CN107706382B - 一种片状钠锰氧化物及其制备方法与应用 - Google Patents
一种片状钠锰氧化物及其制备方法与应用 Download PDFInfo
- Publication number
- CN107706382B CN107706382B CN201710888897.XA CN201710888897A CN107706382B CN 107706382 B CN107706382 B CN 107706382B CN 201710888897 A CN201710888897 A CN 201710888897A CN 107706382 B CN107706382 B CN 107706382B
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- China
- Prior art keywords
- manganese oxide
- sodium manganese
- electrode
- flaky
- sheet
- Prior art date
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- IKULXUCKGDPJMZ-UHFFFAOYSA-N sodium manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Na+] IKULXUCKGDPJMZ-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000002242 deionisation method Methods 0.000 claims abstract description 17
- 239000011572 manganese Substances 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 238000001291 vacuum drying Methods 0.000 claims abstract description 11
- 239000000725 suspension Substances 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 239000000376 reactant Substances 0.000 claims abstract description 4
- 238000007789 sealing Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- 239000007772 electrode material Substances 0.000 claims description 9
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- 239000006230 acetylene black Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002033 PVDF binder Substances 0.000 claims description 3
- 239000003990 capacitor Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000003011 anion exchange membrane Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000010612 desalination reaction Methods 0.000 abstract description 10
- 239000013535 sea water Substances 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000003837 high-temperature calcination Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000007630 basic procedure Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201710888897.XA CN107706382B (zh) | 2017-09-27 | 2017-09-27 | 一种片状钠锰氧化物及其制备方法与应用 |
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CN201710888897.XA CN107706382B (zh) | 2017-09-27 | 2017-09-27 | 一种片状钠锰氧化物及其制备方法与应用 |
Publications (2)
Publication Number | Publication Date |
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CN107706382A CN107706382A (zh) | 2018-02-16 |
CN107706382B true CN107706382B (zh) | 2019-12-10 |
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CN201710888897.XA Active CN107706382B (zh) | 2017-09-27 | 2017-09-27 | 一种片状钠锰氧化物及其制备方法与应用 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103065806A (zh) * | 2013-01-31 | 2013-04-24 | 武汉理工大学 | 钠离子嵌入型二氧化锰纳米片电极及其制备方法和应用 |
CN104828869A (zh) * | 2015-05-08 | 2015-08-12 | 湖南汇通科技有限责任公司 | 一种钠锰氧化物微粉及其制备方法 |
CN105990043A (zh) * | 2015-03-02 | 2016-10-05 | 江南石墨烯研究院 | 一种应用于电容式去离子的高效多孔薄膜电极的制备方法 |
-
2017
- 2017-09-27 CN CN201710888897.XA patent/CN107706382B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103065806A (zh) * | 2013-01-31 | 2013-04-24 | 武汉理工大学 | 钠离子嵌入型二氧化锰纳米片电极及其制备方法和应用 |
CN105990043A (zh) * | 2015-03-02 | 2016-10-05 | 江南石墨烯研究院 | 一种应用于电容式去离子的高效多孔薄膜电极的制备方法 |
CN104828869A (zh) * | 2015-05-08 | 2015-08-12 | 湖南汇通科技有限责任公司 | 一种钠锰氧化物微粉及其制备方法 |
Non-Patent Citations (2)
Title |
---|
"Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques";Jaehan Lee, et al.;《Energy Environ. Sci.》;20140820;第7卷;第3683-3689页 * |
"Sodium Manganese Oxide Nanobelts with a 2 × 4 Tunnel Structure: One-Step Hydrothermal Synthesis and Electrocatalytic Properties";Xiong Zhang, et al.;《J. Nanosci. Nanotechnol.》;20091231;第9卷;第5860-5864页 * |
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CN107706382A (zh) | 2018-02-16 |
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Inventor after: Dan Yuanyuan Inventor after: Teng Teng Inventor after: Sha Chunfan Inventor after: Gu Leixiang Inventor after: Ge Chichao Inventor after: Hu Ronghua Inventor before: Teng Teng Inventor before: Sha Chunfan Inventor before: Gu Leixiang Inventor before: Ge Chichao Inventor before: Hu Ronghua Inventor before: Dan Yuanyuan |