CN104727137A - Preparation method of composite conductive fabric - Google Patents
Preparation method of composite conductive fabric Download PDFInfo
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- CN104727137A CN104727137A CN201510120507.5A CN201510120507A CN104727137A CN 104727137 A CN104727137 A CN 104727137A CN 201510120507 A CN201510120507 A CN 201510120507A CN 104727137 A CN104727137 A CN 104727137A
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Abstract
The invention discloses a preparation method of a composite conductive fabric. The preparation method of the composite conductive fabric comprises the following steps: firstly, carrying out pretreatment on a base cloth material, wherein pretreatment comprises an alkali peeling process on the base cloth material and a low-temperature plasma treatment technology on the base cloth material; and mixing the pretreated base cloth material with a polyaniline mixed solution, and thus obtaining the composite conductive fabric. The preparation method is simple, feasible and low in preparation cost; the conductivity of the prepared polyester fabric is good; and the combining property of polyaniline and the polyester fabric is good.
Description
Technical field
The present invention relates to a kind of preparation of fabric, be specifically related to a kind of preparation method of composite conductive fabric, belong to textile technology field.
Background technology
Polyaniline because of monomer low price, be easy to preparation, the characteristic such as electrical conductivity is high, environmental stability is good, demonstrate tempting application prospect in many aspects, but the insoluble infusibility of polyaniline limits its processing, if can by polyaniline and fabric compound, then can the premium properties of polyaniline be incorporated in fabric, make composite fabric keep mechanical performance, the flexility of fabric, make polyaniline good characteristic be well used simultaneously.
Polyaniline is well combined with fabric by current people, enhance the mechanical performance of fabric, and polyaniline is combined the method mainly situ aggregation method preparing polyaniline composite fabric with fabric, but it is lower to there is polyaniline adsorbance in the polyaniline composite fabric prepared, electric conductivity is not high, and the problem such as is loosely combined with base fabric, for above problem, provide a kind of polyaniline composite fabric that can overcome above defect to become those skilled in the art's technical problem urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is, for the shortcoming that above prior art exists, proposes a kind of preparation method of composite conductive fabric, this preparation method is simple, cost of manufacture is cheap, and the dacron prepared conducts electricity very well, and the associativity of polyaniline and dacron is good.
The technical scheme that the present invention solves above technical problem is:
A preparation method for composite conductive fabric, the preparation method of this composite conductive fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 20-25g/L, and scrim material is placed in the sodium hydroxide solution of 20g/L; bath raio is 1:100; dipping bath 50-65min at 30-50 DEG C; use the warm water washing of 30-50 DEG C after taking out scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 28-35Pa, under the condition of 100-200W, carry out Low Temperature Plasma Treating 5-10min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20-30 DEG C is in 0.3mol/L polyaniline mixed solution, after constant temperature oscillation 10-20min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 20-28min and carry out oxidation polymerization 1-3h, after reaction terminates, scrim material is taken out, 1-3h is soaked in 0.5mol/L acetum, wash 2-5 time respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
The further technical scheme of the present invention is:
In the preparation method of aforementioned composite conductive fabric, the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 23g/L, and scrim material is placed in the sodium hydroxide solution of 230g/L; bath raio is 1:100; dipping bath 60min at 42 DEG C; with the warm water washing of 40 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 30Pa, under the condition of 150W, carry out Low Temperature Plasma Treating 7min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20-30 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 15min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 25min and carry out oxidation polymerization 2h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 1h, wash 3 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
In the preparation method of aforementioned composite conductive fabric, the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 20g/L, and scrim material is placed in the sodium hydroxide solution of 20g/L; bath raio is 1:100; dipping bath 65min at 30 DEG C; with the warm water washing of 30 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 35Pa, under the condition of 200W, carry out Low Temperature Plasma Treating 5min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 20min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 20in and carry out oxidation polymerization 1h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 2h, wash 5 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
In the preparation method of aforementioned composite conductive fabric, step (one) scrim material is the compound of spandex and dacron, and wherein dacron is polyester knitting fabric.
In the preparation method of aforementioned composite conductive fabric, in step (two) dopant acid be hydrochloric acid, formic acid, to the one in toluene sulphur or citric acid.
In the preparation method of aforementioned composite conductive fabric, concrete preparation technology is as follows for polyaniline mixed solution:
Adulterant is added in poly-vinyl alcohol solution, stirs 10-15min and obtain mixed liquor, in mixed liquor, add the derivative of aniline and aniline, continue to stir 15-28min, finally add oxidant, stir 20-25min and be obtained by reacting polyaniline mixed solution, wherein:
Adulterant is must be a kind of in DBSA, camphorsulfonic acid, perchloric acid, sulfosalicylic acid or phosphoric acid; Anil is o-toluidine, N-(4-sulfophenyl) one in aniline or adjacent anilinesulfonic acid; Oxidant is K
2cr
2o
7, H
20
2, FeCl
3, KIO
3or (NH
4)
2s
2o
8in one
The invention has the beneficial effects as follows:
In the present invention, the fabric that polyaniline mixes with by spandex and terylene is carried out compound, the premium properties through polyaniline is incorporated in fabric, makes fabric keep mechanical performance, the flexility of fabric, makes polyaniline good characteristic be well used simultaneously.
Because polyaniline indissoluble, difficulty are melted, so prepare body polyaniline fiber there is suitable difficulty, currently used spinning solution is mostly the concentrated sulfuric acid or 1-METHYLPYRROLIDONE (NMP), but make solvent with the concentrated sulfuric acid, harsh requirement is proposed to the corrosion resistance of spinning equipment, poor operability, and 1-METHYLPYRROLIDONE (NMP) is expensive on the other hand.Spinning cost will improve greatly; In addition the fiber be made up of them is frangible and stiff, and not wear-resistant when using as textile material, practical value is not high yet.
The present invention adopts polyaniline and terylene polyethylene terephthalate (PET) to carry out compound, a series of premium properties such as intensity is high owing to having for dacron, good springiness, heat-resisting, wear-resisting, fast light, acid and alkali-resistance, and become one of kind that in synthetic fabrics, output is high, the most with fastest developing speed.
Dacron is after Alkali reduction, and fabric fibre attenuates, and thus fabric void rate improves, thus improves the gas permeability of fabric, hygroscopicity, feel and gloss; Moisture absorption regain improves, and fracture strength reduces, and Young's modulus increases; After Alkali reduction, fiber surface forms pit, and the contact area between dye solution and fiber is increased, and dye-uptake is improved.
The present invention carries out alkali decrement treatment to dacron, and the polyester fabric fibers surface after alkali decrement treatment engenders a large amount of depressions and bark shape gully, and the specific area of fiber increases, and the adsorbance of fiber surface polyaniline increases, and improves electric conductivity; Simultaneously, due to the effect of Alkali reduction, dacron not only there will be etching, also certain group layer effect is had, fiber attenuates, and make the relatively loose of original structure limit closely, fiber surface is formed and is coated with polyaniline film, good conductive path can be formed, make composite conductive fabric electric conductivity have larger change.
The dopant acid added in benzene invention provides Hydrogen Proton on the one hand, p-poly-phenyl amine macromolecular chain adulterates, by the migration of electric charge on strand after doping or the transition of interchain, impart polyaniline conductivity, on the other hand for the oxidative polymerization of aniline provides suitable pH value, ensure that reaction is carried out smoothly.
After Alkali reduction-low temperature plasma preliminary treatment, polyaniline can enter fabric construction inside has good combination with fabric, and the large molecule of polyaniline can adhere to preferably at fiber surface, and binding strength has greatly improved, and shows good wash durability.
Detailed description of the invention
embodiment 1
The present embodiment provides a kind of preparation method of composite conductive fabric, and the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 23g/L, and scrim material is placed in the sodium hydroxide solution of 23g/L; bath raio is 1:100; dipping bath 60min at 42 DEG C; with the warm water washing of 40 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
Scrim material is the compound of spandex and dacron, and wherein dacron is polyester knitting fabric;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 30Pa, under the condition of 150W, carry out Low Temperature Plasma Treating 7min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 25 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 15min, moving into concentration is in the mixed solution of the hydrochloric acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 25min and carry out oxidation polymerization 2h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 1h, wash 3 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
Concrete preparation technology is as follows for polyaniline mixed solution:
Adulterant DBSA is added in poly-vinyl alcohol solution, stirs 10min and obtain mixed liquor, in mixed liquor, add the derivative N-(4-sulfophenyl of aniline and aniline) aniline, continues to stir 20min, finally adds oxidant FeCl
3, stir 25min and be obtained by reacting polyaniline mixed solution.
embodiment 2
The present embodiment provides a kind of preparation method of composite conductive fabric, and the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 20g/L, and scrim material is placed in the sodium hydroxide solution of 20g/L; bath raio is 1:100; dipping bath 65min at 30 DEG C; with the warm water washing of 30 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
Scrim material is the compound of spandex and dacron, and wherein dacron is polyester knitting fabric;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 35Pa, under the condition of 200W, carry out Low Temperature Plasma Treating 5min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 20min, moving into concentration is in the mixed solution of the citric acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 20in and carry out oxidation polymerization 1h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 2h, wash 5 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
Concrete preparation technology is as follows for polyaniline mixed solution:
Adulterant sulfosalicylic acid is added in poly-vinyl alcohol solution, stirs 15min and obtain mixed liquor, in mixed liquor, add the adjacent anilinesulfonic acid of derivative of aniline and aniline, continue to stir 15min, finally add oxidant (NH
4)
2s
2o
8, stir 20min and be obtained by reacting polyaniline mixed solution.
embodiment 3
The present embodiment provides a kind of preparation method of composite conductive fabric, and the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 25g/L, and scrim material is placed in the sodium hydroxide solution of 25g/L; bath raio is 1:100; dipping bath 50min at 50 DEG C; with the warm water washing of 50 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
Scrim material is the compound of spandex and dacron, and wherein dacron is polyester knitting fabric;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 280Pa, under the condition of 100W, carry out Low Temperature Plasma Treating 10min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 30 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 10min, moving into concentration is in the mixed solution of the ammonium persulfate to toluene sulphur and 0.03g/ml of 0.3mol/L, continue vibration 28min and carry out oxidation polymerization 3h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 3h, wash 2 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
Concrete preparation technology is as follows for polyaniline mixed solution:
Adulterant camphorsulfonic acid is added in poly-vinyl alcohol solution, stirs 12min and obtain mixed liquor, in mixed liquor, add the derivative o-toluidine of aniline and aniline, continue to stir 28min, finally add oxidant K
2cr
2o
7, stir 22min and be obtained by reacting polyaniline mixed solution.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (6)
1. a preparation method for composite conductive fabric, is characterized in that, the preparation method of this composite conductive fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 20-25g/L, and scrim material is placed in the sodium hydroxide solution of 20g/L; bath raio is 1:100; dipping bath 50-65min at 30-50 DEG C; use the warm water washing of 30-50 DEG C after taking out scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 28-35Pa, under the condition of 100-200W, carry out Low Temperature Plasma Treating 5-10min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20-30 DEG C is in 0.3mol/L polyaniline mixed solution, after constant temperature oscillation 10-20min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 20-28min and carry out oxidation polymerization 1-3h, after reaction terminates, scrim material is taken out, 1-3h is soaked in 0.5mol/L acetum, wash 2-5 time respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
2. the preparation method of composite conductive fabric according to claim 1, is characterized in that, the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 23g/L, and scrim material is placed in the sodium hydroxide solution of 23g/L; bath raio is 1:100; dipping bath 60min at 42 DEG C; with the warm water washing of 40 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 30Pa, under the condition of 150W, carry out Low Temperature Plasma Treating 7min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 25 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 15min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 25min and carry out oxidation polymerization 2h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 1h, wash 3 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
3. the preparation method of composite conductive fabric according to claim 1, is characterized in that, the preparation method of this conductive dacron fabric specifically comprises the following steps:
(1) preliminary treatment of scrim material:
(1) caustic reduction processing is carried out to scrim material:
NaOH is dissolved in the sodium hydroxide solution that deionized water is configured to 20g/L, and scrim material is placed in the sodium hydroxide solution of 20g/L; bath raio is 1:100; dipping bath 65min at 30 DEG C; with the warm water washing of 30 DEG C after taking-up scrim material; then use cold water washing, finally extremely neutral with acetic acid again, cleans oven dry stand-by;
(2) Low Temperature Plasma Treating technique is carried out to scrim material:
By scrim material in ar gas environment, under 35Pa, under the condition of 200W, carry out Low Temperature Plasma Treating 5min, after process, sealed preservation;
(2) preparation of composite conductive fabric:
Pretreated scrim material is weighed, by bath raio 1:100, immersing concentration at 20 DEG C is in 0.3mol/L polyaniline mixed solution, and after constant temperature oscillation 20min, moving into concentration is in the mixed solution of the dopant acid of 0.3mol/L and the ammonium persulfate of 0.03g/ml, continue vibration 20in and carry out oxidation polymerization 1h, after reaction terminates, scrim material is taken out, in 0.5mol/L acetum, soak 2h, wash 5 times respectively with acetone, deionized water, freeze-day with constant temperature, to constant weight, obtains composite conductive fabric.
4. the preparation method of composite conductive fabric according to claim 1, is characterized in that: the scrim material described in step () is the compound of spandex and dacron, and wherein said dacron is polyester knitting fabric.
5. the preparation method of composite conductive fabric according to claim 1, is characterized in that: the dopant acid described in step (two) be hydrochloric acid, formic acid, to the one in toluene sulphur or citric acid.
6. the preparation method of composite conductive fabric according to claim 1, is characterized in that: the described concrete preparation technology of polyaniline mixed solution is as follows:
Adulterant is added in poly-vinyl alcohol solution, stirs 10-15min and obtain mixed liquor, in mixed liquor, add the derivative of aniline and aniline, continue to stir 15-28min, finally add oxidant, stir 20-25min and be obtained by reacting polyaniline mixed solution, wherein:
Described adulterant is must be a kind of in DBSA, camphorsulfonic acid, perchloric acid, sulfosalicylic acid or phosphoric acid; Described anil is o-toluidine, N-(4-sulfophenyl) one in aniline or adjacent anilinesulfonic acid; Described oxidant is K
2cr
2o
7, H
20
2, FeCl
3, KIO
3or (NH
4)
2s
2o
8in one.
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| CN105398104A (en) * | 2015-12-18 | 2016-03-16 | 常熟市爱尚纺织科技有限公司 | Air-permeable moisture-guiding coral fleece fabrics |
| CN105970601A (en) * | 2016-06-07 | 2016-09-28 | 浙江大学 | Method for preparing titanium dioxide nanorod/polypyrrole/dacron compound fabric |
| CN106521684A (en) * | 2016-11-23 | 2017-03-22 | 浙江华峰氨纶股份有限公司 | Production method of intelligent clothing spandex with conductive performance |
| CN106637983A (en) * | 2016-12-01 | 2017-05-10 | 西南大学 | Preparation method of polypyrrole conductive cotton fabric |
| CN106637993A (en) * | 2016-12-01 | 2017-05-10 | 西南大学 | Preparation method for polyaniline conductive silk fabric |
| CN106702746A (en) * | 2016-12-01 | 2017-05-24 | 西南大学 | Preparation method of polyaniline conductive wool fabric |
| CN106758240A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conduction wool fabric |
| CN106758241A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conductive dacron fabric |
| CN106758256A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of layer/polyaniline conductive dacron |
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| CN105088412A (en) * | 2015-08-06 | 2015-11-25 | 丁德凤 | Preparation method for polyaniline compound conductive fibers |
| CN105398104A (en) * | 2015-12-18 | 2016-03-16 | 常熟市爱尚纺织科技有限公司 | Air-permeable moisture-guiding coral fleece fabrics |
| CN105970601A (en) * | 2016-06-07 | 2016-09-28 | 浙江大学 | Method for preparing titanium dioxide nanorod/polypyrrole/dacron compound fabric |
| CN105970601B (en) * | 2016-06-07 | 2018-06-26 | 浙江大学 | A kind of preparation method of titanium dioxide nano-rod/polypyrrole/terylene compound fabric |
| CN106521684A (en) * | 2016-11-23 | 2017-03-22 | 浙江华峰氨纶股份有限公司 | Production method of intelligent clothing spandex with conductive performance |
| CN106758241A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conductive dacron fabric |
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Application publication date: 20150624 |