CN106758240A - The preparation method of polypyrrole conduction wool fabric - Google Patents
The preparation method of polypyrrole conduction wool fabric Download PDFInfo
- Publication number
- CN106758240A CN106758240A CN201611089432.XA CN201611089432A CN106758240A CN 106758240 A CN106758240 A CN 106758240A CN 201611089432 A CN201611089432 A CN 201611089432A CN 106758240 A CN106758240 A CN 106758240A
- Authority
- CN
- China
- Prior art keywords
- polypyrrole
- carbon tetrachloride
- wool fabric
- preparation
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Abstract
The invention provides a kind of preparation method of polypyrrole conduction wool fabric, it is related to textile finishing technical field, the method to comprise the following steps：（1）Phenol is dissolved in carbon tetrachloride；（2）Eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion soln is obtained under ultrasound；（3）During wool fabric put into above-mentioned dye liquor, vibration is heated to 30 ~ 60oC, and insulation continues 5 ~ 30min；（4）Washed for several times with carbon tetrachloride and ethanol respectively；（5）Fabric after washing is finally placed in 30 ~ 120min of doping in the p-methyl benzenesulfonic acid solution of 200g/L, is dried under 80oC after taking-up, you can obtain polypyrrole conduction wool fabric.This technology of preparing process is simple, it is not necessary to complicated reaction and high temperature；The good conductivity of the conductive fabric of preparation.
Description
Technical field
The present invention relates to textile finishing technical field, and in particular to a kind of preparation side of polypyrrole conduction wool fabric
Method.
Background technology
Conductive fabric has conductive, antistatic and electromagnetic radiation resisting function, can prepare sensor, intelligent clothing and can roll over
The high-tech products such as folded battery, therefore have important in multiple fields such as sensor, chemistry, biology, medical science and Aero-Space
Effect.Due to light weight, raw material is easy to get organic composite conductive fabric with wool as substrate, cheap, good stability, conductance
The features such as rate is adjustable, is one of most promising conductive fabric.Due to polypyrrole, dissolubility is very poor in usual vehicle, to equipment
Requirement with spinning technique is very harsh, so the preparation method of polypyrrole conductive fabric mainly uses situ aggregation method, but
Polypyrrole needs processing step more the in-situ polymerization of wool, and technique is more long, is difficult the shortcomings of uniformly processing.
The content of the invention
Problem to be solved by this invention is to provide a kind of preparation process is simple, and the polypyrrole conduction wool of good conductivity is knitted
The preparation method of thing, the present invention is adopted the following technical scheme that.
A kind of preparation method of polypyrrole conduction wool fabric, comprises the following steps：（1）Phenol is dissolved in carbon tetrachloride
In；（2）Eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion soln is obtained under ultrasound；
（3）During wool fabric put into above-mentioned solution, vibration is heated to 30 ~ 60oC, and insulation continues 5 ~ 30min；（4）Tetrachloro is used respectively
Change carbon and ethanol washing for several times；（5）Finally the fabric after washing is placed in the p-methyl benzenesulfonic acid solution of 200g/L doping 30 ~
120min, dries after taking-up under 80oC, you can obtain polypyrrole conduction wool fabric.
Further, the carbon tetrachloride of described carbon tetrachloride/phenol mixed solution and the mass ratio of phenol are 1:0.1~
3。
Further, described polypyrrole and the mass ratio of carbon tetrachloride/phenol mixed solution are 1:200~4000.
The beneficial effects of the present invention are the preparation method of polypyrrole conduction wool fabric is simple, it is not necessary to which complicated is anti-
Should and high temperature；The good conductivity of the conductive fabric of preparation.
Specific embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic be not construed as it is isolated, they can be mutually combined so as to reach preferably
Technique effect.
Embodiment 1
The preparation method detailed step of polypyrrole conduction wool fabric is as follows：
（1）20g phenol is dissolved in 180g carbon tetrachloride；
（2）0.2g eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion is obtained under ultrasound molten
Liquid；
（3）During 10g wool fabrics are put into above-mentioned solution, vibration is heated to 60oC, and insulation continues 30min；
（4）Washed for several times with carbon tetrachloride and ethanol respectively；
（5）Fabric after washing is finally placed in the 30min that adulterated in the p-methyl benzenesulfonic acid solution of 200g/L, is dried under 80oC after taking-up
It is dry, you can to obtain polypyrrole conduction wool fabric.
Embodiment 2
The preparation method detailed step of polypyrrole conduction wool fabric is as follows：
（1）300g phenol is dissolved in 100g carbon tetrachloride；
（2）0.9g eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion is obtained under ultrasound molten
Liquid；
（3）During 10g wool fabrics are put into above-mentioned solution, vibration is heated to 30oC, and insulation continues 30min；
（4）Washed for several times with carbon tetrachloride and ethanol respectively；
（5）Fabric after washing is finally placed in the 80min that adulterated in the p-methyl benzenesulfonic acid solution of 200g/L, is dried under 80oC after taking-up
It is dry, you can to obtain polypyrrole conduction wool fabric.
Embodiment 3
The preparation method detailed step of polypyrrole conduction wool fabric is as follows：
（1）50g phenol is dissolved in 250g carbon tetrachloride；
（2）0.1g eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion is obtained under ultrasound molten
Liquid；
（3）During 10g wool fabrics are put into above-mentioned solution, vibration is heated to 50oC, and insulation continues 10min；
（4）Washed for several times with carbon tetrachloride and ethanol respectively；
（5）Fabric after washing is finally placed in the 40min that adulterated in the p-methyl benzenesulfonic acid solution of 200g/L, is dried under 80oC after taking-up
It is dry, you can to obtain polypyrrole conduction wool fabric.
Embodiment 4
The preparation method detailed step of polypyrrole conduction wool fabric is as follows：
（1）200g phenol is dissolved in 200g carbon tetrachloride；
（2）1g eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion is obtained under ultrasound molten
Liquid；
（3）During 10g wool fabrics are put into above-mentioned solution, vibration is heated to 40oC, and insulation continues 15min；
（4）Washed for several times with carbon tetrachloride and ethanol respectively；
（5）Fabric after washing is finally placed in the 120min that adulterated in the p-methyl benzenesulfonic acid solution of 200g/L, after taking-up under 80oC
Drying, you can obtain polypyrrole conduction wool fabric.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
Should be using the embodiments herein as the restriction of interest field of the present invention.
Claims (3)
1. the preparation method of a kind of polypyrrole conduction wool fabric, it is characterised in that comprise the following steps：
（1）Phenol is dissolved in carbon tetrachloride；
（2）Eigenstate polypyrrole powder is placed in carbon tetrachloride/phenol mixed solution, black dispersion soln is obtained under ultrasound；
（3）During wool fabric put into above-mentioned solution, vibration is heated to 30 ~ 60oC, and insulation continues 5 ~ 30min；
（4）Washed for several times with carbon tetrachloride and ethanol respectively；
（5）Fabric after washing is finally placed in doping 30 ~ 120min, 80oC after taking-up in the p-methyl benzenesulfonic acid solution of 200g/L
Lower drying, you can obtain polypyrrole conduction wool fabric.
2. the preparation method of polypyrrole as claimed in claim 1 conduction wool fabric, described carbon tetrachloride/phenol mixing is molten
The carbon tetrachloride of liquid is 1 with the mass ratio of phenol:0.1~3.
3. the preparation method of polypyrrole as claimed in claim 1 conduction wool fabric, described polypyrrole and carbon tetrachloride/benzene
The mass ratio of phenol mixed solution is 1:200~4000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089432.XA CN106758240A (en) | 2016-12-01 | 2016-12-01 | The preparation method of polypyrrole conduction wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089432.XA CN106758240A (en) | 2016-12-01 | 2016-12-01 | The preparation method of polypyrrole conduction wool fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106758240A true CN106758240A (en) | 2017-05-31 |
Family
ID=58915262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611089432.XA Pending CN106758240A (en) | 2016-12-01 | 2016-12-01 | The preparation method of polypyrrole conduction wool fabric |
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| CN (1) | CN106758240A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106930110A (en) * | 2017-03-30 | 2017-07-07 | 武汉纺织大学 | A kind of method for improving polypyrrole wool conductive fabric electric conductivity |
| CN111455654A (en) * | 2020-04-29 | 2020-07-28 | 上海工程技术大学 | Preparation method of polypyrrole composite wool conductive fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104727137A (en) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | Preparation method of composite conductive fabric |
| CN105646921A (en) * | 2016-03-18 | 2016-06-08 | 华东师范大学 | Preparation method of independent PAN (Polyaniline) conducting membrane |
-
2016
- 2016-12-01 CN CN201611089432.XA patent/CN106758240A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104727137A (en) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | Preparation method of composite conductive fabric |
| CN105646921A (en) * | 2016-03-18 | 2016-06-08 | 华东师范大学 | Preparation method of independent PAN (Polyaniline) conducting membrane |
Non-Patent Citations (3)
| Title |
|---|
| 刘维锦等: ""以聚苯胺为导电覆盖层制备导电性涤纶的研究"", 《合成纤维工业》 * |
| 刘维锦等: ""聚苯胺导电纤维的结构与性能"", 《纺织学报》 * |
| 钟汉权等: ""聚苯胺导电纤维的研究动态"", 《纺织科学研究》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106930110A (en) * | 2017-03-30 | 2017-07-07 | 武汉纺织大学 | A kind of method for improving polypyrrole wool conductive fabric electric conductivity |
| CN106930110B (en) * | 2017-03-30 | 2019-08-20 | 武汉纺织大学 | A method of improving polypyrrole wool conductive fabric electric conductivity |
| CN111455654A (en) * | 2020-04-29 | 2020-07-28 | 上海工程技术大学 | Preparation method of polypyrrole composite wool conductive fabric |
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Application publication date: 20170531 |