CN106082953A - 一种添加金刚药石的瓷砖及其制备方法 - Google Patents

一种添加金刚药石的瓷砖及其制备方法 Download PDF

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CN106082953A
CN106082953A CN201610420707.7A CN201610420707A CN106082953A CN 106082953 A CN106082953 A CN 106082953A CN 201610420707 A CN201610420707 A CN 201610420707A CN 106082953 A CN106082953 A CN 106082953A
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郑辉
郭孝建
王俊武
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ANHUI YA'OU CERAMIC Co Ltd
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Abstract

本发明公开了一种添加金刚药石的瓷砖及其制备方法，其由以下重量份的原料制成：金刚药石21‑29、石英粉17‑24、滑石15‑20、钙镁渣23‑31、骨炭粉12‑19、提钒尾渣26‑33、白云土14‑21、铸造废砂19‑26、碎砾石16‑22、陶瓷抛光渣24‑32、固硫灰18‑25、转炉钢渣16‑23、克砂岩20‑27、偏磷酸钡10‑16。本发明添加的钙镁渣、铸造废砂、克砂岩等原料，可以显著提高瓷砖的耐火性、耐候性和耐腐蚀性，添加的金刚药石，可以提高瓷砖的抗菌防霉性能。本发明制得的瓷砖综合性能优异，具有较高的机械强度外，还具有优良的耐火性、耐腐蚀、耐候性、耐磨性和抗热震性。

Description

一种添加金刚药石的瓷砖及其制备方法
技术领域
本发明涉及一种瓷砖及其制备方法，具体涉及一种添加金刚药石的瓷砖及其制备方法。
背景技术
瓷砖是以耐火的金属氧化物及半金属氧化物，经由研磨、混合、压制、烧结等步骤制作而成，是一种常用的建筑装饰材料。由于其具有高强度、高硬度、耐高温、耐腐蚀等优点，被广泛的应用。随着我国建筑行业的快速发展以及人们生活水平的不断提高，人们对瓷砖的性能要求日益苛刻，传统瓷砖的综合性能越来越无法满足现有市场的需求。
发明内容
本发明的目的在于提供一种综合性能优异的添加金刚药石的瓷砖及其制备方法。
为实现上述目的，本发明采用如下的技术方案：
一种添加金刚药石的瓷砖，由以下重量份的原料制成：金刚药石21-29、石英粉17-24、滑石15-20、钙镁渣23-31、骨炭粉12-19、提钒尾渣26-33、白云土14-21、铸造废砂19-26、碎砾石16-22、陶瓷抛光渣24-32、固硫灰18-25、转炉钢渣16-23、克砂岩20-27、偏磷酸钡10-16。
一种添加金刚药石的瓷砖的制备方法，包括以下步骤：
(1)将钙镁渣、克砂岩、碎砾石混合均匀，加入相当于上述混合矿物重量6-7倍量的1-1.5mol/L盐酸溶液中，水浴加热至75-95℃，浸泡1.5-2h，过滤，滤渣洗涤至中性，烘干后送入转锤式矿物纤维粉碎机粉碎，得到初级矿物纤维，然后加入适量的水搅拌制成浓度为55-60％的浆状矿物纤维，在2000-3000r/min的转速下球磨40-50min，再在1000-2000r/min的转速下搅拌20-30min，再在功率为600-700W的超声波下振荡25-35min，再在1600-2400r/min的转速下离心6-12min，静置16-24h，过滤，烘干，得物料A；
(2)将提钒尾渣、陶瓷抛光渣、转炉钢渣、滑石混合均匀，加热熔化成熔融液，然后采用压缩空气以250-450m/s的速度喷雾，在喷雾的同时进行风冷，使雾滴的温度降至120℃以下，再经重力收集、旋风收集，得物料B；
(3)将金刚药石、白云土、铸造废砂混合均匀，粉碎，过140-160目筛，然后加入石英粉、骨炭粉、铸造废砂、固硫灰、偏磷酸钡等原料，在1400-2200r/min的转速下球磨20-30min，得物料C；
(4)将上述制得的物料A、物料B、物料C混合，在2200-2800r/min的转速下搅拌2-5min，然后加入相当于混合料重量8-10％的固含量为30％的水玻璃，在1500-2000r/min的转速下搅拌5-7min，静置15-25h后送入到成型机在50-70MPa的压力下压制成型，然后将压制好的砖坯在60-80℃的温度下干燥至含水量低于3％；
(5)将烘干后的砖坯置于微波煅烧炉内进行煅烧：先控制微波功率在300-400W，煅烧45-55min，再控制微波功率在850-950W，煅烧25-35min，再控制微波功率在500-600W，煅烧30-40min；再置于马弗炉内进行煅烧：先以10-12℃/min的速率升温至1130-1210℃，保温3-4h，再以4-7℃/min的速率降温至810-870℃，保温1.5-2.5h，再以3-6℃/min的速率降温至360-420℃，保温0.5-1.5h，随炉冷却至室温，即得成品。
本发明的有益效果：
本发明添加的钙镁渣、铸造废砂、克砂岩等原料，可以显著提高瓷砖的耐火性、耐候性和耐腐蚀性，添加的金刚药石，可以提高瓷砖的抗菌防霉性能。本发明制得的瓷砖综合性能优异，具有较高的机械强度外，还具有优良的耐火性、耐腐蚀、耐候性、耐磨性和抗热震性。
具体实施方式
一种添加金刚药石的瓷砖，由以下重量份的原料制成：金刚药石23、石英粉20、滑石18、钙镁渣26、骨炭粉14、提钒尾渣29、白云土17、铸造废砂21、碎砾石18、陶瓷抛光渣27、固硫灰21、转炉钢渣19、克砂岩23、偏磷酸钡13。
一种添加金刚药石的瓷砖的制备方法，包括以下步骤：
(1)将钙镁渣、克砂岩、碎砾石混合均匀，加入相当于上述混合矿物重量7倍量的1.5mol/L盐酸溶液中，水浴加热至85℃，浸泡1.5h，过滤，滤渣洗涤至中性，烘干后送入转锤式矿物纤维粉碎机粉碎，得到初级矿物纤维，然后加入适量的水搅拌制成浓度为57％的浆状矿物纤维，在2500r/min的转速下球磨45min，再在1500r/min的转速下搅拌25min，再在功率为650W的超声波下振荡30min，再在2200r/min的转速下离心8min，静置22h，过滤，烘干，得物料A；
(2)将提钒尾渣、陶瓷抛光渣、转炉钢渣、滑石混合均匀，加热熔化成熔融液，然后采用压缩空气以350m/s的速度喷雾，在喷雾的同时进行风冷，使雾滴的温度降至120℃以下，再经重力收集、旋风收集，得物料B；
(3)将金刚药石、白云土、铸造废砂混合均匀，粉碎，过150目筛，然后加入石英粉、骨炭粉、铸造废砂、固硫灰、偏磷酸钡等原料，在1800r/min的转速下球磨25min，得物料C；
(4)将上述制得的物料A、物料B、物料C混合，在2600r/min的转速下搅拌3min，然后加入相当于混合料重量9％的固含量为30％的水玻璃，在1800r/min的转速下搅拌6min，静置20h后送入到成型机在60MPa的压力下压制成型，然后将压制好的砖坯在70℃的温度下干燥至含水量低于3％；
(5)将烘干后的砖坯置于微波煅烧炉内进行煅烧：先控制微波功率在350W，煅烧50min，再控制微波功率在900W，煅烧30min，再控制微波功率在500-600W，煅烧35min；再置于马弗炉内进行煅烧：先以11℃/min的速率升温至1170℃，保温3.5h，再以6℃/min的速率降温至840℃，保温2h，再以4℃/min的速率降温至390℃，保温1h，随炉冷却至室温，即得成品。
上述实施例生产出来的瓷砖的性能检测结果如下表所示：
项目 单位 检测结果
破坏强度 N 2074
断裂模数 MPa 39
吸水率 ％ 0.24
热膨胀系数 m/m·k 5.2×10-6
抑菌率 ％ 99.4

Claims (2)

1.一种添加金刚药石的瓷砖，其特征在于，由以下重量份的原料制成：金刚药石21-29、石英粉17-24、滑石15-20、钙镁渣23-31、骨炭粉12-19、提钒尾渣26-33、白云土14-21、铸造废砂19-26、碎砾石16-22、陶瓷抛光渣24-32、固硫灰18-25、转炉钢渣16-23、克砂岩20-27、偏磷酸钡10-16。
2.一种如权利要求1所述的添加金刚药石的瓷砖的制备方法，其特征在于，包括以下步骤：
（1）将钙镁渣、克砂岩、碎砾石混合均匀，加入相当于上述混合矿物重量6-7倍量的1-1.5mol/L盐酸溶液中，水浴加热至75-95℃，浸泡1.5-2h，过滤，滤渣洗涤至中性，烘干后送入转锤式矿物纤维粉碎机粉碎，得到初级矿物纤维，然后加入适量的水搅拌制成浓度为55-60%的浆状矿物纤维，在2000-3000r/min的转速下球磨40-50min，再在1000-2000r/min的转速下搅拌20-30min，再在功率为600-700W的超声波下振荡25-35min，再在1600-2400r/min的转速下离心6-12min，静置16-24h，过滤，烘干，得物料A；
（2）将提钒尾渣、陶瓷抛光渣、转炉钢渣、滑石混合均匀，加热熔化成熔融液，然后采用压缩空气以250-450m/s的速度喷雾，在喷雾的同时进行风冷，使雾滴的温度降至120℃以下，再经重力收集、旋风收集，得物料B；
（3）将金刚药石、白云土、铸造废砂混合均匀，粉碎，过140-160目筛，然后加入石英粉、骨炭粉、铸造废砂、固硫灰、偏磷酸钡等原料，在1400-2200r/min的转速下球磨20-30min，得物料C；
（4）将上述制得的物料A、物料B、物料C混合，在2200-2800r/min的转速下搅拌2-5min，然后加入相当于混合料重量8-10%的固含量为30%的水玻璃，在1500-2000r/min的转速下搅拌5-7min，静置15-25h后送入到成型机在50-70MPa的压力下压制成型，然后将压制好的砖坯在60-80℃的温度下干燥至含水量低于3%；
（5）将烘干后的砖坯置于微波煅烧炉内进行煅烧：先控制微波功率在300-400W，煅烧45-55min，再控制微波功率在850-950W，煅烧25-35min，再控制微波功率在500-600W，煅烧30-40min；再置于马弗炉内进行煅烧：先以10-12℃/min的速率升温至1130-1210℃，保温3-4h，再以4-7℃/min的速率降温至810-870℃，保温1.5-2.5h，再以3-6℃/min的速率降温至360-420℃，保温0.5-1.5h，随炉冷却至室温，即得成品。
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