CN106635300A - 一种环境友好钛合金Ti6A14V切削液的组合物 - Google Patents

一种环境友好钛合金Ti6A14V切削液的组合物 Download PDF

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CN106635300A
CN106635300A CN201610840980.5A CN201610840980A CN106635300A CN 106635300 A CN106635300 A CN 106635300A CN 201610840980 A CN201610840980 A CN 201610840980A CN 106635300 A CN106635300 A CN 106635300A
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titanium alloy
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i6a14v
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oil
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黄福川
肖锋
黄军
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Guangxi University
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Abstract

本发明公开了一种环境友好钛合金Ti6A14V切削液的组合物，采用质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合作为基础油，配合多种复合添加剂，包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、抗泡剂、防雾剂、催冷剂、补强剂、抗氧防腐剂等。本发明的组合物具有良好的冷却性、润滑性、承载能力、减摩减振性、清洗和排屑作用，防锈、抗氧防腐蚀、消泡性好、抗腐败、低气味、无刺激性。

Description

一种环境友好钛合金Ti6A14V切削液的组合物
技术领域
本发明属于金属加工润滑剂领域，特别涉及一种环境友好钛合金Ti6A14V切削液的组合物。
背景技术
由于钛合金Ti6A14V具有优越的机械性能特性，被广泛应用于海洋工程和航空航天工业结构组件的制造。它具有良好的比强度，较强的耐腐蚀性和高温下保持高强度的能力。可是钛合金Ti6A14V不仅是一种很难进行机械加工的材料，而且在加工过程中会导致刀具的快速磨损。磨损是由于摩擦的存在使得在相对运动过程中，产生能量的损耗或表面材料的磨损情况。若仅仅宏观上看其接触表面是光滑的，但从细观上看，确是众多微凸体之间的相互作用。
钛合金Ti6A14V材料具有导热系数低。在高温下，材料的强度和硬度变化不大。因此切削阻力大。此外，由于其韧性高，切削易黏附，故在加工时，切具磨损快，易崩刀，加工件表面质量差，易出现裂纹及切屑瘤残系数等瑕疵。
金属的加工方法繁多，但切削加工始终是最常见、应用最广泛的一种。金属切削是重要的机械加工手段，按其所用切削工具类型可分为两大类；一类是用刀具进行的切削加工；另一类是用磨料进行磨削加工。金属切削和磨削加工是一种利用带刃口的切削工具(刀具或砂轮)在切削机床上将工件的多余金属切去，从而是工件获得规则的几何形状，尺寸精度和表面质量的加工方法。金属切削过程通常可分为两个阶段，即切削的产生和及时清除。这两个阶段存在着刀具与工件、刀具与切屑之间的摩擦，这种摩擦消耗的能量转变为热，它会影响加工效率和工件质量。由于严重的摩擦产生大量的热，使刀具和工件过热，降低刀具寿命，影响产品精度。为了冷却和润滑刀具及工件，必须使用切削润滑剂以及时带走切削产生的热量，降低刀具和工件的温度并起到润滑作用；提高工件表面光洁度，并延长刀具的使用寿命。
切削油与普通润滑油使用工况不同，普通润滑油是处在反复移动的不变摩擦面之间，尽管有的压力很大，但容易形成润滑油膜。而切削油则是时时接触切削所形成的新鲜表面，加工面连续发生弹性形变，因而刀具与被加工面间所承受的压力要比一般润滑状态大得多。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却性、润滑性、承载能力、减摩减振性、清洗和排屑作用，防锈、抗氧防腐蚀、消泡性好、抗腐败、低气味、无刺激性的环境友好钛合金Ti6A14V切削液的组合物。
本发明采用如下技术方案解决上述技术问题：
一种环境友好钛合金Ti6A14V切削液的组合物，采用质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.1％～0.6％
金属减活剂 0.2％～1％
油性剂 4％～6％
摩擦改进剂 1％～3％
极压剂 2％～5％
抗磨剂 4％～6％
抗泡剂 10～50ppm
防雾剂 3％～4％
催冷剂 1％～6％
补强剂 3％～4％
抗氧防腐剂 0.5％～1.5％
以上各组分质量百分比总和为100％。
抗氧剂是质量比67％的合铜抗氧剂T541与2,6-二叔丁基混合酚T502A复合；金属减活剂是苯***衍生物T551。
油性剂是硫化烯烃棉籽油T405；摩擦改进剂是二烷基二硫代磷酸氧钼T462。
极压剂是酸性亚磷酸二丁酯T304；抗磨剂是硫化三聚丁烯；抗泡剂是甲基硅油T901。
防雾剂是乙丙共聚物T612；催冷剂是石油磺酸钠T702。
补强剂是氯化石蜡T302；抗氧防腐剂是二烷基二硫代氨基甲酸酯。
本发明的组合物优点在于：具有良好的冷却性、润滑性、承载能力、减摩减振性、清洗和排屑作用，防锈、抗氧防腐蚀、消泡性好、抗腐败、低气味、无刺激性。
具体实施方式
实施例1：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合 余量
质量比67％的合铜抗氧剂(T541)与2,6-二叔丁基混合酚(T502A)复合 0.1％
苯***衍生物(T551) 1％
硫化烯烃棉籽油(T405) 4％
二烷基二硫代磷酸氧钼(T462) 3％
酸性亚磷酸二丁酯(T304) 5％
硫化三聚丁烯 5％
甲基硅油(T901) 50ppm
乙丙共聚物(T612) 3％
石油磺酸钠(T702) 4％
氯化石蜡(T302) 4％
二烷基二硫代氨基甲酸酯 1％
以上各组分质量百分比总和为100％。
实施例2：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合 69.5％
质量比67％的合铜抗氧剂(T541)与2,6-二叔丁基混合酚(T502A)复合 0.5％
苯***衍生物(T551) 1％
硫化烯烃棉籽油(T405) 6％
二烷基二硫代磷酸氧钼(T462) 1％
酸性亚磷酸二丁酯(T304) 5％
硫化三聚丁烯 5％
甲基硅油(T901) 50ppm
乙丙共聚物(T612) 4％
石油磺酸钠(T702) 4％
氯化石蜡(T302) 3％
二烷基二硫代氨基甲酸酯 1％
以上各组分质量百分比总和为100％。
实施例3：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合 70.4％
质量比67％的合铜抗氧剂(T541)与2,6-二叔丁基混合酚(T502A)复合 0.6％
苯***衍生物(T551) 1％
硫化烯烃棉籽油(T405) 5％
二烷基二硫代磷酸氧钼(T462) 1％
酸性亚磷酸二丁酯(T304) 3％
硫化三聚丁烯 6％
甲基硅油(T901) 50ppm
乙丙共聚物(T612) 4％
石油磺酸钠(T702) 5％
氯化石蜡(T302) 3％
二烷基二硫代氨基甲酸酯 1％
以上各组分质量百分比总和为100％。
实施例3产品的主要理化指标：

Claims (7)

1.一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于：采用质量比75％的5号全损耗***用油与25％的蓖麻基癸二酸二辛酯复合作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.1％～0.6％ 金属减活剂 0.2％～1％ 油性剂 4％～6％ 摩擦改进剂 1％～3％ 极压剂 2％～5％ 抗磨剂 4％～6％ 抗泡剂 10～50ppm 防雾剂 3％～4％ 催冷剂 1％～6％ 补强剂 3％～4％ 抗氧防腐剂 0.5％～1.5％
以上各组分质量百分比总和为100％。
2.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于抗氧剂是质量比67％的合铜抗氧剂T541与2,6-二叔丁基混合酚T502A复合。
3.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于金属减活剂是苯***衍生物T551。
4.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于油性剂是硫化烯烃棉籽油T405；摩擦改进剂是二烷基二硫代磷酸氧钼T462。
5.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于极压剂是酸性亚磷酸二丁酯T304；抗磨剂是硫化三聚丁烯；抗泡剂是甲基硅油T901。
6.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于防雾剂是乙丙共聚物T612；催冷剂是石油磺酸钠T702。
7.如权利要求1所述的一种环境友好钛合金Ti6A14V切削液的组合物，其特征在于补强剂是氯化石蜡T302；抗氧防腐剂是二烷基二硫代氨基甲酸酯。
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