CN105524530A - 一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 - Google Patents
一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 Download PDFInfo
- Publication number
- CN105524530A CN105524530A CN201610007563.2A CN201610007563A CN105524530A CN 105524530 A CN105524530 A CN 105524530A CN 201610007563 A CN201610007563 A CN 201610007563A CN 105524530 A CN105524530 A CN 105524530A
- Authority
- CN
- China
- Prior art keywords
- nano
- mildew
- antibacterial
- coating material
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 44
- 239000000463 material Substances 0.000 title claims abstract description 40
- 239000002103 nanocoating Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000004132 cross linking Methods 0.000 title abstract description 6
- 239000002105 nanoparticle Substances 0.000 claims abstract description 33
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 9
- 229920000620 organic polymer Polymers 0.000 claims abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 19
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 10
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 9
- 229960000834 vinyl ether Drugs 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 5
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 5
- 230000001588 bifunctional effect Effects 0.000 claims description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920003987 resole Polymers 0.000 claims description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 3
- 235000006491 Acacia senegal Nutrition 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229920003180 amino resin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 235000018102 proteins Nutrition 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 241000978776 Senegalia senegal Species 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 48
- 239000011787 zinc oxide Substances 0.000 abstract description 24
- 238000000576 coating method Methods 0.000 abstract description 19
- 238000000227 grinding Methods 0.000 abstract description 18
- 239000011248 coating agent Substances 0.000 abstract description 17
- 239000000758 substrate Substances 0.000 abstract description 6
- 238000004528 spin coating Methods 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000001029 thermal curing Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 69
- 238000012544 monitoring process Methods 0.000 description 17
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- -1 Atomic oxygen radical anion Chemical class 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- 241000405217 Viola <butterfly> Species 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 description 4
- 235000001892 vitamin D2 Nutrition 0.000 description 4
- 239000011653 vitamin D2 Substances 0.000 description 4
- SAMJGBVVQUEMGC-UHFFFAOYSA-N 1-ethenoxy-2-(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOC=C SAMJGBVVQUEMGC-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 229940059574 pentaerithrityl Drugs 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 description 1
- JOSFJABFAXRZJQ-UHFFFAOYSA-N 1,6-bis(ethenoxy)hexane Chemical compound C=COCCCCCCOC=C JOSFJABFAXRZJQ-UHFFFAOYSA-N 0.000 description 1
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- WVXLLHWEQSZBLW-UHFFFAOYSA-N 2-(4-acetyl-2-methoxyphenoxy)acetic acid Chemical compound COC1=CC(C(C)=O)=CC=C1OCC(O)=O WVXLLHWEQSZBLW-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 108010058846 Ovalbumin Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000008717 functional decline Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229940092253 ovalbumin Drugs 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- ROVRRJSRRSGUOL-UHFFFAOYSA-N victoria blue bo Chemical compound [Cl-].C12=CC=CC=C2C(NCC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 ROVRRJSRRSGUOL-UHFFFAOYSA-N 0.000 description 1
- 239000004846 water-soluble epoxy resin Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/04—Epoxynovolacs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法,该涂层材料由以下质量百分比的成分组成:由0.2-7%的热交联剂或聚合物、0.1-10%的有机高分子、0-2%着色染料、2-15%纳米粒子、60-80%溶剂组成。其制备方法为:溶剂中加入热交联剂、有机高分子、着色染料,混匀后加入纳米氧化锌或者纳米氧化锌和纳米二氧化钛的纳米粒子,在500-10000转/分钟的转速下以搅拌、分散和乳化中的其中一种方式进行操作1小时,然后用高效研磨机研磨。本发明的有益效果:本发明可用挤压、喷涂,旋涂、刮涂等方式涂布在基材表面,通过热固化在基材表面形成一层耐磨性优良、可耐化学品腐蚀及耐候性极佳的具有抗菌、防霉及分解甲醛的纳米涂层。
Description
技术领域
本发明属于纳米涂层制备及应用技术领域,具体来说,涉及到一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法。
背景技术
抗菌防霉涂料主要有两大类型:第一类是有机抗菌剂或有机防霉剂,其缺点是作用时间短,随着有机物的自行分解,抗菌或防霉作用逐渐消失,有害微生物会形成耐药性,并且某些有机物对人体和环境有负面影响。第二类是无机材料抗菌剂或防霉剂。而无机系列抗菌剂或防霉剂又分为两种:一种是以银、铜、锌等金属离子负载在无机载体上而制成的抗菌剂或防霉剂,其缺点是银、铜、锌等金属离子会流失,抗菌或防霉作用逐渐下降,并且难以做到抗菌和防霉同时兼顾;另一种是纳米氧化锌、二氧化钛等金属氧化的光催化作用来实现抗菌或防霉的无机抗菌剂或防霉剂,缺点是光催化作用必需借助紫外光、水、空气等条件。但是最新的研究表明,纳米氧化物的抗菌防霉活性主要取决于纳米粒子表面的缺陷数,该缺陷通过和空气中的水作用,形成氧负离子自由基。
中国专利CN200610157289.3中公开了一种纳米抗菌防霉涂料,按照重量百分比包括以下组分:水性涂料75-90%,纳米银3-7%,纳米铜或纳米锌3-7%,纳米氧化锌或纳米二氧化钛4-11%。但是该专利所述的纳米氧化物基本上都被水性涂料包覆,在表面裸露的纳米氧化物有限,非固化纳米涂层耐磨性、耐化学品腐蚀性,耐候性都很差,很容易脱落,其抗菌防霉性能有限。
中国专利CN101701120中公开了一种纳米氧化锌抗菌抗污涂料及其制备方法,但是根据该发明专利制作的纳米涂层很容易脱落,更重要的是这种纳米涂料做的非固化涂层耐磨性、耐化学品腐蚀性,耐候性都很差,很容易脱落,同时有大量的助溶剂挥发造成环境的污染。
氧化锌具有吸收紫外线(UV)特性,故含氧化锌的涂料具有极好的抗老化作用,延长涂层的使用寿命,并且一定数量的氧化锌还可以提高涂料的韧性和硬度如美国专利US41395150。另一方面,美国专利US7348029说明纳米氧化锌颗粒除了抗紫外线外还具备抑制病菌滋生的能力。纳米氧化锌作为理想的普适性抗菌能力,长效地抗污性,对环境质量无污染对环境质量无污染,具有环保型等特点。
发明内容
针对相关技术中的上述技术问题,本发明提出一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法。
为实现上述技术目的,本发明的技术方案是这样实现的:
一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其由以下质量百分比的成分组成:热交联剂或聚合物0.2-7%、有机高分子0.1-10%、着色染料0-2%、纳米粒子2-15%、溶剂60-80%。
优选的,所述的热交联剂选自双官能团的二环氧,如:二环氧化-1,3-丁二烯、二环氧甘油醚、二环氧己烷、1,2,7,8-二环氧酮、聚乙二醇二环氧乙烷甲基醚、二环戊二烯环氧化物等;或者所述的热交联剂选自双官能团的二乙烯基醚,如1,4-二环己烷二甲基二乙烯基醚、四(乙二醇)二乙烯基醚、1,6-己二醇二乙烯醚、三乙二醇二乙烯基醚、1,4-环己烷二甲醇二乙烯醚、1,4-丁二醇乙烯醚、二乙二醇二乙烯基醚等;或者所述的热交联剂选自双官能团的双苯酐,如4,4'-氧双邻苯二甲酸酐、均苯四甲酸酐、1,4,5,8-萘四甲酸酐、3,4,9,10-四羧酸酐等;或者所述的热交联剂选自双官能团的二异氰酸酯,如1,4-环己烷二异氰酸酯、1,5-奈二异氰酸酯、二苯基甲烷二异氰酸酯、异佛尔酮二异氰酸酯、1,6-二异氰酸酯基己烷、反-1,4-环己基二异氰酸酯、二甲苯烷二异氰酸酯、L-赖氨酸二异氰酸酯、1,6-己二异氰酸酯、三甲基六亚甲基二异氰酸酯等;或者所述的热交联剂选自多官能团的环氧、氮丙啶、乙烯基醚、苯酐、异氰酸酯的单体,如:三(环氧丙基)异氰尿酸酯、异氰脲酸Β-三缩水甘油酯、缩水甘油醚、异氰脲酸Β-三缩水甘油酯、三羟甲基丙烷-三[3-(2-甲基吖丙啶基)丙酸酯]、三羟甲基丙烷-三(3-吖丙啶基丙酸酯)、季戊四醇三(3-氮丙啶基)丙酸酯等;或者所述的热交联剂选自多官能团的环氧、氮丙啶、乙烯基醚、苯酐、异氰酸酯的聚合物,如环氧树脂、酚醛环氧树脂、聚氮丙啶交联剂等。
优选的,所述有机高分子选自以下物质中的一种或多种:丙烯酸树脂或其酯类树脂、酚醛树脂、聚氨酯、脲醛树脂、聚乙烯醇、聚乙烯醇缩醛、氨基树脂、醇酸树脂、***树胶、明胶、蛋白质、淀粉、纤维素。
优选的,所述的着色染料选用溶于溶剂的无色或者颜色为蓝色、黄色、紫色、红色的染料。
优选的,所述纳米粒子为纳米氧化锌或者纳米氧化锌和纳米二氧化钛的组合物,且粒径为1nm-1000nm。
优选的,所述的溶剂选自水或者以下物质中的一种或多种:四氢呋喃、丁酮、二乙醇甲醚、丙二醇甲醚、乙二醇***、DMF、二乙二醇二甲醚、丁酮、N-甲基吡咯烷酮。
一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料的制备方法,包括如下步骤:
溶剂中加入热交联剂、有机高分子、着色染料,混匀后加入纳米氧化锌或者纳米氧化锌和纳米二氧化钛的纳米粒子,在500-10000转/分钟的转速下以搅拌、分散和乳化中的其中一种方式进行操作1小时,用研磨机研磨至纳米粒子的粒径小于1000nm。
本发明的有益效果:本发明不但具有抗菌的性能,而且还具有很好的防霉及去除甲醛的特性,因此本发明提供一种含有纳米氧化锌的涂层材料,将其通过挤压、喷涂,旋涂、刮涂等方式涂布在基材表面,通过热交联固化在基材表面形成一层致密的三维网状结构,大幅提高了涂层的耐磨性、耐化学品腐蚀性及耐候性;同时由于表面被大量纳米粒子覆盖,因而该涂层具有抗菌、防霉及分解甲醛的纳米涂层;与光照交联固化比较,热固化使用范围更广,更适合于异形表面或者器件内部的涂层制备;该涂层使用范围广,可用于家装、油漆,外墙,码头和舰船等领域。
具体实施方式
为了使本发明实现的技术手段和创作特征易于明白了解,下面对本发明进一步阐述。
下面结合具体的实施例对本发明所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料做进一步说明,但是本发明的保护范围并不限于此。
实施例1
100g水中加入10g聚丙烯酸、8g水溶环氧树脂、0.5g甲基紫,混匀后加入50g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟搅拌1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例2
100g水中加入10g聚乙烯醇缩醛、6g三羟甲基丙烷-三[3-(2-甲基吖丙啶基)丙酸酯]、1g甲基紫,混匀后加入41g初始粒径为20nm的二氧化钛和11g初始粒径为30nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于300nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例3
100g丁酮中加入8g脲醛树脂、4g二乙二醇二乙烯基醚、3g环氧树脂128、0.5g维多利亚纯蓝,混匀后加入45g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟乳化1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例4
100gDMF中加入8g环氧树脂、10g酚醛树脂、0.5g结晶紫,混匀后加入68g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于400nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例5
100g乙二醇***中加入9g酚醛树脂、4g1,6-二异氰酸酯基己烷、4g环氧树脂、1g染料黄,混匀后加入61g初始粒径为25nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例6
100g水中加入8g卵清蛋白、9g水性环氧,混匀后加入51g初始粒径为50nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于500nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例7
100g丙烯酸异辛酯中加入8g丙烯酸马来酸酐共聚物、6g缩水甘油醚、0.5g纯蓝,混匀后加入40g初始粒径为50nm的氧化锌纳米粒子、11g初始粒径为30nm的氧化钛,4000转/分钟乳化1小时,用高效研磨机研磨至粒度仪监控平均粒径小于600nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例8
100gN-甲基吡咯烷酮中加入7g丙烯酸-丙烯酸羟乙酯共聚物、6g异氰脲酸Β-三缩水甘油酯,混匀后加入50g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于300nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例9
100gN,N-二乙基甲酰胺中加入10g聚氨酯、7g三(环氧丙基)异氰尿酸酯、0.5g纯蓝、0.5g燃料黄,混匀后加入53g初始粒径为20nm的氧化锌纳米粒子4000转/分钟搅拌1小时,用高效研磨机研磨至粒度仪监控平均粒径小于400nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例10
100g丙二醇甲醚中加入8g酚醛树脂、6g3,4,9,10-四羧酸酐等、1g染料黄,混匀后加入46g初始粒径为20nm的氧化锌纳米粒子4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例11
100g甲基丙烯酸羟乙酯中加入10g脲醛树脂、7g季戊四醇三(3-氮丙啶基)丙酸酯,混匀后加入41g初始粒径为30nm的氧化锌纳米粒子、10g初始粒径为50nm的二氧化钛纳米粒子,4000转/分钟搅拌1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例12
100g异戊二烯中加入5g醇酸树脂、12g酚醛环氧树脂、0.8g结晶紫,混匀后加入35g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟乳化1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例13
100g二乙醇甲醚中加入12g***树胶、6g三羟甲基丙烷-三(3-吖丙啶基丙酸酯)、0.5g维多利艳蓝,混匀后加入42g初始粒径为40nm的氧化锌纳米粒子、6g初始粒径为20nm的二氧化钛纳米粒子,4000转/分钟搅拌1小时,用高效研磨机研磨至粒度仪监控平均粒径小于400nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例14
100g二乙二醇二甲醚中加入9g聚乙烯醇、7g聚氮丙啶交联剂、0.5g艳蓝、0.5g甲基紫,混匀后加入46g初始粒径为40nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例15
100g四氢呋喃中加入10g纤维素、6g季戊四醇三(3-氮丙啶基)丙酸酯,混匀后加入56g初始粒径为40nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例16
80g丙二醇甲醚、50gDMF中加入14g丙烯酸甲酯-丙烯酸羟乙酯共聚物、8g二乙二醇二乙烯基醚、0.5g结晶紫、0.8g纯蓝,混匀后加入61g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
实施例17
80g丙二醇甲醚中加入1g醇酸树脂、2g酚醛环氧树脂、15g结晶紫,混匀后加入2g初始粒径为20nm的氧化锌纳米粒子,4000转/分钟分散1小时,用高效研磨机研磨至粒度仪监控平均粒径小于200nm,即可得到热交联型抗菌、防霉及分解甲醛的纳米涂层材料。
综上所述,借助于本发明的上述技术方案,本发明可用挤压、喷涂,旋涂、刮涂等方式涂布在基材表面,通过热交联固化在基材表面形成一层致密的三维网状结构,大幅提高了涂层的耐磨性、耐化学品腐蚀性及耐候性;同时由于表面被大量纳米粒子覆盖,因而该涂层具有抗菌、防霉及分解甲醛的纳米涂层;与光照交联固化比较,热固化使用范围更广,更适合于异形表面或者器件内部的涂层制备;该涂层使用范围广,可用于家装、油漆,外墙,码头和舰船等领域。
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (7)
1.一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其特征在于,其由以下质量百分比的成分组成:热交联剂或聚合物0.2-7%、有机高分子0.1-10%、着色染料0-2%、纳米粒子2-15%、溶剂60-80%。
2.根据权利要求1所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其特征在于,所述的热交联剂选自双官能团的二环氧单体、二氮丙啶单体、二乙烯基醚单体、双苯酐单体、二异氰酸酯单体;或者所述的热交联剂选自多官能团的环氧单体、氮丙啶单体、乙烯基醚单体、苯酐单体、异氰酸酯单体;或者所述的热交联剂选自多官能团的环氧、氮丙啶、乙烯基醚、苯酐、异氰酸酯的聚合物。
3.根据权利要求1所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其特征在于,所述有机高分子选自以下物质中的一种或多种:丙烯酸树脂或其酯类树脂、酚醛树脂、聚氨酯、脲醛树脂、聚乙烯醇、聚乙烯醇缩醛、氨基树脂、醇酸树脂、***树胶、明胶、蛋白质、淀粉、纤维素。
4.根据权利要求1所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料,所述的着色染料选用溶于溶剂的无色或者颜色为蓝色、黄色、紫色、红色的染料。
5.根据权利要求1所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其特征在于,所述的纳米粒子为纳米氧化锌或者纳米氧化锌和纳米二氧化钛的组合物,所述纳米粒子的粒径为1nm-1000nm。
6.根据权利要求1所述的热交联型抗菌、防霉及分解甲醛的纳米涂层材料,其特征在于,所述的溶剂选自水或者以下物质中的一种或多种:四氢呋喃、丁酮、二乙醇甲醚、丙二醇甲醚、乙二醇***、DMF、二乙二醇二甲醚、丁酮、N-甲基吡咯烷酮。
7.一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料的制备方法,其特征在于,包括如下步骤:
溶剂中加入热交联剂、有机高分子、着色染料,混匀后加入纳米氧化锌或者纳米氧化锌和纳米二氧化钛的纳米粒子,在500-10000转/分钟的转速下以搅拌、分散和乳化中的其中一种方式进行操作1小时,用研磨机研磨至纳米粒子的粒径小于1000nm。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610007563.2A CN105524530A (zh) | 2016-01-07 | 2016-01-07 | 一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610007563.2A CN105524530A (zh) | 2016-01-07 | 2016-01-07 | 一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105524530A true CN105524530A (zh) | 2016-04-27 |
Family
ID=55767067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610007563.2A Pending CN105524530A (zh) | 2016-01-07 | 2016-01-07 | 一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105524530A (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107573781A (zh) * | 2017-09-30 | 2018-01-12 | 广东福临门世家智能家居有限公司 | 一种具有分解甲醛功能的节能防晒玻璃纳米涂料 |
CN107760131A (zh) * | 2017-09-30 | 2018-03-06 | 广东福临门世家智能家居有限公司 | 一种节能防晒玻璃纳米涂料 |
CN108727914A (zh) * | 2018-05-23 | 2018-11-02 | 芜湖市创源新材料有限公司 | 一种功能性隔热抗菌淀粉涂料的制备方法 |
CN108864688A (zh) * | 2018-06-05 | 2018-11-23 | 瑞安市吉尔康鞋业有限公司 | 防霉抗菌鞋底用聚氨酯原液及防霉抗菌鞋底的生产工艺 |
CN109162110A (zh) * | 2018-09-25 | 2019-01-08 | 四川大学 | 一种基于光敏反应型增塑剂同步内增塑制造聚氯乙烯人造革的方法 |
CN109666386A (zh) * | 2017-10-14 | 2019-04-23 | 梁秋云 | 一种醇酸树脂复合外墙涂料 |
CN110354440A (zh) * | 2019-07-02 | 2019-10-22 | 襄阳水木南山装饰工程有限公司 | 一种装修工程中预防和控制甲醛污染的方法 |
CN110484086A (zh) * | 2018-05-15 | 2019-11-22 | 淄博华森粘合剂有限公司 | 一种抗菌抑菌改性脲醛树脂及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001001453A (ja) * | 1999-06-21 | 2001-01-09 | Dainippon Printing Co Ltd | 化粧材 |
JP2008050402A (ja) * | 2006-08-22 | 2008-03-06 | Sumitomo Osaka Cement Co Ltd | 水垢固着防止製品、及びその製造方法 |
CN103333571A (zh) * | 2013-06-24 | 2013-10-02 | 广州慧谷化学有限公司 | 用于热交换器翅片表面处理的水性抗菌防霉亲水涂料 |
CN104629606A (zh) * | 2015-02-05 | 2015-05-20 | 金林墨 | 一种抗菌防水聚氨酯涂料及其制备方法 |
CN104962148A (zh) * | 2015-07-07 | 2015-10-07 | 饶烨 | 一种抗菌阻燃涂料及其制备方法 |
-
2016
- 2016-01-07 CN CN201610007563.2A patent/CN105524530A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001001453A (ja) * | 1999-06-21 | 2001-01-09 | Dainippon Printing Co Ltd | 化粧材 |
JP2008050402A (ja) * | 2006-08-22 | 2008-03-06 | Sumitomo Osaka Cement Co Ltd | 水垢固着防止製品、及びその製造方法 |
CN103333571A (zh) * | 2013-06-24 | 2013-10-02 | 广州慧谷化学有限公司 | 用于热交换器翅片表面处理的水性抗菌防霉亲水涂料 |
CN104629606A (zh) * | 2015-02-05 | 2015-05-20 | 金林墨 | 一种抗菌防水聚氨酯涂料及其制备方法 |
CN104962148A (zh) * | 2015-07-07 | 2015-10-07 | 饶烨 | 一种抗菌阻燃涂料及其制备方法 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107573781A (zh) * | 2017-09-30 | 2018-01-12 | 广东福临门世家智能家居有限公司 | 一种具有分解甲醛功能的节能防晒玻璃纳米涂料 |
CN107760131A (zh) * | 2017-09-30 | 2018-03-06 | 广东福临门世家智能家居有限公司 | 一种节能防晒玻璃纳米涂料 |
CN109666386A (zh) * | 2017-10-14 | 2019-04-23 | 梁秋云 | 一种醇酸树脂复合外墙涂料 |
CN110484086A (zh) * | 2018-05-15 | 2019-11-22 | 淄博华森粘合剂有限公司 | 一种抗菌抑菌改性脲醛树脂及其制备方法 |
CN108727914A (zh) * | 2018-05-23 | 2018-11-02 | 芜湖市创源新材料有限公司 | 一种功能性隔热抗菌淀粉涂料的制备方法 |
CN108864688A (zh) * | 2018-06-05 | 2018-11-23 | 瑞安市吉尔康鞋业有限公司 | 防霉抗菌鞋底用聚氨酯原液及防霉抗菌鞋底的生产工艺 |
CN109162110A (zh) * | 2018-09-25 | 2019-01-08 | 四川大学 | 一种基于光敏反应型增塑剂同步内增塑制造聚氯乙烯人造革的方法 |
CN109162110B (zh) * | 2018-09-25 | 2020-12-08 | 四川大学 | 一种基于光敏反应型增塑剂同步内增塑制造聚氯乙烯人造革的方法 |
CN110354440A (zh) * | 2019-07-02 | 2019-10-22 | 襄阳水木南山装饰工程有限公司 | 一种装修工程中预防和控制甲醛污染的方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105524530A (zh) | 一种热交联型抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 | |
CN102040885B (zh) | 一种油墨组合物及其制备方法和一种不锈钢工件 | |
CN105504926A (zh) | 一种阳离子聚合抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 | |
CN104610806B (zh) | 一种纳米二氧化硅改性的复合型水性油墨及其制备方法 | |
CN104629532B (zh) | 一种纳米二氧化钛改性的复合型水性油墨及其制备方法 | |
CN100455634C (zh) | 环保型无毒含氟卷材涂料 | |
CN103436079A (zh) | 一种环保型网印水性尼龙油墨及其制备方法 | |
CN102167941A (zh) | 一种水性塑料涂装漆 | |
CN101445330B (zh) | 透明防紫外线玻璃涂料 | |
CN101701120A (zh) | 一种纳米氧化锌抗菌抗污涂料及其制备方法 | |
CN101982513A (zh) | 面漆组合物及其制备方法和使用方法 | |
CN105885658B (zh) | 一种含氧化铁颜料的水性单组份汽车漆及其制备方法 | |
CN105349019A (zh) | 双组份水性丙烯酸聚氨酯底面合一防腐装饰漆及其制备方法 | |
CN103555174B (zh) | 一种耐沾污的高速公路护栏涂料的制备方法 | |
CN103740205A (zh) | 一种水性喷漆及其制备方法 | |
CN109456675A (zh) | 一种水性防腐蚀隔热迷彩伪装复合涂层 | |
CN106189567B (zh) | 一种非沥青基高分子防水卷材涂层涂料及其制备方法 | |
CN104449273A (zh) | 一种抗紫外降低涂膜亮度的玻璃门用水性涂料及其制备方法 | |
CN100404631C (zh) | 一种生物纳米水性抗菌清漆及其制备方法 | |
CN114525062A (zh) | 植物基多彩真石漆仿大理石涂料及其制备方法 | |
CN109504266A (zh) | 一种基于生物基聚合物改性的快干无溶剂聚氨酯漆及其制备方法 | |
CN111234630A (zh) | 一种车辆用水性免罩光高光实色漆 | |
CN104356862A (zh) | 一种耐紫外老化的防锈环氧面漆及其制备方法 | |
CN104610808B (zh) | 一种纳米氧化锌改性的复合型水性油墨及其制备方法 | |
CN105542526A (zh) | 一种自由基聚合抗菌、防霉及分解甲醛的纳米涂层材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20171106 Address after: 100010 room 1, unit 4, building 1503, 18 North Hospital, Anhua, Beijing, Dongcheng District Applicant after: Peng Wei Address before: The village of 032000 Shanxi city of Jinzhong province Jiexiu City Yi'an town Applicant before: SHANXI KEQI TECHNOLOGY CO., LTD. |
|
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160427 |