an amide group. It has high antibacterial property, high abrasion resistance, moisture absorption and ventilation, superconducting antistatic and so on.
  • the main material of the graphene oxide polyamide 6 fiber is a polyamide 6 resin chip. The pre-formed masterbatch process is used to uniformly disperse the graphene oxide in the polyamide 6 slice, and the melt-spinning and post-spinning treatment results in the inclusion of graphene oxide. Polyamide 6 fiber. Thereby the graphene oxide function is introduced into the polyamide 6 fiber. Compared with the conventional polyamide 6 fiber, the graphene oxide polyamide 6 fiber has obvious improvement in antibacterial and antibacterial properties.
  • carpets do not have antibacterial function.
  • the carpets with antibacterial function use organic antibacterial agents or inorganic heavy metal antibacterial agents to kill harmful single cells, but at the same time cause environmental pollution to the urban environment, and to users. Produces certain allergic effects.
  • the present invention provides a graphene oxide high antibacterial flame retardant antistatic carpet and a preparation method thereof.
  • a graphene oxide high antibacterial flame retardant antistatic carpet the carpet material is oxygen a graphene polyamide 6 fiber/wool blended yarn comprising a graphene oxide polyamide 6 fiber and wool, wherein the graphene oxide polyamide 6 fiber has a graphene oxide ratio of 0.1 to 1%
  • the ratio of the graphene oxide polyamide 6 fiber to the wool is 10-90:90-10
  • the blended yarn is a differential wool-like twist yarn with a twist of 200-210 ⁇ /m.
  • the specification of the graphene oxide polyamide 6 fiber is 2.78 dtex ⁇ 51 mm
  • the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, A blending ratio of 60/40, 65/35, 90/10.
  • the graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
  • the graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame retardant antistatic slice, and the graphene oxide content is 0.3-0.8%, and the polyamide 6 fiber has Excellent antibacterial flame retardant and antistatic properties.
  • the invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
  • the printing of the carpet is printed with an acid dye.
  • one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is carried out, and the rolling rate is 80-90%, 90-100 °C. Dry and bake at 150-180 °C.
  • the graphene oxide polyamide 6 fiber of the present invention provides antibacterial, flame retardant, antistatic, and insect resistant functions.
  • the shaped graphene oxide polyamide 6 fiber reduces reflection, eliminates aurora and enhances the hair feel.
  • the strong twist makes the blended yarn have short hairiness, overcome the shortcomings of the pure wool yarn pilling, anti-wrinkle and rich hand feeling.
  • the unique antibacterial property of the graphene oxide high antibacterial flame retardant antistatic carpet of the invention is not produced to the human body. Sensitive; has the dual characteristics of chemical fiber and wool, antibacterial, insect resistant, flame retardant and antistatic. The process is reasonable and simple, and is suitable for industrial production.
  • a graphene oxide high-bacteriostatic flame-retardant antistatic carpet wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool.
  • the ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 0.1%; the ratio of the graphene oxide polyamide 6 fiber to the wool is: 10:90, and the blended yarn is a differential wool-like twist yarn.
  • the temperature is 200 ⁇ / m.
  • the specification of the graphene oxide polyamide 6 fiber is 2.78 dtex ⁇ 51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
  • the graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
  • the graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.3%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
  • a method for preparing a graphene-based high antibacterial flame-retardant antistatic carpet comprising the following Step: weaving - splitting - printing - steaming - washing - finishing - dehydration - tenter drying - napping - bristles - raising - shearing - wrapping - packaging;
  • the print of the carpet is printed with an acid dye.
  • one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 80%, and the drying is performed at 90 ° C, 150 Baking at °C.
  • a graphene oxide high-bacteriostatic flame-retardant antistatic carpet wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool.
  • the ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 1%; the ratio of graphene oxide polyamide 6 fiber to wool is: 90:10, and the blended yarn is a differentiated imitation wool strong twist yarn.
  • the temperature is 210 ⁇ /m.
  • the specification of the graphene oxide polyamide 6 fiber is 2.78 dtex ⁇ 51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
  • the graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
  • the graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.8%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
  • the invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
  • the print of the carpet is printed with an acid dye.
  • one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 90%, and the drying is performed at 100 ° C. Baking at °C.
  • a graphene oxide high-bacteriostatic flame-retardant antistatic carpet wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool.
  • the ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 0.7%; the ratio of the graphene oxide polyamide 6 fiber to the wool is 40:60, and the blended yarn is a differential wool-like twisted yarn.
  • the temperature is 207 ⁇ / m.
  • the specification of the graphene oxide polyamide 6 fiber is 2.78 dtex ⁇ 51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
  • the graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
  • the graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.6%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
  • the invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
  • the print of the carpet is printed with an acid dye.
  • one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 84%, and the drying is performed at 96 ° C. Baking at °C.
  • the graphene oxide polyamide 6 fiber of the present invention provides antibacterial, flame retardant, antistatic, and insect resistant functions.
  • the shaped graphene oxide polyamide 6 fiber reduces reflection, eliminates aurora and enhances the hair feel.
  • the strong twist makes the blended yarn have short hairiness, overcome the shortcomings of the pure wool yarn pilling, anti-wrinkle and rich hand feeling.
  • the unique antibacterial property of the graphene oxide high antibacterial flame retardant antistatic carpet of the invention is not allergic to the human body; it has the dual characteristics of chemical fiber and wool, and has the advantages of antibacterial, antimony, flame retardant and antistatic property.
  • the process is reasonable and simple, and is suitable for industrial production.

Abstract

Disclosed are a highly bacteriostatic flame-retardant anti-static carpet with graphene oxide and a method for preparing same, wherein graphene oxide polyamide 6 fibers and wool are comprised in the yarns of the graphene oxide highly bacteriostatic flame-retardant antistatic carpet, and the proportion of graphene oxide in the graphene oxide polyamide 6 fibers is 0.3%-0.8%. The ratio of the graphene oxide polyamide 6 fibers to the wool is: 10-90 : 90-10. The unique antimicrobial properties of the graphene oxide highly bacteriostatic flame-retardant antistatic carpet do not cause allergic reactions in humans; and have dual characteristics of chemical fibers and wool, and good antibacterial, worm damage resistant, flame-retardant and antistatic properties. The process therefor is rational and simple, and is suitable for industrial production.

Description

一种氧化石墨烯高抑菌阻燃抗静电地毯及其制备方法Graphene oxide high antibacterial flame retardant antistatic carpet and preparation method thereof 技术领域Technical field
本发明属于纺织地毯生产技术领域，具体涉及一种氧化石墨烯高抑菌阻燃抗静电地毯及其制备方法。The invention belongs to the technical field of textile carpet production, and particularly relates to a graphene oxide high antibacterial flame retardant antistatic carpet and a preparation method thereof.
背景技术Background technique
氧化石墨烯聚酰胺6纤维，是将氧化石墨烯与含有酰胺基团的热塑性树脂共混制备出的一种复合性纤维。具有高抑菌性，耐磨性高、吸湿透气、超导抗静电等特点。氧化石墨烯聚酰胺6纤维的主体材料为聚酰胺6树脂切片，采用预制母粒工艺，将氧化石墨烯均匀的分散在聚酰胺6切片中，经熔融纺丝和后纺处理得到含有氧化石墨烯的聚酰胺6纤维。从而将氧化石墨烯功能引入聚酰胺6纤维中。该氧化石墨烯聚酰胺6纤维与传统聚酰胺6纤维相比，在抗菌抑菌性、抗紫外性等方面都有明显提高。Graphene oxide polyamide 6 fiber is a composite fiber prepared by blending graphene oxide with a thermoplastic resin containing an amide group. It has high antibacterial property, high abrasion resistance, moisture absorption and ventilation, superconducting antistatic and so on. The main material of the graphene oxide polyamide 6 fiber is a polyamide 6 resin chip. The pre-formed masterbatch process is used to uniformly disperse the graphene oxide in the polyamide 6 slice, and the melt-spinning and post-spinning treatment results in the inclusion of graphene oxide. Polyamide 6 fiber. Thereby the graphene oxide function is introduced into the polyamide 6 fiber. Compared with the conventional polyamide 6 fiber, the graphene oxide polyamide 6 fiber has obvious improvement in antibacterial and antibacterial properties.
目前地毯绝大部分不具有抗菌功能，具有抗菌的功能的地毯，采用有机抗菌剂或无机重金属抗菌剂，将有害菌单细胞体杀死，但同时对市内环境造成环境污染，而且对使用者产生一定的过敏效应。At present, most carpets do not have antibacterial function. The carpets with antibacterial function use organic antibacterial agents or inorganic heavy metal antibacterial agents to kill harmful single cells, but at the same time cause environmental pollution to the urban environment, and to users. Produces certain allergic effects.
为了提高地毯使用的安全性，在织造地毯的纱线上进行改进，使地毯自身具有一定的抗菌功能。氧化石墨烯产生“石墨刀”效果，具有良好的抗菌性能，细胞毒性很小对人体不产生过敏。In order to improve the safety of carpet use, improvements are made on the yarn of the woven carpet to give the carpet itself a certain antibacterial function. Graphene oxide produces a "graphite knife" effect, has good antibacterial properties, and has little cytotoxicity and is not allergic to the human body.
发明内容Summary of the invention
发明目的：为了解决现有技术的不足，本发明提供了一种氧化石墨烯高抑菌阻燃抗静电地毯及其制备方法。OBJECT OF THE INVENTION In order to solve the deficiencies of the prior art, the present invention provides a graphene oxide high antibacterial flame retardant antistatic carpet and a preparation method thereof.
技术方案：一种氧化石墨烯高抑菌阻燃抗静电地毯，所述的地毯原料为氧 化石墨烯聚酰胺6纤维/羊毛混纺纱线，所述混纺纱线中包括氧化石墨烯聚酰胺6纤维和羊毛，所述的氧化石墨烯聚酰胺6纤维中氧化石墨烯比例为0.1-1％；氧化石墨烯聚酰胺6纤维和羊毛的比例为：10-90:90-10，所述混纺纱线为差别化仿毛强捻纱，捻度200-210捻/米。Technical solution: a graphene oxide high antibacterial flame retardant antistatic carpet, the carpet material is oxygen a graphene polyamide 6 fiber/wool blended yarn comprising a graphene oxide polyamide 6 fiber and wool, wherein the graphene oxide polyamide 6 fiber has a graphene oxide ratio of 0.1 to 1% The ratio of the graphene oxide polyamide 6 fiber to the wool is 10-90:90-10, and the blended yarn is a differential wool-like twist yarn with a twist of 200-210 捻/m.
进一步的，所述氧化石墨烯聚酰胺6纤维的规格为：2.78dtex×51mm，所述氧化石墨烯聚酰胺6纤维与羊毛的混纺比例选自：10/90、40/60、50/50、60/40、65/35、90/10中的一种混纺比。Further, the specification of the graphene oxide polyamide 6 fiber is 2.78 dtex×51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, A blending ratio of 60/40, 65/35, 90/10.
进一步的，所述氧化石墨烯聚酰胺6纤维为差别化纤维，其断面形状为三角形、三叶形、椭圆形、X形或Y形。Further, the graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
进一步的，所述氧化石墨烯聚酰胺6纤维由原位聚合氧化石墨烯聚酰胺6阻燃抗静电切片由熔融纺丝制得，氧化石墨烯含量为0.3-0.8％，该聚酰胺6纤维具有优异的抗菌阻燃抗静电性能。Further, the graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame retardant antistatic slice, and the graphene oxide content is 0.3-0.8%, and the polyamide 6 fiber has Excellent antibacterial flame retardant and antistatic properties.
一种按照所述的氧化石墨烯高抑菌阻燃抗静电地毯的制备方法，包括以下步骤：织造—剖绒—印花—蒸化—水洗—整理—脱水—拉幅烘干—拉毛—刷毛—起绒—剪毛—包边—包装；The invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
所述的印花的过程中，绒毯的印花采用酸性染料印花。In the printing process, the printing of the carpet is printed with an acid dye.
所述的整理的过程中，使用DC-200、KF-96、GE-9981中的一种或几种有机硅柔软剂，两浸两轧整理，轧液率80-90％，90-100℃烘干，150-180℃焙烘。In the process of finishing, one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is carried out, and the rolling rate is 80-90%, 90-100 °C. Dry and bake at 150-180 °C.
有益效果：本发明中的氧化石墨烯聚酰胺6纤维提供抗菌、阻燃、抗静电、抗虫蛀功能。异形氧化石墨烯聚酰胺6纤维减少反射，消除极光，增强毛感。强捻使混纺纱具有毛羽短、克服纯羊毛纱线起毛起球的缺点、抗折皱、手感丰厚。Advantageous Effects: The graphene oxide polyamide 6 fiber of the present invention provides antibacterial, flame retardant, antistatic, and insect resistant functions. The shaped graphene oxide polyamide 6 fiber reduces reflection, eliminates aurora and enhances the hair feel. The strong twist makes the blended yarn have short hairiness, overcome the shortcomings of the pure wool yarn pilling, anti-wrinkle and rich hand feeling.
本发明的氧化石墨烯高抑菌阻燃抗静电地毯独特的抗菌性不对人体产生过 敏；具有化纤和羊毛的双重特点，抗菌抗虫蛀、阻燃抗静电性好。其工艺合理、简单，适合工业化生产。The unique antibacterial property of the graphene oxide high antibacterial flame retardant antistatic carpet of the invention is not produced to the human body. Sensitive; has the dual characteristics of chemical fiber and wool, antibacterial, insect resistant, flame retardant and antistatic. The process is reasonable and simple, and is suitable for industrial production.
具体实施方式Detailed ways
下面将对本发明实施例中的技术方案进行清楚、完整地描述，以使本领域的技术人员能够更好的理解本发明的优点和特征，从而对本发明的保护范围做出更为清楚的界定。本发明所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例，基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described in the following, so that those skilled in the art can better understand the advantages and features of the present invention, and the scope of the present invention is more clearly defined. The embodiments described herein are merely a part of the embodiments of the present invention, and not all of the embodiments, based on the embodiments of the present invention, all other implementations obtained by those skilled in the art without creative efforts. For example, all fall within the scope of protection of the present invention.
实施例1Example 1
一种氧化石墨烯高抑菌阻燃抗静电地毯，所述的地毯原料为氧化石墨烯聚酰胺6纤维/羊毛混纺纱线，所述混纺纱线中包括氧化石墨烯聚酰胺6纤维和羊毛，所述的氧化石墨烯聚酰胺6纤维中氧化石墨烯比例为0.1％；氧化石墨烯聚酰胺6纤维和羊毛的比例为：10:90，所述混纺纱线为差别化仿毛强捻纱，捻度200捻/米。A graphene oxide high-bacteriostatic flame-retardant antistatic carpet, wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool. The ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 0.1%; the ratio of the graphene oxide polyamide 6 fiber to the wool is: 10:90, and the blended yarn is a differential wool-like twist yarn. The temperature is 200 捻 / m.
所述氧化石墨烯聚酰胺6纤维的规格为：2.78dtex×51mm，所述氧化石墨烯聚酰胺6纤维与羊毛的混纺比例选自：10/90、40/60、50/50、60/40、65/35、90/10中的一种混纺比。The specification of the graphene oxide polyamide 6 fiber is 2.78 dtex×51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
所述氧化石墨烯聚酰胺6纤维为差别化纤维，其断面形状为三角形、三叶形、椭圆形、X形或Y形。The graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
所述氧化石墨烯聚酰胺6纤维由原位聚合氧化石墨烯聚酰胺6阻燃抗静电切片由熔融纺丝制得，氧化石墨烯含量为0.3％，该聚酰胺6纤维具有优异的抗菌阻燃抗静电性能。The graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.3%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
一种按照所述的氧化石墨烯高抑菌阻燃抗静电地毯的制备方法，包括以下 步骤：织造—剖绒—印花—蒸化—水洗—整理—脱水—拉幅烘干—拉毛—刷毛—起绒—剪毛—包边—包装；A method for preparing a graphene-based high antibacterial flame-retardant antistatic carpet according to the above, comprising the following Step: weaving - splitting - printing - steaming - washing - finishing - dehydration - tenter drying - napping - bristles - raising - shearing - wrapping - packaging;
绒毯的印花采用酸性染料印花。The print of the carpet is printed with an acid dye.
所述的整理的过程中，使用DC-200、KF-96、GE-9981中的一种或几种有机硅柔软剂，两浸两轧整理，轧液率80％，90℃烘干，150℃焙烘。In the process of finishing, one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 80%, and the drying is performed at 90 ° C, 150 Baking at °C.
实施例2Example 2
一种氧化石墨烯高抑菌阻燃抗静电地毯，所述的地毯原料为氧化石墨烯聚酰胺6纤维/羊毛混纺纱线，所述混纺纱线中包括氧化石墨烯聚酰胺6纤维和羊毛，所述的氧化石墨烯聚酰胺6纤维中氧化石墨烯比例为1％；氧化石墨烯聚酰胺6纤维和羊毛的比例为：90:10，所述混纺纱线为差别化仿毛强捻纱，捻度210捻/米。A graphene oxide high-bacteriostatic flame-retardant antistatic carpet, wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool. The ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 1%; the ratio of graphene oxide polyamide 6 fiber to wool is: 90:10, and the blended yarn is a differentiated imitation wool strong twist yarn. The temperature is 210捻/m.
所述氧化石墨烯聚酰胺6纤维的规格为：2.78dtex×51mm，所述氧化石墨烯聚酰胺6纤维与羊毛的混纺比例选自：10/90、40/60、50/50、60/40、65/35、90/10中的一种混纺比。The specification of the graphene oxide polyamide 6 fiber is 2.78 dtex×51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
所述氧化石墨烯聚酰胺6纤维为差别化纤维，其断面形状为三角形、三叶形、椭圆形、X形或Y形。The graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
所述氧化石墨烯聚酰胺6纤维由原位聚合氧化石墨烯聚酰胺6阻燃抗静电切片由熔融纺丝制得，氧化石墨烯含量为0.8％，该聚酰胺6纤维具有优异的抗菌阻燃抗静电性能。The graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.8%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
一种按照所述的氧化石墨烯高抑菌阻燃抗静电地毯的制备方法，包括以下步骤：织造—剖绒—印花—蒸化—水洗—整理—脱水—拉幅烘干—拉毛—刷毛—起绒—剪毛—包边—包装；The invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
绒毯的印花采用酸性染料印花。 The print of the carpet is printed with an acid dye.
所述的整理的过程中，使用DC-200、KF-96、GE-9981中的一种或几种有机硅柔软剂，两浸两轧整理，轧液率90％，100℃烘干，180℃焙烘。In the process of finishing, one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 90%, and the drying is performed at 100 ° C. Baking at °C.
实施例3Example 3
一种氧化石墨烯高抑菌阻燃抗静电地毯，所述的地毯原料为氧化石墨烯聚酰胺6纤维/羊毛混纺纱线，所述混纺纱线中包括氧化石墨烯聚酰胺6纤维和羊毛，所述的氧化石墨烯聚酰胺6纤维中氧化石墨烯比例为0.7％；氧化石墨烯聚酰胺6纤维和羊毛的比例为：40:60，所述混纺纱线为差别化仿毛强捻纱，捻度207捻/米。A graphene oxide high-bacteriostatic flame-retardant antistatic carpet, wherein the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 fiber and wool. The ratio of graphene oxide in the graphene oxide polyamide 6 fiber is 0.7%; the ratio of the graphene oxide polyamide 6 fiber to the wool is 40:60, and the blended yarn is a differential wool-like twisted yarn. The temperature is 207 捻 / m.
所述氧化石墨烯聚酰胺6纤维的规格为：2.78dtex×51mm，所述氧化石墨烯聚酰胺6纤维与羊毛的混纺比例选自：10/90、40/60、50/50、60/40、65/35、90/10中的一种混纺比。The specification of the graphene oxide polyamide 6 fiber is 2.78 dtex×51 mm, and the blend ratio of the graphene oxide polyamide 6 fiber to the wool is selected from: 10/90, 40/60, 50/50, 60/40. A blending ratio of 65/35, 90/10.
所述氧化石墨烯聚酰胺6纤维为差别化纤维，其断面形状为三角形、三叶形、椭圆形、X形或Y形。The graphene oxide polyamide 6 fiber is a differentiated fiber having a triangular, trilobal, elliptical, X-shaped or Y-shaped cross-sectional shape.
所述氧化石墨烯聚酰胺6纤维由原位聚合氧化石墨烯聚酰胺6阻燃抗静电切片由熔融纺丝制得，氧化石墨烯含量为0.6％，该聚酰胺6纤维具有优异的抗菌阻燃抗静电性能。The graphene oxide polyamide 6 fiber is obtained by melt spinning from an in-situ polymerized graphene oxide polyamide 6 flame-retardant antistatic slice, and the graphene oxide content is 0.6%, and the polyamide 6 fiber has excellent antibacterial flame retardancy. Antistatic properties.
一种按照所述的氧化石墨烯高抑菌阻燃抗静电地毯的制备方法，包括以下步骤：织造—剖绒—印花—蒸化—水洗—整理—脱水—拉幅烘干—拉毛—刷毛—起绒—剪毛—包边—包装；The invention relates to a preparation method of the high antibacterial flame-retardant antistatic carpet of graphene oxide, comprising the following steps: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - napping - bristles - Fleece-shearing-enveloping-packaging;
绒毯的印花采用酸性染料印花。The print of the carpet is printed with an acid dye.
所述的整理的过程中，使用DC-200、KF-96、GE-9981中的一种或几种有机硅柔软剂，两浸两轧整理，轧液率84％，96℃烘干，170℃焙烘。In the process of finishing, one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is performed, the rolling rate is 84%, and the drying is performed at 96 ° C. Baking at °C.
本发明中的氧化石墨烯聚酰胺6纤维提供抗菌、阻燃、抗静电、抗虫蛀功能。 异形氧化石墨烯聚酰胺6纤维减少反射，消除极光，增强毛感。强捻使混纺纱具有毛羽短、克服纯羊毛纱线起毛起球的缺点、抗折皱、手感丰厚。The graphene oxide polyamide 6 fiber of the present invention provides antibacterial, flame retardant, antistatic, and insect resistant functions. The shaped graphene oxide polyamide 6 fiber reduces reflection, eliminates aurora and enhances the hair feel. The strong twist makes the blended yarn have short hairiness, overcome the shortcomings of the pure wool yarn pilling, anti-wrinkle and rich hand feeling.
本发明的氧化石墨烯高抑菌阻燃抗静电地毯独特的抗菌性不对人体产生过敏；具有化纤和羊毛的双重特点，抗菌抗虫蛀、阻燃抗静电性好。其工艺合理、简单，适合工业化生产。 The unique antibacterial property of the graphene oxide high antibacterial flame retardant antistatic carpet of the invention is not allergic to the human body; it has the dual characteristics of chemical fiber and wool, and has the advantages of antibacterial, antimony, flame retardant and antistatic property. The process is reasonable and simple, and is suitable for industrial production.

Claims (5)

  1. 一种氧化石墨烯高抑菌阻燃抗静电地毯，其特征在于：所述的地毯原料为氧化石墨烯聚酰胺6纤维/羊毛混纺纱线，所述混纺纱线中包括氧化石墨烯聚酰胺6纤维和羊毛，所述的氧化石墨烯聚酰胺6纤维中氧化石墨烯比例为0.1-1％；氧化石墨烯聚酰胺6纤维和羊毛的比例为：10-90:90-10，所述混纺纱线为差别化仿毛强捻纱，捻度200-210捻/米。A graphene-based high-bacteriostatic flame-retardant antistatic carpet, characterized in that: the carpet material is a graphene oxide polyamide 6 fiber/wool blend yarn, and the blended yarn comprises graphene oxide polyamide 6 Fiber and wool, the graphene oxide polyamide 6 fiber has a ratio of graphene oxide of 0.1-1%; the ratio of graphene oxide polyamide 6 fiber to wool is 10-90:90-10, the blended yarn The line is a differentiated, wool-like crepe with a twist of 200-210 ft/m.
  2. 按照权利要求1所述的氧化石墨烯高抑菌阻燃抗静电地毯，其特征在于：所述氧化石墨烯聚酰胺6纤维的规格为：2.78dtex×51mm，所述氧化石墨烯聚酰胺6纤维与羊毛的混纺比例选自：10/90、40/60、50/50、60/40、65/35、90/10中的一种混纺比。The graphene oxide high antibacterial flame-retardant antistatic carpet according to claim 1, wherein the graphene oxide polyamide 6 fiber has a specification of 2.78 dtex × 51 mm, and the graphene oxide polyamide 6 fiber. The blend ratio with wool is selected from a blend ratio of 10/90, 40/60, 50/50, 60/40, 65/35, 90/10.
  3. 按照权利要求1所述的氧化石墨烯高抑菌阻燃抗静电地毯，其特征在于：所述氧化石墨烯聚酰胺6纤维为差别化纤维，其断面形状为三角形、三叶形、椭圆形、X形或Y形。The graphene oxide high antibacterial flame-retardant antistatic carpet according to claim 1, wherein the graphene oxide polyamide 6 fiber is a differentiated fiber, and the cross-sectional shape thereof is a triangle, a trilobal shape, an elliptical shape, X or Y shape.
  4. 按照权利要求1所述的氧化石墨烯高抑菌阻燃抗静电地毯，其特征在于：所述氧化石墨烯聚酰胺6纤维由原位聚合氧化石墨烯聚酰胺6阻燃抗静电切片由熔融纺丝制得，氧化石墨烯含量为0.3-0.8％。The graphene oxide high bacteriostatic flame-retardant antistatic carpet according to claim 1, wherein the graphene oxide polyamide 6 fiber is melt-spun by in-situ polymerization of graphene oxide polyamide 6 flame retardant antistatic slice Made of silk, the graphene oxide content is 0.3-0.8%.
  5. 按照权利要求1所述的氧化石墨烯高抑菌阻燃抗静电地毯的制备方法，其特征在于：包括以下步骤：织造—剖绒—印花—蒸化—水洗—整理—脱水—拉幅烘干—拉毛—刷毛—起绒—剪毛—包边—包装；The method for preparing a graphene oxide high-bacteriostatic flame-retardant antistatic carpet according to claim 1, comprising the steps of: weaving - splitting - printing - steaming - washing - finishing - dehydrating - tenter drying - pulling hair - bristles - raising - shearing - wrapping - packaging;
    所述的印花的过程中，绒毯的印花采用酸性染料印花；In the process of printing, the printing of the carpet is printed with an acid dye;
    所述的整理的过程中，使用DC-200、KF-96、GE-9981中的一种或几种有机硅柔软剂，两浸两轧整理，轧液率80-90％，90-100℃烘干，150-180℃焙烘。 In the process of finishing, one or several silicone softeners of DC-200, KF-96 and GE-9981 are used, and two-dip two-rolling finishing is carried out, and the rolling rate is 80-90%, 90-100 °C. Dry and bake at 150-180 °C.
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CN102168370A (en) * 2011-01-11 2011-08-31 中国科学院上海应用物理研究所 Antibacterial fabric and preparing method thereof
US20130075326A1 (en) * 2011-09-27 2013-03-28 Electronics And Telecommunications Research Institute Filter fabrication method and the filter formed thereby
CN105463598A (en) * 2015-11-16 2016-04-06 四川大学 Graphite-enhanced ultrafine synthetic leather fiber

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CN110204897A (en) * 2019-06-21 2019-09-06 平顶山华邦工程塑料有限公司 A kind of flame-retardant and anti-static type polyamide compoiste material and preparation method thereof
CN112273750A (en) * 2020-09-25 2021-01-29 上海燕莎服饰有限公司 Double-faced woolen overcoat and manufacturing method thereof
CN112359465A (en) * 2020-10-29 2021-02-12 胡小雪 Preparation method of antibacterial and antiviral textile

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