CN105776855A - Abrasion-resistant glass and preparation method thereof - Google Patents
Abrasion-resistant glass and preparation method thereof Download PDFInfo
- Publication number
- CN105776855A CN105776855A CN201610114509.8A CN201610114509A CN105776855A CN 105776855 A CN105776855 A CN 105776855A CN 201610114509 A CN201610114509 A CN 201610114509A CN 105776855 A CN105776855 A CN 105776855A
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- Prior art keywords
- weight portion
- glass
- abrasion
- barium
- resistance glass
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/111—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
Abstract
The invention discloses an abrasion-resistant glass and a preparation method thereof.The abrasion-resistant glass is prepared from, by weight, 70-80 parts of zirconium dioxide, 3-4 parts of glass beads, 2-4 parts of silicon nitride, 2-3 parts of chlorinated paraffin, 1-2 parts of barium metaborate, 1-2 parts of barium oxide, 1-2 parts of aluminum sulfate, 0.5-1.3 parts of zirconium oxychloride, 0.5-1 part of sodium hydroxide, 0.05-0.1 part of dibutyltin maleate, 0.02-0.3 part of carbaldrate and 0.01-0.04 part of sodium tripolyphosphate.The invention further provides the preparation method of the abrasion-resistant glass.
Description
Technical field
The invention belongs to glass material field, particularly to a kind of abrasion-resistance glass and preparation method thereof.
Background technology
Glass can be divided into oxide glass and nonoxide glass by its main component, and it is steady that zirconium dioxide has excellent heat
Qualitative and chemical stability, have high-melting-point, higher boiling, thermal conductivity factor is little, hardness is big, wearability is good, under normal temperature for insulator,
The feature that refractive index is high, but owing to zirconium dioxide has the highest fusing point, so limiting its application in glass art.
The preparation process of existing glass needs use alkali metal and lead oxide, owing to alkali-metal addition makes preparation
Glass is easily generated alkali-metal diffusion and exchange in some processing procedures in later stage, thus produces the stress of inside, affects glass
The mechanical property of glass itself；Meanwhile, although the addition of lead oxide can make the refractive index of glass and hardness improve, but harm can be produced
The unfavorable factors such as human health.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of abrasion-resistance glass and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of abrasion-resistance glass, is made up of the component comprising following weight portion:
Zirconium dioxide 70-80 part,
Glass microballoon 3-4 part,
Silicon nitride 2-4 part,
Chlorinated paraffin 2-3 part,
Barium metaborate 1-2 part,
Barium monoxide 1-2 part,
Aluminum sulfate 1-2 part,
Basic zirconium chloride 0.5-1.3 part,
NaOH 0.5-1 part,
Maleic acid di-n-butyl tin 0.05-0.1 part,
Dawsonite Kompensan 0.02-0.3 part,
Sodium tripolyphosphate 0.01-0.04 part.
Described component also includes sodium metasilicate 0-0.2 weight portion.
Described component also includes toner 0-0.05 weight portion.
Described barium monoxide is nano oxidized barium, and the particle diameter of described nano oxidized barium is 20-30 nanometer.
A kind of preparation method of abrasion-resistance glass, the method comprises the following steps:
(1) zirconium dioxide 70-80 weight portion, glass microballoon 3-4 weight portion, silicon nitride 2-4 weight portion, chlorinated paraffin 2-3 are weighed
Weight portion, barium metaborate 1-2 weight portion, barium monoxide 1-2 weight portion, aluminum sulfate 1-2 weight portion, basic zirconium chloride 0.5-1.3 weight
Part, NaOH 0.5-1 weight portion, maleic acid di-n-butyl tin 0.05-0.1 weight portion, Dawsonite Kompensan 0.02-0.3 weight
Amount part, sodium tripolyphosphate 0.01-0.04 weight portion, sodium metasilicate 0-0.2 weight portion and toner 0-0.05 weight portion；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, heating, is incubated 2-3 hour, obtains glass metal；
(3) glass metal described in step 2 is poured into and shape on preheated graphite jig, anneal at 1200-1350 DEG C
Process, obtain abrasion-resistance glass.
Described in step (2), the temperature of heating is 1350-1450 DEG C.
Compared with prior art, it has the beneficial effect that the present invention
(1) abrasion-resistance glass that the present invention prepares, by adding zirconium dioxide, glass microballoon, silicon nitride, chlorinated paraffin, metaboric acid
Barium, barium monoxide, aluminum sulfate, basic zirconium chloride, NaOH, maleic acid di-n-butyl tin, Dawsonite Kompensan and sodium tripolyphosphate,
The abrasion-resistance glass prepared has good wear-resisting and heat resistance, and has good transparency.
(2) the abrasion-resistance glass processing method that the present invention prepares is simple, has good surface property, through the long period
After using, remain to keep color constant, do not have yellowing phenomenon.
(3) abrasion-resistance glass of the present invention, its preparation method is simple, it is easy to industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) weigh zirconium dioxide 70kg, glass microballoon 3kg, silicon nitride 2kg, chlorinated paraffin 2kg, barium metaborate 1kg, particle diameter are
The barium monoxide 1kg of 20 nanometers, aluminum sulfate 1kg, basic zirconium chloride 0.5kg, NaOH 0.5kg, maleic acid di-n-butyl tin
0.05kg, Dawsonite Kompensan 0.02kg and sodium tripolyphosphate 0.01kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1350 DEG C, be incubated 2 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1200 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Embodiment 2
(1) weigh zirconium dioxide 70kg, glass microballoon 3kg, silicon nitride 2kg, chlorinated paraffin 2kg, barium metaborate 1kg, particle diameter are
The barium monoxide 1kg of 20 nanometers, aluminum sulfate 1kg, basic zirconium chloride 0.5kg, NaOH 0.5kg, maleic acid di-n-butyl tin
0.05kg, Dawsonite Kompensan 0.02kg, sodium tripolyphosphate 0.01kg, sodium metasilicate 0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1350 DEG C, be incubated 2 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1200 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Embodiment 3
(1) weigh zirconium dioxide 80kg, glass microballoon 4kg, silicon nitride 4kg, chlorinated paraffin 3kg, barium metaborate 2kg, particle diameter are
The barium monoxide 2kg of 30 nanometers, aluminum sulfate 2kg, basic zirconium chloride 1.3kg, NaOH 1kg, maleic acid di-n-butyl tin 0.1kg,
Dawsonite Kompensan 0.3kg, sodium tripolyphosphate 0.04kg, sodium metasilicate 0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1450 DEG C, be incubated 3 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1350 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Embodiment 4
(1) weigh zirconium dioxide 80kg, glass microballoon 4kg, silicon nitride 4kg, chlorinated paraffin 3kg, barium metaborate 2kg, particle diameter are
The barium monoxide 2kg of 30 nanometers, aluminum sulfate 2kg, basic zirconium chloride 0.5kg, NaOH 1kg, maleic acid di-n-butyl tin 0.05kg,
Dawsonite Kompensan 0.02kg, sodium tripolyphosphate 0.04kg, sodium metasilicate 0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1450 DEG C, be incubated 3 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1350 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Embodiment 5
(1) weigh zirconium dioxide 75kg, glass microballoon 3.5kg, silicon nitride 3kg, chlorinated paraffin 2.5kg, barium metaborate 1.5kg,
Particle diameter be the barium monoxide 1.5kg of 25 nanometers, aluminum sulfate 1.5kg, basic zirconium chloride 0.9kg, NaOH 0.8kg, maleic acid two just
Butyl tin 0.08kg, Dawsonite Kompensan 0.2kg, sodium tripolyphosphate 0.03kg, sodium metasilicate 0.1kg and toner 0.02kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1400 DEG C, be incubated 2 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1250 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Comparative example 1
(1) zirconium dioxide 80kg, glass microballoon 4kg, silicon nitride 4kg, chlorinated paraffin 3kg, barium monoxide 2kg, aluminum sulfate are weighed
2kg, basic zirconium chloride 1.3kg, NaOH 1kg, maleic acid di-n-butyl tin 0.1kg, sodium tripolyphosphate 0.04kg, sodium metasilicate
0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1450 DEG C, be incubated 3 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1350 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Comparative example 2
(1) zirconium dioxide 80kg, glass microballoon 4kg, silicon nitride 4kg, chlorinated paraffin 3kg, barium metaborate 2kg, barium monoxide are weighed
2kg, aluminum sulfate 2kg, NaOH 1kg, maleic acid di-n-butyl tin 0.1kg, Dawsonite Kompensan 0.3kg, sodium tripolyphosphate
0.04kg, sodium metasilicate 0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1450 DEG C, be incubated 3 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1350 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Comparative example 3
(1) zirconium dioxide 80kg, glass microballoon 4kg, silicon nitride 4kg, chlorinated paraffin 3kg, barium metaborate 2kg, barium monoxide are weighed
2kg, aluminum sulfate 2kg, basic zirconium chloride 1.3kg, NaOH 1kg, Dawsonite Kompensan 0.3kg, sodium tripolyphosphate 0.04kg, partially
Sodium metasilicate 0.2kg and toner 0.05kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, is heated to 1450 DEG C, be incubated 3 hours, obtain glass metal；
(3) glass metal described in step 2 is poured into and shapes on preheated graphite jig, make annealing treatment at 1350 DEG C,
Obtain abrasion-resistance glass.
The performance test results preparing abrasion-resistance glass is as shown in table 1.
Table 1
| Test event | Vickers hardness | Refractive index |
| Embodiment 1 | 668 | 1.698 |
| Embodiment 2 | 674 | 1.687 |
| Embodiment 3 | 728 | 1.712 |
| Embodiment 4 | 714 | 1.719 |
| Embodiment 5 | 718 | 1.707 |
| Comparative example 1 | 498 | 1.415 |
| Comparative example 2 | 502 | 1.438 |
| Comparative example 3 | 514 | 1.428 |
The invention is not restricted to embodiment here, those skilled in the art are according to the announcement of the present invention, without departing from scope
Improvement and the amendment made all should be within protection scope of the present invention.
Claims (6)
1. an abrasion-resistance glass, it is characterised in that be made up of the component comprising following weight portion:
Zirconium dioxide 70-80 part,
Glass microballoon 3-4 part,
Silicon nitride 2-4 part,
Chlorinated paraffin 2-3 part,
Barium metaborate 1-2 part,
Barium monoxide 1-2 part,
Aluminum sulfate 1-2 part,
Basic zirconium chloride 0.5-1.3 part,
NaOH 0.5-1 part,
Maleic acid di-n-butyl tin 0.05-0.1 part,
Dawsonite Kompensan 0.02-0.3 part,
Sodium tripolyphosphate 0.01-0.04 part.
Abrasion-resistance glass the most according to claim 1, it is characterised in that described component also includes sodium metasilicate 0-0.2 weight portion.
Abrasion-resistance glass the most according to claim 1, it is characterised in that described component also includes toner 0-0.05 weight portion.
Abrasion-resistance glass the most according to claim 1, it is characterised in that described barium monoxide is nano oxidized barium, described nano oxygen
The particle diameter changing barium is 20-30 nanometer.
5. the preparation method of an abrasion-resistance glass, it is characterised in that the method comprises the following steps:
(1) zirconium dioxide 70-80 weight portion, glass microballoon 3-4 weight portion, silicon nitride 2-4 weight portion, chlorinated paraffin 2-3 are weighed
Weight portion, barium metaborate 1-2 weight portion, barium monoxide 1-2 weight portion, aluminum sulfate 1-2 weight portion, basic zirconium chloride 0.5-1.3 weight
Part, NaOH 0.5-1 weight portion, maleic acid di-n-butyl tin 0.05-0.1 weight portion, Dawsonite Kompensan 0.02-0.3 weight
Amount part, sodium tripolyphosphate 0.01-0.04 weight portion, sodium metasilicate 0-0.2 weight portion and toner 0-0.05 weight portion；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, heating, is incubated 2-3 hour, obtains glass metal；
(3) glass metal described in step 2 is poured into and shape on preheated graphite jig, anneal at 1200-1350 DEG C
Process, obtain abrasion-resistance glass.
The preparation method of abrasion-resistance glass the most according to claim 5, it is characterised in that the temperature of heating described in step (2)
Degree is for 1350-1450 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610114509.8A CN105776855A (en) | 2016-03-01 | 2016-03-01 | Abrasion-resistant glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610114509.8A CN105776855A (en) | 2016-03-01 | 2016-03-01 | Abrasion-resistant glass and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105776855A true CN105776855A (en) | 2016-07-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610114509.8A Pending CN105776855A (en) | 2016-03-01 | 2016-03-01 | Abrasion-resistant glass and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
| CN108147663A (en) * | 2017-12-29 | 2018-06-12 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of environmental protection fluorine-free glass |
| CN113845303A (en) * | 2021-10-25 | 2021-12-28 | 湖南兴龙环境艺术工程有限公司 | Wear-resistant toughened glass plate and manufacturing process thereof |
| CN114031294A (en) * | 2021-12-21 | 2022-02-11 | 苏州晶生新材料有限公司 | High-refractive-index optical material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4501819A (en) * | 1982-12-23 | 1985-02-26 | Kabushiki Kaisha Ohara Kogaku Garasu Seizosho | Glass for a photomask |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| CN101838106A (en) * | 2010-05-14 | 2010-09-22 | 北京工业大学 | Borosilicate glass tube for photo-thermal power generation |
-
2016
- 2016-03-01 CN CN201610114509.8A patent/CN105776855A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4501819A (en) * | 1982-12-23 | 1985-02-26 | Kabushiki Kaisha Ohara Kogaku Garasu Seizosho | Glass for a photomask |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| CN101838106A (en) * | 2010-05-14 | 2010-09-22 | 北京工业大学 | Borosilicate glass tube for photo-thermal power generation |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108147663A (en) * | 2017-12-29 | 2018-06-12 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of environmental protection fluorine-free glass |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
| CN113845303A (en) * | 2021-10-25 | 2021-12-28 | 湖南兴龙环境艺术工程有限公司 | Wear-resistant toughened glass plate and manufacturing process thereof |
| CN114031294A (en) * | 2021-12-21 | 2022-02-11 | 苏州晶生新材料有限公司 | High-refractive-index optical material and preparation method thereof |
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Application publication date: 20160720 |
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