CN104829131A - High-strength glass material and production method thereof - Google Patents
High-strength glass material and production method thereof Download PDFInfo
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- CN104829131A CN104829131A CN201510299733.4A CN201510299733A CN104829131A CN 104829131 A CN104829131 A CN 104829131A CN 201510299733 A CN201510299733 A CN 201510299733A CN 104829131 A CN104829131 A CN 104829131A
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Abstract
The invention relates to a high-strength glass material and a production method thereof. The high-strength glass material comprises, by weight, 55 to 65 parts of silicon dioxide, 8 to 15 parts of zirconium dioxide, 5 to 12 parts of boron oxide, 1.5 to 2 parts of aluminum oxide, 0.01 to 0.06 part of cobalt sulfide, 0.02 to 0.04 part of copper acetate trihydrate, and 0.01 to 0.08 part of Cu2V2.5O6.5. The invention further provides a production method of the high-strength glass material.
Description
Technical field
The invention belongs to special glass field, particularly relate to a kind of high strength glass material and preparation method thereof.
Background technology
Glass can be divided into oxide glass and nonoxide glass by its main component, its main component is that SiO2, SiO2 are widely used in the industrial circles such as glass, casting, pottery and refractory materials, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber, abrasive material.
Zirconium dioxide has excellent thermostability and chemical stability, there is high-melting-point, high boiling point, thermal conductivity is little, hardness is large, wear resistance is good, be isolator, feature that specific refractory power is high under normal temperature, but because zirconium dioxide has very high fusing point, so limit its application in glass art.
The main component of borosilicate glass is transparent plate or tubulose borosilicate glass, generally by SiO
2, A1
2o
3, Na
2o+K
2o, B
2o
3make.
Summary of the invention
The object of the invention is to for solving the problem, providing a kind of high strength glass material and preparation method thereof.The high strength glass material that the present invention obtains has good surface hardness, can chemically-resistant solvent corrosion.
Object of the present invention can be realized by following technical proposals:
A kind of high strength glass material, be made up of the component comprising following weight part:
Described component also comprises nanometer silver 0-1.1 weight part.
Described nanometer silver is the mixing of one or more in nanometer silver rod, nano-silver thread, nanometer ping-pong ball.
Described component also comprises ferric oxide nanometer particle 0-0.02 weight part.
A preparation method for high strength glass material, comprises the following steps:
(1) by silicon-dioxide 55-65 weight part, zirconium dioxide 8-15 weight part, boron oxide 5-12 weight part, aluminum oxide 1.5-2 weight part, cobaltous sulfide 0.01-0.06 weight part, three hydration neutralized verdigris 0.02-0.04 weight parts, Cu
2v
1.5o
6.50.01-0.08 weight part, nanometer silver 0-1.1 weight part and ferric oxide nanometer particle 0-0.02 weight part, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt, raised temperature is to 1300-1450 DEG C gradually, insulation 8-11 hour;
(3) shaping, anneal 2-4 hour at 700-800 DEG C, and naturally cooling obtains high strength glass material.
Temperature of fusion in described High Temperature Furnaces Heating Apparatus is 1050-1200 DEG C.
Beneficial effect:
(1) the high strength glass material that obtains of the present invention, by adding zirconium dioxide, cobaltous sulfide, three hydration neutralized verdigris and Cu
2v
1.5o
6.5, obtained homogeneous, surface finish is high, and the glass of mechanical strength excellence.
(2) the high strength glass material that obtains of the present invention, has low-transmittance, can be applicable to electronic plane, the fields such as glass screen, highway signs, household electrical appliance and load-bearing glass.
(3) do not add the harmful elements such as As, Sb in high strength glass material of the present invention, there is low thermal expansion, high temperature resistant, the technical characteristic such as high strength, high rigidity, high chemical stability.
(4) preparation method of the present invention is simple, and the problem that the processing temperature overcoming conventional zirconium dioxide glass in preparation process is high, energy-conserving and environment-protective, are suitable for suitability for industrialized production.
Embodiment
Embodiment 1
(1) by silicon-dioxide 55kg, zirconium dioxide 8kg, boron oxide 5kg, aluminum oxide 1.5kg, cobaltous sulfide 0.01kg, three hydration neutralized verdigris 0.02kg, Cu
2v
1.5o
6.50.01kg, nanometer silver 1.1kg, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1050 DEG C, gradually raised temperature to 1450 DEG C, be incubated 8 hours;
(3) shaping, anneal 2 hours at 700 DEG C, naturally cooling, obtains high strength glass material.
Embodiment 2
(1) by silicon-dioxide 55kg, zirconium dioxide 8kg, boron oxide 5kg, aluminum oxide 1.5kg, cobaltous sulfide 0.01kg, three hydration neutralized verdigris 0.02kg, Cu
2v
1.5o
6.50.01kg and ferric oxide nanometer particle 0.02kg, mixes;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1050 DEG C, gradually raised temperature to 1450 DEG C, be incubated 8 hours;
(3) shaping, anneal 2 hours at 700 DEG C, naturally cooling, obtains high strength glass material.
Embodiment 3
(1) by silicon-dioxide 65kg, zirconium dioxide 15kg, boron oxide 12kg, aluminum oxide 2kg, cobaltous sulfide 0.06kg, three hydration neutralized verdigris 0.04kg, Cu
2v
1.5o
6.50.08kg, nanometer silver 1.1kg and ferric oxide nanometer particle 0.02kg, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1200 DEG C, gradually raised temperature to 1300 DEG C, be incubated 11 hours;
(3) shaping, anneal 4 hours at 800 DEG C, naturally cooling, obtains high strength glass material.
Embodiment 4
(1) by silicon-dioxide 65kg, zirconium dioxide 15kg, boron oxide 12kg, aluminum oxide 2kg, cobaltous sulfide 0.06kg, three hydration neutralized verdigris 0.04kg, Cu
2v
1.5o
6.50.01kg, nanometer silver 1.1kg and ferric oxide nanometer particle 0.02kg, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1200 DEG C, gradually raised temperature to 1300 DEG C, be incubated 11 hours;
(3) shaping, anneal 4 hours at 800 DEG C, naturally cooling, obtains high strength glass material.
Embodiment 5
(1) by silicon-dioxide 60kg, zirconium dioxide 10kg, boron oxide 8kg, aluminum oxide 1.8kg, cobaltous sulfide 0.04kg, three hydration neutralized verdigris 0.03kg, Cu
2v
1.5o
6.50.04kg, mixes;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1100 DEG C, gradually raised temperature to 1350 DEG C, be incubated 10 hours;
(3) shaping, anneal 3 hours at 700 DEG C, naturally cooling, obtains high strength glass material.
Comparative example
(1) by silicon-dioxide 60kg, zirconium dioxide 10kg, sodium oxide 8kg, zinc oxide 1.8kg, boron oxide 0.5kg, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt at 1100 DEG C, gradually raised temperature to 1650 DEG C, be incubated 12 hours;
(3) shaping, anneal 3 hours at 700 DEG C, naturally cooling, obtains high strength glass material.
Be 4mm glass print by high strength glass material grinding and polishing to the thickness obtained in embodiment 1-5 and comparative example, test, concrete test result is as shown in table 1.
Table 1
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (6)
1. a high strength glass material, is characterized in that, is made up of the component comprising following weight part:
2. high strength glass material according to claim 1, is characterized in that, described component also comprises nanometer silver 0-1.1 weight part.
3. high strength glass material according to claim 2, is characterized in that, described nanometer silver is the mixing of one or more in nanometer silver rod, nano-silver thread, nanometer ping-pong ball.
4. high strength glass material according to claim 1, is characterized in that, described component also comprises ferric oxide nanometer particle 0-0.02 weight part.
5. a preparation method for high strength glass material, is characterized in that, comprises the following steps:
(1) by silicon-dioxide 55-65 weight part, zirconium dioxide 8-15 weight part, boron oxide 5-12 weight part, aluminum oxide 1.5-2 weight part, cobaltous sulfide 0.01-0.06 weight part, three hydration neutralized verdigris 0.02-0.04 weight parts, Cu2V1.5O6.50.01-0.08 weight part, nanometer silver 0-1.1 weight part and ferric oxide nanometer particle 0-0.02 weight part, mix;
(2) material after mixing is added in quartz crucible, be placed in High Temperature Furnaces Heating Apparatus and melt, raised temperature is to 1300-1450 DEG C gradually, insulation 8-11 hour;
(3) shaping, anneal 2-4 hour at 700-800 DEG C, and naturally cooling obtains high strength glass material.
6. the preparation method of high strength glass material according to claim 5, is characterized in that, the temperature of fusion in described High Temperature Furnaces Heating Apparatus is 1050-1200 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510299733.4A CN104829131A (en) | 2015-06-03 | 2015-06-03 | High-strength glass material and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510299733.4A CN104829131A (en) | 2015-06-03 | 2015-06-03 | High-strength glass material and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104829131A true CN104829131A (en) | 2015-08-12 |
Family
ID=53807389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510299733.4A Pending CN104829131A (en) | 2015-06-03 | 2015-06-03 | High-strength glass material and production method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104829131A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107285626A (en) * | 2017-07-25 | 2017-10-24 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength glass material and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031826A (en) * | 1987-09-08 | 1989-03-22 | 国营光明器材厂 | Blue discolouration glass |
| CN101100354A (en) * | 2007-06-25 | 2008-01-09 | 沈阳建筑大学 | Method for manufacturing low radiation glass |
| CN101112295A (en) * | 2007-07-20 | 2008-01-30 | 胡伟添 | Glass inner container for the electric cooker and the processing technics thereof |
| CN103524037A (en) * | 2013-07-26 | 2014-01-22 | 宁波大学 | Silver nanoparticle composite block bismuthate glass material and preparation method thereof |
-
2015
- 2015-06-03 CN CN201510299733.4A patent/CN104829131A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031826A (en) * | 1987-09-08 | 1989-03-22 | 国营光明器材厂 | Blue discolouration glass |
| CN101100354A (en) * | 2007-06-25 | 2008-01-09 | 沈阳建筑大学 | Method for manufacturing low radiation glass |
| CN101112295A (en) * | 2007-07-20 | 2008-01-30 | 胡伟添 | Glass inner container for the electric cooker and the processing technics thereof |
| CN103524037A (en) * | 2013-07-26 | 2014-01-22 | 宁波大学 | Silver nanoparticle composite block bismuthate glass material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107285626A (en) * | 2017-07-25 | 2017-10-24 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength glass material and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
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| PB01 | Publication | ||
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Application publication date: 20150812 |