CN106544869A - The preparation method of layer/polyaniline conductive bafta - Google Patents
The preparation method of layer/polyaniline conductive bafta Download PDFInfo
- Publication number
- CN106544869A CN106544869A CN201611089758.2A CN201611089758A CN106544869A CN 106544869 A CN106544869 A CN 106544869A CN 201611089758 A CN201611089758 A CN 201611089758A CN 106544869 A CN106544869 A CN 106544869A
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- China
- Prior art keywords
- bafta
- dimethyl sulfoxide
- polyaniline
- layer
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The invention provides a kind of preparation method of layer/polyaniline conductive bafta, is related to textile finishing technical field, the method comprises the steps：（1）Phenol is dissolved in dimethyl sulfoxide；（2）Polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, blackish green clear solution is obtained；（3）Bafta is put in above-mentioned dye liquor, vibration is heated to 30 ~ 60 C, insulation continues 5 ~ 30min；（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；（5）Fabric after washing is finally placed in 30 ~ 120min of doping in the camphorsulfonic acid solution of 200g/L, is dried under 80 C after taking-up, you can obtain layer/polyaniline conductive bafta.This technology of preparing process is simple, it is not necessary to complicated reaction and high temperature；The good conductivity of the conductive fabric of preparation.
Description
Technical field
The present invention relates to textile finishing technical field, and in particular to a kind of preparation method of layer/polyaniline conductive bafta.
Background technology
Conductive fabric has conductive, antistatic and electromagnetic radiation resisting function, can prepare sensor, intelligent clothing and can roll over
The high-tech products such as folded battery, therefore have important in multiple fields such as sensor, chemistry, biology, medical science and Aero-Space
Effect.Due to light weight, raw material is easy to get organic composite conductive fabric with cotton as substrate, low price, good stability, electrical conductivity
Adjustable the features such as, be one of most promising conductive fabric.Due to polyaniline, in usual vehicle, dissolubility is very poor, to equipment and
The requirement of spinning technique is very harsh, so the preparation method of polyaniline conductive fabric mainly adopts situ aggregation method, but it is poly-
Aniline needs processing step more the in-situ polymerization of cotton, and technique is longer, is difficult the shortcomings of uniformly processing.
The content of the invention
Problem to be solved by this invention is to provide a kind of preparation process is simple, the layer/polyaniline conductive bafta of good conductivity
Preparation method, the present invention adopts the following technical scheme that.
A kind of preparation method of layer/polyaniline conductive bafta, comprises the steps：（1）Phenol is dissolved in into dimethyl sulfoxide
In；（2）Polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, blackish green clear solution is obtained；
（3）Bafta is put in above-mentioned solution, vibration is heated to 30 ~ 60 C, insulation continues 5 ~ 30min；（4）Dimethyl is used respectively
Sulfoxide and washing with alcohol are for several times；（5）Finally the fabric after washing is placed in the camphorsulfonic acid solution of 200g/L doping 30 ~
120min, dries under 80 C after taking-up, you can obtain layer/polyaniline conductive bafta.
Further, the dimethyl sulfoxide of described dimethyl sulfoxide/phenol mixed solution and the mass ratio of phenol are 1:
0.1~3。
Further, described polyaniline and the mass ratio of dimethyl sulfoxide/phenol mixed solution are 1:200~4000.
The beneficial effects of the present invention is, the preparation method of layer/polyaniline conductive bafta is simple, it is not necessary to complicated reaction
And high temperature；The good conductivity of the conductive fabric of preparation.
Specific embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic is not construed as isolated, and they can be mutually combined so as to reach preferably
Technique effect.
Embodiment 1
The preparation method detailed step of layer/polyaniline conductive bafta is as follows：
（1）20g phenol is dissolved in 180g dimethyl sulfoxide；
（2）0.2g polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, obtains blackish green transparent
Solution；
（3）10g baftas are put in above-mentioned solution, vibration is heated to 60 C, insulation continues 30min；
（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；
（5）Fabric after washing is finally placed in the camphorsulfonic acid solution of 200g/L the 60min that adulterates, is dried under 80 C after taking-up
It is dry, you can to obtain layer/polyaniline conductive bafta.
Embodiment 2
The preparation method detailed step of layer/polyaniline conductive bafta is as follows：
（1）300g phenol is dissolved in 100g dimethyl sulfoxide；
（2）0.9g polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, obtains blackish green transparent
Solution；
（3）10g baftas are put in above-mentioned solution, vibration is heated to 30 C, insulation continues 30min；
（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；
（5）Fabric after washing is finally placed in the camphorsulfonic acid solution of 200g/L the 120min that adulterates, is dried under 80 C after taking-up
It is dry, you can to obtain layer/polyaniline conductive bafta.
Embodiment 3
The preparation method detailed step of layer/polyaniline conductive bafta is as follows：
（1）50g phenol is dissolved in 250g dimethyl sulfoxide；
（2）0.1g polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, obtains blackish green transparent
Solution；
（3）10g baftas are put in above-mentioned solution, vibration is heated to 50 C, insulation continues 10min；
（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；
（5）Fabric after washing is finally placed in the camphorsulfonic acid solution of 200g/L the 30min that adulterates, is dried under 80 C after taking-up
It is dry, you can to obtain layer/polyaniline conductive bafta.
Embodiment 4
The preparation method detailed step of layer/polyaniline conductive bafta is as follows：
（1）200g phenol is dissolved in 200g dimethyl sulfoxide；
（2）1g polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, obtains blackish green transparent molten
Liquid；
（3）10g baftas are put in above-mentioned solution, vibration is heated to 40 C, insulation continues 15min；
（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；
（5）Fabric after washing is finally placed in the camphorsulfonic acid solution of 200g/L the 90min that adulterates, is dried under 80 C after taking-up
It is dry, you can to obtain layer/polyaniline conductive bafta.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
Should be using the embodiments herein as the restriction of interest field of the present invention.
Claims (3)
1. a kind of preparation method of layer/polyaniline conductive bafta, it is characterised in that comprise the steps：
（1）Phenol is dissolved in dimethyl sulfoxide；
（2）Polyaniline in eigenstate is dissolved in dimethyl sulfoxide/phenol mixed solution, under ultrasound, obtains blackish green transparent molten
Liquid；
（3）Bafta is put in above-mentioned solution, vibration is heated to 30 ~ 60 C, insulation continues 5 ~ 30min；
（4）Use dimethyl sulfoxide and washing with alcohol for several times respectively；
（5）Fabric after washing is finally placed in 30 ~ 120min of doping in the camphorsulfonic acid solution of 200g/L, after taking-up under 80 C
Drying, you can obtain layer/polyaniline conductive bafta.
2. the preparation method of layer/polyaniline conductive bafta as claimed in claim 1, described dimethyl sulfoxide/phenol mixing are molten
The dimethyl sulfoxide of liquid is 1 with the mass ratio of phenol:0.1~3.
3. the preparation method of layer/polyaniline conductive bafta as claimed in claim 1, described polyaniline and dimethyl sulfoxide/benzene
The mass ratio of phenol mixed solution is 1:200~4000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089758.2A CN106544869A (en) | 2016-12-01 | 2016-12-01 | The preparation method of layer/polyaniline conductive bafta |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611089758.2A CN106544869A (en) | 2016-12-01 | 2016-12-01 | The preparation method of layer/polyaniline conductive bafta |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106544869A true CN106544869A (en) | 2017-03-29 |
Family
ID=58396067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611089758.2A Pending CN106544869A (en) | 2016-12-01 | 2016-12-01 | The preparation method of layer/polyaniline conductive bafta |
Country Status (1)
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| CN (1) | CN106544869A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845753A (en) * | 2010-05-14 | 2010-09-29 | 苏州新纶超净技术有限公司 | Anti-static/conductive fabric and manufacture method thereof |
| CN102619093A (en) * | 2011-01-26 | 2012-08-01 | 北京服装学院 | Super-hydrophobic washable conductive fabric and preparation method thereof |
| CN105088412A (en) * | 2015-08-06 | 2015-11-25 | 丁德凤 | Preparation method for polyaniline compound conductive fibers |
| CN105133293A (en) * | 2015-07-07 | 2015-12-09 | 哈尔滨工业大学 | Preparation method of conductive nanocomposite material |
-
2016
- 2016-12-01 CN CN201611089758.2A patent/CN106544869A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845753A (en) * | 2010-05-14 | 2010-09-29 | 苏州新纶超净技术有限公司 | Anti-static/conductive fabric and manufacture method thereof |
| CN102619093A (en) * | 2011-01-26 | 2012-08-01 | 北京服装学院 | Super-hydrophobic washable conductive fabric and preparation method thereof |
| CN105133293A (en) * | 2015-07-07 | 2015-12-09 | 哈尔滨工业大学 | Preparation method of conductive nanocomposite material |
| CN105088412A (en) * | 2015-08-06 | 2015-11-25 | 丁德凤 | Preparation method for polyaniline compound conductive fibers |
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Application publication date: 20170329 |