CN107285625A - Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof - Google Patents

Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof Download PDF

Info

Publication number
CN107285625A
CN107285625A CN201710407000.7A CN201710407000A CN107285625A CN 107285625 A CN107285625 A CN 107285625A CN 201710407000 A CN201710407000 A CN 201710407000A CN 107285625 A CN107285625 A CN 107285625A
Authority
CN
China
Prior art keywords
glass
safety glass
heat transfer
corrosion
transfer rate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710407000.7A
Other languages
Chinese (zh)
Inventor
王红胜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Wohaisen Technology Co Ltd
Original Assignee
Shenzhen Wohaisen Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Wohaisen Technology Co Ltd filed Critical Shenzhen Wohaisen Technology Co Ltd
Priority to CN201710407000.7A priority Critical patent/CN107285625A/en
Publication of CN107285625A publication Critical patent/CN107285625A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/20—Compositions for glass with special properties for chemical resistant glass

Abstract

The invention belongs to safety glass production technical field, and in particular to corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof；The safety glass includes the raw material of following mass fraction：Basic components 80 85%, carborundum 1 5%, glass fibre 1 10%, boron nitride 1 3%, silicon nitride 1 5%, indium oxide 0.01 2%；The present invention adds the components such as carborundum, boron nitride, silicon nitride and indium oxide in conventional safety glass, the structural strength of safety glass can be improved, the heat transfer rate and corrosion resistance of glass can be improved again, in addition, the addition of glass fibre can reduce the fragility of safety glass, its toughness is improved, makes its more robust, safety in utilization is higher.

Description

Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof
Technical field
The invention belongs to safety glass production technical field, and in particular to a kind of corrosion-resistant tempering glass of the high heat transfer rate of idle call Glass and preparation method thereof.
Background technology
Safety glass refers to plate glass after heating-quenching method or the processing of other methods, and its surface forms pressure Stressor layers, mechanical strength and heat shock resistance intensity are improved, when glass breakage, safety glass can be formed granular debris with A kind of safety glass for danger of causing injury is reduced, as a kind of form of the most frequently used safety glass, the intensity of safety glass is general 4-5 times of logical glass, warping resistance degree is 3-5 times of simple glass, and impact strength is 5-10 times of simple glass, in addition, steel It is in the fractionlet without acute angle to change after glass is destroyed, and resistance to chilling urgency, thermal property have 2-3 times of raising than simple glass, typically More than 300 DEG C of difference variation can be born, with the development and progress of society, application of the safety glass in household electric appliances is more next It is more extensive.
Because the thermal change amplitude of air-conditioning is larger, therefore, when safety glass is used for air-conditioning household electrical appliances, it is necessary in existing tempering On the basis of glass, it is modified, strong good heat-sinking capability and corrosion resistance is made it have, to adapt to the work of air-conditioning Make environment and improve its safety in utilization.
The content of the invention
It is applied to air-conditioning assembling, using safety, with high heat transfer rate and corrosion-resistant it is an object of the invention to provide one kind The strong safety glass of property, and its preparation method.
To achieve the above object, the technical solution adopted by the present invention is：The corrosion-resistant safety glass of the high heat transfer rate of idle call, bag Include the raw material of following mass fraction：Basic components 80-85%, carborundum 1-5%, glass fibre 1-10%, boron nitride 1-3%, nitridation Silicon 1-5%, indium oxide 0.01-2%.
Further, described basic components include the raw material of following mass fraction：SiO255-80%, Al2O38-15%, B2O30.2-3%, TiO20.01-3%, Li2O 5-15%, Na2O 5-12%, K2O 0.5-3%, MgO 0.05-3%, CaO 0.01- 2%, MoO30.005-0.5%, ZnO 0.005-0.5%.
Further, described basic components include the raw material of following mass fraction：SiO258-75%, Al2O3 10- 12%, B2O30.5-2.5%, TiO20.05-2%, Li2O 6-12%, Na2O 8-10%, K2O 0.6-1.5%, MgO 0.05-1%, CaO 0.01-1%, MoO30.005-0.2%, ZnO 0.005-0.2%.
Further, described basic components include the raw material of following mass fraction：SiO265%, Al2O310%, B2O3 2%, TiO21%, Li2O 10%, Na2O 9.8%, K2O 1.8%, MgO 0.2%, CaO 0.05%, MoO30.1%, ZnO 0.05%.
The preparation method of the corrosion-resistant safety glass of the high heat transfer rate of idle call, comprises the following steps：
（1）Each raw material is measured respectively by formula；
（2）By in basic components all input pot furnace, 500 DEG C are warming up to 100-200 DEG C/h programming rate；
（3）Surplus stock is put into pot furnace, continuation is warming up to 1000-1500 DEG C with 300-500 DEG C/h programming rate, leads to Nitrogen carries out flow-disturbing reaction, is allowed to be formed the glass metal of bubble-free, is incubated 1-2 hours；
（4）Glass metal is swum in molten tin using float glass process, then annealed, produced.
Further, the step（4）In method for annealing be：120-200 is cooled to 3-6 DEG C/min cooling rate DEG C, it is then air-cooled to normal temperature.
The beneficial effect that above-mentioned technical proposal is produced is：The present invention added in conventional safety glass carborundum, The components such as boron nitride, silicon nitride and indium oxide, can improve the structural strength of safety glass, can improve again glass heat transfer rate and Corrosion resistance, in addition, the addition of glass fibre can reduce the fragility of safety glass, improves its toughness, makes its more robust, use peace Full property is higher.
Embodiment
Below by way of 5 embodiments, the present invention is further disclosed.
Embodiment 1：The corrosion-resistant safety glass of the high heat transfer rate of idle call, includes the raw material of following mass fraction：Basic components 80%, carborundum 5%, glass fibre 7.5%, boron nitride 1%, silicon nitride 5%, indium oxide 1.5%.
Basic components include the raw material of following mass fraction in the present embodiment：SiO255%, Al2O312%, B2O33%, TiO23%, Li2O 11.9%, Na2O 10%, K2O 3%, MgO 1%, CaO 0.5%, MoO30.5%, ZnO 0.1%.
The preparation method of the corrosion-resistant safety glass of the high heat transfer rate of idle call, comprises the following steps：
（1）Each raw material is measured respectively by formula；
（2）By in basic components all input pot furnace, 500 DEG C are warming up to 100-200 DEG C/h programming rate；
（3）Surplus stock is put into pot furnace, continuation is warming up to 1000-1500 DEG C with 300-500 DEG C/h programming rate, leads to Nitrogen carries out flow-disturbing reaction, is allowed to be formed the glass metal of bubble-free, is incubated 1-2 hours；
（4）Glass metal is swum in molten tin using float glass process, then annealed, produced.
Further, the step（4）In method for annealing be：120-200 is cooled to 3-6 DEG C/min cooling rate DEG C, it is then air-cooled to normal temperature.
Embodiment 2：The corrosion-resistant safety glass of the high heat transfer rate of idle call, includes the raw material of following mass fraction：Basic components 82%, carborundum 3%, glass fibre 8%, boron nitride 2%, silicon nitride 4%, indium oxide 1%.
Basic components include the raw material of following mass fraction in the present embodiment：SiO260%, Al2O313%, B2O31%, TiO20.5%, Li2O 13%, Na2O 7.5%, K2O 2%, MgO 1%, CaO 1.5%, MoO30.2%, ZnO 0.3%.
Its preparation method be the same as Example 1.
Embodiment 3：The corrosion-resistant safety glass of the high heat transfer rate of idle call, includes the raw material of following mass fraction：Basic components 85%, carborundum 1%, glass fibre 10%, boron nitride 2%, silicon nitride 1%, indium oxide 1%.
Basic components include the raw material of following mass fraction in the present embodiment：SiO261.49%, Al2O312%, B2O3 0.5%, TiO22%, Li2O 12%, Na2O 10%, K2O 0.6%, MgO 1%, CaO 0.01%, MoO30.2%, ZnO 0.2%.
Its preparation method be the same as Example 1.
Embodiment 4：The corrosion-resistant safety glass of the high heat transfer rate of idle call, includes the raw material of following mass fraction：Basic components 80%, carborundum 5%, glass fibre 8.99%, boron nitride 1%, silicon nitride 5%, indium oxide 0.01%.
Basic components include the raw material of following mass fraction in the present embodiment：SiO270%, Al2O310%, B2O32.5%, TiO20.05%, Li2O 6%, Na2O 8.89%, K2O 1.5%, MgO 0.05%, CaO 1%, MoO30.005%, ZnO 0.005%.
Its preparation method be the same as Example 1.
Embodiment 5：The corrosion-resistant safety glass of the high heat transfer rate of idle call, includes the raw material of following mass fraction：Basic components 85%, carborundum 1%, glass fibre 10%, boron nitride 1%, silicon nitride 2%, indium oxide 1%.
Basic components include the raw material of following mass fraction in the present embodiment：SiO265%, Al2O310%, B2O32%, TiO21%, Li2O 10%, Na2O 9.8%, K2O 1.8%, MgO 0.2%, CaO 0.05%, MoO30.1%, ZnO 0.05%.
Its preparation method be the same as Example 1.

Claims (6)

1. the corrosion-resistant safety glass of the high heat transfer rate of idle call, it is characterised in that include the raw material of following mass fraction：Basic components 80-85%, carborundum 1-5%, glass fibre 1-10%, boron nitride 1-3%, silicon nitride 1-5%, indium oxide 0.01-2%.
2. the corrosion-resistant safety glass of the high heat transfer rate of idle call as claimed in claim 1, it is characterised in that described basic components Include the raw material of following mass fraction：SiO255-80%, Al2O38-15%, B2O30.2-3%, TiO20.01-3%, Li2O 5- 15%, Na2O 5-12%, K2O 0.5-3%, MgO 0.05-3%, CaO 0.01-2%, MoO30.005-0.5%, ZnO 0.005- 0.5%。
3. the corrosion-resistant safety glass of the high heat transfer rate of idle call as claimed in claim 2, it is characterised in that described basic components Include the raw material of following mass fraction：SiO258-75%, Al2O310-12%, B2O30.5-2.5%, TiO20.05-2%, Li2O 6-12%, Na2O 8-10%, K2O 0.6-1.5%, MgO 0.05-1%, CaO 0.01-1%, MoO30.005-0.2%, ZnO 0.005-0.2%。
4. the corrosion-resistant safety glass of the high heat transfer rate of idle call as claimed in claim 2, it is characterised in that described basic components Include the raw material of following mass fraction：SiO265%, Al2O310%, B2O32%, TiO21%, Li2O 10%, Na2O 9.8%, K2O 1.8%, MgO 0.2%, CaO 0.05%, MoO30.1%, ZnO 0.05%.
5. the preparation method of the corrosion-resistant safety glass of the high heat transfer rate of idle call as any one of claim 1-4, it is special Levy and be, comprise the following steps：
（1）Each raw material is measured respectively by formula；
（2）By in basic components all input pot furnace, 500 DEG C are warming up to 100-200 DEG C/h programming rate；
（3）Surplus stock is put into pot furnace, continuation is warming up to 1000-1500 DEG C with 300-500 DEG C/h programming rate, leads to Nitrogen carries out flow-disturbing reaction, is allowed to be formed the glass metal of bubble-free, is incubated 1-2 hours；
（4）Glass metal is swum in molten tin using float glass process, then annealed, produced.
6. the preparation method of the corrosion-resistant safety glass of the high heat transfer rate of idle call as claimed in claim 5, it is characterised in that described Step（4）In method for annealing be：120-200 DEG C is cooled to 3-6 DEG C/min cooling rate, it is then air-cooled to normal temperature.
CN201710407000.7A 2017-06-02 2017-06-02 Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof Pending CN107285625A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710407000.7A CN107285625A (en) 2017-06-02 2017-06-02 Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710407000.7A CN107285625A (en) 2017-06-02 2017-06-02 Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107285625A true CN107285625A (en) 2017-10-24

Family

ID=60094698

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710407000.7A Pending CN107285625A (en) 2017-06-02 2017-06-02 Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107285625A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117266A (en) * 2017-12-30 2018-06-05 安徽杜氏高科玻璃有限公司 A kind of wear-resisting acid corrosion-resistant glass
CN108891105A (en) * 2018-06-13 2018-11-27 浙江西溪玻璃有限公司 Explosion-proof glass and preparation method thereof
CN113135656A (en) * 2021-05-27 2021-07-20 常州亚玛顿股份有限公司 anti-PID glass for solar cell and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020061810A1 (en) * 1997-05-16 2002-05-23 Sumitomo Electric Industries, Ltd. Silica glass article and manufacturing process therefor
CN2495644Y (en) * 2001-10-19 2002-06-19 洛阳北方玻璃技术股份有限公司 Armoured glass prodn. equipment using static pressure lifting method
CN102826756A (en) * 2012-09-24 2012-12-19 绍兴杰龙玻璃有限公司 Preparation method of white jade glass tableware

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020061810A1 (en) * 1997-05-16 2002-05-23 Sumitomo Electric Industries, Ltd. Silica glass article and manufacturing process therefor
CN2495644Y (en) * 2001-10-19 2002-06-19 洛阳北方玻璃技术股份有限公司 Armoured glass prodn. equipment using static pressure lifting method
CN102826756A (en) * 2012-09-24 2012-12-19 绍兴杰龙玻璃有限公司 Preparation method of white jade glass tableware

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117266A (en) * 2017-12-30 2018-06-05 安徽杜氏高科玻璃有限公司 A kind of wear-resisting acid corrosion-resistant glass
CN108891105A (en) * 2018-06-13 2018-11-27 浙江西溪玻璃有限公司 Explosion-proof glass and preparation method thereof
CN108891105B (en) * 2018-06-13 2020-09-04 浙江西溪玻璃有限公司 Explosion-proof glass and preparation method thereof
CN113135656A (en) * 2021-05-27 2021-07-20 常州亚玛顿股份有限公司 anti-PID glass for solar cell and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106587606B (en) The production technology of tempered glass
CN108503213B (en) Aluminosilicate glass and tempered glass
KR20190022707A (en) Chemically temperable glass plate
US20140248495A1 (en) Chemically strengthened glass and method for producing same
CN107285625A (en) Corrosion-resistant safety glass of the high heat transfer rate of idle call and preparation method thereof
WO2011103798A1 (en) Chemically strengthened glass capable of subsequently cutting
JP5764084B2 (en) Glass composition, glass composition for chemical strengthening, tempered glass article, cover glass for display and method for producing tempered glass article
CN102503101A (en) Additive and chemical tempering process for glass
CN101348327B (en) Manufacturing method of toughened glass
CN101285113B (en) Control method for quenching buckling distortion of elongated metal shear-blade
US9789665B2 (en) Alkali-aluminosilicate glass
JP2017519715A (en) Chemically strengthened glass composition for alkali aluminosilicate glass and method for producing the same
CN102260818A (en) High-silicon anticorrosion cast iron and manufacturing method thereof
CN108409151A (en) A kind of no boron high-performance glass fiber and preparation method thereof
JP2013028506A (en) Cover glass for display
CN107324658A (en) A kind of photosensitive glass-ceramics shell and preparation method thereof
CN104843997B (en) Tempered glass for electro-tricycle
CN107601900A (en) A kind of photosensitive glass-ceramics shell and preparation method thereof
CN101215105A (en) Surface strengthening method for lithium silicon aluminum micro-crystal glass
CN109354403A (en) It is a kind of with alkaline-resisting explosion-proof tempered glass
CN101921053A (en) Conductive glass toughening method
CN109734309A (en) A kind of preparation method of high aluminosilicate ultra-thin glass
CN101007704A (en) Process for preparing coloured quartz glass tube
CN108929030A (en) A kind of production method of tempered glass
KR20130143525A (en) Alkali glass and method for manufacturing the same

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20171024