CN105776856A - Nanometer transparent scratch-resistant glass and preparation method thereof - Google Patents
Nanometer transparent scratch-resistant glass and preparation method thereof Download PDFInfo
- Publication number
- CN105776856A CN105776856A CN201610114546.9A CN201610114546A CN105776856A CN 105776856 A CN105776856 A CN 105776856A CN 201610114546 A CN201610114546 A CN 201610114546A CN 105776856 A CN105776856 A CN 105776856A
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- Prior art keywords
- weight portion
- glass
- scratch resistance
- transparent scratch
- nanometer transparent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/111—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
Abstract
The invention discloses nanometer transparent scratch-resistant glass and a preparation method thereof.The nanometer transparent scratch-resistant glass is prepared from, by weight, 60-70 parts of silicon dioxide, 20-30 parts of zirconium dioxide, 3-5 parts of glass beads, 1-2 parts of sodium hexafluorozirconate, 1-2 parts of sodium fluosilicate, 1-2 parts of barium oxide, 1-1.5 parts of methyltriacetoxysilane, 1-1.5 parts of sodium hydroxide, 0.5-1 part of nickel foam, 0.5-0.8 part of di-n-butyltin dilaurate and 0.4-0.8 part of polydithiazole.The invention further provides a preparation method of the nanometer transparent scratch-resistant glass.
Description
Technical field
The invention belongs to glass material field, particularly to a kind of nanometer transparent scratch resistance glass and preparation method thereof.
Background technology
Glass can be divided into oxide glass and nonoxide glass by its main component, and it is mainly composed of silica,
Silica be widely used in glass, casting, pottery and refractory material, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry,
The industry such as plastics, rubber, abrasive material.
Zirconium dioxide has excellent heat endurance and chemical stability, have high-melting-point, higher boiling, thermal conductivity factor little,
Hardness is big, wearability good, be insulator under normal temperature, feature that refractive index is high.
Heat-reflecting glass reduces the transmitance of visible ray while reducing the transmitance of sunlight intermediate waves and long-wave radiation,
Causing the increase of heat supply in winter energy consumption, the shortcoming that this glass is bigger is that it can be to outdoor generation light pollution.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of nanometer transparent scratch resistance glass and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of nanometer transparent scratch resistance glass, is made up of the component comprising following weight portion:
Silica 60-70 part,
Zirconium dioxide 20-30 part,
Glass microballoon 3-5 part,
Sodium fluozirconate 1-2 part,
Prodan 1-2 part,
Barium monoxide 1-2 part,
Methyl triacetoxysilane 1-1.5 part,
NaOH 1-1.5 part,
Nickel foam 0.5-1 part,
Di-n-butyltin dilaurate 0.5-0.8 part,
Polydithiazole 0.4-0.8 part.
Described component also includes ammonium molybdate 0-1 weight portion.
Described component also includes toner 0-1 weight portion.
Described barium monoxide is nano oxidized barium, and the particle diameter of described nano oxidized barium is 20-30 nanometer.
A kind of preparation method of nanometer transparent scratch resistance glass, the method comprises the following steps:
(1) silica 60-70 weight portion, zirconium dioxide 20-30 weight portion, glass microballoon 3-5 weight portion, sodium fluozirconate are weighed
1-2 weight portion, prodan 1-2 weight portion, barium monoxide 1-2 weight portion, methyl triacetoxysilane 1-1.5 weight portion, hydrogen
Sodium oxide molybdena 1-1.5 weight portion, nickel foam 0.5-1 weight portion, di-n-butyltin dilaurate 0.5-0.8 weight portion, polydithiazole
0.4-0.8 weight portion, ammonium molybdate 0-1 weight portion and toner 0-1 weight portion, mix, and grinds 5-10 minute；
(2) add in crucible, be incubated 2-3 hour at 800-900 DEG C, be warming up to 1200-1300 DEG C and be incubated 2-3 hour, obtain glass
Glass liquid；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 700-800 DEG C
After annealing 1-2 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The speed heated up described in step (2) is 100 DEG C/min.
Compared with prior art, it has the beneficial effect that the present invention
(1) the nanometer transparent scratch resistance glass that the present invention prepares, by adding silica, zirconium dioxide, glass microballoon, fluorine zirconic acid
Sodium, prodan, barium monoxide, methyl triacetoxysilane, NaOH, nickel foam, di-n-butyltin dilaurate and poly-
Dithiazole, prepared nanometer transparent scratch resistance glass has good scratch resistance performance, and has good processability.
(2) the nanometer transparent scratch resistance glass treating method that the present invention prepares is simple, has good transparency, makes longer
After the time, remain to keep color constant, do not have yellowing phenomenon.
(3) the nanometer transparent scratch resistance glass of the present invention, its preparation method is simple, it is easy to industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) silica 60kg, zirconium dioxide 20kg, glass microballoon 3kg, sodium fluozirconate 1kg, prodan 1kg, particle diameter are weighed
It is the barium monoxide 1kg of 30 nanometers, methyl triacetoxysilane 1kg, NaOH 1kg, nickel foam 0.5kg, tin dilaurate two
Normal-butyl tin 0.5kg, polydithiazole 0.4kg, ammonium molybdate 1kg and toner 1kg, mix, and grinds 5 minutes；
(2) add in crucible, be incubated 2 hours at 900 DEG C, be warming up to 1200 DEG C of insulations 2 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 700 DEG C and anneal
After 2 hours, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Embodiment 2
(1) silica 60kg, zirconium dioxide 20kg, glass microballoon 3kg, sodium fluozirconate 1kg, prodan 1kg, particle diameter are weighed
It is the barium monoxide 1kg of 30 nanometers, methyl triacetoxysilane 1kg, NaOH 1kg, nickel foam 0.5kg, tin dilaurate two
Normal-butyl tin 0.5kg and polydithiazole 0.4kg, mixes, and grinds 5 minutes；
(2) add in crucible, be incubated 2 hours at 900 DEG C, be warming up to 1200 DEG C of insulations 2 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 700 DEG C and anneal
After 2 hours, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Embodiment 3
(1) silica 70kg, zirconium dioxide 30kg, glass microballoon 5kg, sodium fluozirconate 2kg, prodan 2kg, particle diameter are weighed
It is the barium monoxide 2kg of 20 nanometers, methyl triacetoxysilane 1.5kg, NaOH 1.5kg, nickel foam 1kg, tin dilaurate
Di-n-butyl tin 0.8kg, polydithiazole 0.8kg, ammonium molybdate 1kg and toner 1kg, mix, and grinds 10 minutes；
(2) add in crucible, be incubated 3 hours at 900 DEG C, be warming up to 1300 DEG C of insulations 3 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 800 DEG C and anneal
After 1 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Embodiment 4
(1) silica 70kg, zirconium dioxide 30kg, glass microballoon 5kg, sodium fluozirconate 1kg, prodan 1kg, particle diameter are weighed
It is the barium monoxide 2kg of 20 nanometers, methyl triacetoxysilane 1kg, NaOH 1.5kg, nickel foam 1kg, tin dilaurate two
Normal-butyl tin 0.5kg, polydithiazole 0.4kg, ammonium molybdate 1kg and toner 1kg, mix, and grinds 10 minutes；
(2) add in crucible, be incubated 3 hours at 900 DEG C, be warming up to 1300 DEG C of insulations 3 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 800 DEG C and anneal
After 1 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Embodiment 5
(1) weigh silica 65kg, zirconium dioxide 25kg, glass microballoon 4kg, sodium fluozirconate 1.5kg, prodan 1.5kg,
Particle diameter is the barium monoxide 1.5kg of 25 nanometers, methyl triacetoxysilane 1.2kg, NaOH 1.2kg, nickel foam 0.8kg,
Di-n-butyltin dilaurate 0.6kg, polydithiazole 0.6kg, ammonium molybdate 0.5kg and toner 0.5kg, mix, and grinds 7
Minute；
(2) add in crucible, be incubated 3 hours at 850 DEG C, be warming up to 1250 DEG C of insulations 2 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 750 DEG C and move back
Fire, after 2 hours, is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Comparative example 1
(1) silica 70kg, zirconium dioxide 30kg, glass microballoon 5kg, sodium fluozirconate 2kg, prodan 2kg, oxidation are weighed
Barium 2kg, methyl triacetoxysilane 1.5kg, NaOH 1.5kg, di-n-butyltin dilaurate 0.8kg, polydithiazole
0.8kg, ammonium molybdate 1kg and toner 1kg, mix, and grinds 10 minutes；
(2) add in crucible, be incubated 3 hours at 900 DEG C, be warming up to 1300 DEG C of insulations 3 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 800 DEG C and anneal
After 1 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Comparative example 2
(1) silica 70kg, zirconium dioxide 30kg, glass microballoon 5kg, barium monoxide 2kg, methyl triacetoxysilane are weighed
1.5kg, NaOH 1.5kg, nickel foam 1kg, di-n-butyltin dilaurate 0.8kg, polydithiazole 0.8kg, ammonium molybdate
1kg and toner 1kg, mixes, and grinds 10 minutes；
(2) add in crucible, be incubated 3 hours at 900 DEG C, be warming up to 1300 DEG C of insulations 3 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 800 DEG C and anneal
After 1 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Comparative example 3
(1) silica 70kg, zirconium dioxide 30kg, glass microballoon 5kg, sodium fluozirconate 2kg, prodan 2kg, oxidation are weighed
Barium 2kg, methyl triacetoxysilane 1.5kg, NaOH 1.5kg, nickel foam 1kg, polydithiazole 0.8kg, ammonium molybdate
1kg and toner 1kg, mixes, and grinds 10 minutes；
(2) add in crucible, be incubated 3 hours at 900 DEG C, be warming up to 1300 DEG C of insulations 3 with the heating rate of 100 DEG C/min little
Time, obtain glass metal；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 800 DEG C and anneal
After 1 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The performance test results preparing nanometer transparent scratch resistance glass is as shown in table 1.
Table 1
| Test event | Refractive index | Vickers hardness | Light transmittance (%) |
| Embodiment 1 | 1.684 | 672 | 96 |
| Embodiment 2 | 1.691 | 675 | 96 |
| Embodiment 3 | 1.775 | 698 | 99 |
| Embodiment 4 | 1.751 | 701 | 99 |
| Embodiment 5 | 1.785 | 704 | 98 |
| Comparative example 1 | 1.524 | 569 | 82 |
| Comparative example 2 | 1.546 | 574 | 85 |
| Comparative example 3 | 1.479 | 562 | 87 |
The invention is not restricted to embodiment here, those skilled in the art are according to the announcement of the present invention, without departing from scope
Improvement and the amendment made all should be within protection scope of the present invention.
Claims (6)
1. a nanometer transparent scratch resistance glass, it is characterised in that be made up of the component comprising following weight portion:
Silica 60-70 part,
Zirconium dioxide 20-30 part,
Glass microballoon 3-5 part,
Sodium fluozirconate 1-2 part,
Prodan 1-2 part,
Barium monoxide 1-2 part,
Methyl triacetoxysilane 1-1.5 part,
NaOH 1-1.5 part,
Nickel foam 0.5-1 part,
Di-n-butyltin dilaurate 0.5-0.8 part,
Polydithiazole 0.4-0.8 part.
Nanometer transparent scratch resistance glass the most according to claim 1, it is characterised in that described component also includes ammonium molybdate 0-1 weight
Amount part.
Nanometer transparent scratch resistance glass the most according to claim 1, it is characterised in that described component also includes toner 0-1 weight
Part.
Nanometer transparent scratch resistance glass the most according to claim 1, it is characterised in that described barium monoxide is nano oxidized barium, institute
The particle diameter stating nano oxidized barium is 20-30 nanometer.
5. the preparation method of a nanometer transparent scratch resistance glass, it is characterised in that the method comprises the following steps:
(1) silica 60-70 weight portion, zirconium dioxide 20-30 weight portion, glass microballoon 3-5 weight portion, sodium fluozirconate are weighed
1-2 weight portion, prodan 1-2 weight portion, barium monoxide 1-2 weight portion, methyl triacetoxysilane 1-1.5 weight portion, hydrogen
Sodium oxide molybdena 1-1.5 weight portion, nickel foam 0.5-1 weight portion, di-n-butyltin dilaurate 0.5-0.8 weight portion, polydithiazole
0.4-0.8 weight portion, ammonium molybdate 0-1 weight portion and toner 0-1 weight portion, mix, and grinds 5-10 minute；
(2) add in crucible, be incubated 2-3 hour at 800-900 DEG C, be warming up to 1200-1300 DEG C and be incubated 2-3 hour, obtain glass
Glass liquid；
(3) described glass metal is poured preheated copper coin die for molding into, put in the Muffle furnace being preheated to 700-800 DEG C
After annealing 1-2 hour, it is cooled to room temperature with stove, obtains nanometer transparent scratch resistance glass.
The preparation method of nanometer transparent scratch resistance glass the most according to claim 5, it is characterised in that described in step (2)
The speed heated up is 100 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610114546.9A CN105776856A (en) | 2016-03-01 | 2016-03-01 | Nanometer transparent scratch-resistant glass and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610114546.9A CN105776856A (en) | 2016-03-01 | 2016-03-01 | Nanometer transparent scratch-resistant glass and preparation method thereof |
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| CN105776856A true CN105776856A (en) | 2016-07-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610114546.9A Pending CN105776856A (en) | 2016-03-01 | 2016-03-01 | Nanometer transparent scratch-resistant glass and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673427A (en) * | 2016-12-11 | 2017-05-17 | 安徽兆利光电科技有限公司 | Energy-saving fluorescent LED (light-emitting diode) lamp glass and preparation method thereof |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1653007A (en) * | 2002-05-16 | 2005-08-10 | 肖特股份有限公司 | UV-blocking borosilicate glass, the use of the same, and a fluorescent lamp |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| US20100108914A1 (en) * | 2008-10-30 | 2010-05-06 | Joerg Hinrich Fechner | Solarization-resistant glass composition having a UV-cutoff with a definite transmittance gradient and radiating device for a weathering apparatus containing a glass of said composition |
-
2016
- 2016-03-01 CN CN201610114546.9A patent/CN105776856A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1653007A (en) * | 2002-05-16 | 2005-08-10 | 肖特股份有限公司 | UV-blocking borosilicate glass, the use of the same, and a fluorescent lamp |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| US20100108914A1 (en) * | 2008-10-30 | 2010-05-06 | Joerg Hinrich Fechner | Solarization-resistant glass composition having a UV-cutoff with a definite transmittance gradient and radiating device for a weathering apparatus containing a glass of said composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673427A (en) * | 2016-12-11 | 2017-05-17 | 安徽兆利光电科技有限公司 | Energy-saving fluorescent LED (light-emitting diode) lamp glass and preparation method thereof |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
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Application publication date: 20160720 |