CN106348589B - A kind of colour enamels and preparation method thereof - Google Patents
A kind of colour enamels and preparation method thereof Download PDFInfo
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- CN106348589B CN106348589B CN201610704523.3A CN201610704523A CN106348589B CN 106348589 B CN106348589 B CN 106348589B CN 201610704523 A CN201610704523 A CN 201610704523A CN 106348589 B CN106348589 B CN 106348589B
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- cordierite
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of colour enamels, the component including following parts by weight: 100 ~ 150 parts of potassium feldspar, 100 ~ 120 parts of medical stone, 80 ~ 100 parts of cordierite, 60 ~ 80 parts of quartz, 10 ~ 30 parts of zinc oxide and 10 ~ 40 parts of calcium oxide.Meanwhile the invention also discloses the preparation methods of above-mentioned colour enamels.The present invention is compared with traditional technology, and the present invention is compared with traditional technology, and formula science, cost of material is low, and the stability for further increasing colour enamels itself due to passing through twice firing in the preparation is suitble to the colored drawing of various ceramic matrixes.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of colour enamels and preparation method thereof.
Background technique
The characteristics of enamel ceramics are that infiltration and development comes out from painted enamel craftwork, colour enamels is that porcelain is fine and glossy, color material
Dignified, bright in colour beautiful, painter is exquisite.Traditional enamel ceramics needs carry out secondary firing on carcass after colored drawing, therefore
To carcass and colour enamels be test, especially colour enamels fire when area may drying shrinkage or expansion, may return influence burn
Perception after, and it is careless slightly will lead to colour enamels directly fire when cracking.
Summary of the invention
Goal of the invention: in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of colour enamels.
Another object of the present invention is to provide the preparation methods of above-mentioned colour enamels.
Technical solution: in order to achieve the above object of the invention, the present invention is specifically achieved like this kind of colour enamels, including
The component of following parts by weight: 100 ~ 150 parts of potassium feldspar, 100 ~ 120 parts of medical stone, 80 ~ 100 parts of cordierite, 60 ~ 80
The quartz of part, 10 ~ 30 parts of zinc oxide and 10 ~ 40 parts of calcium oxide.
Wherein it is preferred to be composed of the following parts by weight: 150 parts of potassium feldspar, 100 parts of medical stone, 80 parts
Cordierite, 60 parts of quartz, 20 parts of zinc oxide and 30 parts of calcium oxide.
The method for preparing above-mentioned colour enamels, comprising the following steps:
(1) each raw material is measured by formula, carries out grinding and sieving;
(2) smashed potassium feldspar, medical stone, cordierite and quartz are added kiln and calcined, control temperature 1000 ~
It 1100 DEG C, calcines 12 ~ 24 hours;
(3) oily cold, the addition oxidation when temperature is reduced to 600 ~ 700 DEG C is carried out to the resulting calcined mixed material of step (2)
Zinc and calcium oxide continue to be warming up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours;
(4) after to step (3), 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 40 ~ 60% is added is sent together
Enter ball mill ball milling 12 ~ 24 hours to obtain the final product.
The utility model has the advantages that the present invention, compared with traditional technology, the present invention is compared with traditional technology, formula science, cost of material
Stability that is low, further increasing colour enamels itself due to passing through twice firing in the preparation, is suitble to the colored drawing of various ceramic matrixes.
Specific embodiment
Embodiment 1:
Take 100 parts of parts by weight of potassium feldspar, 100 parts of medical stone, 80 parts of cordierite, 60 parts of quartz, 10 parts
Zinc oxide and 10 parts of calcium oxide, carry out grinding and sieving, preferably 100 meshes;By smashed potassium feldspar, medical stone, violet
Kiln calcining is added in green stone and quartz, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours;To resulting calcined mixed material
It is cold to carry out oil, zinc oxide and calcium oxide are added when temperature is reduced to 600 ~ 700 DEG C, continues to be warming up to 800 ~ 900 DEG C, persistently plus
Heat 24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 40% is added is sent together
Enter ball mill ball milling 12 ~ 24 hours to obtain the final product.
Embodiment 2:
Take 150 parts of parts by weight of potassium feldspar, 120 parts of medical stone, 100 parts of cordierite, 80 parts of quartz,
30 parts of zinc oxide and 40 parts of calcium oxide carry out grinding and sieving, preferably 100 meshes;By smashed potassium feldspar, wheat meal
Kiln calcining is added in stone, cordierite and quartz, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours;To resulting calcining
Mixture progress oil is cold, and zinc oxide and calcium oxide are added when temperature is reduced to 600 ~ 700 DEG C, continues to be warming up to 800 ~ 900 DEG C,
Continuous heating 24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, the water of total mass of raw material 60% is added
It is sent into ball mill ball milling together 12 ~ 24 hours to obtain the final product.
Embodiment 3:
Take 140 parts of parts by weight of potassium feldspar, 115 parts of 90 parts of medical stone of cordierite, 70 parts of quartz, 20 parts
Zinc oxide and 30 parts of calcium oxide carry out grinding and sieving, preferably 100 meshes;By smashed potassium feldspar, medical stone, violet is green
Kiln calcining is added in stone and quartz, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours;To resulting calcined mixed material into
Row oil is cold, and zinc oxide and calcium oxide are added when temperature is reduced to 600 ~ 700 DEG C, continues to be warming up to 800 ~ 900 DEG C, continuous heating
24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 50% is added is sent into together
Ball mill ball milling 12 ~ 24 hours to obtain the final product.
Embodiment 4:
Take 120 parts of parts by weight of potassium feldspar, 110 parts of medical stone, 85 parts of cordierite, 75 parts of quartz, 15 parts
Zinc oxide and 35 parts of calcium oxide, carry out grinding and sieving, preferably 100 meshes;By smashed potassium feldspar, medical stone, violet
Kiln calcining is added in green stone and quartz, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours;To resulting calcined mixed material
It is cold to carry out oil, zinc oxide and calcium oxide are added when temperature is reduced to 600 ~ 700 DEG C, continues to be warming up to 800 ~ 900 DEG C, persistently plus
Heat 24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 45% is added is sent together
Enter ball mill ball milling 12 ~ 24 hours to obtain the final product.
Embodiment 5:
Take 145 parts of parts by weight of potassium feldspar, 105 parts of medical stone, 95 parts of cordierite, 70 parts of quartz, 15 parts
Zinc oxide and 25 parts of calcium oxide, carry out grinding and sieving, preferably 100 meshes;By smashed potassium feldspar, medical stone, violet
Kiln calcining is added in green stone and quartz, controls 1000 ~ 1100 DEG C of temperature, calcines 12 ~ 24 hours;To resulting calcined mixed material
It is cold to carry out oil, zinc oxide and calcium oxide are added when temperature is reduced to 600 ~ 700 DEG C, continues to be warming up to 800 ~ 900 DEG C, persistently plus
Heat 24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 50% is added is sent together
Enter ball mill ball milling 12 ~ 24 hours to obtain the final product.
Claims (1)
1. a kind of preparation method of colour enamels, which is characterized in that take 140 parts of parts by weight of potassium feldspar, 115 parts of medical stone,
90 parts of cordierite, 70 parts of quartz, 20 parts of zinc oxide and 30 parts of calcium oxide carry out smashing it through 100 meshes;By powder
Kiln calcining is added in potassium feldspar after broken, medical stone, cordierite and quartz, controls 1000 ~ 1100 DEG C of temperature, calcining 12 ~ 24
Hour;Oily cold, addition zinc oxide and calcium oxide when temperature is reduced to 600 ~ 700 DEG C are carried out to resulting calcined mixed material, after
It is continuous to be warming up to 800 ~ 900 DEG C, continuous heating 24 ~ 36 hours;After to reheating, 100 DEG C are naturally cooled to hereinafter, being added
The water of total mass of raw material 50% is sent into ball mill ball milling 12 ~ 24 hours together to obtain the final product.
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CN201610704523.3A CN106348589B (en) | 2016-08-23 | 2016-08-23 | A kind of colour enamels and preparation method thereof |
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CN201610704523.3A CN106348589B (en) | 2016-08-23 | 2016-08-23 | A kind of colour enamels and preparation method thereof |
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CN106348589B true CN106348589B (en) | 2019-11-08 |
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CN108107706B (en) * | 2018-01-17 | 2023-10-20 | 广州番禺职业技术学院 | Micro-painted enamel dial and manufacturing method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101157572A (en) * | 2007-09-21 | 2008-04-09 | 陕西科技大学 | Method for preparing complex-color glaze |
CN101786795A (en) * | 2009-12-31 | 2010-07-28 | 深圳市永丰源实业有限公司 | Enamel glaze and preparation process thereof |
CN102320864A (en) * | 2011-06-02 | 2012-01-18 | 无锡暗星陶瓷有限公司 | Purple-clay color enamel and preparation method thereof |
CN102548920A (en) * | 2009-04-06 | 2012-07-04 | 你和我技术有限公司 | Exothermic enamel glaze, and exothermic container coated with same |
CN105274424A (en) * | 2015-09-02 | 2016-01-27 | 安徽灶上煌机械有限公司 | Enamel wok with patterns on outer surface and manufacturing method of enamel wok |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB674359A (en) * | 1950-02-13 | 1952-06-25 | Fulmer Res Inst Ltd | Improvements relating to low emissivity coatings for metal surfaces |
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2016
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101157572A (en) * | 2007-09-21 | 2008-04-09 | 陕西科技大学 | Method for preparing complex-color glaze |
CN102548920A (en) * | 2009-04-06 | 2012-07-04 | 你和我技术有限公司 | Exothermic enamel glaze, and exothermic container coated with same |
CN101786795A (en) * | 2009-12-31 | 2010-07-28 | 深圳市永丰源实业有限公司 | Enamel glaze and preparation process thereof |
CN102320864A (en) * | 2011-06-02 | 2012-01-18 | 无锡暗星陶瓷有限公司 | Purple-clay color enamel and preparation method thereof |
CN105274424A (en) * | 2015-09-02 | 2016-01-27 | 安徽灶上煌机械有限公司 | Enamel wok with patterns on outer surface and manufacturing method of enamel wok |
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