CN105962499A - 一种亚麻粘胶弹力面料 - Google Patents
一种亚麻粘胶弹力面料 Download PDFInfo
- Publication number
- CN105962499A CN105962499A CN201610453992.2A CN201610453992A CN105962499A CN 105962499 A CN105962499 A CN 105962499A CN 201610453992 A CN201610453992 A CN 201610453992A CN 105962499 A CN105962499 A CN 105962499A
- Authority
- CN
- China
- Prior art keywords
- flax
- fabric
- enzyme
- viscose
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
- D06B19/0005—Fixing of chemicals, e.g. dyestuffs, on textile materials
- D06B19/0029—Fixing of chemicals, e.g. dyestuffs, on textile materials by steam
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/65—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/828—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种亚麻粘胶弹力面料,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,再进行前处理,染色,柔软整理,烘干定型得到,其中,所述面料中氨纶弹力丝的含量为3‑10wt%,所述前处理采用生物酶进行冷堆和氧漂工艺;所述染色采用还原染料的湿短蒸轧染染色工艺;所述柔软整理中采用两次柔软处理;所述烘干定型中采用FIR4烘干定型机。此外,本发明中,所述亚麻粘胶弹力面料具有染色均匀、各项色牢度高,色泽丰满、手感柔软、且质地紧密、富有弹性的优点。
Description
技术领域
本发明涉及面料技术领域,尤其涉及一种亚麻粘胶弹力面料。
背景技术
众所周知,亚麻属于韧皮纤维,主要成分为纤维素纤维。天然亚麻纤维中含有果胶、木质素、蜡质和灰分等杂质,一般高达20%,其分子聚合度在10000以上,结晶度达70%。亚麻纤维断裂强度较高,湿强力高,断裂延伸度低。因此,以亚麻为组分的织物前处理难度大,要求高。粘胶纤维是以天然纤维素为原料,经过一定的化学方法加工而成。普通粘胶纤维分子湿强力差,断裂强度低而断裂延伸度高;其皮层结构对染色有较大的影响,耐碱性低。
由亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造可以得到一种新型弹力面料,其可以兼有亚麻、粘胶、氨纶的坚实,透气性强,吸湿性好,高弹性,穿着舒适等优点。但是亚麻、粘胶与氨纶纤维各自的特点却给染整加工带来了一定难度,如果处理不当,同样存在着手感粗硬、易皱、弹性差、贴身穿着有刺痒感及缩水率大等缺点。由于经过一般染整处理的亚麻粘胶弹力面料的手感往往较硬,弹性和延展性较差,样式单调,人们在穿着这种面料制作的服装过程中,会有紧巴、伸缩不自由的感觉。因此,传统的亚麻粘胶弹力面料已经不能满足市场的需求,大力发展高质量产品是目前亚麻粘胶弹力面料甚至服装生产企业面临的关键问题。
发明内容
基于背景技术存在的技术问题,本发明提出了一种亚麻粘胶弹力面料,该面料具有染色均匀、各项色牢度高、色泽丰满、手感柔软、且质地紧密、富有弹性的优点。
本发明提出的一种亚麻粘胶弹力面料,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,再进行前处理,染色,柔软整理,烘干定型得到。
优选地,所述面料中氨纶弹力丝的含量为3-10wt%。
优选地,所述前处理中采用生物酶进行冷堆和氧漂工艺;
其中,所述冷堆工艺包括:50-60℃下浸轧酶退煮液,二浸二轧,轧余率为80-90%,酶退煮液包括:退浆酶4-6g/L、亚麻脱胶酶8-10g/L、纤维素酶0.5-1g/L,酶活化剂0.1-0.3g/L、渗透剂3-5g/L,打卷后以5-6r/min的转速常温堆置20-25小时;
所述氧漂工艺包括:浸轧酶精炼液,酶精炼液包括:复合精练酶5-8g/L、渗透剂1-2g/L,打卷后在50-60℃下以6-7r/min的转速转动放置0.5-1h,80-95℃水洗,再采用有效氯含量为3-4g/L的氯,在25-27℃下漂白0.5-1h,水洗后浸轧氧漂液,氧漂液包括:双氧水5-8g/L、稳定剂3-5g/L、烧碱1-3g/L、螯合分散剂1-3g/L,100-105℃下堆置汽蒸0.4-0.6h,90-95℃水洗。
优选地,所述染色中采用还原染料的湿短蒸轧染染色工艺,其包括:35-55℃下浸轧染液,二浸二轧,轧余率为60-100%,染液包括:超细粉状还原染料0.1-3%(oxf)、渗透剂1-3g/L、扩散剂1-3g/L、氯化钠5-30g/L,45-65℃下浸轧还原液,一浸一轧,轧余率为50-70%,还原液包括:烧碱5-30g/L、保险粉5-10g/L,二氧化硫脲1-5g/L,接着使用饱和蒸汽进行快速汽蒸,还原汽蒸的温度为110-150℃,汽蒸时间为30-50s,水洗后采用0.1-5g/L的双氧水在40-60℃下氧化10-15min,90-100℃下皂洗5-10min,热洗后烘干。
优选地,所述超细粉状还原染料的制备方法包括:将还原染料、改性木质素磺酸钠加水混合后,高速旋切得到细度为10-30um的浆状悬浮体;再将所述浆状悬浮体依次进行超细粉碎和研磨后得到细度为5-10um的初级染料;将所述初级染料经0.1-0.5um的滤芯过滤,再经喷雾干燥,得到所述超细粉状还原染料;优选地,所述还原染料、改性木质素磺酸钠的重量配比为1:1-1.5。
优选地,所述改性木质素磺酸钠的制备方法包括:将木质素磺酸钠、氢氧化钠加水搅拌至溶解完全,加入浓度为28-32wt%的双氧水,搅拌升温至30-60℃,保温反应10-30min,真空干燥后得到所述改性木质素磺酸钠,其中,木质素磺酸钠、氢氧化钠和双氧水的重量配比为1:0.1-0.2:0.05-0.5。
优选地,所述柔软整理中采用两次柔软处理,其中,第一柔软处理的柔软剂组成包括:聚氨酯弹性体15-25wt%、聚醚改性氨基硅酮15-30wt%、分散乳化剂6-10wt%、其余为水;第二次柔软处理采用的柔软剂包括:环氧基硅油10-20wt%、改性氨基硅油5-10wt%、硅油乳化剂10-15wt%、其余为水。
优选地,所述烘干定型中采用FIR4烘干定型机,逆毛进机,温度为110-120℃,定型速度为17-20m/min。
本发明提出的一种亚麻粘胶弹力面料,所述面料将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造而成,因此产品面料同时具有亚麻纤维的刚性、粘胶纤维的柔性和氨纶纤维的弹性优点;并且所述面料采用前处理,染色、柔软整理、烘干定型的工艺得到。
首先,在前处理工艺中,考虑到面料中粘胶及亚麻纤维均不耐碱,因此若采用传统碱退浆工艺,工艺条件稍有不当,即会造成织物泛黄发硬,甚至强降过大,使其服用性受到影响,本发明中通过采用生物酶进行冷堆,通过选择特定的酶退煮液,既保证退浆效果,又不会对织物造成强力损失,同时可符合环保要求;同时为了使得所述面料获得较好的漂白效果,采用氯漂液进行漂白,以3-4g/L有效氯的氯漂液为佳,此时面料的色素、麻皮的去除效果较为明显,使得布面的光洁度、白度明显提高;并且由于麻的杂质及色素含量较高,氯漂主要是去除麻结,白度仍然较差,因此必须经过双氧水再次漂白,使得织物达到一定的白度要求,并且所述氧漂液中还采用渗透剂、磷酸钠以及螯合分散剂作为助剂,可以使得纤维大分子变得圆润,获得耐久性光泽,提高面料织物吸收染料的能力,增加成品的尺寸稳定性,降低缩水率,明显改善织物强力和外观平整度。
其次,在染色工序中,为了解决面料中染色均匀性难度较大的缺陷,具体的染色中,采用还原染料的湿短蒸轧染染色,其不经打底烘干,就直接将织物液封口浸渍还原液,并经汽蒸还原上染,由此不仅大大减少了打底烘干造成的色差、泳移布面发花等疵病,而且可以降低能源消耗,从而可以获得较高的色牢度;在此过程中为了避免省去打底烘干所造成的湿态染料脱落较多,本发明中采用高速旋切、冲击粉碎、以及匀质化处理,得到一种纳米级细度的还原染料,大大提高了染料的上染率,并且加入改性木质素磺酸盐作为分散剂及填充剂使用,其中改性木质素磺酸盐通过在碱性条件下将过氧化氢氧化,使其酚羟基的含量得到提升,极性的酚羟基可以与染料分子中的羟基、氨基、羰基和硝基等形成具有一定结合强度的氢键,在研磨时可提高研磨效果,并提高染料悬浮液的稳定性能,使得还原染料的着色更加均匀。
最后,在后整理工序中,对面料进行两次柔软整理,在第一次柔软整理时,使聚氨酯弹性体分散在硅酮中形成的致密膜间,交叉形成3D空间,为第二次柔软整理时的柔软剂留下间隙,并且赋予面料良好的弹性效果;在第二次柔软整理时,环氧基硅油等的柔软剂正好可以填充上一次柔软剂留下的空隙,使得面料光滑度不受影响的同时,可进一步加强面料的弹性效果,丰满度和持久性;最后在特定温度下烘干定型,使得面料的手感丰满滑爽、光泽柔和,提高了织物的服用性能。
具体实施方式
下面,通过具体实施例对本发明的技术方案进行详细说明。
实施例1
一种亚麻粘胶弹力面料,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,且氨纶弹力丝的含量为3wt%,再进行前处理,染色,柔软整理,烘干定型得到;
其中,所述前处理中采用生物酶进行冷堆和氧漂工艺,所述冷堆工艺包括:50℃下浸轧酶退煮液,二浸二轧,轧余率为90%,酶退煮液包括:退浆酶4g/L、亚麻脱胶酶10g/L、纤维素酶0.5g/L,酶活化剂0.3g/L、渗透剂3g/L,打卷后以6r/min的转速常温堆置20小时;所述氧漂工艺包括:浸轧酶精炼液,酶精炼液包括:复合精练酶8g/L、渗透剂1g/L,打卷后在60℃下以6r/min的转速转动放置1h,80℃水洗,再采用有效氯含量为4g/L的氯,在25℃下漂白1h,水洗后浸轧氧漂液,氧漂液包括:双氧水5g/L、稳定剂5g/L、烧碱1g/L、螯合分散剂3g/L,100℃下堆置汽蒸0.6h,90℃水洗;
所述染色中采用还原染料的湿短蒸轧染染色工艺,其包括:35℃下浸轧染液,二浸二轧,轧余率为100%,染液包括:超细粉状还原染料0.1%(oxf)、渗透剂3g/L、扩散剂1g/L、氯化钠30g/L,45℃下浸轧还原液,一浸一轧,轧余率为70%,还原液包括:烧碱5g/L、保险粉10g/L,二氧化硫脲1g/L,接着使用饱和蒸汽进行快速汽蒸,还原汽蒸的温度为150℃,汽蒸时间为30s,水洗后采用5g/L的双氧水在40℃下氧化15min,90℃下皂洗10min,热洗后烘干;所述超细粉状还原染料的制备方法包括:将还原染料、改性木质素磺酸钠加水混合后,高速旋切得到细度为10-20um的浆状悬浮体;再将所述浆状悬浮体进行超细粉碎,研磨后得到细度为8-10um的初级染料;将所述初级染料经0.1-0.3um的滤芯过滤,再经喷雾干燥,得到所述超细粉状还原染料,所述还原染料、改性木质素磺酸钠的重量配比为1:1,所述改性木质素磺酸钠的制备方法包括:将木质素磺酸钠、氢氧化钠加水搅拌至溶解完全,加入浓度为32wt%的双氧水,搅拌升温至30℃,保温反应30min,真空干燥后得到所述改性木质素磺酸钠,其中,木质素磺酸钠、氢氧化钠和双氧水的重量配比为1:0.1:0.5;
所述柔软整理中采用两次柔软处理,其中,第一柔软处理的柔软剂组成包括:聚氨酯弹性体15wt%、聚醚改性氨基硅酮30wt%、分散乳化剂6wt%、其余为水;第二次柔软处理采用的柔软剂包括:环氧基硅油10wt%、改性氨基硅油10wt%、硅油乳化剂10wt%、其余为水;
所述烘干定型中采用FIR4烘干定型机,逆毛进机,温度为110℃,定型速度为20m/min。
实施例2
一种亚麻粘胶弹力面料,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,且氨纶弹力丝的含量为10wt%,再进行前处理,染色,柔软整理,烘干定型得到;
其中,所述前处理中采用生物酶进行冷堆和氧漂工艺,所述冷堆工艺包括:60℃下浸轧酶退煮液,二浸二轧,轧余率为80%,酶退煮液包括:退浆酶6g/L、亚麻脱胶酶8g/L、纤维素酶1g/L,酶活化剂0.1g/L、渗透剂5g/L,打卷后以5r/min的转速常温堆置25小时;所述氧漂工艺包括:浸轧酶精炼液,酶精炼液包括:复合精练酶5g/L、渗透剂2g/L,打卷后在50℃下以7r/min的转速转动放置0.5h,95℃水洗,再采用有效氯含量为3g/L的氯,在27℃下漂白0.5h,水洗后浸轧氧漂液,氧漂液包括:双氧水8g/L、稳定剂3g/L、烧碱3g/L、螯合分散剂1g/L,105℃下堆置汽蒸0.4h,95℃水洗;
所述染色中采用还原染料的湿短蒸轧染染色工艺,其包括:55℃下浸轧染液,二浸二轧,轧余率为60%,染液包括:超细粉状还原染料3%(oxf)、渗透剂1g/L、扩散剂3g/L、氯化钠5g/L,65℃下浸轧还原液,一浸一轧,轧余率为50%,还原液包括:烧碱30g/L、保险粉5g/L,二氧化硫脲5g/L,接着使用饱和蒸汽进行快速汽蒸,还原汽蒸的温度为110℃,汽蒸时间为50s,水洗后采用0.1g/L的双氧水在60℃下氧化10min,100℃下皂洗5min,热洗后烘干;所述超细粉状还原染料的制备方法包括:将还原染料、改性木质素磺酸钠加水混合后,高速旋切得到细度为20-30um的浆状悬浮体;再将所述浆状悬浮体进行超细粉碎,研磨后得到细度为5-8um的初级染料;将所述初级染料经0.3-0.5um的滤芯过滤,再经喷雾干燥,得到所述超细粉状还原染料,所述还原染料、改性木质素磺酸钠的重量配比为1:1.5,所述改性木质素磺酸钠的制备方法包括:将木质素磺酸钠、氢氧化钠加水搅拌至溶解完全,加入浓度为28wt%的双氧水,搅拌升温至60℃,保温反应10min,真空干燥后得到所述改性木质素磺酸钠,其中,木质素磺酸钠、氢氧化钠和双氧水的重量配比为1:0.2:0.05;
所述柔软整理中采用两次柔软处理,其中,第一柔软处理的柔软剂组成包括:聚氨酯弹性体25wt%、聚醚改性氨基硅酮15wt%、分散乳化剂10wt%、其余为水;第二次柔软处理采用的柔软剂包括:环氧基硅油20wt%、改性氨基硅油5wt%、硅油乳化剂15wt%、其余为水;
所述烘干定型中采用FIR4烘干定型机,逆毛进机,温度为120℃,定型速度为17m/min。
实施例3
一种亚麻粘胶弹力面料,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,且氨纶弹力丝的含量为6wt%,再进行前处理,染色,柔软整理,烘干定型得到;
其中,所述前处理中采用生物酶进行冷堆和氧漂工艺,所述冷堆工艺包括:55℃下浸轧酶退煮液,二浸二轧,轧余率为85%,酶退煮液包括:退浆酶5g/L、亚麻脱胶酶9g/L、纤维素酶0.7g/L,酶活化剂0.2g/L、渗透剂4g/L,打卷后以5.5r/min的转速常温堆置22小时;所述氧漂工艺包括:浸轧酶精炼液,酶精炼液包括:复合精练酶7g/L、渗透剂1.5g/L,打卷后在55℃下以6.5r/min的转速转动放置0.7h,85℃水洗,再采用有效氯含量为3.5g/L的氯,在26℃下漂白0.7h,水洗后浸轧氧漂液,氧漂液包括:双氧水6g/L、稳定剂4g/L、烧碱2g/L、螯合分散剂2g/L,103℃下堆置汽蒸0.5h,93℃水洗;
所述染色中采用还原染料的湿短蒸轧染染色工艺,其包括:45℃下浸轧染液,二浸二轧,轧余率为80%,染液包括:超细粉状还原染料2%(oxf)、渗透剂2g/L、扩散剂2g/L、氯化钠15g/L,55℃下浸轧还原液,一浸一轧,轧余率为60%,还原液包括:烧碱15g/L、保险粉6g/L,二氧化硫脲3g/L,接着使用饱和蒸汽进行快速汽蒸,还原汽蒸的温度为120℃,汽蒸时间为40s,水洗后采用2g/L的双氧水在50℃下氧化12min,95℃下皂洗8min,热洗后烘干;所述超细粉状还原染料的制备方法包括:将还原染料、改性木质素磺酸钠加水混合后,高速旋切得到细度为10-30um的浆状悬浮体;再将所述浆状悬浮体进行超细粉碎,研磨后得到细度为5-10um的初级染料;将所述初级染料经0.1-0.5um的滤芯过滤,再经喷雾干燥,得到所述超细粉状还原染料,所述还原染料、改性木质素磺酸钠的重量配比为1:1.2,所述改性木质素磺酸钠的制备方法包括:将木质素磺酸钠、氢氧化钠加水搅拌至溶解完全,加入浓度为30wt%的双氧水,搅拌升温至45℃,保温反应20min,真空干燥后得到所述改性木质素磺酸钠,其中,木质素磺酸钠、氢氧化钠和双氧水的重量配比为1:0.1:0.1;
所述柔软整理中采用两次柔软处理,其中,第一柔软处理的柔软剂组成包括:聚氨酯弹性体20wt%、聚醚改性氨基硅酮20wt%、分散乳化剂8wt%、其余为水;第二次柔软处理采用的柔软剂包括:环氧基硅油15wt%、改性氨基硅油7wt%、硅油乳化剂12wt%、其余为水;
所述烘干定型中采用FIR4烘干定型机,逆毛进机,温度为115℃,定型速度为18m/min。
将实施例1-3中所述亚麻粘胶弹力面料成品进行测试,结果如表1所述:
表1所述亚麻粘胶弹力面料的性能指标
从表1可以知道,所述亚麻粘胶弹力面料表现出良好强力、手感和色牢度。
本发明提出的一种亚麻粘胶弹力面料,所述面料将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造而成,因此产品面料同时具有亚麻纤维的刚性、粘胶纤维的柔性和氨纶纤维的弹性优点;并且所述面料采用前处理,染色、柔软整理、烘干定型的工艺得到。
首先,在前处理工艺中,考虑到面料中粘胶及亚麻纤维均不耐碱,因此若采用传统碱退浆工艺,工艺条件稍有不当,即会造成织物泛黄发硬,甚至强降过大,使其服用性受到影响,本发明中通过采用生物酶进行冷堆,通过选择特定的酶退煮液,既保证退浆效果,又不会对织物造成强力损失,同时可符合环保要求;同时为了使得所述面料获得较好的漂白效果,采用氯漂液进行漂白,以3-4g/L有效氯的氯漂液为佳,此时面料的色素、麻皮的去除效果较为明显,使得布面的光洁度、白度明显提高;并且由于麻的杂质及色素含量较高,氯漂主要是去除麻结,白度仍然较差,因此必须经过双氧水再次漂白,使得织物达到一定的白度要求,并且所述氧漂液中还采用渗透剂、磷酸钠以及螯合分散剂作为助剂,可以使得纤维大分子变得圆润,获得耐久性光泽,提高面料织物吸收染料的能力,增加成品的尺寸稳定性,降低缩水率,明显改善织物强力和外观平整度。
其次,在染色工序中,为了解决面料中染色均匀性难度较大的缺陷,具体的染色中,采用还原染料的湿短蒸轧染染色,其不经打底烘干,就直接将织物液封口浸渍还原液,并经汽蒸还原上染,由此不仅大大减少了打底烘干造成的色差、泳移布面发花等疵病,而且可以降低能源消耗,从而可以获得较高的色牢度;在此过程中为了避免省去打底烘干所造成的湿态染料脱落较多,本发明中采用高速旋切、冲击粉碎、以及匀质化处理,得到一种纳米级细度的还原染料,大大提高了染料的上染率,并且加入改性木质素磺酸盐作为分散剂及填充剂使用,其中改性木质素磺酸盐通过在碱性条件下将过氧化氢氧化,使其酚羟基的含量得到提升,极性的酚羟基可以与染料分子中的羟基、氨基、羰基和硝基等形成具有一定结合强度的氢键,在研磨时可提高研磨效果,并提高染料悬浮液的稳定性能,使得还原染料的着色更加均匀。
最后,在后整理工序中,对面料进行两次柔软整理,在第一次柔软整理时,使聚氨酯弹性体分散在硅酮中形成的致密膜间,交叉形成3D空间,为第二次柔软整理时的柔软剂留下间隙,并且赋予面料良好的弹性效果;在第二次柔软整理时,环氧基硅油等的柔软剂正好可以填充上一次柔软剂留下的空隙,使得面料光滑度不受影响的同时,可进一步加强面料的弹性效果,丰满度和持久性;最后在特定温度下烘干定型,使得面料的手感丰满滑爽、光泽柔和,提高了织物的服用性能。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (8)
1.一种亚麻粘胶弹力面料,其特征在于,所述面料是将亚麻粘胶混纺纱线和氨纶弹力丝进行混纺织造,再进行前处理,染色,柔软整理,烘干定型得到。
2.根据权利要求1所述的亚麻粘胶弹力面料,其特征在于,所述面料中氨纶弹力丝的含量为3-10wt%。
3.根据权利要求1或2所述的亚麻粘胶弹力面料,其特征在于,所述前处理中采用生物酶进行冷堆和氧漂工艺;
其中,所述冷堆工艺包括:50-60℃下浸轧酶退煮液,二浸二轧,轧余率为80-90%,酶退煮液包括:退浆酶4-6g/L、亚麻脱胶酶8-10g/L、纤维素酶0.5-1g/L,酶活化剂0.1-0.3g/L、渗透剂3-5g/L,打卷后以5-6r/min的转速常温堆置20-25小时;
所述氧漂工艺包括:浸轧酶精炼液,酶精炼液包括:复合精练酶5-8g/L、渗透剂1-2g/L,打卷后在50-60℃下以6-7r/min的转速转动放置0.5-1h,80-95℃水洗,再采用有效氯含量为3-4g/L的氯,在25-27℃下漂白0.5-1h,水洗后浸轧氧漂液,氧漂液包括:双氧水5-8g/L、稳定剂3-5g/L、烧碱1-3g/L、螯合分散剂1-3g/L,100-105℃下堆置汽蒸0.4-0.6h,90-95℃水洗。
4.根据权利要求1-3任一项所述的亚麻粘胶弹力面料,其特征在于,所述染色中采用还原染料的湿短蒸轧染染色工艺,其包括:35-55℃下浸轧染液,二浸二轧,轧余率为60-100%,染液包括:超细粉状还原染料0.1-3%(oxf)、渗透剂1-3g/L、扩散剂1-3g/L、氯化钠5-30g/L,45-65℃下浸轧还原液,一浸一轧,轧余率为50-70%,还原液包括:烧碱5-30g/L、保险粉5-10g/L,二氧化硫脲1-5g/L,接着使用饱和蒸汽进行快速汽蒸,还原汽蒸的温度为110-150℃,汽蒸时间为30-50s,水洗后采用0.1-5g/L的双氧水在40-60℃下氧化10-15min,90-100℃下皂洗5-10min,热洗后烘干。
5.根据权利要求4所述的亚麻粘胶弹力面料,其特征在于,所述超细粉状还原染料的制备方法包括:将还原染料、改性木质素磺酸钠加水混合后,高速旋切得到细度为10-30um的浆状悬浮体;再将所述浆状悬浮体进行超细粉碎,研磨后得到细度为5-10um的初级染料;将所述初级染料经0.1-0.5um的滤芯过滤,再经喷雾干燥,得到所述超细粉状还原染料;优选地,所述还原染料、改性木质素磺酸钠的重量配比为1:1-1.5。
6.根据权利要求5所述的亚麻粘胶弹力面料,其特征在于,所述改性木质素磺酸钠的制备方法包括:将木质素磺酸钠、氢氧化钠加水搅拌至溶解完全,加入浓度为28-32wt%的双氧水,搅拌升温至30-60℃,保温反应10-30min,真空干燥后得到所述改性木质素磺酸钠,其中,木质素磺酸钠、氢氧化钠和双氧水的重量配比为1:0.1-0.2:0.05-0.5。
7.根据权利要求1-6任一项所述的亚麻粘胶弹力面料,其特征在于,所述柔软整理中采用两次柔软处理,其中,第一柔软处理的柔软剂组成包括:聚氨酯弹性体15-25wt%、聚醚改性氨基硅酮15-30wt%、分散乳化剂6-10wt%、其余为水;第二次柔软处理采用的柔软剂包括:环氧基硅油10-20wt%、改性氨基硅油5-10wt%、硅油乳化剂10-15wt%、其余为水。
8.根据权利要求1-7任一项所述的亚麻粘胶弹力面料,其特征在于,所述烘干定型中采用FIR4烘干定型机,逆毛进机,温度为110-120℃,定型速度为17-20m/min。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610453992.2A CN105962499A (zh) | 2016-06-21 | 2016-06-21 | 一种亚麻粘胶弹力面料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610453992.2A CN105962499A (zh) | 2016-06-21 | 2016-06-21 | 一种亚麻粘胶弹力面料 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105962499A true CN105962499A (zh) | 2016-09-28 |
Family
ID=57021481
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610453992.2A Pending CN105962499A (zh) | 2016-06-21 | 2016-06-21 | 一种亚麻粘胶弹力面料 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105962499A (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107173914A (zh) * | 2017-07-14 | 2017-09-19 | 盐城工业职业技术学院 | 鞋垫及其制备工艺 |
CN107201676A (zh) * | 2017-07-03 | 2017-09-26 | 蒋暾 | 一种吸水吸油的纤维素纤维织物及其染色方法 |
CN107313260A (zh) * | 2017-07-25 | 2017-11-03 | 安徽亚源印染有限公司 | 一种亚麻人棉弹力面料的前处理方法 |
WO2019145020A1 (en) * | 2018-01-23 | 2019-08-01 | Calik Denim Tekstil San. Ve Tic. A.S. | Processes and installations for dyeing synthetic fibers and dyed fibers and fabrics containing said dyed fibers |
CN110528102A (zh) * | 2019-08-09 | 2019-12-03 | 青岛大学 | 一种基于麻浆粕的粘胶纤维生产工艺 |
CN110541323A (zh) * | 2019-08-09 | 2019-12-06 | 青岛大学 | 一种利用汉麻原料制备浆粕的方法 |
CN114836972A (zh) * | 2022-03-18 | 2022-08-02 | 永新纺织印染有限公司 | 柔软麻面料的加工工艺 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB776796A (en) * | 1954-02-05 | 1957-06-12 | Sandoz Ltd | Improvements in or relating to the printing and pad-dyeing of textile materials |
CN101880959A (zh) * | 2009-05-07 | 2010-11-10 | 绍兴县金百汇化工有限公司 | 棉亚麻、粘亚麻坯布前处理工艺方法 |
CN103541114A (zh) * | 2013-11-11 | 2014-01-29 | 苏州工业园区友顺制衣厂 | 一种弹力抗静电面料 |
CN103966786A (zh) * | 2014-05-28 | 2014-08-06 | 华纺股份有限公司 | 一种竹浆粘胶纤维织物的冷轧堆染色工艺 |
CN104611936A (zh) * | 2015-02-10 | 2015-05-13 | 苏州陈恒织造有限公司 | 一种亚麻织物的前处理工艺 |
CN104631014A (zh) * | 2013-11-15 | 2015-05-20 | 青岛鑫益发工贸有限公司 | 毛巾织物还原染料湿短蒸工艺 |
CN104892953A (zh) * | 2015-06-24 | 2015-09-09 | 济南圣泉集团股份有限公司 | 改性木质素磺酸盐及其制备方法和应用 |
CN104963205A (zh) * | 2015-06-10 | 2015-10-07 | 上海针织九厂 | 一种细密柔滑针织内衣面料的制备方法 |
-
2016
- 2016-06-21 CN CN201610453992.2A patent/CN105962499A/zh active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB776796A (en) * | 1954-02-05 | 1957-06-12 | Sandoz Ltd | Improvements in or relating to the printing and pad-dyeing of textile materials |
CN101880959A (zh) * | 2009-05-07 | 2010-11-10 | 绍兴县金百汇化工有限公司 | 棉亚麻、粘亚麻坯布前处理工艺方法 |
CN103541114A (zh) * | 2013-11-11 | 2014-01-29 | 苏州工业园区友顺制衣厂 | 一种弹力抗静电面料 |
CN104631014A (zh) * | 2013-11-15 | 2015-05-20 | 青岛鑫益发工贸有限公司 | 毛巾织物还原染料湿短蒸工艺 |
CN103966786A (zh) * | 2014-05-28 | 2014-08-06 | 华纺股份有限公司 | 一种竹浆粘胶纤维织物的冷轧堆染色工艺 |
CN104611936A (zh) * | 2015-02-10 | 2015-05-13 | 苏州陈恒织造有限公司 | 一种亚麻织物的前处理工艺 |
CN104963205A (zh) * | 2015-06-10 | 2015-10-07 | 上海针织九厂 | 一种细密柔滑针织内衣面料的制备方法 |
CN104892953A (zh) * | 2015-06-24 | 2015-09-09 | 济南圣泉集团股份有限公司 | 改性木质素磺酸盐及其制备方法和应用 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107201676A (zh) * | 2017-07-03 | 2017-09-26 | 蒋暾 | 一种吸水吸油的纤维素纤维织物及其染色方法 |
CN107173914A (zh) * | 2017-07-14 | 2017-09-19 | 盐城工业职业技术学院 | 鞋垫及其制备工艺 |
CN107173914B (zh) * | 2017-07-14 | 2020-06-02 | 盐城工业职业技术学院 | 鞋垫及其制备工艺 |
CN107313260A (zh) * | 2017-07-25 | 2017-11-03 | 安徽亚源印染有限公司 | 一种亚麻人棉弹力面料的前处理方法 |
WO2019145020A1 (en) * | 2018-01-23 | 2019-08-01 | Calik Denim Tekstil San. Ve Tic. A.S. | Processes and installations for dyeing synthetic fibers and dyed fibers and fabrics containing said dyed fibers |
AU2018404838B2 (en) * | 2018-01-23 | 2022-08-11 | Calik Denim Tekstil San. Ve Tic. A.S. | Processes and installations for dyeing synthetic fibers and dyed fibers and fabrics containing said dyed fibers |
CN110528102A (zh) * | 2019-08-09 | 2019-12-03 | 青岛大学 | 一种基于麻浆粕的粘胶纤维生产工艺 |
CN110541323A (zh) * | 2019-08-09 | 2019-12-06 | 青岛大学 | 一种利用汉麻原料制备浆粕的方法 |
CN114836972A (zh) * | 2022-03-18 | 2022-08-02 | 永新纺织印染有限公司 | 柔软麻面料的加工工艺 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105962499A (zh) | 一种亚麻粘胶弹力面料 | |
CN106987965B (zh) | 一种索罗娜棉高弹混纺面料的生产工艺 | |
CN103173916B (zh) | 一种涤纶纤维与莫代尔纤维混纺丝光的汗布面料 | |
CN105970696A (zh) | 一种苎麻粘胶交织面料 | |
CN104452283B (zh) | 改性棉纤维、牛仔效果布及其制备方法 | |
CN100582337C (zh) | 玉米纤维与竹纤维混纺家纺面料的生产方法 | |
CN101215790B (zh) | 一种棉/牛奶蛋白混纺拉舍尔织物的染整方法 | |
CN101148801B (zh) | 一种棉粘混纺弹力针织内衣面料及其加工工艺 | |
CN107012685B (zh) | 一种超软滑抗起毛亲肤cvc汗布生产工艺 | |
CN102628236B (zh) | 一种Parster纤维床品及其生产方法 | |
CN106087104B (zh) | 一种负离子保健粘胶纤维面料 | |
CN108342803A (zh) | 表面光泽度高的棉竹纤维混纺阔幅机织物 | |
CN102493059A (zh) | 一种黄麻与棉和粘胶纤维的混纺纱线及其应用 | |
CN106087201A (zh) | 一种使抑菌抗菌有效物质不流失的汉麻布料制作方法 | |
CN106283313B (zh) | 一种多功能色纱线及多功能针织面料和制备方法 | |
CN105970523A (zh) | 一种亚麻人棉弹力交织面料的染整方法 | |
CN102899904A (zh) | 一种羊绒衫防起球处理剂 | |
CN104250931B (zh) | 一种桑紬丝牛仔绸及其制备方法 | |
CN102517934A (zh) | 大豆纤维和棉纤维混纺织物的染色方法 | |
CN106319935A (zh) | 一种蒙娜丽丝纤维拉舍尔毛毯的生产方法 | |
CN102747526A (zh) | 一种咖啡碳玉石纤维针织面料 | |
CN104562499A (zh) | 一种高水洗牢度漂白面料短流程纤维面料印染加工方法 | |
CN102493062A (zh) | 一种黄麻与锦纶和丝纤维的混纺纱线及其应用 | |
CN102493061A (zh) | 一种黄麻与棉和毛纤维的混纺纱线及其应用 | |
CN104522915A (zh) | 一种凉爽夏服面料的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |
|
WD01 | Invention patent application deemed withdrawn after publication |