CN105819686A - Cold-resistant glass material and preparation method thereof - Google Patents
Cold-resistant glass material and preparation method thereof Download PDFInfo
- Publication number
- CN105819686A CN105819686A CN201610124601.2A CN201610124601A CN105819686A CN 105819686 A CN105819686 A CN 105819686A CN 201610124601 A CN201610124601 A CN 201610124601A CN 105819686 A CN105819686 A CN 105819686A
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- CN
- China
- Prior art keywords
- weight portion
- glass material
- cold
- resistant glass
- acid
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
Abstract
The invention discloses a cold-resistant glass material and a preparation method thereof. The cold-resistant glass material is prepared from, by weight, 75-80 parts of silica, 14-16 parts of boric acid, 5-8 parts of magnesium silicoaluminate, 5-8 parts of alumina, 2-4 parts of zirconium dioxide, 1-2 parts of calcium aluminate, 1-2 parts of zirconium oxychloride, 0.5-1 part of butyl acyl peroxybenzoate, 0.5-1 part of 4-guanidinobutyric acid and 0.5-1 part of white carbon black. The invention also provides the preparation method of the cold-resistant glass material.
Description
Technical field
The invention belongs to glass material field, resist cold glass material and preparation thereof particularly to one
Method.
Background technology
The main component of simple glass is silicon dioxide, is that the amorphous state of a kind of random structure is solid
Body.It is widely used in building, is used for every wind printing opacity, separately has glass to be mixed into some metal
Oxide or salt and show the coloured glass of color, and the steel prepared by specific process
Change glass etc..
Silicate glass with quartz sand, soda, Anhydrite and limestone etc. as raw material, through mixing,
High-temperature fusion, homogenize after, shape, more annealed and obtain.Be widely used in building, daily,
The field such as medical treatment, chemistry, electronics, instrument, nuclear engineering.
According to the difference of the glass properties that different application needs, therefore have quartz glass,
Silicate glass, soda-lime glass, fluoride glass, high temp glass, high pressure resistant glass, anti-purple
The glass of the different performances such as outside line glass, implosion guard.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of cold-resistant glass material and preparation thereof
Method.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of cold-resistant glass material, is made up of the component comprising following weight portion:
Silicon dioxide 75-80 part, boric acid 14-16 part, aluminosilicate magnesium 5-8 part,
Aluminium sesquioxide 5-8 part, zirconium dioxide 2-4 part, calcium aluminate 1-2 part,
Basic zirconium chloride 1-2 part, benzoyl peroxide butyl acetate 0.5-1 part,
4-guanidine radicals butanoic acid 0.5-1 part, white carbon 0.5-1 part.
Described component also includes Barium monoxide 0-2 weight portion.
Described component also includes fumaric acid 0-0.5 weight portion.
A kind of preparation method of cold-resistant glass material, the method comprises the following steps:
(1) silicon dioxide 75-80 weight portion, boric acid 14-16 weight portion, aluminosilicate are weighed
Magnesium 5-8 weight portion, aluminium sesquioxide 5-8 weight portion, zirconium dioxide 2-4 weight portion, aluminic acid
Calcium 1-2 weight portion, basic zirconium chloride 1-2 weight portion, benzoyl peroxide butyl acetate 0.5-1
Weight portion, 4-guanidine radicals butanoic acid 0.5-1 weight portion, white carbon 0.5-1 weight portion, Barium monoxide
0-2 weight portion and fumaric acid 0-0.5 weight portion；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, heating, is incubated 1-3
Hour, obtain vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1100-1200 DEG C, obtain cold-resistant glass material.
Described in step (2), the temperature of heating is 1350-1450 DEG C.
Compared with prior art, it has the beneficial effect that the present invention
(1) the cold-resistant glass material that the present invention prepares is with silicon dioxide as primary raw material, passes through
Add boric acid, aluminosilicate magnesium, aluminium sesquioxide, zirconium dioxide, calcium aluminate, basic zirconium chloride,
Benzoyl peroxide butyl acetate, 4-guanidine radicals butanoic acid and white carbon, prepared cold-resistant glass material
There is good mechanical strength, remain to keep good mechanical strength when temperature is relatively low, and
Remain to keep good various aspects of performance in the environment of being quenched and being shock heating.
(2) the cold-resistant glass material of the present invention has good anti-scratch colored performance.
(3) the cold-resistant glass material of the present invention, its preparation method is simple, it is easy to industry metaplasia
Produce.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) silicon dioxide 75kg, boric acid 14kg, aluminosilicate magnesium 5kg, three oxidations two are weighed
Aluminum 5kg, zirconium dioxide 2kg, calcium aluminate 1kg, basic zirconium chloride 1kg, benzoyl peroxide vinegar
Acid butyl ester 0.5kg, 4-guanidine radicals butanoic acid 0.5kg and white carbon 0.5kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1350 DEG C of temperature
Lower insulation 3 hours, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1100 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Embodiment 2
(1) silicon dioxide 75kg, boric acid 14kg, aluminosilicate magnesium 5kg, three oxidations two are weighed
Aluminum 5kg, zirconium dioxide 2kg, calcium aluminate 1kg, basic zirconium chloride 1kg, benzoyl peroxide vinegar
Acid butyl ester 0.5kg, 4-guanidine radicals butanoic acid 0.5kg, white carbon 0.5kg, Barium monoxide 2kg and anti-
Butene dioic acid 0.5kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1350 DEG C of temperature
Lower insulation 3 hours, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1100 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Embodiment 3
(1) silicon dioxide 80kg, boric acid 16kg, aluminosilicate magnesium 8kg, three oxidations two are weighed
Aluminum 8kg, zirconium dioxide 4kg, calcium aluminate 2kg, basic zirconium chloride 2kg, benzoyl peroxide vinegar
Acid butyl ester 1kg, 4-guanidine radicals butanoic acid 1kg, white carbon 1kg, Barium monoxide 2kg and anti-butylene two
Acid 0.5kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1450 DEG C of temperature
Lower insulation 1 hour, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1200 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Embodiment 4
(1) silicon dioxide 80kg, boric acid 16kg, aluminosilicate magnesium 8kg, three oxidations two are weighed
Aluminum 8kg, zirconium dioxide 4kg, calcium aluminate 2kg, basic zirconium chloride 1kg, benzoyl peroxide vinegar
Acid butyl ester 0.5kg, 4-guanidine radicals butanoic acid 1kg, white carbon 0.5kg, Barium monoxide 2kg and anti-fourth
Enedioic acid 0.5kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1450 DEG C of temperature
Lower insulation 1 hour, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1200 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Embodiment 5
(1) silicon dioxide 78kg, boric acid 15kg, aluminosilicate magnesium 7kg, three oxidations two are weighed
Aluminum 7kg, zirconium dioxide 3kg, calcium aluminate 1.5kg, basic zirconium chloride 1.5kg, benzoyl peroxide first
Acyl butyl acetate 0.8kg, 4-guanidine radicals butanoic acid 0.8kg, white carbon 0.8kg, Barium monoxide 1kg
With fumaric acid 0.2kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1400 DEG C of temperature
Lower insulation 2 hours, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1150 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Comparative example 1
(1) silicon dioxide 80kg, boric acid 16kg, aluminosilicate magnesium 8kg, three oxidations two are weighed
Aluminum 8kg, zirconium dioxide 4kg, calcium aluminate 2kg, benzoyl peroxide butyl acetate 1kg, 4-
Guanidine radicals butanoic acid 1kg, white carbon 1kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1450 DEG C of temperature
Lower insulation 1 hour, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1200 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Comparative example 2
(1) silicon dioxide 80kg, boric acid 16kg, aluminosilicate magnesium 8kg, three oxidations two are weighed
Aluminum 8kg, zirconium dioxide 4kg, calcium aluminate 2kg, basic zirconium chloride 2kg, 4-guanidine radicals butanoic acid 1kg,
White carbon 1kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1450 DEG C of temperature
Lower insulation 1 hour, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1200 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Comparative example 3
(1) silicon dioxide 80kg, boric acid 16kg, aluminium sesquioxide 8kg, titanium dioxide are weighed
Zirconium 4kg, calcium aluminate 2kg, basic zirconium chloride 2kg, benzoyl peroxide butyl acetate 1kg, 4-
Guanidine radicals butanoic acid 1kg, white carbon 1kg；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, 1450 DEG C of temperature
Lower insulation 1 hour, obtains vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1200 DEG C, obtain cold-resistant glass material.
The performance test results preparing cold-resistant glass material is as shown in table 1.
Table 1
The invention is not restricted to embodiment here, those skilled in the art's taking off according to the present invention
Showing, improvement and the amendment made without departing from scope all should be at the protection models of the present invention
Within enclosing.
Claims (5)
1. a cold-resistant glass material, it is characterised in that by the component system comprising following weight portion
Become:
Silicon dioxide 75-80 part, boric acid 14-16 part, aluminosilicate magnesium 5-8 part,
Aluminium sesquioxide 5-8 part, zirconium dioxide 2-4 part, calcium aluminate 1-2 part,
Basic zirconium chloride 1-2 part, benzoyl peroxide butyl acetate 0.5-1 part,
4-guanidine radicals butanoic acid 0.5-1 part, white carbon 0.5-1 part.
The most according to claim 1, resist cold glass material, it is characterised in that described component is also
Including Barium monoxide 0-2 weight portion.
The most according to claim 1, resist cold glass material, it is characterised in that described component is also
Including fumaric acid 0-0.5 weight portion.
4. the preparation method of a cold-resistant glass material, it is characterised in that the method includes following
Step:
(1) silicon dioxide 75-80 weight portion, boric acid 14-16 weight portion, aluminosilicate are weighed
Magnesium 5-8 weight portion, aluminium sesquioxide 5-8 weight portion, zirconium dioxide 2-4 weight portion, aluminic acid
Calcium 1-2 weight portion, basic zirconium chloride 1-2 weight portion, benzoyl peroxide butyl acetate 0.5-1
Weight portion, 4-guanidine radicals butanoic acid 0.5-1 weight portion, white carbon 0.5-1 weight portion, Barium monoxide
0-2 weight portion and fumaric acid 0-0.5 weight portion；
(2) by above-mentioned raw materials after fully mixed, it is placed in crucible, heating, is incubated 1-3
Hour, obtain vitreous humour；
(3) vitreous humour described in step (2) is poured into and shapes on preheated graphite jig,
Make annealing treatment at 1100-1200 DEG C, obtain cold-resistant glass material.
The preparation method of cold-resistant glass material the most according to claim 4, its feature exists
In, described in step (2), the temperature of heating is 1350-1450 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610124601.2A CN105819686A (en) | 2016-03-04 | 2016-03-04 | Cold-resistant glass material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610124601.2A CN105819686A (en) | 2016-03-04 | 2016-03-04 | Cold-resistant glass material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105819686A true CN105819686A (en) | 2016-08-03 |
Family
ID=56987523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610124601.2A Pending CN105819686A (en) | 2016-03-04 | 2016-03-04 | Cold-resistant glass material and preparation method thereof |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673430A (en) * | 2016-12-11 | 2017-05-17 | 安徽兆利光电科技有限公司 | LED lamp glass material and preparation method thereof |
| CN106698935A (en) * | 2016-12-11 | 2017-05-24 | 安徽兆利光电科技有限公司 | Luminescent glass for lighting of LED lamp |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4501819A (en) * | 1982-12-23 | 1985-02-26 | Kabushiki Kaisha Ohara Kogaku Garasu Seizosho | Glass for a photomask |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| CN105271784A (en) * | 2015-10-30 | 2016-01-27 | 中国科学院理化技术研究所 | Hollow glass microsphere |
-
2016
- 2016-03-04 CN CN201610124601.2A patent/CN105819686A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4501819A (en) * | 1982-12-23 | 1985-02-26 | Kabushiki Kaisha Ohara Kogaku Garasu Seizosho | Glass for a photomask |
| CN101094818A (en) * | 2004-05-29 | 2007-12-26 | 肖特股份公司 | Nano glass powder and use thereof, particularly multicomponent glass powder with a mean particle size of less than 1 [mu]m |
| CN105271784A (en) * | 2015-10-30 | 2016-01-27 | 中国科学院理化技术研究所 | Hollow glass microsphere |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673430A (en) * | 2016-12-11 | 2017-05-17 | 安徽兆利光电科技有限公司 | LED lamp glass material and preparation method thereof |
| CN106698935A (en) * | 2016-12-11 | 2017-05-24 | 安徽兆利光电科技有限公司 | Luminescent glass for lighting of LED lamp |
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Application publication date: 20160803 |