CN106348589A - Color enamel and preparation method thereof - Google Patents

Color enamel and preparation method thereof Download PDF

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Publication number
CN106348589A
CN106348589A CN201610704523.3A CN201610704523A CN106348589A CN 106348589 A CN106348589 A CN 106348589A CN 201610704523 A CN201610704523 A CN 201610704523A CN 106348589 A CN106348589 A CN 106348589A
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CN
China
Prior art keywords
parts
hours
cordierite
quartz
maifanitum
Prior art date
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Granted
Application number
CN201610704523.3A
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Chinese (zh)
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CN106348589B (en
Inventor
方薛斐
方卫明
张丽
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Wuxi Taihu University
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Yixing Fang Weiming Institute Of Pottery Art
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Application filed by Yixing Fang Weiming Institute Of Pottery Art filed Critical Yixing Fang Weiming Institute Of Pottery Art
Priority to CN201610704523.3A priority Critical patent/CN106348589B/en
Publication of CN106348589A publication Critical patent/CN106348589A/en
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Publication of CN106348589B publication Critical patent/CN106348589B/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses color enamel. The color enamel is prepared from the following components in parts by weight: 100 to 150 parts of potassium feldspar, 100 to 120 parts of medical stone, 80 to 100 parts of cordierite, 60 to 80 parts of quartz, 10 to 30 parts of zinc oxide and 10 to 40 parts of calcium oxide. Meanwhile, the invention further discloses a preparation method of the color enamel. Compared with a conventional technology, the color enamel is scientific in formula and low in raw material cost; secondary sintering is carried out in a preparation process so that the stability of the color enamel is greatly increased and the color enamel is suitable for colored drawing of various ceramic blanks.

Description

A kind of colour enamels and preparation method thereof
Technical field
The invention belongs to paint field is and in particular to a kind of colour enamels and preparation method thereof.
Background technology
Enamel ceramics be from painted enamel artware infiltration and development out, the feature of colour enamels is that porcelain is fine and glossy, color material Dignified, bright in colour beautiful, painter is exquisite.Traditional enamel ceramics need to carry out secondary firing, therefore after colored drawing on carcass All test to carcass and colour enamels, especially colour enamels when firing area may drying shrinkage or expansion, impact may be returned and burn Perception after one-tenth, and careless slightly can lead to colour enamels directly when firing ftracture.
Content of the invention
Goal of the invention: present invention aims to the deficiencies in the prior art, provide a kind of colour enamels.
Another object of the present invention is to providing the preparation method of above-mentioned colour enamels.
Technical scheme: in order to reach foregoing invention purpose, the present invention is specifically achieved like this kind of colour enamels, including The component of following parts by weight: 100 ~ 150 parts of potassium feldspar, 100 ~ 120 parts of Maifanitum, 80 ~ 100 parts of cordierite, 60 ~ 80 Part quartz, the calcium oxide of 10 ~ 30 parts of zinc oxide and 10 ~ 40 parts.
Wherein it is preferred to, it is grouped into by the group of following parts by weight: 150 parts of potassium feldspar, 100 parts of Maifanitum, 80 parts Cordierite, 60 parts of quartz, the calcium oxide of 20 parts of zinc oxide and 30 parts.
The method preparing above-mentioned colour enamels, comprises the following steps:
(1) measure each raw material by formula, carry out grinding and sieving；
(2) by the potassium feldspar after pulverizing, Maifanitum, cordierite and quartz addition kiln calcining, control temperature 1000 ~ 1100 DEG C, calcine 12 ~ 24 hours；
(3) oil cooling is carried out to the calcined mixed material of step (2) gained, when temperature is reduced to 600 ~ 700 DEG C add zinc oxide and Calcium oxide, continues to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；
(4) after step (3) terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 40 ~ 60% to send into ball together Grinding machine ball milling obtains final product for 12 ~ 24 hours.
Beneficial effect: the present invention compared with conventional art, the present invention compared with conventional art, scientific formulation, cost of material Low, due to further increasing the stability of colour enamels itself in the preparation through twice firing, it is suitable for the colored drawing of various ceramic matrixes.
Specific embodiment
Embodiment 1:
Take the potassium feldspar of 100 parts of parts by weight, 100 parts of Maifanitum, 80 parts of cordierite, 60 parts of quartz, 10 parts of oxygen Change the calcium oxide of zinc and 10 parts, carry out grinding and sieving, preferably 100 mesh sieves；By the potassium feldspar after pulverizing, Maifanitum, cordierite Add kiln calcining with quartz, control 1000 ~ 1100 DEG C of temperature, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out Oil cooling, adds zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C, continues to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；After post bake terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 40% to send into ball together Grinding machine ball milling obtains final product for 12 ~ 24 hours.
Embodiment 2:
Take the potassium feldspar of 150 parts of parts by weight, 120 parts of Maifanitum, 100 parts of cordierite, 80 parts of quartz, 30 parts Zinc oxide and 40 parts of calcium oxide, carry out grinding and sieving, preferably 100 mesh sieves；By the potassium feldspar after pulverizing, Maifanitum, violet Cordierite and quartz add kiln calcining, control 1000 ~ 1100 DEG C of temperature, calcine 12 ~ 24 hours；Calcined mixed material to gained Carry out oil cooling, add zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C, continue to be warmed up to 800 ~ 900 DEG C, persistently plus Heat 24 ~ 36 hours；After post bake terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 60% to send together Enter ball mill ball milling to obtain final product for 12 ~ 24 hours.
Embodiment 3:
Take the potassium feldspar of 140 parts of parts by weight, the cordierite of 115 parts of 90 parts of Maifanitum, 70 parts of quartz, 20 parts of oxidation The calcium oxide of zinc and 30 parts, carries out grinding and sieving, preferably 100 mesh sieves；By pulverize after potassium feldspar, Maifanitum, cordierite and Quartz adds kiln calcining, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours；Oil is carried out to the calcined mixed material of gained Cold, add zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C, continue to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；After post bake terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 50% to send into ball milling together Machine ball milling obtains final product for 12 ~ 24 hours.
Embodiment 4:
Take the potassium feldspar of 120 parts of parts by weight, 110 parts of Maifanitum, 85 parts of cordierite, 75 parts of quartz, 15 parts of oxygen Change the calcium oxide of zinc and 35 parts, carry out grinding and sieving, preferably 100 mesh sieves；By the potassium feldspar after pulverizing, Maifanitum, cordierite Add kiln calcining with quartz, control 1000 ~ 1100 DEG C of temperature, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out Oil cooling, adds zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C, continues to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；After post bake terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 45% to send into ball together Grinding machine ball milling obtains final product for 12 ~ 24 hours.
Embodiment 5:
Take the potassium feldspar of 145 parts of parts by weight, 105 parts of Maifanitum, 95 parts of cordierite, 70 parts of quartz, 15 parts of oxygen Change the calcium oxide of zinc and 25 parts, carry out grinding and sieving, preferably 100 mesh sieves；By the potassium feldspar after pulverizing, Maifanitum, cordierite Add kiln calcining with quartz, control 1000 ~ 1100 DEG C of temperature, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out Oil cooling, adds zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C, continues to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；After post bake terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 50% to send into ball together Grinding machine ball milling obtains final product for 12 ~ 24 hours.

Claims (3)

1. a kind of colour enamels it is characterised in that include following parts by weight component: 100 ~ 150 parts of potassium feldspar, 100 ~ 120 Part Maifanitum, 80 ~ 100 parts of cordierite, 60 ~ 80 parts of quartz, the calcium oxide of 10 ~ 30 parts of zinc oxide and 10 ~ 40 parts.
2. colour enamels according to claim 1 is it is characterised in that be grouped into by the group of following parts by weight: 150 parts of potassium Anhydrite, 100 parts of Maifanitum, 80 parts of cordierite, 60 parts of quartz, the calcium oxide of 20 parts of zinc oxide and 30 parts.
3. the method for the colour enamels described in preparation claim 1 or 2 is it is characterised in that comprise the following steps:
(1) measure each raw material by formula, carry out grinding and sieving；
(2) by the potassium feldspar after pulverizing, Maifanitum, cordierite and quartz addition kiln calcining, control temperature 1000 ~ 1100 DEG C, calcine 12 ~ 24 hours；
(3) oil cooling is carried out to the calcined mixed material of step (2) gained, when temperature is reduced to 600 ~ 700 DEG C add zinc oxide and Calcium oxide, continues to be warmed up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours；
(4) after step (3) terminates, naturally cool to less than 100 DEG C, add the water of raw material gross mass 40 ~ 60% to send into ball together Grinding machine ball milling obtains final product for 12 ~ 24 hours.
CN201610704523.3A 2016-08-23 2016-08-23 A kind of colour enamels and preparation method thereof Active CN106348589B (en)

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CN106348589B CN106348589B (en) 2019-11-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108107706A (en) * 2018-01-17 2018-06-01 广州番禺职业技术学院 One kind is micro- to paint enamel dial plate and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB674359A (en) * 1950-02-13 1952-06-25 Fulmer Res Inst Ltd Improvements relating to low emissivity coatings for metal surfaces
CN101157572A (en) * 2007-09-21 2008-04-09 陕西科技大学 Method for preparing complex-color glaze
CN101786795A (en) * 2009-12-31 2010-07-28 深圳市永丰源实业有限公司 Enamel glaze and preparation process thereof
CN102320864A (en) * 2011-06-02 2012-01-18 无锡暗星陶瓷有限公司 Purple-clay color enamel and preparation method thereof
CN102548920A (en) * 2009-04-06 2012-07-04 你和我技术有限公司 Exothermic enamel glaze, and exothermic container coated with same
CN105274424A (en) * 2015-09-02 2016-01-27 安徽灶上煌机械有限公司 Enamel wok with patterns on outer surface and manufacturing method of enamel wok

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB674359A (en) * 1950-02-13 1952-06-25 Fulmer Res Inst Ltd Improvements relating to low emissivity coatings for metal surfaces
CN101157572A (en) * 2007-09-21 2008-04-09 陕西科技大学 Method for preparing complex-color glaze
CN102548920A (en) * 2009-04-06 2012-07-04 你和我技术有限公司 Exothermic enamel glaze, and exothermic container coated with same
CN101786795A (en) * 2009-12-31 2010-07-28 深圳市永丰源实业有限公司 Enamel glaze and preparation process thereof
CN102320864A (en) * 2011-06-02 2012-01-18 无锡暗星陶瓷有限公司 Purple-clay color enamel and preparation method thereof
CN105274424A (en) * 2015-09-02 2016-01-27 安徽灶上煌机械有限公司 Enamel wok with patterns on outer surface and manufacturing method of enamel wok

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108107706A (en) * 2018-01-17 2018-06-01 广州番禺职业技术学院 One kind is micro- to paint enamel dial plate and preparation method thereof
CN108107706B (en) * 2018-01-17 2023-10-20 广州番禺职业技术学院 Micro-painted enamel dial and manufacturing method thereof

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Address after: 214063 Jiangsu province Binhu District of Wuxi City Qian Rong Lu No. 68

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