CN107207999B - 增白组合物 - Google Patents
增白组合物 Download PDFInfo
- Publication number
- CN107207999B CN107207999B CN201580047015.6A CN201580047015A CN107207999B CN 107207999 B CN107207999 B CN 107207999B CN 201580047015 A CN201580047015 A CN 201580047015A CN 107207999 B CN107207999 B CN 107207999B
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- Prior art keywords
- detergent composition
- laundry detergent
- alkyl
- weight
- negatively charged
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 68
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003205 fragrance Substances 0.000 claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000003599 detergent Substances 0.000 claims description 37
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 102000004190 Enzymes Human genes 0.000 claims description 16
- 108090000790 Enzymes Proteins 0.000 claims description 16
- 229940088598 enzyme Drugs 0.000 claims description 15
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 10
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- 108010059892 Cellulase Proteins 0.000 claims description 8
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- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 8
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 7
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- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims description 6
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- XEJGJTYRUWUFFD-FNORWQNLSA-N (e)-1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-FNORWQNLSA-N 0.000 claims description 4
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- WLJVXDMOQOGPHL-UHFFFAOYSA-N benzyl-alpha-carboxylic acid Natural products OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 4
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
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- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims description 4
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- JZQOJFLIJNRDHK-UHFFFAOYSA-N (+)-(1S,5R)-cis-alpha-irone Natural products CC1CC=C(C)C(C=CC(C)=O)C1(C)C JZQOJFLIJNRDHK-UHFFFAOYSA-N 0.000 claims description 2
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 claims description 2
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 claims description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 2
- GQAQVQSNGPADES-UHFFFAOYSA-N 1,3,5-tributyl-2-(2,4,6-tributylphenoxy)benzene Chemical compound CCCCC1=CC(CCCC)=CC(CCCC)=C1OC1=C(CCCC)C=C(CCCC)C=C1CCCC GQAQVQSNGPADES-UHFFFAOYSA-N 0.000 claims description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 claims description 2
- WGPCZPLRVAWXPW-NSHDSACASA-N 5-octyloxolan-2-one Chemical compound CCCCCCCC[C@H]1CCC(=O)O1 WGPCZPLRVAWXPW-NSHDSACASA-N 0.000 claims description 2
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 claims description 2
- PDEQKAVEYSOLJX-UHFFFAOYSA-N Hexahydronerolidol Natural products C1C2C3(C)C2CC1C3(C)CCC=C(CO)C PDEQKAVEYSOLJX-UHFFFAOYSA-N 0.000 claims description 2
- QLRICECRKJGSKQ-SDNWHVSQSA-N [(2e)-3,7-dimethylocta-2,6-dienyl] 2-aminobenzoate Chemical compound CC(C)=CCC\C(C)=C\COC(=O)C1=CC=CC=C1N QLRICECRKJGSKQ-SDNWHVSQSA-N 0.000 claims description 2
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- PDEQKAVEYSOLJX-AIEDFZFUSA-N alpha-Santalol Natural products CC(=CCC[C@@]1(C)[C@H]2C[C@@H]3[C@H](C2)[C@]13C)CO PDEQKAVEYSOLJX-AIEDFZFUSA-N 0.000 claims description 2
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 claims description 2
- PDEQKAVEYSOLJX-BKKZDLJQSA-N alpha-santalol Chemical compound C1C2[C@]3(C)C2C[C@H]1[C@@]3(C)CC/C=C(CO)/C PDEQKAVEYSOLJX-BKKZDLJQSA-N 0.000 claims description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 2
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 claims description 2
- 229940026455 cedrol Drugs 0.000 claims description 2
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 claims description 2
- AHZYNUWTBDLJHG-RHBQXOTJSA-N cedryl formate Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](OC=O)(C)CC2 AHZYNUWTBDLJHG-RHBQXOTJSA-N 0.000 claims description 2
- 235000000484 citronellol Nutrition 0.000 claims description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims description 2
- GCFAUZGWPDYAJN-UHFFFAOYSA-N cyclohexyl 3-phenylprop-2-enoate Chemical compound C=1C=CC=CC=1C=CC(=O)OC1CCCCC1 GCFAUZGWPDYAJN-UHFFFAOYSA-N 0.000 claims description 2
- WGPCZPLRVAWXPW-LLVKDONJSA-N gamma-Dodecalactone Natural products CCCCCCCC[C@@H]1CCC(=O)O1 WGPCZPLRVAWXPW-LLVKDONJSA-N 0.000 claims description 2
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 2
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- 239000000344 soap Substances 0.000 claims description 2
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- 238000005282 brightening Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 12
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- 239000002585 base Substances 0.000 description 8
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- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
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- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
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- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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Abstract
本发明提供了一种家用洗衣用增白和增亮组合物，其包含带电荷的表面活性剂、带负电荷的烷氧基化多烷基苯酚和香料。
Description
技术领域
本发明涉及增白和增亮洗衣组合物的用途。
发明背景
在家庭洗衣过程中期望保持和改善织物的白度和亮度。问题是从一件衣服上除去的污垢又沉积到另一件衣服上。该问题由于衣服上和洗涤中存在的人油(皮脂)加剧，其有助于增强洗涤中的污垢的沉积。该过程导致整个洗涤加载物的白度和清洁的整体损失。为了改善这个问题，分散聚合物例如烷氧基化聚乙烯亚胺已被广泛地加入到洗涤剂中。已知乙氧基化PEI(PEI＝聚乙烯亚胺)是来自CA1210009的抗再沉积聚合物。某些纤维素酶也通过改变棉织物的表面性质已经用于防止再沉积。Novozymes在WO02/099091和WO04/053039中描述了用于家庭洗衣的纤维素酶。
EP1321510(Shipley)描述了一种含有烷氧基化多芳基苯酚的工业清洁组合物，用于从制造半导体和其它电子器件和电路中使用的光致抗蚀剂中剥离有机化学残留物。有机化学残留物是生产过程中剩余的材料，包括光引发剂、热引发剂、丙烯酸和甲基丙烯酸单体。
发明内容
需要进一步的技术以减少家庭洗衣产品中的再沉积并增强清洁。
我们已经发现，带负电荷的烷氧基化多烷基苯酚在家庭洗衣过程中增强衣服的白度和亮度。
在一个方面，本发明提供了一种洗衣用洗涤剂组合物，其包含：
(i)带电荷的表面活性剂，带电荷的表面活性剂的水平优选为4-50重量％，更优选为6-30重量％，最优选为8-20重量％；
(ii)带负电荷的烷氧基化多烷基苯酚，其水平优选为0.1-20重量％，更优选0.5-10重量％，最优选2-9重量％；和
(iii)香料，优选0.05-0.5重量％的香料。
在另一方面，本发明提供了一种洗衣用洗涤剂组合物，其包含：
(i)4-50重量％、优选6-30重量％、更优选8-20重量％的阴离子表面活性剂，其选自：线性烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐和它们的混合物；
(ii)0.5-10重量％，优选2-9重量％的具有以下结构的带负电荷的烷氧基化多烷基苯酚：
其中R选自SO3、COO-和PO3 2-，优选选自SO3 -和COO-；
其中n选自：6、7、8、9、10、11、12、13、14、15、16、17、18、19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39、40、41、42、43、44、45、46、47、48、49和50；和
(iii)香料，优选0.05-0.5重量％的香料。
在另一方面，本发明提供了一种处理织物的家用方法，所述方法包括以下步骤：
(i)用带负电荷的烷氧基化多烷基苯酚的水溶液处理织物，所述水溶液包含10ppm至5000ppm的带负电荷的烷氧基化多烷基苯酚；和0.0-6g/L，优选0.2-4g/L的一种或多种表面活性剂；和
(ii)任选地漂洗和干燥所述织物。
在该方法中，水溶液中的香料的水平优选为0.1-100ppm，更优选为1-10ppm。
在本发明的方法方面，使用的表面活性剂优选为对于本发明的组合物方面是优选的。
织物优选是衣服、床上用品或桌布的一项。优选的衣服是含棉衬衫、裤子、内衣裤和连裤装(jumper)。
发明详述
烷氧基化多烷基苯酚
优选地，带负电荷的烷氧基化多烷基苯酚是带负电荷的烷氧基化三烷基苯酚，最优选烷氧基化三(正丁基)苯酚。
优选地，带负电荷的烷氧基化三烷基苯酚是带负电荷的聚乙二醇单(2,4,6-三(正丁基)苯基)醚。
优选地，带负电荷的烷氧基化多烷基苯酚含有平均2-70个烷氧基，最优选6-50个烷氧基。
优选地，烷氧基化是乙氧基化。
烷氧基化多烷基苯酚中的烷基优选选自线性或支链C3-C15烷基。
优选地，带负电荷的烷氧基化多烷基苯酚具有连接到苯酚上的3个烷基。优选地，它们在苯酚上的2、4、6位。烷氧基化物连接到1位。
优选地，烷氧基化物被选自SO3 -、COO-和PO3 2-，优选选自SO3 -和COO-的带负电荷的基团封端。
烷氧基化多烷基苯酚中的烷基优选选自线性或支链C3-C15烷基。
最优选地，烷氧基化聚乙二醇单(2,4,6-三(正丁基)苯基)醚是具有以下结构的带负电荷的烷氧基化多烷基苯酚：
其中R选自SO3、COO-和PO3 2-，优选选自SO3 -和COO-；最优选SO3 -。
优选n＝2-70，更优选n＝6-50，甚至更优选n＝6-18。
符号n是聚烷氧基链中烷氧基单元的平均摩尔数。
化合物可从工业供应商获得，例如来自Rhodia、Clariant、Aoki Oil、Stepan和TOHO Chemical Industry Co。
在本发明的上下文中，带负电荷的烷氧基化多烷基苯酚不被认为是表面活性剂，并且不对本文定义的表面活性剂在数值上起作用。
表面活性剂
洗衣组合物包含带电荷的表面活性剂，并且最优选带电荷的表面活性剂是阴离子表面活性剂(其包括其的混合物)。
可以使用的合适的阴离子洗涤剂化合物通常是具有含约8至约22个碳原子的烷基的有机硫酸盐和磺酸盐的水溶性碱金属盐，术语烷基用于包括高级烷基的烷基部分。
合适的合成阴离子洗涤剂化合物的实例是烷基硫酸钠和烷基硫酸钾，特别是通过硫酸化例如由牛油或椰子油制得的高级C8-C18醇获得的那些，烷基C9-C20苯磺酸钠和苯磺酸钾，特别是线性仲烷基C10-C15苯磺酸钠；和烷基甘油醚硫酸钠，特别是衍生自牛油或椰子油的高级醇和衍生自石油的合成醇的醚。
阴离子表面活性剂优选选自：线性烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐、皂、烷基(优选甲基)酯磺酸盐及其混合物。
最优选的阴离子表面活性剂选自：线性烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物。优选地，烷基醚硫酸盐是平均具有1至3个EO(乙氧基化物)单元的C12-C14正烷基醚硫酸盐。月桂基醚硫酸钠是特别优选的(SLES)。优选地，线性烷基苯磺酸盐是C11-C15烷基苯磺酸钠。优选地，烷基硫酸盐是线性或支链C12-C18烷基硫酸钠。十二烷基硫酸钠是特别优选的(SDS，也称为伯烷基硫酸盐)。
洗衣组合物中的阴离子表面活性剂的水平优选为4-50重量％，更优选为6-30重量％，最优选为8-20重量％。
优选存在两种或更多种阴离子表面活性剂，例如线性烷基苯磺酸盐与烷基醚硫酸盐。
优选地，除了阴离子表面活性剂之外，洗衣组合物还包含烷基乙氧基化的非离子表面活性剂，优选2-8重量％的烷基烷氧基化，优选乙氧基化的，非离子表面活性剂。
可以使用的合适的非离子洗涤剂化合物特别包括具有脂族疏水基团和反应性氢原子的化合物的反应产物，例如脂族醇、酸或酰胺，特别是单独的环氧乙烷或环氧乙烷与环氧丙烷。具体的非离子洗涤剂化合物是脂族C8-C18伯或仲线性或支链醇与环氧乙烷的缩合产物。
优选地，烷基乙氧基化非离子表面活性剂是平均乙氧基化度为7EO至9EO单元的C8-C18伯醇。
表面活性剂体系的非离子和阴离子表面活性剂可以选自描述于“Surface ActiveAgents”卷1,Schwartz&Perry,Interscience 1949,卷2,Schwartz,Perry&Berch,Interscience 1958,由Manufacturing Confectioners公司出版的“McCutcheon'sEmulsifiers and Detergents”的当前版本或“Tenside-Taschenbuch”,H.Stache，第2版，Carl Hauser Verlag,1981中的表面活性剂。
优选地，使用的表面活性剂是饱和的。
还可使用例如EP-A-328 177(Unilever)中描述的表现出抗盐析性的那些表面活性剂、EP-A-070 074中描述的烷基多糖苷表面活性剂和烷基单糖苷。
在另一方面，带电荷的表面活性剂可以是阳离子的，使得制剂是织物调理剂。然而，基于阴离子或阴离子/非离子表面活性剂的洗涤剂组合物是更优选的实施方案。
阳离子化合物
当本发明用作织物调理剂时，它需要含有阳离子化合物。
最优选的是季铵化合物。
如果季铵化合物是具有至少一个C12至C22烷基链的季铵化合物，则是有利的。
优选地，季铵化合物具有下式：
其中R1是C12-C22烷基或烯基链；R2、R3和R4独立地选自C1-C4烷基链，且X-是可相容的阴离子。这种类型的优选化合物是季铵化合物十六烷基三甲基季铵溴化物。
用于本发明的第二类材料是上述结构的季铵，其中R1和R2独立地选自C12-C22烷基或烯基链；R3和R4独立地选自C1-C4烷基链，且X-是可相容的阴离子。
组合物任选地包含硅树脂。
助洗剂或络合剂
助洗剂材料可以选自1)钙螯合剂材料，2)沉淀材料，3)钙离子交换材料和4)其混合物。
钙螯合剂助洗剂材料的实例包括碱金属多磷酸盐例如三聚磷酸钠，和有机多价螯合剂例如乙二胺四乙酸。
沉淀助剂材料的实例包括正磷酸钠和碳酸钠。
钙离子交换助洗剂材料的实例包括各种类型的水不溶性结晶或无定形铝硅酸盐，其中沸石是众所周知的代表，例如沸石A、沸石B(也称为沸石P)、沸石C、沸石X、沸石Y以及如EP-A-0384070中所述的沸石P型。
组合物还可以含有0-65％的助洗剂或络合剂，例如乙二胺四乙酸、二亚乙基三胺五乙酸、烷基或烯基琥珀酸、次氮基三乙酸或下面提及的其他助洗剂。由于具有络合金属离子的能力，许多助洗剂也是漂白稳定剂。
沸石和碳酸盐(碳酸盐(包括碳酸氢盐和倍半碳酸盐))是优选的助洗剂，其中碳酸盐是特别优选的。
该组合物可含有作为助洗剂的结晶铝硅酸盐，优选碱金属铝硅酸盐，更优选铝硅酸钠。这通常以小于15％w的水平存在。铝硅酸盐是具有下式的材料：
0.8-1.5M2O；Al2O3；0.8-6SiO2。
其中M是一价阳离子，优选钠。这些材料含有一些结合水，并且需要具有至少50mgCaO/g的钙离子交换能力。优选的铝硅酸钠在上式中含有1.5-3.5个SiO2单元。它们可以通过硅酸钠和铝酸钠之间的反应容易地制备，如文献中充分描述的。表面活性剂与铝硅酸盐(当存在时)的比例优选大于5:2，更优选大于3:1。
可选地，或除了硅铝酸盐助洗剂之外，还可以使用磷酸盐助洗剂。在本领域中，术语“磷酸盐”包括磷酸氢盐、三磷酸盐和膦酸盐物质。其他形式的助洗剂包括硅酸盐，例如可溶性硅酸盐、偏硅酸盐、层状硅酸盐(例如来自Hoechst的SKS-6)。
优选地，洗衣用洗涤剂制剂是非磷酸盐作为助剂的洗衣用洗涤剂制剂，即含有小于1重量％的磷酸盐。优选的粉末洗衣用洗涤剂制剂主要是由碳酸盐作为助剂。粉末应优选以pH 9.5-11使用。
最优选地，洗衣用洗涤剂是水性液体洗衣用洗涤剂，优选具有7-9的pH。
在水性液体洗衣用洗涤剂中，优选单丙二醇以1-30重量％，最优选2-18重量％的水平存在，以提供具有适当的可倾倒粘度的制剂。
荧光剂
组合物优选包含荧光剂(荧光增白剂)。荧光剂是众所周知的，许多这样的荧光剂可商购获得。通常，这些荧光剂以其碱金属盐例如钠盐的形式提供和使用。
优选的荧光剂的类型是：二苯乙烯基联苯化合物例如Tinopal(商标)CBS-X，二胺芪二磺酸化合物例如Tinopal DMS pure Xtra和Blankophor(商标)HRH，以及吡唑啉化合物例如Blankophor SN。
优选的荧光增白剂是：2-(4-苯乙烯基-3-磺基苯基)-2H-萘酚[1,2-d]***钠，4,4'-双{[(4-苯胺基-6(N甲基-N-2-羟乙基)氨基1,3,5-三嗪-2-基)]氨基}芪-2-2'二磺酸二钠，4,4'-双{[(4-苯胺基-6-吗啉代-1,3,5-三嗪-2-基)]氨基}芪-2-2'-二磺酸二钠和4,4'-双(2-磺基苯乙烯基)联苯二钠。
香料
组合物包含香料。香料优选在0.001-3wt％，更优选0.05-0.5wt％，最优选0.1-1wt％的范围内。许多合适的香料实例提供在由CFTA Publications出版的CTFA(Cosmetic，Toiletry and Fragrance Association)1992International Buyers Guide和由SchnellPublishing Co.出版的OPD 1993Chemicals Buyers Directory 80th Annual Edition中。
优选地，香料包含以下至少一种香料(化合物)：α-异甲基紫罗兰酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基-戊酸乙酯；辛醛；乙酸苄酯；1,6-辛二烯-3-醇，3,7-二甲基-3-乙酸酯；环己醇，2-(1,1-二甲基乙基)-,1-乙酸酯；δ-突厥酮(delta-damascone)；β-紫罗兰酮；乙酸三环癸烯酯；十二烷醛；己基肉桂醛；环十五内酯；苯乙酸，2-苯乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；苯甲酸β-苯乙酯；α-檀香醇；雪松醇；醋酸柏木酯；甲酸柏木酯；水杨酸环己酯；γ-十二内酯；和苯乙酸β-苯乙酯。
香料的有用组分包括天然和合成来源的材料。它们包括单一化合物和混合物。这些组分的具体实例可以在现有文献中找到，例如Fenaroli's Handbook of FlavorIngredients,1975,CRC Press；Synthetic Food Adjuncts,1947,M.B.Jacobs,编辑VanNostrand；或Perfume and Flavor Chemicals,S.Arctander 1969,Montclair,N.J.(USA)。
通常，多种香料组分存在于制剂中。在本发明的组合物中，设想将存在四种或更多种，优选五种或更多种，更优选六种或更多种或甚至七种或更多种不同的香料组分。
在香料混合物中，优选15-25重量％的头香香料。头香香料由Poucher(Journal ofthe Society of Cosmetic Chemists 6(2)：80[1955])定义。优选的头香香料选自柑橘油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、玫瑰醚和顺式-3-己醇。
国际香料协会在2011年公布了芳香成分(香料)的列表(http://www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)。
芳香材料研究所提供了有安全信息的香料(芳香剂)数据库。
头香香料可用于提示本发明的白度和亮度益处。
一些或所有香料可以被包封，包封有利的典型的香料组分包括具有相对低沸点的那些，优选沸点小于300℃、优选100-250℃的那些。包封具有低CLog P(即具有被分配到水中的更大倾向的那些)的香料组分，优选具有小于3.0的CLog P的香料组分也是有利的。这些具有相对低沸点和相对低CLogP的材料被称为“延迟释香”香料成分，并且包括一种或多种以下材料：
己酸烯丙酯，乙酸戊酯，丙酸戊酯，大茴香醛，苯甲醚，苯甲醛，乙酸苄酯，苄基丙酮，苯甲醇，甲酸苄酯，异戊酸苄酯，丙酸苄酯，β-γ-己烯醇，樟脑胶，左旋香芹酮，右旋香芹酮，肉桂醇，甲酸肉桂酯，顺式-茉莉酮，顺式-3-己烯基乙酸酯，孜然醇，2,4-二甲基-3-环己-1-烯羰醛(cyclal C)，二甲基苄基甲醇，二甲基苄基甲醇乙酸酯，乙酸乙酯，乙酰乙酸乙酯，乙基戊基酮，苯甲酸乙酯，丁酸乙酯，乙基己基酮，苯乙酸乙酯，桉油醇，丁子香酚，乙酸葑酯，弗洛尔(Flor)乙酸酯(乙酸三环癸烯基酯)，Frutene(丙酸三环癸基酯)，香叶醇，己烯醇，乙酸己烯酯，乙酸己酯，甲酸己酯，龙葵醇(Hydratropic Alcohol)，羟基香茅醛，二氢茚酮，异戊醇，异薄荷酮，乙酸异胡薄荷酯，异喹诺酮，女贞醛，芳樟醇，芳樟醇氧化物，甲酸芳樟酯，簿荷酮，薄荷基苯乙酮，甲基戊基酮，邻氨基苯甲酸甲酯，苯甲酸甲酯，苯乙酸甲酯，甲基丁子香酚，甲基庚烯酮，庚炔羧酸甲酯，甲基庚基酮，甲基己基酮，乙酸甲基苯基原酯，水杨酸甲酯，甲基-N-甲基邻氨基苯甲酸酯，橙花醇，辛内酯，辛醇，对甲酚，对甲酚甲醚，对甲氧基苯乙酮，对甲基苯乙酮，苯氧基乙醇，苯基乙醛，苯基乙基乙酸酯，苯基乙基醇，苯基乙基二甲基甲醇，乙酸戊烯酯，硼酸丙酯，蒲勒酮，玫瑰醚，黄樟素，4-萜品醇，α-萜品醇和/或锰红柱石。通常，多种香料组分存在于制剂中。在本发明的组合物中，设想将存在四种或更多种，优选五种或更多种，更优选六种或更多种，或甚至七种或更多种不同的香料组分，其来自上面给出的延迟释香香料。
本发明可以应用的另一组香料是所谓的“芳香疗法”材料。这些包括也用于香料中的许多组分，包括精油组分，例如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻提取物、橙花油、肉豆蔻、绿薄荷、甜紫叶和缬草。
优选的是，衣物处理组合物不含有过氧漂白剂，例如过碳酸钠、过硼酸钠和过酸。
聚合物
组合物可以包含一种或多种另外的聚合物。实例是羧甲基纤维素，聚(乙二醇)，聚(乙烯醇)，聚羧酸酯如聚丙烯酸酯，马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。
可存在用于防止染料沉积的聚合物，例如聚(乙烯基吡咯烷酮)、聚(乙烯基吡啶-N-氧化物)和聚(乙烯基咪唑)。
酶
当实施本发明的方法时一种或多种酶优选存在于本发明的洗衣组合物中。
优选地，本发明的洗衣组合物中每种酶的水平为0.0001重量％至0.1重量％的蛋白质。
酶优选选自蛋白酶、脂肪酶和纤维素酶，更优选蛋白酶。
特别考虑的酶包括蛋白酶、α-淀粉酶、纤维素酶、脂肪酶、过氧化物酶/氧化酶、果胶酸裂合酶和甘露聚糖酶或其混合物。
合适的脂肪酶包括细菌或真菌来源的那些。包括化学改性的或蛋白质工程改造的突变体。有用的脂肪酶的实例包括来自腐质霉属(Humicola)(同义词嗜热霉属(Thermomyces))的脂肪酶，如来自EP 258068和EP 305 216中所述的H.lanuginose(疏棉状嗜热真菌属(T.lanuginosus))，或来自WO 96/13580中所述的特异腐质霉(H.insolens)，假单胞菌属(Pseudomonas)脂肪酶，例如来自产碱假单胞属菌(P.alcaligenes)或假产碱假单胞菌属(P.pseudoalcaligenes)(EP 218 272)，洋葱假单胞菌(P.cepacia)(EP 331 376)，施氏假单胞菌(P.stutzeri)(GB 1,372,034)，荧光假单胞菌(P.fluorescens)，假单胞菌菌株SD 705(Pseudomonas sp.strain SD 705)(WO 95/06720和WO 96/27002)，威斯康星假单胞菌属(P.wisconsinensis)(WO 96/12012)，芽孢杆菌(Bacillus)脂肪酶，例如来自枯草芽孢杆菌(B.subtilis)(Dartois等人(1993)，Biochemica et Biophysica Acta，1131,253-360)，嗜热脂肪芽孢杆菌(B.stearothermophilus)(JP64/744992)或短小芽孢杆菌(B.pumilus)(WO91/16422)。
其他实例是脂肪酶变体，例如WO 92/05249、WO 94/01541、EP 407 225、EP 260105、WO 95/35381、WO 96/00292、WO 95/30744、WO 94/25578、WO 95/14783、WO 95/22615、WO 97/04079和WO 97/07202、WO 00/60063中描述的那些。
优选的市售脂肪酶包括LipolaseTM和Lipolase UltraTM、LipexTM和LipocleanTM(Novozymes A/S)。
本发明的方法可以在归类为EC 3.1.1.4和/或EC 3.1.1.32的磷脂酶的存在下进行。如本文所用，术语磷脂酶是对磷脂具有活性的酶。
磷脂，例如卵磷脂或磷脂酰胆碱，由在外面(sn-1)和中间(sn-2)位置被两个脂肪酸酯化并在第三个位置被磷酸酯化的甘油组成；该磷酸进而可被酯化成氨基醇。磷脂酶是参与磷脂水解的酶。可以区分几种类型的磷脂酶活性，包括水解一个脂肪酰基(分别在sn-1和sn-2位置)以形成溶血磷脂的磷脂酶A1和A2；和可以水解溶血磷脂中的剩余脂肪酰基的溶血磷脂酶(或磷脂酶B)。磷脂酶C和磷脂酶D(磷酸二酯酶)分别释放二酰基甘油或磷脂酸。
合适的蛋白酶包括动物、植物或微生物来源的那些。优选微生物来源。包括化学修饰或蛋白质工程改造的突变体。蛋白酶可以是丝氨酸蛋白酶或金属蛋白酶，优选碱性微生物蛋白酶或胰蛋白酶样蛋白酶。优选的市售蛋白酶包括AlcalaseTM、SavinaseTM、PrimaseTM、DuralaseTM、DyrazymTM、EsperaseTM、EverlaseTM、PolarzymeTM和Kannase TM(Novozymes A/S)、Maxatase TM、Maxacal TM、Maxapem TM、ProperaseTM、PurafectTM、Purafect OxPTM、FN2TM和FN3TM(Genencor International Inc.)。
本发明的方法可以在分类在EC 3.1.1.74的角质酶的存在下进行。根据本发明使用的角质酶可以是任何来源的。优选地，角质酶是微生物来源的，特别是细菌、真菌或酵母来源的。
合适的淀粉酶(α和/或β)包括细菌或真菌来源的那些。包括化学改性的或蛋白质工程改造的突变体。淀粉酶包括例如从芽孢杆菌(Bacillus)获得的α-淀粉酶，例如在GB 1,296,839中更详细地描述的地衣芽孢杆菌(B.licheniformis)特殊菌株，或在WO 95/026397或WO00/060060中公开的芽孢杆菌属(Bacillus sp.)菌株。可商购的淀粉酶是DuramylTM、TermamylTM、Termamyl UltraTM、NatalaseTM、StainzymeTM、FungamylTM和BANTM(Novozymes A/S)、RapidaseTM和PurastarTM(来自Genencor International Inc.)。
合适的纤维素酶包括细菌或真菌来源的那些。包括化学改性的或蛋白质工程改造的突变体。合适的纤维素酶包括来自芽孢杆菌属(Bacillus)、假单胞菌属(Pseudomonas)、腐质霉属(Humicola)、镰刀菌属(Fusarium)、梭孢壳属(Thielavia)、枝顶孢属(Acremonium)的纤维素酶，例如由公开于US 4,435,307、US 5,648,263、US 5,691,178、US5,776,757、WO 89/09259、WO 96/029397和WO 98/012307的特异腐质霉(Humicolainsolens)、土生梭孢壳霉(Thielavia terrestris)、嗜热毁丝霉(Myceliophthorathermophila)和尖孢镰刀菌(Fusarium oxysporum)产生的真菌纤维素酶。市售纤维素酶包括CelluzymeTM、CarezymeTM、CellucleanTM、EndolaseTM、RenozymeTM(Novozymes A/S)、ClazinaseTM和Puradax HATM(Genencor International Inc.)以及KAC-500(B)TM(KaoCorporation)。优选CellucleanTM。
合适的过氧化物酶/氧化酶包括植物、细菌或真菌来源的那些。包括化学改性的或蛋白质工程改造的突变体。有用的过氧化物酶的实例包括来自鬼伞属(Coprinus)的过氧化物酶，例如来自如WO 93/24618、WO 95/10602和WO 98/15257中所述的灰盖鬼伞(C.cinereus)及其变体。市售的过氧化物酶包括GuardzymeTM和NovozymTM 51004(Novozymes A/S)。
适合使用的其他酶在WO2009/087524、WO2009/090576、WO2009/107091、WO2009/111258和WO2009/148983中讨论。
酶稳定剂
组合物中存在的任何酶可以使用常规稳定剂稳定，例如多元醇，如丙二醇或甘油，糖或糖醇，乳酸，硼酸或硼酸衍生物，例如芳族硼酸酯，或苯基硼酸衍生物例如4-甲酰基苯基硼酸，并且所述组合物可以按照例如WO 92/19709和WO 92/19708中所述配制。
当烷基足够长以形成支链或环状链时，烷基包括支链、环状和线性烷基链。烷基优选是线性或支链的，最优选是线性的。
除非另有说明，否则本文使用的不定冠词“一”或“一个”及其相应的定冠词“所述”是指至少一个或一个或多个。
实验
实施例1
由以下配方制备水性液体洗衣用洗涤剂：
| 成分 | 重量％ |
| 单丙二醇 | 2 |
| 三乙胺 | 1.5 |
| 具有7摩尔环氧乙烷的C12-C15醇乙氧基化物 | 2.1 |
| 线性烷基苯磺酸盐 | 8.4 |
| 具有3摩尔环氧乙烷的月桂醇聚醚硫酸钠 | 10.5 |
| 柠檬酸 | 0.5 |
| 香料 | 0.3 |
| 抗再沉积技术 | 参见文本 |
| 氢氧化钠 | 至pH＝8.4 |
| 水 | 余量 |
该制剂用于在设定为200rpm的Tergotometer中洗涤8个5×5cm的针织棉布片。在800ml的6℃的法国硬水中在20℃下用2.3g/L的制剂进行1小时的洗涤。为了模拟微粒污垢，将0.04g/L的100％压缩炭黑(来自Sigma-Aldrich)加入洗涤液体中。为了模拟油状污垢，将6.3g SBL2004污垢条(soil strip)(来自Warwick Equest)加入洗涤液体中。
一旦完成洗涤，就将棉布测试片移去干燥，并在反射计上测量反射率。由740nm下的反射率值R740(排除UV)评估灰度。
测试含有8.7重量％Sokalan HP20(BASF)即乙氧基化聚乙烯亚胺聚合物PEI(600)20EO的制剂，其作为抗再沉积益处的对比聚合物。
测试含有8.7重量％带负电荷的烷氧基化多烷基苯酚的制剂(Hostapal BV CONC，来自Clariant，其为具有7EO的2,4,6-三丁基苯酚醚硫酸盐)。
结果总结在下表中。还从8个测试片的测量的标准偏差计算95％置信限。R740值是来自8个测试片的测量的平均值。
三丁基苯酚醚硫酸钠盐增加了测试片的R740。高R740值相当于更干净、更白的织物。烷氧基化多烷基苯酚提供了比乙氧基化聚乙烯亚胺Sokalan HP20显著更好的益处，后者在当前条件下没有提供明显的益处。
Claims (20)
1.一种洗衣用洗涤剂组合物，其包含：
(i)4-50重量％的带电荷的表面活性剂；
(ii)0.1-20重量％的除了(i)的带电荷的表面活性剂以外的带负电荷的烷氧基化多烷基苯酚，其中烷氧基化多烷基苯酚中的烷基选自C3-C15的线性烷基；和
(iii)0.001-3重量％的香料。
2.根据权利要求1所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚是带负电荷的烷氧基化三(正丁基)苯酚。
3.根据权利要求1所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚是带负电荷的乙氧基化多烷基苯酚，且带负电荷的烷氧基化多烷基苯酚具有连接到苯酚上2、4、6位置的3个烷基。
4.根据权利要求2所述的洗衣用洗涤剂组合物，其中带负电荷的烷氧基化三烷基苯酚是带负电荷的聚乙二醇单(2,4,6-三(正丁基)苯基)醚。
5.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚包含平均2-70个烷氧基。
6.根据权利要求5所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚包含平均6-18个烷氧基。
7.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚以0.5-10重量％的水平存在。
8.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述带负电荷的烷氧基化多烷基苯酚以2-9重量％的水平存在。
9.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述带电荷的表面活性剂是阴离子表面活性剂。
10.根据权利要求9所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂选自：线性烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐、皂、甲基酯磺酸盐及其混合物。
11.根据权利要求10所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂选自：线性烷基苯磺酸盐、烷基硫酸盐、烷基醚硫酸盐及其混合物。
12.根据权利要求9所述的洗衣用洗涤剂组合物，其中所述阴离子表面活性剂的水平为4-50重量％。
13.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述组合物包含2-8重量％的烷基乙氧基化非离子表面活性剂。
14.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中香料以0.001-3重量％存在并且包含一种或多种香料化合物：α-异甲基紫罗兰酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基-戊酸乙酯；辛醛；乙酸苄酯；1,6-辛二烯-3-醇，3,7-二甲基-3-乙酸酯；环己醇，2-(1,1-二甲基乙基)-,1-乙酸酯；δ-突厥酮(delta-damascone)；β-紫罗兰酮；乙酸三环癸烯酯；十二烷醛；己基肉桂醛；环十五内酯；苯乙酸2-苯乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；苯甲酸β-苯乙酯；α-檀香醇；雪松醇；醋酸柏木酯；甲酸柏木酯；水杨酸环己酯；γ-十二内酯；和苯乙酸β-苯乙酯。
15.根据权利要求1所述的洗衣用洗涤剂组合物，其包含：
(i)4-50重量％的阴离子表面活性剂，其选自：线性烷基苯磺酸盐、烷基硫酸盐和烷基醚硫酸盐；
(ii)0.5-10重量％的具有以下结构的带负电荷的烷氧基化多烷基苯酚：
其中R选自SO4 2-、COO-和PO3 -；
其中n选自：6、7、8、9、10、11、12、13、14、15、16、17、18、19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39、40、41、42、43、44、45、46、47、48、49和50；和
(iii)0.001-3重量％的香料。
16.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述组合物包含0.0001重量％至0.1重量％的酶，所述酶选自：蛋白酶、脂肪酶、纤维素酶及其混合物。
17.根据权利要求16所述的洗衣用洗涤剂组合物，其中所述酶包含蛋白酶。
18.根据权利要求1-4中任一项所述的洗衣用洗涤剂组合物，其中所述洗衣用洗涤剂组合物是洗衣用水性液体洗涤剂组合物。
19.一种处理织物的家用方法，所述方法包括以下步骤：
(i)用权利要求1-18中任一项所述的洗衣用洗涤剂组合物的水溶液处理所述织物，所述水溶液包含10ppm至5000ppm的带负电荷的烷氧基化多烷基苯酚和最高6g/L的表面活性剂；和
(ii)任选地漂洗和干燥所述织物。
20.根据权利要求19所述的处理织物的家用方法，其中所述水溶液包含0.2-4g/L的表面活性剂。
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| PCT/EP2015/067274 WO2016041676A1 (en) | 2014-09-18 | 2015-07-28 | Whitening composition |
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| BR112017005495B1 (pt) | 2021-11-30 |
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| BR112017005495A2 (pt) | 2017-12-19 |
| EP3194543A1 (en) | 2017-07-26 |
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