CN112499970A - Production process of ceramic tile with decorative glaze with golden bright metal cracks - Google Patents

Production process of ceramic tile with decorative glaze with golden bright metal cracks Download PDF

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Publication number
CN112499970A
CN112499970A CN202011618989.4A CN202011618989A CN112499970A CN 112499970 A CN112499970 A CN 112499970A CN 202011618989 A CN202011618989 A CN 202011618989A CN 112499970 A CN112499970 A CN 112499970A
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glaze
decorative
bright metal
quartz
raw materials
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CN202011618989.4A
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Inventor
朱琴芳
陈莉
邹菲菲
林吉芳
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Karobia China High Tech Materials Co ltd
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Karobia China High Tech Materials Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/10Frit compositions, i.e. in a powdered or comminuted form containing lead
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5037Clay, Kaolin
    • C04B41/504Engobes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a production process of a ceramic tile with a decorative glaze with golden bright metal cracks, which comprises the following steps: 1) preparing a blank; 2) preparing a ground glaze; 3) preparing overglaze; 4) producing ceramic tiles with the decorative glaze with golden bright metal cracks: firstly, spraying the ground glaze on a 10 x 10cm plain baked brick by using a high-pressure spray gun with the caliber of 2mm, and naturally drying; secondly, spraying the overglaze on the brick sprayed in the first step by using a high-pressure spray gun with the caliber of 2 mm; placing the bricks sprayed in the step two into drying equipment for drying; and fourthly, firing the dried bricks in the third step through a roller kiln to finally obtain the ceramic bricks with the decorative glaze with golden bright metal cracks. The invention is applied to the production of ceramic tiles, so that the decorative effect of the tiles is richer, the glossiness is good, the single metal glaze surface is richer, vivid and unique in texture, the metal glaze surface has unique decoration and artistry, the raw materials are unique, the effect controllability is strong, the universality is strong, and the popularization is convenient.

Description

Production process of ceramic tile with decorative glaze with golden bright metal cracks
Technical Field
The invention relates to a production process of a ceramic tile with decorative glaze with golden bright metal cracks.
Background
The glazed tile is a glazed tile with the surface being fired at high temperature and high pressure, and the glazed tile consists of two parts, namely a soil blank and a glazed surface. The crack glaze in the current market is only white or is similar to the traditional colored glaze, and in order to achieve the effect of golden bright metal cracks, secondary processing of noble metal is required, the process mode is complex, the stability is poor, and the control is difficult.
Disclosure of Invention
The invention aims to provide a production process of ceramic tiles with decorative glaze with golden and bright metal cracks, which is applied to ceramic tile production, enables the decorative effect of the tiles to be richer and more vivid, has good glossiness, enables a single metal glaze surface to be richer and more vivid, has unique textures, has unique decoration and artistry, has single raw material, strong controllability of effect, strong universality and convenient popularization.
The technical scheme of the invention is that the production process of the ceramic tile with the decorative glaze with golden bright metal cracks comprises the following steps:
1) preparing a blank: placing the low water absorption green body with the water absorption of less than 3% into a roller kiln for sintering;
2) preparing a ground glaze: selecting feldspar, soil, quartz and zirconium silicate as raw materials, mixing the raw materials in proportion, and ball-milling the mixture by using a rapid ball mill, wherein the specific gravity of the fineness is 1.70g/cm3The screen residue is less than 1 g;
3) preparing overglaze: frit, soil, quartz, feldspar, manganese oxide, coloring metal oxide and crystallization agent are selected as raw materials, mixed according to a certain proportion and then ball-milled, and the specific gravity of the fineness is 1.75g/cm3The residue on sieve is less than 0.6 g; wherein, the frit uses lead oxide and quartz as raw materials, the lead oxide and the quartz are mixed by a mixer and then put into a frit tank kiln for melting, the melted high-temperature liquid flows into water to be quenched into conformal particles with the diameter of 1-5mm, and the particles are dried to obtain the frit;
4) producing ceramic tiles with the decorative glaze with golden bright metal cracks:
preparing the ground glaze to the specific gravity of 1.6g/cm3Spraying the mixture onto 10 × 10cm baked brick with high-pressure spray gun with diameter of 2mm, and weight of 56g, and naturally drying for 1-2 min;
② preparing the overglaze to the specific gravity of 1.65g/cm3Spraying the brick sprayed in the first step with a high-pressure spray gun with the caliber of 2mm, wherein the weight is 8-10 g;
placing the bricks sprayed in the step two into drying equipment for drying;
and fourthly, firing the dried bricks in the third step through a roller kiln to finally obtain the ceramic bricks with the decorative glaze with golden bright metal cracks.
In a preferred embodiment of the present invention, the sintering temperature in step 1) is 800-.
In a preferred embodiment of the present invention, the raw materials in step 2) are weighed according to parts by weight: 35-45% of feldspar, 10-25% of soil, 10-20% of quartz and 10-20% of zirconium silicate.
In a preferred embodiment of the present invention, in the step 3), the glaze raw material is weighed according to the following parts by weight: 60-70% of clinker, 3-6% of soil, 3-5% of quartz, 10-13% of feldspar, 5-8% of manganese oxide, 1-3% of coloring metal oxide and 3-5% of crystallizing agent.
In a preferred embodiment of the present invention, in the step 3), the frit raw materials are weighed according to parts by weight: 60-70% of lead oxide and 20-40% of quartz, the melting temperature is 1500 ℃, the drying temperature is 120-180 ℃, and the drying time is 40-70 min.
In a preferred embodiment of the present invention, the drying temperature in the third step of step 4) is 100 ℃, and the drying time is 45-60 min.
In a preferred embodiment of the present invention: the sintering temperature in the fourth step 4) is 1120-1140 ℃, and the sintering time is 2-3 h.
The invention relates to a production process of a ceramic tile with a golden bright metal crack decoration glaze, which is applied to the production of the ceramic tile, so that the decoration effect of the tile is richer, the glossiness is good, a single metal glaze surface is richer and vivid, unique textures are provided, the tile has unique decoration and artistry, the raw materials are unique, the effect controllability is strong, the universality is strong, and the popularization is convenient.
Detailed Description
The following detailed description of the preferred embodiments of the present invention is provided to enable those skilled in the art to more readily understand the advantages and features of the present invention, and to clearly and unequivocally define the scope of the present invention.
The invention relates to a production process of a ceramic tile with decorative glaze with golden bright metal cracks, which comprises the following steps:
1) preparing a blank: placing the low water absorption green body with the water absorption of less than 3 percent into a roller kiln for sintering, wherein the sintering temperature is 800-900 ℃, and the sintering time is 1-2 h;
2) preparing a ground glaze: feldspar, soil, quartz and zirconium silicate are selected as raw materials, and the raw materials are weighed according to the parts by weight: 35-45% of feldspar, 10-25% of soil, 10-20% of quartz and 10-20% of zirconium silicate, mixing the components in proportion, and then ball-milling the mixture by adopting a rapid ball mill, wherein the specific gravity of the fineness is 1.70g/cm3The screen residue is less than 1 g;
3) preparing overglaze: frit, soil, quartz, feldspar, manganese oxide, coloring metal oxide and a crystallizing agent are selected as raw materials, and the raw materials are weighed according to the parts by weight: 60-70% of clinker, 3-6% of soil, 3-5% of quartz, 10-13% of feldspar, 5-8% of manganese oxide, 1-3% of coloring metal oxide and 3-5% of crystallizing agent, mixing the components according to a certain proportion, and then ball-milling the mixture, wherein the specific gravity of the fineness is 1.75g/cm3The residue on sieve is less than 0.6 g; wherein, the frit uses lead oxide and quartz as raw materials, and is weighed according to the parts by weight: 60-70% of lead oxide and 20-40% of quartz, mixing by a mixer, putting into a frit tank furnace for melting, wherein the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal particles with the diameter of 1-5mm, and drying to obtain the frit, wherein the drying temperature is 120-;
4) producing ceramic tiles with the decorative glaze with golden bright metal cracks:
preparing the ground glaze to the specific gravity of 1.6g/cm3Spraying the baked bricks with weight of 5-6g on a plain baked brick with diameter of 2mm with a high-pressure spray gun of 10 x 10cm for 1-2 min;
② preparing the overglaze to the specific gravity of 1.65g/cm3Spraying the brick sprayed in the first step with a high-pressure spray gun with the caliber of 2mm, wherein the weight is 8-10 g;
thirdly, placing the bricks sprayed in the second step into drying equipment for drying, wherein the drying temperature is 100 ℃, and the drying time is 45-60 min;
and fourthly, firing the dried bricks in the third step in a roller kiln at 1120-1140 ℃ for 2-3h to finally obtain the ceramic bricks of the decorative glaze with golden bright metal cracks.
Example one
Placing the low water absorption green body with the water absorption of less than 3 percent into a roller kiln for sintering, wherein the sintering temperature is 820 ℃, and the sintering time is 1.2 h; weighing the ground glaze according to the following weight parts: 42 percent of feldspar, 22 percent of soil, 18 percent of quartz and 18 percent of zirconium silicate are mixed according to the proportion and then are ball-milled by a rapid ball mill, and the specific gravity of the fineness is 1.70g/cm3The screen residue is less than 1 g; the overglaze is prepared by the following weight portions: 67% of clinker, 5% of soil, 4% of quartz, 11% of feldspar, 7% of manganese oxide, 2% of coloring metal oxide and 4% of crystallizing agent are mixed according to a certain proportion and then ball-milled, and the specific gravity of the fineness is 1.75g/cm3The residue on sieve is less than 0.6 g; wherein, the frit raw materials are weighed according to the parts by weight: 64% of lead oxide and 36% of quartz are mixed by a mixer and then put into a frit tank kiln for melting, wherein the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal particles with the diameter of 1-4mm, and the particles are dried to obtain the frit, the drying temperature is 170 ℃, and the drying time is 60 min; regulating the specific gravity of the ground glaze to 1.6g/cm3Spraying the mixture on a baked brick of 10 x 10cm by a high-pressure spray gun with the caliber of 2mm, wherein the weight is 5.3g, and the time is 1.7min after the mixture is naturally dried; then the overglaze is prepared to the specific gravity of 1.65g/cm3Spraying the mixture on the brick sprayed with the ground glaze by using a high-pressure spray gun with the caliber of the spray gun being 2mm, wherein the weight of the spray gun is 8.6 g; then, putting the brick sprayed with the overglaze into drying equipment for drying, wherein the drying temperature is 100 ℃, and the drying time is 55 min; and finally, firing the dried ceramic tile after the overglaze spraying through a roller kiln at the firing temperature of 1135 ℃ for 2.6 hours to finally obtain the ceramic tile with the golden bright metal crack decorative glaze.
Example two
Placing the low water absorption green body with the water absorption of less than 3 percent into a roller kiln for sintering, wherein the sintering temperature is 800-900 ℃, and the sintering time is 1-2 h; weighing the ground glaze according to the following weight parts: 45 percent of feldspar, 20 percent of soil, 16 percent of quartz,19 percent of zirconium silicate is mixed according to the proportion and then is ball milled by a rapid ball mill, and the specific gravity of the fineness is 1.70g/cm3The screen residue is less than 1 g; the overglaze is prepared by the following weight portions: 70 percent of clinker, 3 percent of soil, 5 percent of quartz, 12 percent of feldspar, 6 percent of manganese oxide, 1 percent of coloring metal oxide and 3 percent of crystallization agent are mixed according to the proportion and then ball milled, and the specific gravity of the fineness is 1.75g/cm3The residue on sieve is less than 0.6 g; wherein, the frit raw materials are weighed according to the parts by weight: 69% of lead oxide and 31% of quartz are mixed by a mixer and then put into a frit tank kiln for melting, wherein the melting temperature is 1500 ℃, the melted high-temperature liquid flows into water to be water-quenched into conformal particles with the diameter of 3-5mm, and the particles are dried to obtain the frit, wherein the drying temperature is 155 ℃, and the drying time is 65 min; regulating the specific gravity of the ground glaze to 1.6g/cm3Spraying the mixture on a baked brick of 10 x 10cm by a high-pressure spray gun with the caliber of 2mm, wherein the weight is 5.8g, and the time is 1.8min after the mixture is naturally dried; then the overglaze is prepared to the specific gravity of 1.65g/cm3Spraying the mixture on the brick sprayed with the ground glaze by using a high-pressure spray gun with the caliber of the spray gun being 2mm, wherein the weight of the spray gun is 9.2 g; then putting the brick sprayed with the overglaze into drying equipment for drying, wherein the drying temperature is 100 ℃, and the drying time is 60 min; and finally, firing the dried tile after the overglaze spraying through a roller kiln at 1140 ℃ for 2.4h to finally obtain the ceramic tile with the golden bright metal crack decorative glaze.
The ceramic tile with the golden bright metal crack decorative glaze produced by the process improves the decorative effect of the traditional glaze surface at one time. The decorative effect of the brick is richer, the glossiness is good, and a single metal glaze surface is richer, vivid and unique in texture, so that the brick has unique decoration and artistry. And the raw materials have unicity, strong controllability of effect and strong universality, and can be popularized in the industry.
The invention relates to a production process of ceramic tiles with decorative glaze with golden and bright metal cracks, which is applied to the production of ceramic tiles, so that the decorative effect of the tiles is richer, the glossiness is good, a single metal glaze surface is richer and vivid, unique textures are provided, the ceramic tiles have unique decoration and artistry, the raw materials are unique, the controllability of the effect is strong, the universality is strong, and the popularization is convenient.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be made by those skilled in the art without inventive work within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope defined by the claims.

Claims (7)

1. A production process of ceramic tiles with decorative glaze with golden bright metal cracks is characterized in that: the method comprises the following steps:
1) preparing a blank: placing the low water absorption green body with the water absorption of less than 3% into a roller kiln for sintering;
2) preparing a ground glaze: selecting feldspar, soil, quartz and zirconium silicate as raw materials, mixing the raw materials in proportion, and ball-milling the mixture by using a rapid ball mill, wherein the specific gravity of the fineness is 1.70g/cm3The screen residue is less than 1 g;
3) preparing overglaze: frit, soil, quartz, feldspar, manganese oxide, coloring metal oxide and crystallization agent are selected as raw materials, mixed according to a certain proportion and then ball-milled, and the specific gravity of the fineness is 1.75g/cm3The residue on sieve is less than 0.6 g; wherein, the frit uses lead oxide and quartz as raw materials, the lead oxide and the quartz are mixed by a mixer and then put into a frit tank kiln for melting, the melted high-temperature liquid flows into water to be quenched into conformal particles with the diameter of 1-5mm, and the particles are dried to obtain the frit;
4) producing ceramic tiles with the decorative glaze with golden bright metal cracks:
preparing the ground glaze to the specific gravity of 1.6g/cm3Spraying the baked bricks with weight of 5-6g on a plain baked brick with diameter of 2mm with a high-pressure spray gun of 10 x 10cm for 1-2 min;
② preparing the overglaze to the specific gravity of 1.65g/cm3Spraying the brick sprayed in the first step with a high-pressure spray gun with the caliber of 2mm, wherein the weight is 8-10 g;
placing the bricks sprayed in the step two into drying equipment for drying;
and fourthly, firing the dried bricks in the third step through a roller kiln to finally obtain the ceramic bricks with the decorative glaze with golden bright metal cracks.
2. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: the sintering temperature in the step 1) is 800-900 ℃, and the sintering time is 1-2 h.
3. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: the raw materials in the step 2) are weighed according to the parts by weight: 35-45% of feldspar, 10-25% of soil, 10-20% of quartz and 10-20% of zirconium silicate.
4. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: the glaze in the step 3) is prepared from the following raw materials in parts by weight: 60-70% of clinker, 3-6% of soil, 3-5% of quartz, 10-13% of feldspar, 5-8% of manganese oxide, 1-3% of coloring metal oxide and 3-5% of crystallizing agent.
5. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: in the step 3), the frit raw materials are weighed according to the parts by weight: 60-70% of lead oxide and 20-40% of quartz, the melting temperature is 1500 ℃, the drying temperature is 120-180 ℃, and the drying time is 40-70 min.
6. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: the drying temperature in the third step of the step 4) is 100 ℃, and the drying time is 45-60 min.
7. The process for producing ceramic tiles with a decorative glaze having golden bright metal cracks according to claim 1, wherein: the sintering temperature in the fourth step 4) is 1120-1140 ℃, and the sintering time is 2-3 h.
CN202011618989.4A 2020-12-31 2020-12-31 Production process of ceramic tile with decorative glaze with golden bright metal cracks Pending CN112499970A (en)

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CN114276166A (en) * 2021-11-30 2022-04-05 卡罗比亚(中国)高新材料有限公司 Processing technology of fast-fired colorful-luster metal-effect decorative glaze
CN116813387A (en) * 2023-07-27 2023-09-29 广东宏海陶瓷实业发展有限公司 Ceramic tile with ice cracking and flashing effects and preparation method thereof

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CN107500548A (en) * 2017-10-17 2017-12-22 湖南铜官海旭陶瓷有限公司 A kind of metal glaze and preparation method thereof
CN108715517A (en) * 2018-08-30 2018-10-30 佛山市荣冠玻璃建材有限公司 Potlery tile low temperature is burnt joss sticks Bin golden metallic luster glaze and preparation method slowly
CN111087253A (en) * 2019-12-19 2020-05-01 卡罗比亚(中国)高新材料有限公司 Decoration process on low-water-absorption ceramic surface

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114276166A (en) * 2021-11-30 2022-04-05 卡罗比亚(中国)高新材料有限公司 Processing technology of fast-fired colorful-luster metal-effect decorative glaze
CN116813387A (en) * 2023-07-27 2023-09-29 广东宏海陶瓷实业发展有限公司 Ceramic tile with ice cracking and flashing effects and preparation method thereof
CN116813387B (en) * 2023-07-27 2024-05-28 广东宏海陶瓷实业发展有限公司 Ceramic tile with ice cracking and flashing effects and preparation method thereof

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Application publication date: 20210316