CN1071777C - 氯化紫蒽酮或氯化异紫蒽酮的制备 - Google Patents
氯化紫蒽酮或氯化异紫蒽酮的制备 Download PDFInfo
- Publication number
- CN1071777C CN1071777C CN95102736A CN95102736A CN1071777C CN 1071777 C CN1071777 C CN 1071777C CN 95102736 A CN95102736 A CN 95102736A CN 95102736 A CN95102736 A CN 95102736A CN 1071777 C CN1071777 C CN 1071777C
- Authority
- CN
- China
- Prior art keywords
- violanthrone
- thinner
- iso
- chlorination
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title description 4
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 claims abstract description 22
- BSIHWSXXPBAGTC-UHFFFAOYSA-N isoviolanthrone Chemical compound C12=CC=CC=C2C(=O)C2=CC=C3C(C4=C56)=CC=C5C5=CC=CC=C5C(=O)C6=CC=C4C4=C3C2=C1C=C4 BSIHWSXXPBAGTC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000460 chlorine Substances 0.000 claims abstract description 12
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 20
- 238000005660 chlorination reaction Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 12
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 229910052740 iodine Inorganic materials 0.000 claims description 8
- 239000011630 iodine Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 230000026030 halogenation Effects 0.000 claims description 6
- 238000005658 halogenation reaction Methods 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 claims 1
- 125000001475 halogen functional group Chemical group 0.000 claims 1
- -1 aliphatic halo carboxylic acids Chemical class 0.000 abstract description 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 22
- 229960000583 acetic acid Drugs 0.000 description 11
- 239000012362 glacial acetic acid Substances 0.000 description 11
- 125000001309 chloro group Chemical group Cl* 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- DCIGCIBVJSBHMN-UHFFFAOYSA-N 6373-20-2 Chemical compound C12=C3C4=C(Cl)C=C2C2=CC=C(Cl)C=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC(Cl)=CC=C3C3=CC(Cl)=C4C1=C32 DCIGCIBVJSBHMN-UHFFFAOYSA-N 0.000 description 1
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
- C09B3/22—Dibenzanthrones; Isodibenzanthrones
- C09B3/30—Preparation from starting materials already containing the dibenzanthrone or isodibenzanthrone nucleus
- C09B3/32—Preparation from starting materials already containing the dibenzanthrone or isodibenzanthrone nucleus by halogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
实施例 | x克(Ia)或(Ib) | a克 D | b克水 | c克 C | T[℃] | t1小时 | y克氯气 | t2小时 | 产量克 | 产物(氯的重量%,实测值/计算值) | |||
1 | 150 | Ib | 2000 | 冰乙酸 | - | 10 | 碘 | 110 | 8 | 110 | 193 | 二氯代异紫蒽酮(14.0/13.5) | |
2 | 160 | Ia | 1800 | 冰乙酸 | 200 | 10 | 碘 | 107 | 18 | 284 | - | 193 | 三氯代异紫蒽酮(20.5/19.0) |
3 | 160 | Ia | 1900 | 冰乙酸 | 100 | 10 | 碘 | 110 | 23 | 360 | 24 | 221 | 四氯代紫蒽酮(25.5/23.9) |
4 | 43 | Ia | 300 | 冰乙酸 | - | 0.5 | FeCl3 | 110 | 6 | 76 | 12 | 54 | 三氯代紫蒽酮(18.8/19.0) |
5 | 43 | Ia | 300 | 丙酸 | - | - | - | 130 | 7 | 94 | 12 | 47 | 三氯代紫蒽酮(16.2/19.0) |
6* | 43 | Ia | 300 | 冰乙酸 | - | - | - | 60 | 4 | 65 | 6 | 63 | 四氯代紫蒽酮(22.3/23.9) |
7 | 160 | Ia | 2000 | 冰乙酸 | - | 10 | 碘 | 110 | 15 | 350 | 12 | 255 | 五氯代紫蒽酮(28.8/28.2) |
8 | 24 | Ia | 300 | 氯乙酸 | - | 1.5 | 碘 | 110 | 5 | 65 | - | 27 | 四氯代紫蒽酮(23.9/23.9) |
9 | 150 | Ib | 2000 | 冰乙酸 | - | 10 | 碘 | 110 | 15 | 217 | 10 | 205 | 三氯代异紫蒽酮(18.0/19.0) |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4404587 | 1994-02-12 | ||
DEP4404587.5 | 1994-02-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1111663A CN1111663A (zh) | 1995-11-15 |
CN1071777C true CN1071777C (zh) | 2001-09-26 |
Family
ID=6510161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95102736A Expired - Fee Related CN1071777C (zh) | 1994-02-12 | 1995-02-11 | 氯化紫蒽酮或氯化异紫蒽酮的制备 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5554774A (zh) |
JP (1) | JPH07252424A (zh) |
CN (1) | CN1071777C (zh) |
CH (1) | CH688377A5 (zh) |
FR (1) | FR2716203B1 (zh) |
GB (1) | GB2286404B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022147994A1 (zh) | 2021-01-06 | 2022-07-14 | 贺潇寒 | 一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004060968B4 (de) * | 2004-12-17 | 2008-12-04 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Marineblau- und Schwarzmischungen, Verfahren zu ihrer Herstellung und ihre Verwendung zum Färben von Hydroxygruppen-haltigen Material |
US8129190B2 (en) * | 2006-11-17 | 2012-03-06 | Applied Nanotech Holdings, Inc. | Tagged petroleum products and methods of detecting same |
CN102660130B (zh) * | 2012-04-19 | 2014-05-07 | 徐州开达精细化工有限公司 | 生产还原直接黑bcn原染料的方法 |
US9181652B2 (en) | 2013-07-02 | 2015-11-10 | Phillip Harrison | Bedding product having different colors for hem and body |
CN108047017B (zh) * | 2017-12-22 | 2021-04-20 | 江苏嘉利精细化工有限公司 | 一种异紫蒽酮二氯化物的制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1842694A (en) * | 1930-04-24 | 1932-01-26 | Ici Ltd | Manufacture of halogenated dyes and halogenated intermediated for dyes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE177574C (zh) * | ||||
US837775A (en) * | 1906-05-18 | 1906-12-04 | Basf Ag | Halogenated dye and process of making same. |
DE465988C (de) * | 1925-12-08 | 1928-09-27 | Chemische Ind Ges | Verfahren zur Herstellung von Kuepenfarbstoffen der Dibenzanthronreihe |
DE4014172A1 (de) * | 1990-05-02 | 1991-11-07 | Basf Ag | Verfahren zur halogenierung von polycyclischen verbindungen |
-
1995
- 1995-02-02 CH CH00291/95A patent/CH688377A5/de not_active IP Right Cessation
- 1995-02-09 JP JP7022124A patent/JPH07252424A/ja not_active Withdrawn
- 1995-02-10 US US08/386,665 patent/US5554774A/en not_active Expired - Fee Related
- 1995-02-10 GB GB9502718A patent/GB2286404B/en not_active Expired - Fee Related
- 1995-02-10 FR FR9501569A patent/FR2716203B1/fr not_active Expired - Fee Related
- 1995-02-11 CN CN95102736A patent/CN1071777C/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1842694A (en) * | 1930-04-24 | 1932-01-26 | Ici Ltd | Manufacture of halogenated dyes and halogenated intermediated for dyes |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022147994A1 (zh) | 2021-01-06 | 2022-07-14 | 贺潇寒 | 一种氯化蓝蒽酮、紫蒽酮或异紫蒽酮的方法 |
Also Published As
Publication number | Publication date |
---|---|
GB2286404A (en) | 1995-08-16 |
US5554774A (en) | 1996-09-10 |
FR2716203A1 (fr) | 1995-08-18 |
GB2286404B (en) | 1997-12-03 |
FR2716203B1 (fr) | 1997-09-12 |
CN1111663A (zh) | 1995-11-15 |
JPH07252424A (ja) | 1995-10-03 |
CH688377A5 (de) | 1997-08-29 |
GB9502718D0 (en) | 1995-03-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: STAFFAN WEARING TEXTILE FIBERS CO., LTD. GERMANY Free format text: FORMER OWNER: BASF COMPANY Effective date: 20051014 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20051014 Address after: Frankfurt, Germany Patentee after: Dystar Textilfarben GmbH & Co Dutschland K G Address before: Ludwigshafen, Federal Republic of Germany Patentee before: BASF AG |
|
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: DyStar (Nanjing) dye Co. Ltd. Assignor: Dystar Textilfarben GmbH & Co. Deutxchland KG Contract fulfillment period: 2006.4.1 to 2014.3.21 contract change Contract record no.: 2008990000019 Denomination of invention: The preparation of chlorinated violanthrones or isoviolanthrones Granted publication date: 20010926 License type: General permission Record date: 2008.1.22 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2006.4.1 TO 2014.3.21 Name of requester: DYSTAR (NANJING) DYE LTD. Effective date: 20080122 |
|
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20010926 Termination date: 20110211 |