CN106930110B - A method of improving polypyrrole wool conductive fabric electric conductivity - Google Patents
A method of improving polypyrrole wool conductive fabric electric conductivity Download PDFInfo
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- CN106930110B CN106930110B CN201710201684.5A CN201710201684A CN106930110B CN 106930110 B CN106930110 B CN 106930110B CN 201710201684 A CN201710201684 A CN 201710201684A CN 106930110 B CN106930110 B CN 106930110B
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- 239000004744 fabric Substances 0.000 title claims abstract description 55
- 210000002268 wool Anatomy 0.000 title claims abstract description 55
- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000000243 solution Substances 0.000 claims abstract description 56
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 47
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 31
- 239000011651 chromium Substances 0.000 claims abstract description 31
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 27
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 27
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 description 24
- 230000035484 reaction time Effects 0.000 description 13
- 238000001514 detection method Methods 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 5
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920001940 conductive polymer Polymers 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 206010011224 Cough Diseases 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005424 photoluminescence Methods 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polyparaphenylene Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0611—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polypyrroles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of methods for improving polypyrrole wool conductive fabric electric conductivity, immerse in pure liquefied ammonia wool cloth handle 20-60 seconds first, dry after taking-up；Wool cloth through Liquid Ammonia Treatment is immersed in the chromium solution of 0.02-0.1mol/L；It is added dropwise to the ferric chloride in aqueous solution of 0.02-0.2mol/L while stirring, reacts 1-6 hours；It rinses well and is dried in vacuo at room temperature.The beneficial effects of the invention are as follows the electric conductivity of the polypyrrole wool conductive fabric of treated wool is good.
Description
Technical field
The invention belongs to textile fiber technology fields, are related to a kind of side for improving polypyrrole wool conductive fabric electric conductivity
Method.
Background technique
Conductive fiber is widely used in people's lives, including for prevent electromagnetic radiation pollution, electromagnetic-wave leakage,
The electromagnetic shielding material of human health etc. is protected, and for treating chronic wounds using electro photoluminescence as supplementary mode
Conductive material.Conductive material is usually to prepare conductive fabric by top finish method using metal material as filler.But
The conductive fabric of this top finish using metal packing can be such that the performances such as fabric feeling, washable, antifriction, perspiration resistance decline.
And the conductive fabric of conductive polymer polymer is used, compared with the conductive fabric that metal coating arranges, have feel frivolous, saturating
The advantages that gas is good has more advantage than metal shield materials.
The representative conducting polymer synthesized at present has polyacetylene, polyparaphenylene, polyaniline, polythiophene, polyphenyl
Acetylene and polypyrrole etc..Wherein, polypyrrole is a kind of typically with the conducting polymer of big conjugated double bond structures, is led with height
The advantages that stable and easily prepared in electric rate, air, thus it is widely used in electrochemistry, electrode material, optics and conduction material
Material etc..The method for preparing Polypyrrole Conducting Materials has chemical oxidising polymerisation and electrochemical polymerization, develops again on this basis
Template sol-gel method and method of electrostatic spinning.Wherein chemical oxidization method synthesis polypyrrole is relatively easy, easy, is common
One of method.But the electric conductivity of the polypyrrole wool conductive fiber of the wool of non-Liquid Ammonia Treatment is poor at present, and has waste water
It generates.
Summary of the invention
The purpose of the present invention is to provide a kind of methods for improving polypyrrole wool conductive fabric electric conductivity, solve at present
The poor problem of the electric conductivity of the polypyrrole wool conductive fabric of the wool of non-Liquid Ammonia Treatment.
The technical scheme adopted by the invention is that following the steps below:
Step 1: wool cloth being immersed in pure liquefied ammonia and is handled 20-60 seconds, is dried after taking-up；
Step 2: the wool cloth through Liquid Ammonia Treatment being immersed in the chromium solution of 0.02-0.1mol/L and is handled；
Step 3: being added dropwise to the ferric chloride in aqueous solution of 0.02-0.2mol/L while stirring, react 1-6 hours；
Step 4: rinsing well and be dried in vacuo at room temperature.
Further, wool cloth is immersed in pure liquefied ammonia in the step 1 and is handled 30 seconds.
Further, chromium solution concentration is 0.06mol/L in the step 2, and the processing time is 20 minutes.
Further, ferric chloride in aqueous solution concentration is 2 times of chromium solution concentration in the step 3.
Further, the reaction time is 4 hours in the step 3.
The beneficial effects of the invention are as follows the polypyrrole wool conductive fabric electric conductivity of treated wool is good.
Specific embodiment
The present invention is described in detail With reference to embodiment.
The present invention improves the electric conductivity of polypyrrole wool conductive fabric using Liquid Ammonia Treatment wool cloth.Wool cloth is soaked first
Enter and handle 20-60 seconds, preferably 30 seconds in pure liquefied ammonia, is dried after taking-up；Wool cloth through Liquid Ammonia Treatment is immersed in chromium solution
In (0.02-0.1mol/L, preferential 0.06mol/L) processing, be added dropwise to while stirring ferric chloride in aqueous solution (0.02-0.2mol/L,
Preferred content is 2 times of chromium solution concentration), it reacts 1-6 hours, preferably 4 hours, rinses well and vacuum is dry at room temperature
It is dry, the preparation of the excellent polypyrrole wool conductive fabric of electric conductivity is completed, its surface resistivity is detected.
Embodiment 1
The wool cloth of 4g is immersed in pure liquefied ammonia and is handled 20,30,40,50 and 60 seconds, drying is then taken out.Will without and warp
The wool cloth of Liquid Ammonia Treatment be immersed in the chromium solution of 200mL (0.02mol/L) handle 20 minutes, stirring, be slowly added dropwise into
The ferric chloride solution of the 0.04mol/L of 20mL carries out home position polymerization reaction, and reaction maintains 2 hours.Then polypyrrole wool is led
Electric cloth takes out, and is dried in vacuo at room temperature after being rinsed with water completely.
Polypyrrole wool conductive fabric after drying is subjected to surface resistivity detection, each sample detection 5 times, and is averaged
Value, the results are shown in Table 1.Surface resistivity is higher, and its electric conductivity of expression is poorer.Polypyrrole wool in table 1 through Liquid Ammonia Treatment
The surface resistivity of conductive fabric is lower than the surface resistivity without Liquid Ammonia Treatment, shows that Liquid Ammonia Treatment can reduce polypyrrole wool and lead
The surface resistivity of electric cloth, and after Liquid Ammonia Treatment 30 seconds, the poly- pyrrole of polymerization preparation in 2 hours in 0.02mol/L chromium solution
The surface resistivity for coughing up wool conductive fabric is minimum, it was demonstrated that its electric conductivity is best.
The surface resistivity of the polypyrrole wool conductive fabric of the different Liquid Ammonia Treatment time preparations of table 1.
| Liquid Ammonia Treatment | Surface resistivity (Ω/cm-2) |
| Without liquefied ammonia pre-treatment | 465.28 |
| Liquid Ammonia Treatment 20 seconds | 326.13 |
| Liquid Ammonia Treatment 30 seconds | 254.73 |
| Liquid Ammonia Treatment 40 seconds | 289.26 |
| Liquid Ammonia Treatment 50 seconds | 302.84 |
| Liquid Ammonia Treatment 60 seconds | 322.68 |
Embodiment 2
The wool cloth of 4g is immersed in pure liquefied ammonia and is handled 30 seconds, drying is then taken out.By the wool cloth leaching through Liquid Ammonia Treatment
Enter into the chromium solution of 200mL (0.02mol/L) to handle 20 minutes, the chlorine of the 0.04mol/L into 20mL is slowly added dropwise in stirring
Change ferrous solution and carry out home position polymerization reaction, reaction maintains 1,2,3,4,5 and 6 hour.Then polypyrrole wool conductive fabric is taken out,
It is dried in vacuo at room temperature after being rinsed with water completely.
Polypyrrole wool conductive fabric after drying is subjected to surface resistivity detection, each sample detection 5 times, and is averaged
Value, the results are shown in Table 2.Surface resistivity is higher, and its electric conductivity of expression is poorer.4 hours samples of polymerization reaction time in table 2
Surface resistivity it is low minimum, although when the surface resistivity and polymerization reaction of 5 hours and 6 hours samples of polymerization reaction time
Between 4 hours samples it is close, consider combined coefficient and cost factor, determine polymerization reaction time 4 hours for optimal polymerization reaction
Time.
The different polymerization reaction times of table 2. prepare the surface resistivity of polypyrrole wool conductive fabric
| Polymerization reaction time | Surface resistivity (Ω/cm-2) |
| Polymerization reaction time 1 hour | 327.58 |
| Polymerization reaction time 2 hours | 254.73 |
| Polymerization reaction time 3 hours | 224.65 |
| Polymerization reaction time 4 hours | 203.98 |
| Polymerization reaction time 5 hours | 206.04 |
| Polymerization reaction time 6 hours | 205.41 |
Embodiment 3
The wool cloth of 4g is immersed in pure liquefied ammonia and is handled 30 seconds, drying is then taken out.By the wool cloth leaching through Liquid Ammonia Treatment
Enter into the chromium solution of 200mL (0.02,0.04,0.06,0.08 and 0.10mol/L) to handle 20 minutes, stirring, correspondingly
Ferric chloride solution (the i.e. concentration of ferric chloride solution of 0.04 into 20mL, 0.08,0.12,0.16 and 0.2mol/L is slowly added dropwise
It is 2 times of chromium solution concentration) home position polymerization reaction is carried out, reaction maintains 4 hours.Then polypyrrole wool conductive fabric is taken
Out, it is dried in vacuo at room temperature after being rinsed with water completely.
Polypyrrole wool conductive fabric after drying is subjected to surface resistivity detection, each sample detection 5 times, and is averaged
Value, the results are shown in Table 3.Surface resistivity is higher, and its electric conductivity of expression is poorer.0.06mol/L chromium solution polymerize in table 3
The surface resistivity of manufactured polypyrrole wool conductive fabric is low minimum, although in the pyrrole that concentration is 0.08mol/L and 0.10mol/L
The surface resistivity for coughing up manufactured polypyrrole wool conductive fabric in solution is close with the sample of 0.06mol/L chromium solution, considers
Combined coefficient and cost factor, it is optimal polymerization reaction concentration that the concentration for determining chromium solution, which is 0.06mol/L,.
The surface resistivity of the polypyrrole wool conductive fabric of 3. various concentration chromium solution of table polymerization preparation
| Chromium solution concentration | Ferric chloride solution concentration | Surface resistivity (Ω/cm-2) |
| 0.02mol/L chromium solution | 0.04mol/L ferric chloride solution | 203.98 |
| 0.04mol/L chromium solution | 0.08mol/L ferric chloride solution | 194.23 |
| 0.06mol/L chromium solution | 0.12mol/L ferric chloride solution | 180.46 |
| 0.08mol/L chromium solution | 0.16mol/L ferric chloride solution | 181.98 |
| 0.10mol/L chromium solution | 0.20mol/L ferric chloride solution | 182.04 |
Embodiment 4
The wool cloth of 4g is immersed in pure liquefied ammonia and is handled 30 seconds, drying is then taken out.By the wool cloth leaching through Liquid Ammonia Treatment
Enter the 0.06mol/L into the chromium solution of 200mL) processing 20 minutes, stirring is slowly added dropwise 0.04 into 20mL, 0.08 respectively,
The ferric chloride solution of 0.12,0.16 and 0.2mol/L carries out home position polymerization reaction, and reaction maintains 4 hours.Then by polypyrrole sheep
Hair conductive fabric takes out, and is dried in vacuo at room temperature after being rinsed with water completely.
Polypyrrole wool conductive fabric after drying is subjected to surface resistivity detection, each sample detection 5 times, and is averaged
Value, the results are shown in Table 4.Surface resistivity is higher, and its electric conductivity of expression is poorer.In table 4 in 0.06mol/L chromium solution
The surface resistivity for being added dropwise to polypyrrole wool conductive fabric made of the polymerization of 0.12mol/L ferric chloride solution is low minimum, although
The surface resistivity of polypyrrole wool conductive fabric made of the ferric chloride solution that concentration is 0.16mol/L and 0.20mol/L is added dropwise
It is close with the sample of 0.12mol/L ferric chloride solution, consider combined coefficient and cost factor, determines that the concentration of ferric chloride solution is
0.12mol/L is optimal polymerization reaction concentration, i.e., it is most preferably to compare that the concentration of ferric chloride solution, which is 2 times of chromium solution concentration,
Example.
The surface resistivity of the polypyrrole wool conductive fabric of 4. various concentration ferric chloride solution of table polymerization preparation
| Chromium solution concentration | Ferric chloride solution concentration | Surface resistivity (Ω/cm-2) |
| 0.06mol/L chromium solution | 0.04mol/L ferric chloride solution | 253.62 |
| 0.06mol/L chromium solution | 0.08mol/L ferric chloride solution | 215.59 |
| 0.06mol/L chromium solution | 0.12mol/L ferric chloride solution | 180.46 |
| 0.06mol/L chromium solution | 0.16mol/L ferric chloride solution | 189.07 |
| 0.06mol/L chromium solution | 0.20mol/L ferric chloride solution | 191.33 |
The present invention improves the electric conductivity of polypyrrole wool conductive fabric, liquefied ammonia after processing by wool liquefied ammonia pre-treating method
It is easy recycling and reusing, reduces pollution；The electric conductivity of polypyrrole wool conductive fabric by the method for the present invention Liquid Ammonia Treatment is good
It is good, and generated without waste water.
The above is only not to make limit in any form to the present invention to better embodiment of the invention
System, any simple modification that embodiment of above is made according to the technical essence of the invention, equivalent variations and modification,
Belong in the range of technical solution of the present invention.
Claims (1)
1. a kind of method for improving polypyrrole wool conductive fabric electric conductivity, it is characterised in that follow the steps below:
Step 1: wool cloth being immersed in pure liquefied ammonia and is handled 30 seconds, is dried after taking-up；
Step 2: the wool cloth through Liquid Ammonia Treatment being immersed in the chromium solution of 0.06mol/L and is handled；
Step 3: being added dropwise to the ferric chloride in aqueous solution of 0.12mol/L while stirring, react 4 hours；
Step 4: rinsing well and be dried in vacuo at room temperature.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710201684.5A CN106930110B (en) | 2017-03-30 | 2017-03-30 | A method of improving polypyrrole wool conductive fabric electric conductivity |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201684.5A CN106930110B (en) | 2017-03-30 | 2017-03-30 | A method of improving polypyrrole wool conductive fabric electric conductivity |
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| CN106930110A CN106930110A (en) | 2017-07-07 |
| CN106930110B true CN106930110B (en) | 2019-08-20 |
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| CN110656497A (en) * | 2019-09-05 | 2020-01-07 | 浙江省检验检疫科学技术研究院 | Preparation method of poly (3, 4-ethylenedioxythiophene)/cotton composite fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103276500A (en) * | 2013-05-31 | 2013-09-04 | 江阴福斯特纺织有限公司 | Super cotton-like cashmere double-side fabric and production process thereof |
| CN103981719A (en) * | 2014-05-23 | 2014-08-13 | 青岛大学 | Method for preparing anti-ultraviolet polyaniline titanium dioxide conductive fabric |
| CN104562403A (en) * | 2014-12-31 | 2015-04-29 | 宁波天亚服装有限公司 | Environment-friendly soft anti-wrinkle knitted fabric and production method thereof |
| CN105088797A (en) * | 2015-09-07 | 2015-11-25 | 江苏阳光股份有限公司 | Non-ironing treatment method capable of improving strength of wool fabric |
| CN106758240A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conduction wool fabric |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103276500A (en) * | 2013-05-31 | 2013-09-04 | 江阴福斯特纺织有限公司 | Super cotton-like cashmere double-side fabric and production process thereof |
| CN103981719A (en) * | 2014-05-23 | 2014-08-13 | 青岛大学 | Method for preparing anti-ultraviolet polyaniline titanium dioxide conductive fabric |
| CN104562403A (en) * | 2014-12-31 | 2015-04-29 | 宁波天亚服装有限公司 | Environment-friendly soft anti-wrinkle knitted fabric and production method thereof |
| CN105088797A (en) * | 2015-09-07 | 2015-11-25 | 江苏阳光股份有限公司 | Non-ironing treatment method capable of improving strength of wool fabric |
| CN106758240A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conduction wool fabric |
Non-Patent Citations (1)
| Title |
|---|
| 液氨整理对纺织纤维的作用;孙伟;《纺织科技进展》;20080825(第4期);第11,28页 |
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