CN105970671A - Dyeing and coating integrated dye dyeing and printing paste-shaped compound and application thereof - Google Patents
Dyeing and coating integrated dye dyeing and printing paste-shaped compound and application thereof Download PDFInfo
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- CN105970671A CN105970671A CN201610580392.2A CN201610580392A CN105970671A CN 105970671 A CN105970671 A CN 105970671A CN 201610580392 A CN201610580392 A CN 201610580392A CN 105970671 A CN105970671 A CN 105970671A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a textile dyeing and printing technique and specifically relates to a dyeing and coating integrated dye dyeing and printing paste-shaped compound for a hydrophobic textile material and an application thereof. The dye dyeing and printing paste-shaped compound is composed of 1-25% of dyeing and printing concentrated paste, 0.5-10% of thickening agents, 0.05-3% of pH modifiers and 62-98.45% of water. The paste-shaped compound provided by the invention is used for dyeing and printing the hydrophobic textile material and has the advantages of dye dyeing and printing and pigment dyeing and printing; the high sublimation, washing and dry and humid rubbing fastness are ensured while the color is bright and the hand feeling is soft; the generation of high concentration waste water in the traditional disperse dyeing and printing processes is avoided; and therefore, the dyeing and coating integrated dye dyeing and printing paste-shaped compound is a clean and environment-friendly dye dyeing and printing product.
Description
Technical field
The present invention relates to textile dyeing, printing technique, a kind of hydrophobic textile material
Dye is coated with one dyeing, stamp paste composition and application thereof.
Background technology
Textile dyeing, stamp generally can be divided into two kinds of dyeing, stamp and pigment dyeing, stamp.
Dyeing, stamp enter with fibration typically by molecular separating force or the active group of dyestuff itself
Row dyeing, stamp.Pigment dyeing, stamp are with thing by the binding agent in pigment dyeing, printing paste
Mode and the fabric of reason bonding combine.The dyeing that as a rule obtains after dye printing, Printing
More environmentally friendly, content of formaldehyde is low, bright, and color fastness is preferable, the most soft, stamp position
Tack-free;Pigment printing technique is simple, and stamp low cost does not has the three wastes to produce substantially.
Conventional dyes dyeing, printing technology are generally: textile → stamp → drying → decatize → washing
→ reduction wash → soap → wash → dry → arrange → stamp finished product.Conventional dyes dyeing, printing paste
In typically require addition the sodium alginate of dye dosage 1-1.5 times amount, sodium lignin sulfonate, LOMAR PWA EINECS 246-676-2
The Additives Products such as formaldehyde condensation products, dispersant, levelling agent, penetrating agent, these auxiliary agents are in dyeing, print
Flower process needs washing, reduction to wash after completing and the step such as soap makes it peel off from fiber surface, thus
Enter in dyeing, printing waste water.During conventional dyes dyeing simultaneously, stamp, the upper dye of dyestuff
Rate is generally 90-95%, the dyestuff of remaining 5-10% after dyeing, stamp complete with the form of loose colour
Be present in fiber surface, wash, reduce wash and soap during also can enter in dyeing waste water.This
Enter into the auxiliary agent in dyeing, printing waste water a bit and dyestuff has resulted in high COD and the height of dyeing waste water
Colourity, intractability is relatively big, and processing cost is higher, and according to authority's statistics, print works often process one
Myriametre chemical fiber plus material is it is necessary to water consumption about 250 tons, and wherein 90% is color water, waste water.And
Effective measures the most only rest on reduce discharging and color water, sewage post processing on, do not had
The elimination of effect.It is sustainable that these dyeing waste waters become puzzlement China textile printing, printing and dyeing industry
The obstacle of development.
Pigment printing technique relatively dye printing is simply a lot, and generally textile → stamp → drying →
Baking → arrangement → stamp finished product, does not has water-washing step during stamp, control of drying and shrink, with
And cross contamination, the removal of naturally occurring or synthetic thickener, the existence of alkaline agent, surfactant and other dirts
Dye thing all can be left in the basket, for environment protection type dye, printing technology.But, the coloring that pigment printing is selected
Component is generally pigment, and itself does not has affinity with fiber, needs to adhere to fiber by binding agent
Surface, and color typically cannot penetrate into fibrous inside, this has resulted in the general color of pigment printing product
Color permeability is poor, color is the most bright-coloured, and color fastness is poor, not wash resistant, and feel is partially hard, color inhibition
The shortcomings such as poor performance.
Dyeing, stamp are combined with pigment dyeing, stamp, takes into account its respective advantage, with
Time its defect is complementary to one another, the new way of can yet be regarded as a kind of dyeing, stamp, the present invention be exactly
Produce under the conditions of such.
Summary of the invention
It is desirable to provide a kind of dye is coated with one hydrophobic textile material dyeing, stamp pulpous state group
Compound and application thereof.
A kind of dye is coated with one dyeing, stamp paste composition,
Dyeing, stamp paste composition are consisting of dyeing, stamp concentrated pulp 1-25%, thickening agent
0.5-10%, pH value regulator 0.05-3% and water 62-98.45%.
Described dyeing, stamp concentrated pulp by weight percentage, by the dyeing of 20-80%, print paste
Dyeing with 20-80%, printing assistant composition.
Described dyeing, print paste be by by the filter cake of disperse dyes or dry powder with auxiliary agent together with water
It is made into slurry, then by micronization processes, prepares the dyeing of fineness D90=0.1-2 μm, stamp color
Slurry.
Described dyeing, each composition of print paste by weight percentage, disperse dyes (filter cake or dry powder)
20-60%, auxiliary agent 5-30% and water 10-75%.
In described dyeing, print paste, disperse dyes are selected from: C.I. disperse yellow 3, C.I. disperse yellow 5,
C.I. disperse yellow 7, C.I. disperse yellow 11, C.I. disperse yellow 23, C.I. Disperse Yellow 42, C.I. dispersion
Yellow 49, C.I. disperse yellow 50, C.I. disperse yellow 54, C.I. disperse yellow 56, C.I. disperse yellow 60,
C.I. disperse yellow 61, C.I. dispersion yellow 64, C.I. disperse yellow 71, C.I. disperse yellow 79, C.I. divide
Dissipate yellow 82, C.I. disperse yellow 93, C.I. disperse yellow 97, C.I. disperse yellow 104, C.I. disperse yellow 114,
C.I. disperse yellow 119, C.I. disperse yellow 124, C.I. disperse yellow 126, C.I. disperse yellow 134, C.I.
Disperse yellow 163, C.I. disperse yellow 182, C.I. disperse yellow 184, C.I. disperse yellow 201, C.I. divide
Dissipate yellow 211, C.I. disperse yellow 235, C.I. disperse yellow 241, C.I. disperse orange 3, C.I. disperse orange 5,
C.I. disperse orange 13, C.I. disperse orange 20, C.I. disperse orange 25, C.I. disperse orange 25: 1, C.I.
Disperse orange 29, C.I. disperse orange 30, C.I. disperse orange 31, C.I. disperse orange 32, C.I. disperse orange
37, C.I. disperse orange 38:2, C.I. disperse orange 41, C.I. disperse orange 44, C.I. disperse orange 61,
C.I. disperse orange 62, C.I. disperse orange 73, C.I. disperse orange 76, C.I. disperse orange 97, C.I. divide
Dissipate orange 127, C.I. disperse orange 288, C.I. Red-1 200, C.I. disperse red 4, C.I. disperse red 5,
C.I. disperse red 9, C.I. dispersion red 11, C.I. DISPERSE Red 13, C.I. disperse red 50, C.I. dispersion
Red 53, C.I. disperse red 54, C.I. disperse red 54: 1, C.I. disperse red 60, C.I. disperse red 65,
C.I. disperse red 72, C.I. disperse red 73, C.I. disperse red 74, C.I. disperse red 82, C.I. divide
Dissipate red 86, C.I. disperse red 91, C.I. disperse red 92, C.I. dispersion red 11 8, C.I. DISPERSE Red 13 5,
C.I. Red-1 200 45, C.I. Red-1 200 52, C.I. Red-1 200 53, C.I. Red 167, C.I.
Red 167: 1, C.I. Red-1 200 77, C.I. Red-1 200 79, C.I. disperse red 200, C.I.
Disperse red 210, C.I. disperse red 220, C.I. disperse red 277, C.I. Disperse Red 278, C.I. divide
Dissipate red 343, C.I. disperse red 356, C.I. disperse violet 1, C.I. disperse violet 8, C.I. disperse violet 17,
C.I. disperse violet 26, C.I. disperse violet 27, C.I. disperse violet 28, C.I. disperse violet 33, C.I. divide
Dissipate purple 38, C.I. disperse violet 43, C.I. disperse violet 63, C.I. disperse violet 77, C.I. disperse violet 93,
C.I. disperse violet 93:1, C.I. disperse blue 3, C.I. disperse blue 14, C.I. disperse blue 20, C.I. divide
Scattered indigo plant 26, C.I. disperse blue 27, C.I. Disperse Blue-56, C.I. Disperse Blue-56: 1, C.I. disperse blue
56:2, C.I. Disperse Blue-56: 3, C.I. disperse blue 58, C.I. disperse blue 60, C.I. disperse blue 73,
C.I. disperse blue 77, C.I. Disperse Blue-79, C.I. Disperse Blue-79: 1, C.I. Disperse Blue-79: 2, C.I.
Disperse blue 81, C.I. disperse blue 82, C.I. disperse blue 87, C.I. disperse blue 102, C.I. disperse blue
104, C.I. disperse blue 106, C.I. disperse blue 118, C.I. disperse blue 143, C.I. disperse blue 148,
C.I. disperse blue 165, C.I. disperse blue 165:1, C.I. disperse blue 165:2, C.I. disperse blue 165:3,
C.I. disperse blue 183, C.I. disperse blue 183:1, C.I. disperse blue 225, C.I. disperse blue 257,
C.I. disperse blue 270, C.I. disperse blue 281, C.I. disperse blue 291, C.I. disperse blue 291:1,
C.I. disperse blue 301, C.I. disperse blue 354, C.I. disperse blue 359, C.I. disperse blue 366, C.I.
Disperse blue 367, C.I. disperse brown 1, C.I. disperse brown 1:1, C.I. disperse brown 19, C.I. dispersion is black
One or more in 1;
Auxiliary agent is selected from polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, bright
Glue, carboxymethyl cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, second two
Alcohol, propylene glycol, carbamide, diethylene glycol, thiourea, mineral oils, high-carbon alcohols, polyethers or organic
One or more in silicon class defoamer and sodium alginate, polyacrylamide, N-methyl-N oleoyl ammonia
Base ethyl sulfonic acid sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol epoxy
Oxide condensate, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic acid
Glyceryl alcohol, dodecylbenzene sodium sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, expansion
Powder N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, cresol (or phenol)
Sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;
Fatty acid salt form anion surfactant, sulfonate type anion surfactant, sulfate type are cloudy
Ionic surface active agent, phosphate ester salt form anion surfactant, 2-Sulfosuccinic acid ester type anion
Surfactant, fatty acid type anion surfactant, peptide condensation substance type anion surfactant;
Ammonium salt type cationic surfactant, quaternary ammonium salt cationic surfactant, oxidation ammonium type cation
Surfactant, betaine type amphoteric ionic surface active agent, imidazoline type amphion surface activity
Agent, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fatty alcohol
Ether type nonionic surfactant, alkyl phenol ether type nonionic surfactant, alkylamine ether type non-from
Sub-surface activating agent, polyether nonionic surfactant, fatty acid polyglycol alkoxide ester type nonionic
Surfactant, castor oil polyoxyethylene type nonionic surfactant, lanoline polyoxyethylene-type are non-
Ionic surface active agent, sorbitol polyoxyethylene type nonionic surfactant, glycerol ester type nonionic
Surfactant, sorbitol ester type nonionic surfactant, fatty acid alkanamine type non-ionic surface are lived
Property agent, alkylolamides type nonionic surfactant, alkyl polyglucoside type nonionic surfactant,
Alkyl pyrrolidone type nonionic surfactant, alcohol surfactants, acids surfactant,
Amine surfactants, amide surfactants, esters surface active agent, ether surfactant,
Ketone surfactant, polymer types of surfactants, Semen Ricini oils surfactant, Pilus Caprae seu Ovis lipid
Surfactant, three polyglyceryl laurate, four polyglyceryl laurate, six polyglyceryl laurate,
The mixing of one or more in Tripolyglycerol monostearates, three polyglycerol acrylate;
Described wet concentration from tap water, deionized water, distilled water, high purity water, ultra-pure water one or more.
Preferred coloring agent, is selected from: C.I. disperse yellow 49, C.I. disperse yellow 50, C.I. disperse yellow 54,
C.I. dispersion yellow 64, C.I. disperse yellow 71, C.I. disperse yellow 79, C.I. disperse yellow 82, C.I. divide
Dissipate Huang 93, C.I. disperse yellow 114, C.I. disperse yellow 119, C.I. disperse yellow 134, C.I. disperse yellow
163, C.I. disperse yellow 182, C.I. disperse yellow 184, C.I. disperse yellow 201, C.I. DISPERSE Yellow 211,
C.I. disperse yellow 241, C.I. disperse orange 25, C.I. disperse orange 25: 1, C.I. disperse orange 29, C.I.
Disperse orange 30, C.I. disperse orange 31, C.I. disperse orange 44, C.I. disperse orange 73, C.I. disperse orange
76, C.I. disperse orange 97, C.I. disperse orange 288, C.I. disperse red 54, C.I. disperse red 54: 1,
C.I. disperse red 60, C.I. disperse red 73, C.I. disperse red 74, C.I. disperse red 92, C.I.C.I.
DISPERSE Red 13 5, C.I. Red-1 200 45, C.I. Red-1 200 52, C.I. Red-1 200 53, C.I. divide
Dissipate red 167, C.I. Red 167: 1, C.I. Red-1 200 79, C.I. disperse red 277, C.I. divide
Dissipate red 278, C.I. Disperse Red 343, C.I. disperse red 356, C.I. disperse violet 33, C.I. disperse violet
38, C.I. disperse violet 43, C.I. disperse violet 63, C.I. disperse violet 77, C.I. disperse violet 93, C.I.
Disperse violet 93:1, C.I. Disperse Blue-56, C.I. Disperse Blue-56: 1, C.I. Disperse Blue-56: 2, C.I.
Disperse Blue-56: 3, C.I. disperse blue 60, C.I. disperse blue 73, C.I. Disperse Blue-79, C.I. dispersion
Blue 79:1, C.I. Disperse Blue-79: 2, C.I. disperse blue 102, C.I. disperse blue 104, C.I. dispersion
Indigo plant 106, C.I. disperse blue 118, C.I. disperse blue 165, C.I. disperse blue 165:1, C.I. dispersion
Blue 165:2, C.I. disperse blue 165:3, C.I. disperse blue 183, C.I. disperse blue 183:1, C.I.
Disperse blue 291, C.I. disperse blue 291:1, C.I. disperse blue 354, C.I. disperse blue 359, C.I.
One or more in disperse blue 366, C.I. disperse blue 367, C.I. disperse brown 19;
Preferred promoter, in mineral oils, high-carbon alcohols, polyethers or silicone defoamer
Plant or multiple and LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol epoxy second
Alkane condensation substance, sodium lignin sulfonate, Oleum Ricini oleic alcohol, dodecylbenzene sodium sulfonate, diffusion
Agent SS, diffusion agent N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 2-naphthalene
Phenol sulfonic formaldehyde condensation compound, dispersing agent C S, fatty acid salt form anion surfactant, sulfonate type
Anion surfactant, sulfate type anion surfactant, phosphate ester salt form anionic surface
Activating agent, 2-Sulfosuccinic acid ester type anion surfactant, betaine type amphoteric ion surface active
Agent, imidazoline type zwitterionic surfactant, amino acid type amphoteric ionic surface active agent, phospholipid
Type zwitterionic surfactant, fatty alcohol ether type nonionic surfactant, alkyl phenol ether type non-from
Sub-surface activating agent, alkylamine ether type nonionic surfactant, polyether nonionic surfactant,
Fatty acid polyglycol alkoxide ester type nonionic surfactant, castor oil polyoxyethylene type non-ionic surface
Activating agent, lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type nonionic
Surfactant, glycerol ester type nonionic surfactant, sorbitol ester type nonionic surfactant,
Fatty acid alkanamine type nonionic surfactant, alkylolamides type nonionic surfactant, alkyl
Glucoside type nonionic surfactant, alkyl pyrrolidone type nonionic surfactant, ethylene glycol,
The mixing of one or more in propylene glycol, carbamide, diethylene glycol.
Described dyeing, printing assistant form by weight percentage, binding agent 25-80%, softening agent
0.5-5%, cross-linking agent 0.1-5%, other auxiliary agents 1-5% and water 5-73.4%.
Described binding agent selected from pure third binding agent, phenylpropyl alcohol binding agent, butylbenzene binding agent, butyronitrile binding agent,
One or many in silicone adhesive, organosilicon modified acrylic ester binding agent, polyurethane binder
Kind;
Described softening agent is selected from: quaternary ammonium salt cationic type softening agent, fatty acid ester type cationic are soft
Soft dose, right wax pattern cationic softener, polyethylene cationic softener, organic siliconresin type
Cationic softener, silicone softening agent, soap film class softening agent, polyphosphazene polymer second
One or more of alkene wax;
Described cross-linking agent is selected from: cyanate cross-linking agent (JQ-1, JQ-1E, JQ-2E, JQ-4, JQ-5,
JQ-6, PAPI, emulsifiable MDI, tetraisocyanate, blocked isocyanate etc.), polyalcohols cross-links
Agent (Polyethylene Glycol, polypropylene glycol, trimethylolpropane etc.), (+)-2,3-Epoxy-1-propanol ethers cross-linking agent, inorganic
Thing cross-linking agent (zinc chloride, aluminum chloride, aluminum sulfate, sulfur, boric acid etc.), organic monomer class cross-linking agent
(styrene, α-methyl styrene, acrylonitrile, acrylic acid, methacrylic acid, Biformyl, nitrogen third
Pyridine etc.), silicone cross-linking agent (tetraethyl orthosilicate, methyl silicate, trimethicone, amino
Modified siloxane, carboxy-modified siloxanes, hydroxyl modification siloxanes, vinylsiloxane etc.), benzene sulphur
Acids cross-linking agent (p-methyl benzenesulfonic acid, paratoluensulfonyl chloride etc.), acrylic ester cross-linking agent (two propylene
Acid-1,4-butanediol ester, Ethylene glycol dimethacrylate, TAC, butyl acrylate, HEA, HPA,
HPMA, MMA etc.), organic peroxide cross-linking agent (cumyl peroxide, peroxidating 2,4-bis-
Chlorobenzoyl etc.), metallo-organic compound cross-linking agent (aluminum isopropylate., zinc acetate, titanium acetylacetone etc.),
One or more in multi-functional polycarbodiimide class cross-linking agent;
Other auxiliary agents described are selected from: sodium alginate, polyacrylamide, N-methyl-N oleoyl amino second
Sodium sulfonate, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol oxirane
Condensation substance, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic
Alcohol, dodecylbenzene sodium sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusant
N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, cresol (or phenol) sulfonic acid
Sodium formaldehyde condensation substance, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;Fat
Fat hydrochlorate type, sulfonate type, sulfate type, phosphate ester salt form, 2-Sulfosuccinic acid ester type, fatty acid/
Peptide condensation substance type anion surfactant;Ammonium salt type, quaternary, oxidation ammonium type cationic surface
Activating agent;Betaine type, imidazoline type, amino acid pattern, phosphatide type zwitterionic surfactant;
Fatty alcohol ether type, alkyl phenol ether type, alkylamine ether type, polyether-type, fatty acid polyglycol alkoxide ester type,
Castor oil polyoxyethylene type, lanoline polyoxyethylene-type, sorbitol polyoxyethylene type, glycerol ester type,
Sorbitol ester type, fatty acid alkanamine type, alkylolamides type, alkyl polyglucoside type, alkyl pyrrolidone
Type nonionic surfactant;Alcohols, acids, amine, amide-type, esters, ethers, ketone,
Other surfactants such as polymerization species, Semen Ricini oils, Pilus Caprae seu Ovis lipid;Polyvinyl alcohol, poly-acetic acid second
Alkene, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl cellulose, carboxyethyl cellulose,
Hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea,
Organic silicon defoamer, mineral oil antifoam agent, polyethers defoamer, three polyglyceryl laurate, four gather
Glycerol monolaurate, six polyglyceryl laurate, Tripolyglycerol monostearates, three polyglycereol oleic acid
One or more in ester;
Described wet concentration one in tap water, deionized water, distilled water, high purity water, ultra-pure water or
Several.
Described thickening agent is selected from: white carbon, sodium bentonite, organobentonite, kieselguhr, concavo-convex
The inorganic thickening agents such as rod stone soil, molecular sieve, Silica hydrogel, methylcellulose, ethyl cellulose, hydroxyl first
Base cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose,
The cellulose thickeners such as carboxy-propyl cellulose, starch, gelatin, sodium alginate, casein, Guar
Glue, chitosan, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber, lanoline, fine jade
The natural polymers such as fat and derivant thereof, polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone,
Polyoxyethylene, modified paraffin resin, carbomer, polyacrylic acid, Polyacrylate Emulsion,
The synthesis macromolecule such as butadiene rubber, butadiene-styrene rubber, polyurethane, modified polyurea, low-molecular polyethylene wax
Thickening agent, one in the solvay-type organo-metallic compound thickening agent such as amino alcohol solvay-type titanate esters or
Multiple;
PH adjusting agent is selected from: citric acid, adipic acid, potassium citrate, lactic acid, fumaric acid, phosphoric acid hydrogen
The acidity regulators such as trisodium, tartaric acid, sodium dihydrogen citrate, malic acid, phosphoric acid, acetic acid, hydrochloric acid,
2-amino-2-methyl-1-propanol, N-methylethanolamine, monoethanolamine, diethanolamine, triethanolamine,
Butylethanolamine, N-aminopropyl-methylethanolamine, 2-amino-2-ethyl-1,3-propylene glycol, butyl two
Ethanolamine etc. have alkanolamine, ammonia, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, carbon
One or more in the inorganic base regulators such as acid hydrogen sodium, potassium bicarbonate.
A kind of dye is coated with one dyeing, the application of stamp paste composition, and described paste composition exists
Application in dyeing, stamp;Wherein, dyeing, the range of viscosities of printing paste are selected from 500-30000 li
Pool, pH scope is selected from 4-10.
During in described dye painting one stamp, dyeing slurry technique for applying, color development process is selected from decatize or bakees
One;Color development temperature is 160-210 DEG C;The color development time is 1-30 minute;Textile after color development
Can wash, soap, wash again, it is possible to directly wash post-drying, or without washing, soaping
Journey;Concrete technology is selected from: textile → stamp → drying → decatize → wash → soap → wash → dry
Dry → arrangement → stamp finished product, textile → stamp → drying → decatize → washing → drying → arrangement →
Stamp finished product, textile → stamp → drying → decatize → drying → arrangement → stamp finished product, textile
→ stamp → dry → bakee → wash → soap → wash → dry → arrange → stamp finished product, weaving
Product → stamp → drying → baking → washing → drying → arrangement → stamp finished product, textile → stamp →
One in dyeing, the printing technologies such as drying → baking → arrangement → stamp finished product.
Concrete: hydrophobic textile material dyeing, printing technology method, technical process is to spin pending
Fabric is successively through stamp → drying → color development → post processing, and then obtains stamp finished product;Wherein, color development
Can the most scrubbed and drying with arranging interprocedual;Described color development temperature is 160-210 DEG C;The color development time is
1-30 minute;Described last handling process can use wash → soap → wash → dry → arrange, wash
→ dry → arrange or individually arrange.Described color development uses decatize or the mode of baking;Described washing can
Use washing repeatedly and/or mode of soaping.
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → drying → decatize → wash → soap → wash → dry → arrange, and then obtain print
Flower finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → drying → decatize → washing → drying → arrangement, and then obtain stamp finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → drying → decatize → arrangement, and then obtain stamp finished product.Wherein steam temperature is
160-210 DEG C, steaming time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → dry → bakee → wash → soap → wash → dry → arrange, and then obtain print
Flower finished product.Wherein stoving temperature is 160-210 DEG C, and the baking time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → drying → baking → washing → drying → arrangement, and then obtain stamp finished product.Wherein
Stoving temperature is 160-210 DEG C, and the baking time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is pending textile
Successively through stamp → drying → baking → arrangement, and then obtain stamp finished product.Wherein stoving temperature is
160-210 DEG C, the baking time is 1-30 minute.
Advantage for present invention:
Disperse dyeing of the present invention, stamp paste composition for disperse dyes dye be coated with one dyeing,
Stamp.The dyeing of this paste composition, printing paste by dyeing, stamp concentrated pulp, dyeing, printing paste help
Agent, dyeing, printing paste thickening agent and water composition.Use this paste composition for hydrophobic textile material
When material carries out stamp, before stamp, process is similar to conventional dyes stamp, can pass through cylinder, PLATE SCREAM PRINTING
Machine by paste composition printing in textile material surface.During high temperature color development, most dispersion dyes
Material is combined with hydrophobic fiber material by molecular separating force, and the printing assistant in concentrator is at disperse dyes
While high temperature color development, crosslinking curing film forming, make the loose colour not being combined with fiber adhere to fiber surface.
Slurry of the present invention for the dyeing of hydrophobic textile materials and stamp can take into account dyeing, stamp and
Pigment dyeing, the advantage of stamp, ensure height distillation, wash and do, while fastness to wet rubbing,
There is again gay colours, soft feel, the most also can avoid tradition disperse dyeing, stamp
During the generation of high concentration color water, be the disperse dyeing of a kind of clean environment firendly, Printing.
And utilize above-mentioned paste composition to carry out dyeing, stamp, if technique is selected and is washed, soaps
Process, washes the wash water COD of textile between 30-2000ppm, part kind < 200ppm, portion
Graded kind < 50ppm;Colourity (extension rate) < 200, part kind colourity (extension rate) <
80, part kind colourity (extension rate) < 30;
Specific implementation method
Below example can make those of ordinary skill in the art that the present invention is more fully understood, but
Limit the present invention never in any form.The raw materials used specification of following example is as follows: dyestuff C.I. disperses
Blue 56, C.I. disperse yellow 54, C.I. disperse red 60, C.I. Disperse Blue-79, C.I. disperse orange 30,
C.I. Red 167, C.I. disperse blue 291:1, C.I. disperse orange 288, C.I. disperse violet 93 etc.
It is the former powder of commercial dispersants dyestuff, sodium lignin sulfonate, dodecylbenzene sodium sulfonate, lauryl alcohol polyoxy
Vinylcarboxylic acid sodium, dodecyl polyoxyethylene sodium sulfate, dispersing agent NNO, dispersing agent MF, diffusant
CNF, surfactant B C-50, surfactant LS-60, surfactant LS-70, organosilicon change
Property acrylic ester adhesive SY-8001, ethylene glycol are commercially available industrial goods, and water used is deionized water.
Device therefor includes:Test-type dispersion machine, the resistance to limited public affairs of (Shanghai) mechanical device of speeding
Department, LHP-0.4 type pottery laboratory horizontal sand mill, Shanghai De Yu mechanical & electronic equipment corporation, Ltd entirely,
APV2000 test-type high pressure homogenizer, Shanghai are along instrument experimental facilities company limited, H-TS-III high temperature
Evaporating baking oven, Ya Nuo precision optical machinery Manufacturing Co., Ltd of Foshan City, DH6-9070 electric heating constant temperature air blast is done
Dry case, Yuhua Instrument Co., Ltd., Gongyi City.
Every application performance detection method is with reference to following national standard:
The generic condition regulation that GB/T 2374-2007 dyeing measures
GB/T 4841.1-2006 dyeing standard depth colour atla 1/1
GB/T 2394-2013 disperse dyes coloured light and the mensuration of intensity
The mensuration of GB/T 2397-2012 disperse dyes lifting force
GB/T 3921-2008 textile color stability test fastness to soaping
GB/T 3920-2008 textile color stability test colour fastness to rubbing
GB/T 6152-1997 textile color stability test color fastness to hot pressing
The GB/T 8427-2008 textile color stability test color fastness of resistance to artificial light: xenon arc
Embodiment 1
(1) dyeing, the preparation of print paste B-1
By surfactant B C-50 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. Disperse Blue-56
350g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and followed by high speed dispersion
Ring grinds, and milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenizer
Homogenize 2 times, obtain blue dyes dyeing, print paste B-1 1000g, fineness d50≤0.5 μm,
PH=6.8.
(2) dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, successively
Surfactant FC-1 15g, penetrating agent SA-50 30g, diffusant WAX 28g is added in dispersion tank,
Silicone softening agent 208C 55g, cross-linking agent CLA-80 45g, organosilicon modified acrylic ester binding agent
SY-800 600g, adds each raw material, dispersion stirring 30 minutes.Dyeed, printing assistant Z-1 1000g,
PH=6.7, viscosity 1300mPa.S (NDJ-1 type rotor viscometer, 2# rotor, 12r/min).
(3) dyeing, the preparation of stamp concentrated pulp B-1
The dyeing, the print paste 500g that step (1) are prepared join in dispersion machine dispersion tank,
Be slowly added under stirring dyeing, printing assistant Z1 500g, dye after stirring, stamp concentration
Slurry B-1, pH=6.7, viscosity 1550mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
(4) dyeing, the preparation of printing paste B-1
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into dyeing, stamp concentrated pulp B-1 20g,
Dispersion is dyeed after stirring, printing paste B-1 1000g, and (NDJ-1 revolves viscosity 2520mPa.S
Turn viscometer, 3# rotor, 30r/min)
Using the dyeing prepared, printing paste to carry out PLATE SCREAM PRINTING, printing technology is: textile →
Stamp → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes,
Stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 2
(1) dyeing, the preparation of print paste Y-1
By surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse yellow 54
345g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and followed by high speed dispersion
Ring grinds, and milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenizer
Homogenize 2 times, obtain weld dyeing, print paste Y-1 1000g, fineness d50≤0.7 μm,
PH=7.2.
(2) dyeing, the preparation of printing assistant Z-1, with embodiment 1
(3) dyeing, the preparation of stamp concentrated pulp Y-1
The dyeing, the print paste Y-1 500g that step (1) are prepared join dispersion machine dispersion
In tank, under stirring, it is slowly added to dyeing, printing assistant Z-1 500g, dyeed after stirring,
Stamp concentrated pulp Y-1, pH=7.0, viscosity 1500mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste Y-1
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into yellow dyeing, stamp concentrated pulp Y-1 20g,
Dispersion is dyeed after stirring, printing paste Y-1 1000g, and (NDJ-1 revolves viscosity 2500mPa.S
Turn viscometer, 3# rotor, 30r/min)
Using the dyeing prepared, printing paste Y-1 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.
Every detection data of stamp finished product are as follows:
Embodiment 3
(1) dyeing, the preparation of print paste R-1
By surfactant LS-70 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse red 60
345g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and followed by high speed dispersion
Ring grinds, and milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenizer
Homogenize 2 times, obtain orchil dyeing, print paste R-1 1000g, fineness d50≤0.7 μm,
PH=7.2.
(2) dyeing, the preparation of printing assistant Z-1, with embodiment 1
(3) dyeing, the preparation of stamp concentrated pulp R-1
The dyeing, the print paste R-1 500g that step (1) are prepared join dispersion machine dispersion
In tank, it is slowly added to dyeing, printing assistant 500g under stirring, is dyeed after stirring, stamp
Concentrated pulp R-1, pH=7.0, viscosity 1450mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste R-1
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into red staining, stamp concentrated pulp R-1 20g,
Dispersion is dyeed after stirring, printing paste R-1 1000g, and (NDJ-1 revolves viscosity 1500mPa.S
Turn viscometer, 3# rotor, 30r/min)
Using the dyeing prepared, printing paste R-1 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 4
(1) dyeing, the preparation of print paste B-2
Surfactant B C-50 45g, dispersing agent MF 50g, ethylene glycol 30g and water 525g are added
In dispersion tank, after dispersion stirring makes it the most molten, it is added thereto to C.I. Disperse Blue-79 former powder 350g,
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding by high speed dispersion,
Milling time 10 hours, slurry grinding obtained after grinding homogenizes 2 through high pressure homogenizer
Time, obtain blue dyes dyeing, print paste B-2 1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, successively
Surfactant EL-40 15g, penetrating agent SA-60 30g, diffusant RPG 28g is added in dispersion tank,
Silicone softening agent RM-1 55g, cross-linking agent TAC 45g, organosilicon modified acrylic ester binding agent SY-800
600g, adds each raw material, dispersion stirring 30 minutes.Dyeed, printing assistant Z-2 1000g,
PH=6.7, viscosity 1350mPa.S (NDJ-1 type rotor viscometer, 2# rotor, 12r/min).
(3) dyeing, the preparation of stamp concentrated pulp B-2
The dyeing, the print paste 500g that step (1) are prepared join in dispersion machine dispersion tank,
Be slowly added under stirring dyeing, printing assistant Z-2 500g, dyeed after stirring, stamp dense
Contracting slurry B-2, pH=6.7, viscosity 1500mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
(4) dyeing, the preparation of printing paste B-2
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into dyeing, stamp concentrated pulp B-2 20g,
Dispersion is dyeed after stirring, printing paste B-2 1000g, viscosity 2500mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste to carry out PLATE SCREAM PRINTING, printing technology is: textile →
Stamp → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes,
Stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 5
(1) dyeing, the preparation of print paste Y-2
Surfactant LS-60 45g, dispersing agent CNF 50g, ethylene glycol 30g and water 530g are added
Enter in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to C.I. disperse orange 30 former powder 345g,
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding by high speed dispersion,
Milling time 10 hours, slurry grinding obtained after grinding homogenizes 2 through high pressure homogenizer
Time, obtain weld dyeing, print paste Y-2 1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dyeing, the preparation of printing assistant Z-2, with embodiment 4
(3) dyeing, the preparation of stamp concentrated pulp Y-2
The dyeing, the print paste Y-2 500g that step (1) are prepared join dispersion machine dispersion
In tank, under stirring, it is slowly added to dyeing, printing assistant Z-2 500g, obtains after stirring contaminating painting one
Body dyeing, stamp concentrated pulp Y-2, pH=7.0, viscosity 1550mPa.S (NDJ-1 type rotating cylinder viscometer,
2# rotor, 12r/min).
(4) dyeing, the preparation of printing paste Y-2
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into yellow dyeing, stamp concentrated pulp Y-2 20g,
Dispersion is dyeed after stirring, printing paste Y-2 1000g, viscosity 2520mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste Y-2 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 6
(1) dyeing, the preparation of print paste R-2
Surfactant LS-60 45g, diffusion agent N 50g, ethylene glycol 30g and water 530g are added
In dispersion tank, after dispersion stirring makes it the most molten, it is added thereto to C.I. Red 167 former powder 345g,
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding by high speed dispersion,
Milling time 10 hours, slurry grinding obtained after grinding homogenizes 2 through high pressure homogenizer
Time, obtain orchil dyeing, print paste R-2 1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dyeing, the preparation of printing assistant Z-2, with embodiment 4
(3) dyeing, the preparation of stamp concentrated pulp R-2
The dyeing, the print paste R-2 500g that step (1) are prepared join dispersion machine dispersion
In tank, it is slowly added to dyeing, printing assistant 500g under stirring, is dyeed after stirring, stamp
Concentrated pulp R-2, pH=7.0, viscosity 1500mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste R-2
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into red staining, stamp concentrated pulp R-2 20g,
Dispersion is dyeed after stirring, printing paste R-2 1000g, viscosity 2520mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste R-2 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 7
(1) dyeing, the preparation of print paste B-3
By surfactant B C-50 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to C.I. disperse blue 291:1 former
Powder 350g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and carried out by high speed dispersion
Circular grinding, milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenize
Machine homogenizes 2 times, obtains blue dyes dyeing, print paste B-3 1000g, fineness d50≤0.5
μm, pH=6.8.
(2) dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, successively
Surfactant FM 15g, penetrating agent FN-2 30g, diffusant PBE 28g is added in dispersion tank,
High-molecular polythene wax PEC-1 55g, cross-linking agent CTA 45g, organosilicon modified acrylic ester binding agent
SY-800 600g, adds each raw material, dispersion stirring 30 minutes.Dyeed, printing assistant Z-3 1000g,
PH=6.7, viscosity 1350mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
(3) dyeing, the preparation of stamp concentrated pulp B-3
The dyeing, the print paste 500g that step (1) are prepared join in dispersion machine dispersion tank,
Be slowly added under stirring dyeing, printing assistant Z-3 500g, dyeed after stirring, stamp dense
Contracting slurry B-2, pH=6.7, viscosity 1550mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
(4) dyeing, the preparation of printing paste B-3
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into dyeing, stamp concentrated pulp B-3 20g,
Dispersion is dyeed after stirring, printing paste B-3 1000g, viscosity 2480mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste to carry out PLATE SCREAM PRINTING, printing technology is: textile →
Stamp → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes,
Stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 8
(1) dyeing, the preparation of print paste Y-3
By surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse orange 288
345g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and followed by high speed dispersion
Ring grinds, and milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenizer
Homogenize 2 times, obtain weld dyeing, print paste Y-3 1000g, fineness d50≤0.7 μm,
PH=7.2.
(2) dyeing, the preparation of printing assistant Z-3, with embodiment 7
(3) dyeing, the preparation of stamp concentrated pulp Y-3
The dyeing, the print paste Y-3 500g that step (1) are prepared join dispersion machine dispersion
In tank, under stirring, it is slowly added to dyeing, printing assistant Z-3 500g, dyeed after stirring,
Stamp concentrated pulp Y-3, pH=7.0, viscosity 1600mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste Y-3
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into yellow dyeing, stamp concentrated pulp Y-3 20g,
Dispersion is dyeed after stirring, printing paste Y-3 1000g, viscosity 2480mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste Y-3 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 9
(1) dyeing, the preparation of print paste R-3
By surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse violet 93
345g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and followed by high speed dispersion
Ring grinds, and milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenizer
Homogenize 2 times, obtain orchil dyeing, print paste R-3 1000g, fineness d50≤0.7 μm,
PH=7.2.
(2) dyeing, the preparation of printing assistant Z-3, with embodiment 7
(3) dyeing, the preparation of stamp concentrated pulp R-3
The dyeing, the print paste R-3 500g that step (1) are prepared join dispersion machine dispersion
In tank, it is slowly added to dyeing, printing assistant 500g under stirring, is dyeed after stirring, stamp
Concentrated pulp R-3, pH=7.0, viscosity 1500mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste R-3
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into red staining, stamp concentrated pulp R-3 20g,
Dispersion is dyeed after stirring, printing paste R-2 1000g, viscosity 2520mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste R-3 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 10
(1) dyeing, the preparation of print paste Y-4
By surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse orange 288
45g, C.I. disperse yellow 54 former powder 300g, starts dispersion machine, and high speed dispersion, will dispersion after 2 hours
Slurry is squeezed into horizontal sand mill and is circulated grinding, milling time 10 hours, will grind after grinding
To slurry homogenize 2 times through high pressure homogenizer, obtain weld dyeing, print paste Y-4
1000g, fineness d50≤0.7 μm, pH=7.1.
(2) dyeing, the preparation of printing assistant Z-1, with embodiment 1
(3) dyeing, the preparation of stamp concentrated pulp Y-4
The dyeing, the print paste Y-4 500g that step (1) are prepared join dispersion machine dispersion
In tank, under stirring, it is slowly added to dyeing, printing assistant Z-1 500g, dyeed after stirring,
Stamp concentrated pulp Y-4, pH=6.9, viscosity 1750mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor,
12r/min)。
(4) dyeing, the preparation of printing paste Y-4
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into yellow dyeing, stamp concentrated pulp Y-4 20g,
Dispersion is dyeed after stirring, printing paste Y-4 1000g, viscosity 2480mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste Y-4 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 11
(1) dyeing, the preparation of print paste BL-1
By surfactant LS-60 47g, alkalescence sodium lignin sulfonate 55g, ethylene glycol 30g and water 523g
Join in dispersion tank, after dispersion stirring makes it the most molten, be added thereto to the former powder of C.I. disperse orange 288
95g, C.I. Red 167 former powder 50g, C.I. Disperse Blue-79 former powder 150g, C.I. disperse blue 291:1
Former powder 50g, starts dispersion machine, and dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and carried out by high speed dispersion
Circular grinding, milling time 10 hours, slurry grinding obtained after grinding is through high pressure homogenize
Machine homogenizes 2 times, obtains black dyes dyeing, print paste BL-1 1000g, fineness d50≤0.7
μm, pH=6.8.
(2) dyeing, the preparation of printing assistant Z-2, with embodiment 4
(3) dyeing, the preparation of stamp concentrated pulp BL-1
The dyeing, the print paste BL-1 500g that step (1) are prepared join dispersion machine dispersion
In tank, under stirring, it is slowly added to dyeing, printing assistant Z-2 500g, dyeed after stirring,
Stamp concentrated pulp BL-1, pH=6.9, (NDJ-1 type rotating cylinder viscometer, 2# turns viscosity 1750mPa.S
Son, 12r/min).
(4) dyeing, the preparation of printing paste BL-1
By in deionized water 960g water, add in dispersion machine dispersion tank, start dispersion machine, high-speed stirred
Under be slowly added to thickening agent PF 20g, be stirring evenly and then adding into yellow dyeing, stamp concentrated pulp BL-1 20g,
Dispersion is dyeed after stirring, printing paste Y-4 1000g, viscosity 2480mPa.S (NDJ-1 type
Rotating cylinder viscometer, 3# rotor, 30r/min).
Using the dyeing prepared, printing paste BL-1 to carry out PLATE SCREAM PRINTING, printing technology is: weaving
Product → stamp → drying → baking → arrangement → stamp finished product, wherein: dry temperature be 100 DEG C, 10
Minute, stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Claims (9)
1. a dye is coated with one dyeing, stamp paste composition, it is characterised in that: dyeing, print
Flower paste composition consisting of dyeing, stamp concentrated pulp 1-25%, thickening agent 0.5-10%, pH value tune
Joint agent 0.05-3% and water 62-98.45%.
2. the dye as described in claim 1 is coated with one dyeing, stamp paste composition, it is characterised in that:
Described dyeing, stamp concentrated pulp by weight percentage, by the dyeing of 20-80%, print paste and
The dyeing of 20-80%, printing assistant composition.
3. the dye as described in claim 2 is coated with one dyeing, stamp paste composition, it is characterised in that:
Described dyeing, print paste are by the filter cake of disperse dyes or dry powder being made into together with water with auxiliary agent
Slurry, then by micronization processes, prepare the dyeing of fineness D90=0.1-2 μm, print paste.
4. the dye as described in claim 3 is coated with one dyeing, stamp paste composition, it is characterised in that:
In described dyeing, print paste, disperse dyes are selected from: C.I. disperse yellow 3, C.I. disperse yellow 5,
C.I. disperse yellow 7, C.I. disperse yellow 11, C.I. disperse yellow 23, C.I. Disperse Yellow 42, C.I. dispersion
Yellow 49, C.I. disperse yellow 50, C.I. disperse yellow 54, C.I. disperse yellow 56, C.I. disperse yellow 60,
C.I. disperse yellow 61, C.I. dispersion yellow 64, C.I. disperse yellow 71, C.I. disperse yellow 79, C.I. divide
Dissipate yellow 82, C.I. disperse yellow 93, C.I. disperse yellow 97, C.I. disperse yellow 104, C.I. disperse yellow 114,
C.I. disperse yellow 119, C.I. disperse yellow 124, C.I. disperse yellow 126, C.I. disperse yellow 134, C.I.
Disperse yellow 163, C.I. disperse yellow 182, C.I. disperse yellow 184, C.I. disperse yellow 201, C.I. divide
Dissipate yellow 211, C.I. disperse yellow 235, C.I. disperse yellow 241, C.I. disperse orange 3, C.I. disperse orange 5,
C.I. disperse orange 13, C.I. disperse orange 20, C.I. disperse orange 25, C.I. disperse orange 25: 1, C.I.
Disperse orange 29, C.I. disperse orange 30, C.I. disperse orange 31, C.I. disperse orange 32, C.I. disperse orange
37, C.I. disperse orange 38:2, C.I. disperse orange 41, C.I. disperse orange 44, C.I. disperse orange 61,
C.I. disperse orange 62, C.I. disperse orange 73, C.I. disperse orange 76, C.I. disperse orange 97, C.I. divide
Dissipate orange 127, C.I. disperse orange 288, C.I. Red-1 200, C.I. disperse red 4, C.I. disperse red 5,
C.I. disperse red 9, C.I. dispersion red 11, C.I. DISPERSE Red 13, C.I. disperse red 50, C.I. dispersion
Red 53, C.I. disperse red 54, C.I. disperse red 54: 1, C.I. disperse red 60, C.I. disperse red 65,
C.I. disperse red 72, C.I. disperse red 73, C.I. disperse red 74, C.I. disperse red 82, C.I. divide
Dissipate red 86, C.I. disperse red 91, C.I. disperse red 92, C.I. dispersion red 11 8, C.I. DISPERSE Red 13 5,
C.I. Red-1 200 45, C.I. Red-1 200 52, C.I. Red-1 200 53, C.I. Red 167, C.I.
Red 167: 1, C.I. Red-1 200 77, C.I. Red-1 200 79, C.I. disperse red 200, C.I.
Disperse red 210, C.I. disperse red 220, C.I. disperse red 277, C.I. Disperse Red 278, C.I. divide
Dissipate red 343, C.I. disperse red 356, C.I. disperse violet 1, C.I. disperse violet 8, C.I. disperse violet 17,
C.I. disperse violet 26, C.I. disperse violet 27, C.I. disperse violet 28, C.I. disperse violet 33, C.I. divide
Dissipate purple 38, C.I. disperse violet 43, C.I. disperse violet 63, C.I. disperse violet 77, C.I. disperse violet 93,
C.I. disperse violet 93:1, C.I. disperse blue 3, C.I. disperse blue 14, C.I. disperse blue 20, C.I. divide
Scattered indigo plant 26, C.I. disperse blue 27, C.I. Disperse Blue-56, C.I. Disperse Blue-56: 1, C.I. disperse blue
56:2, C.I. Disperse Blue-56: 3, C.I. disperse blue 58, C.I. disperse blue 60, C.I. disperse blue 73,
C.I. disperse blue 77, C.I. Disperse Blue-79, C.I. Disperse Blue-79: 1, C.I. Disperse Blue-79: 2, C.I.
Disperse blue 81, C.I. disperse blue 82, C.I. disperse blue 87, C.I. disperse blue 102, C.I. disperse blue
104, C.I. disperse blue 106, C.I. disperse blue 118, C.I. disperse blue 143, C.I. disperse blue 148,
C.I. disperse blue 165, C.I. disperse blue 165:1, C.I. disperse blue 165:2, C.I. disperse blue 165:3,
C.I. disperse blue 183, C.I. disperse blue 183:1, C.I. disperse blue 225, C.I. disperse blue 257,
C.I. disperse blue 270, C.I. disperse blue 281, C.I. disperse blue 291, C.I. disperse blue 291:1,
C.I. disperse blue 301, C.I. disperse blue 354, C.I. disperse blue 359, C.I. disperse blue 366, C.I.
Disperse blue 367, C.I. disperse brown 1, C.I. disperse brown 1:1, C.I. disperse brown 19, C.I. dispersion is black
One or more in 1;
Auxiliary agent is selected from polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, bright
Glue, carboxymethyl cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, second two
Alcohol, propylene glycol, carbamide, diethylene glycol, thiourea, mineral oils, high-carbon alcohols, polyethers or organic
One or more in silicon class defoamer and sodium alginate, polyacrylamide, N-methyl-N oleoyl ammonia
Base ethyl sulfonic acid sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol epoxy
Oxide condensate, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic acid
Glyceryl alcohol, dodecylbenzene sodium sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, expansion
Powder N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, cresol (or phenol)
Sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;
Fatty acid salt form anion surfactant, sulfonate type anion surfactant, sulfate type are cloudy
Ionic surface active agent, phosphate ester salt form anion surfactant, 2-Sulfosuccinic acid ester type anion
Surfactant, fatty acid type anion surfactant, peptide condensation substance type anion surfactant;
Ammonium salt type cationic surfactant, quaternary ammonium salt cationic surfactant, oxidation ammonium type cation
Surfactant, betaine type amphoteric ionic surface active agent, imidazoline type amphion surface activity
Agent, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fatty alcohol
Ether type nonionic surfactant, alkyl phenol ether type nonionic surfactant, alkylamine ether type non-from
Sub-surface activating agent, polyether nonionic surfactant, fatty acid polyglycol alkoxide ester type nonionic
Surfactant, castor oil polyoxyethylene type nonionic surfactant, lanoline polyoxyethylene-type are non-
Ionic surface active agent, sorbitol polyoxyethylene type nonionic surfactant, glycerol ester type nonionic
Surfactant, sorbitol ester type nonionic surfactant, fatty acid alkanamine type non-ionic surface are lived
Property agent, alkylolamides type nonionic surfactant, alkyl polyglucoside type nonionic surfactant,
Alkyl pyrrolidone type nonionic surfactant, alcohol surfactants, acids surfactant,
Amine surfactants, amide surfactants, esters surface active agent, ether surfactant,
Ketone surfactant, polymer types of surfactants, Semen Ricini oils surfactant, Pilus Caprae seu Ovis lipid
Surfactant, three polyglyceryl laurate, four polyglyceryl laurate, six polyglyceryl laurate,
The mixing of one or more in Tripolyglycerol monostearates, three polyglycerol acrylate;
Described wet concentration from tap water, deionized water, distilled water, high purity water, ultra-pure water one or more.
5. the dye as described in claim 4 is coated with one dyeing, stamp paste composition, it is characterised in that:
Described disperse dyes are selected from: C.I. disperse yellow 49, C.I. disperse yellow 50, C.I. disperse yellow 54,
C.I. dispersion yellow 64, C.I. disperse yellow 71, C.I. disperse yellow 79, C.I. disperse yellow 82, C.I. divide
Dissipate Huang 93, C.I. disperse yellow 114, C.I. disperse yellow 119, C.I. disperse yellow 134, C.I. disperse yellow
163, C.I. disperse yellow 182, C.I. disperse yellow 184, C.I. disperse yellow 201, C.I. DISPERSE Yellow 211,
C.I. disperse yellow 241, C.I. disperse orange 25, C.I. disperse orange 25: 1, C.I. disperse orange 29, C.I.
Disperse orange 30, C.I. disperse orange 31, C.I. disperse orange 44, C.I. disperse orange 73, C.I. disperse orange
76, C.I. disperse orange 97, C.I. disperse orange 288, C.I. disperse red 54, C.I. disperse red 54: 1,
C.I. disperse red 60, C.I. disperse red 73, C.I. disperse red 74, C.I. disperse red 92, C.I.C.I.
DISPERSE Red 13 5, C.I. Red-1 200 45, C.I. Red-1 200 52, C.I. Red-1 200 53, C.I. divide
Dissipate red 167, C.I. Red 167: 1, C.I. Red-1 200 79, C.I. disperse red 277, C.I. divide
Dissipate red 278, C.I. Disperse Red 343, C.I. disperse red 356, C.I. disperse violet 33, C.I. disperse violet
38, C.I. disperse violet 43, C.I. disperse violet 63, C.I. disperse violet 77, C.I. disperse violet 93, C.I.
Disperse violet 93:1, C.I. Disperse Blue-56, C.I. Disperse Blue-56: 1, C.I. Disperse Blue-56: 2, C.I.
Disperse Blue-56: 3, C.I. disperse blue 60, C.I. disperse blue 73, C.I. Disperse Blue-79, C.I. dispersion
Blue 79:1, C.I. Disperse Blue-79: 2, C.I. disperse blue 102, C.I. disperse blue 104, C.I. dispersion
Indigo plant 106, C.I. disperse blue 118, C.I. disperse blue 165, C.I. disperse blue 165:1, C.I. dispersion
Blue 165:2, C.I. disperse blue 165:3, C.I. disperse blue 183, C.I. disperse blue 183:1, C.I.
Disperse blue 291, C.I. disperse blue 291:1, C.I. disperse blue 354, C.I. disperse blue 359, C.I.
One or more in disperse blue 366, C.I. disperse blue 367, C.I. disperse brown 19;
Described auxiliary agent is the one in mineral oils, high-carbon alcohols, polyethers or silicone defoamer
Or multiple and LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol oxirane
Condensation substance, sodium lignin sulfonate, Oleum Ricini oleic alcohol, dodecylbenzene sodium sulfonate, diffusant
SS, diffusion agent N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, beta naphthal sulphur
Acid formaldehyde condensation products, dispersing agent C S, fatty acid salt form anion surfactant, sulfonate type cloudy from
Sub-surface activating agent, sulfate type anion surfactant, phosphate ester salt form anion surface active
Agent, 2-Sulfosuccinic acid ester type anion surfactant, betaine type amphoteric ionic surface active agent,
Imidazoline type zwitterionic surfactant, amino acid type amphoteric ionic surface active agent, phosphatide type two
Property ionic surface active agent, fatty alcohol ether type nonionic surfactant, alkyl phenol ether type nonionic table
Face activating agent, alkylamine ether type nonionic surfactant, polyether nonionic surfactant, fat
Fat acid polyalkoxide ester type nonionic surfactant, castor oil polyoxyethylene type non-ionic surface are lived
Property agent, lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type nonionic table
Face activating agent, glycerol ester type nonionic surfactant, sorbitol ester type nonionic surfactant,
Fatty acid alkanamine type nonionic surfactant, alkylolamides type nonionic surfactant, alkyl
Glucoside type nonionic surfactant, alkyl pyrrolidone type nonionic surfactant, ethylene glycol,
The mixing of one or more in propylene glycol, carbamide, diethylene glycol.
6. the dye as described in claim 2 is coated with one dyeing, stamp paste composition, its feature
It is: described dyeing, printing assistant form by weight percentage, binding agent 25-80%, softening agent
0.5-5%, cross-linking agent 0.1-5%, other auxiliary agents 1-5% and water 5-73.4%.
7. the dye as described in claim 6 is coated with one dyeing, stamp paste composition, its feature
It is: described binding agent is selected from pure third binding agent, phenylpropyl alcohol binding agent, butylbenzene binding agent, butyronitrile bonding
One in agent, silicone adhesive, organosilicon modified acrylic ester binding agent, polyurethane binder
Or it is multiple;
Described softening agent is selected from: quaternary ammonium salt cationic type softening agent, fatty acid ester type cationic are soft
Soft dose, right wax pattern cationic softener, polyethylene cationic softener, organic siliconresin type
Cationic softener, silicone softening agent, soap film class softening agent, polyphosphazene polymer second
One or more of alkene wax;
Described cross-linking agent is selected from: cyanate cross-linking agent, polyalcohols cross-linking agent, (+)-2,3-Epoxy-1-propanol ethers
Cross-linking agent, inorganic matter cross-linking agent, organic monomer class cross-linking agent, silicone cross-linking agent, benzenesulfonic acid class
Cross-linking agent, acrylic ester cross-linking agent, organic peroxide cross-linking agent, metallo-organic compound cross-links
Agent, one or more in multi-functional polycarbodiimide class cross-linking agent;
Other auxiliary agents described are selected from: sodium alginate, polyacrylamide, N-methyl-N oleoyl amino second
Sodium sulfonate, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol oxirane
Condensation substance, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic
Alcohol, dodecylbenzene sodium sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusant
N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, cresol (or phenol) sulfonic acid
Sodium formaldehyde condensation substance, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;Fat
Fat hydrochlorate type, sulfonate type, sulfate type, phosphate ester salt form, 2-Sulfosuccinic acid ester type, fatty acid/
Peptide condensation substance type anion surfactant;Ammonium salt type, quaternary, oxidation ammonium type cationic surface
Activating agent;Betaine type, imidazoline type, amino acid pattern, phosphatide type zwitterionic surfactant;
Fatty alcohol ether type, alkyl phenol ether type, alkylamine ether type, polyether-type, fatty acid polyglycol alkoxide ester type,
Castor oil polyoxyethylene type, lanoline polyoxyethylene-type, sorbitol polyoxyethylene type, glycerol ester type,
Sorbitol ester type, fatty acid alkanamine type, alkylolamides type, alkyl polyglucoside type, alkyl pyrrolidone
Type nonionic surfactant;Alcohols, acids, amine, amide-type, esters, ethers, ketone,
Other surfactants such as polymerization species, Semen Ricini oils, Pilus Caprae seu Ovis lipid;Polyvinyl alcohol, poly-acetic acid second
Alkene, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl cellulose, carboxyethyl cellulose,
Hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea,
Organic silicon defoamer, mineral oil antifoam agent, polyethers defoamer, three polyglyceryl laurate, four gather
Glycerol monolaurate, six polyglyceryl laurate, Tripolyglycerol monostearates, three polyglycereol oleic acid
One or more in ester;
Described wet concentration one in tap water, deionized water, distilled water, high purity water, ultra-pure water or
Several.
8. the dye as described in claim 1 is coated with one dyeing, stamp paste composition, its feature
It is: described thickening agent is selected from: white carbon, sodium bentonite, organobentonite, kieselguhr, recessed
The inorganic thickening agents such as convex rod stone soil, molecular sieve, Silica hydrogel, methylcellulose, ethyl cellulose, hydroxyl
Methylcellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, carboxyethylcellulose
The cellulose thickeners such as element, carboxy-propyl cellulose, starch, gelatin, sodium alginate, casein,
Guar gum, chitosan, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber, lanoline,
The natural polymers such as agar and derivant thereof, polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone,
Polyoxyethylene, modified paraffin resin, carbomer, polyacrylic acid, Polyacrylate Emulsion,
The synthesis macromolecule such as butadiene rubber, butadiene-styrene rubber, polyurethane, modified polyurea, low-molecular polyethylene wax
Thickening agent, one in the solvay-type organo-metallic compound thickening agent such as amino alcohol solvay-type titanate esters or
Multiple;
PH adjusting agent is selected from: citric acid, adipic acid, potassium citrate, lactic acid, fumaric acid, phosphoric acid hydrogen
The acidity regulators such as trisodium, tartaric acid, sodium dihydrogen citrate, malic acid, phosphoric acid, acetic acid, hydrochloric acid,
2-amino-2-methyl-1-propanol, N-methylethanolamine, monoethanolamine, diethanolamine, triethanolamine,
Butylethanolamine, N-aminopropyl-methylethanolamine, 2-amino-2-ethyl-1,3-propylene glycol, butyl two
Ethanolamine etc. have alkanolamine, ammonia, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, carbon
One or more in the inorganic base regulators such as acid hydrogen sodium, potassium bicarbonate.
9. dye described in claim 1 is coated with one dyeing, an application for stamp paste composition,
It is characterized in that: the application in dyeing, stamp of the described paste composition.
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