CN105895380B - 一种三维网状聚苯胺/酚醛树脂基碳球复合材料及其制备方法 - Google Patents
一种三维网状聚苯胺/酚醛树脂基碳球复合材料及其制备方法 Download PDFInfo
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- CN105895380B CN105895380B CN201610223902.0A CN201610223902A CN105895380B CN 105895380 B CN105895380 B CN 105895380B CN 201610223902 A CN201610223902 A CN 201610223902A CN 105895380 B CN105895380 B CN 105895380B
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- phenolic resin
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- carbon ball
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- 229920000767 polyaniline Polymers 0.000 title claims abstract description 40
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 27
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000243 solution Substances 0.000 claims abstract description 53
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000003643 water by type Substances 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 11
- 235000019441 ethanol Nutrition 0.000 claims abstract description 11
- 238000005292 vacuum distillation Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010276 construction Methods 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 claims description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 10
- 239000000908 ammonium hydroxide Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 238000005255 carburizing Methods 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 abstract description 10
- 239000004005 microsphere Substances 0.000 abstract description 3
- 239000003575 carbonaceous material Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000007772 electrode material Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002048 multi walled nanotube Substances 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000143432 Daldinia concentrica Species 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Manufacturing & Machinery (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Description
Claims (8)
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CN201610223902.0A CN105895380B (zh) | 2016-04-12 | 2016-04-12 | 一种三维网状聚苯胺/酚醛树脂基碳球复合材料及其制备方法 |
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CN201610223902.0A CN105895380B (zh) | 2016-04-12 | 2016-04-12 | 一种三维网状聚苯胺/酚醛树脂基碳球复合材料及其制备方法 |
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CN105895380A CN105895380A (zh) | 2016-08-24 |
CN105895380B true CN105895380B (zh) | 2018-09-04 |
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CN201610223902.0A Expired - Fee Related CN105895380B (zh) | 2016-04-12 | 2016-04-12 | 一种三维网状聚苯胺/酚醛树脂基碳球复合材料及其制备方法 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107722932B (zh) * | 2017-10-24 | 2020-11-27 | 浙江理工大学 | 一种碳/聚苯胺吸波微球的制备方法 |
CN109289806B (zh) * | 2018-10-24 | 2021-04-06 | 山西新华防化装备研究院有限公司 | 球形甲醛吸附剂的制备方法 |
CN114618467A (zh) * | 2020-12-11 | 2022-06-14 | 中国科学院大连化学物理研究所 | 碳球及其负载的双金属催化剂制备方法与应用 |
CN113009016B (zh) * | 2021-02-24 | 2023-05-12 | 南通市疾病预防控制中心 | 一种固相萃取包及其制备方法和应用 |
CN114307984B (zh) * | 2021-12-17 | 2023-11-03 | 南通市疾病预防控制中心 | 一种碳基吸附材料的制备方法及其应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101290836A (zh) * | 2008-06-13 | 2008-10-22 | 陕西师范大学 | 提高酚醛基活性碳纤维比电容的方法 |
CN102649843A (zh) * | 2012-05-16 | 2012-08-29 | 中国林业科学研究院林产化学工业研究所 | 一种聚苯胺/活性炭复合材料及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000247621A (ja) * | 1999-02-26 | 2000-09-12 | Showa Denko Kk | 活性炭及びその製造方法 |
JP2006282484A (ja) * | 2005-04-04 | 2006-10-19 | Honda Motor Co Ltd | 炭素材料の乾燥システム、炭素材料の乾燥方法、および炭素材料、並びに電気二重層コンデンサ |
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2016
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101290836A (zh) * | 2008-06-13 | 2008-10-22 | 陕西师范大学 | 提高酚醛基活性碳纤维比电容的方法 |
CN102649843A (zh) * | 2012-05-16 | 2012-08-29 | 中国林业科学研究院林产化学工业研究所 | 一种聚苯胺/活性炭复合材料及其制备方法 |
Non-Patent Citations (2)
Title |
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An Experimental Investigation of the Ion Storage/Transfer Behavior in an Electrical Double-Layer Capacitor by Using Monodisperse Carbon Spheres with Microporous Structure;Shunsuke Tanaka etc;《J. Phys. Chem. C》;20121204;第116卷;第26792页左栏最后1段-右栏最后1段,第26798页结尾部分,图2 * |
有序分级多孔炭/聚苯胺杂化材料的制备及电容性能研究;蔡江涛 等;《中国化学会学术年会》;20141231;第1页 * |
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CN105895380A (zh) | 2016-08-24 |
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Effective date of registration: 20210428 Address after: No.13, 3rd floor, building 1, No.1, Tidu street, Qingyang District, Chengdu, Sichuan 610031 Patentee after: Chengdu yishenrui Technology Co.,Ltd. Address before: 250353 Ji'nan University, Changqing, Shandong Road, No. 3501 Patentee before: Qilu University of Technology Effective date of registration: 20210428 Address after: No.99, Tangang Road, Hai'an high tech Zone, Nantong City, Jiangsu Province Patentee after: NANTONG RIZHI ELECTRIC STUFF Co.,Ltd. Address before: No.13, 3rd floor, building 1, No.1, Tidu street, Qingyang District, Chengdu, Sichuan 610031 Patentee before: Chengdu yishenrui Technology Co.,Ltd. |
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